JP5428147B2 - 有機蛍光体材料 - Google Patents
有機蛍光体材料 Download PDFInfo
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- JP5428147B2 JP5428147B2 JP2007294516A JP2007294516A JP5428147B2 JP 5428147 B2 JP5428147 B2 JP 5428147B2 JP 2007294516 A JP2007294516 A JP 2007294516A JP 2007294516 A JP2007294516 A JP 2007294516A JP 5428147 B2 JP5428147 B2 JP 5428147B2
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- substituent
- light
- phosphor
- organic
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 297
- 239000000463 material Substances 0.000 title claims description 133
- 125000001424 substituent group Chemical group 0.000 claims description 302
- 150000001875 compounds Chemical class 0.000 claims description 108
- -1 phosphino group Chemical group 0.000 claims description 49
- 125000000217 alkyl group Chemical group 0.000 claims description 40
- 238000006243 chemical reaction Methods 0.000 claims description 38
- 239000007787 solid Substances 0.000 claims description 38
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 32
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 32
- 125000000623 heterocyclic group Chemical group 0.000 claims description 30
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 29
- 125000001769 aryl amino group Chemical group 0.000 claims description 25
- 125000003342 alkenyl group Chemical group 0.000 claims description 23
- 125000000304 alkynyl group Chemical group 0.000 claims description 23
- 125000003545 alkoxy group Chemical group 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 10
- 125000001153 fluoro group Chemical group F* 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 66
- 229910052712 strontium Inorganic materials 0.000 description 66
- 239000011575 calcium Substances 0.000 description 63
- 229910052788 barium Inorganic materials 0.000 description 61
- 229910052791 calcium Inorganic materials 0.000 description 61
- 239000003153 chemical reaction reagent Substances 0.000 description 60
- 125000004432 carbon atom Chemical group C* 0.000 description 59
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 51
- 229920001296 polysiloxane Polymers 0.000 description 38
- 239000010410 layer Substances 0.000 description 34
- 239000007788 liquid Substances 0.000 description 33
- 230000015572 biosynthetic process Effects 0.000 description 32
- 238000003786 synthesis reaction Methods 0.000 description 31
- 239000011777 magnesium Substances 0.000 description 30
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- 229910052693 Europium Inorganic materials 0.000 description 28
- 229910052749 magnesium Inorganic materials 0.000 description 28
- 229910052757 nitrogen Inorganic materials 0.000 description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 26
- 230000005284 excitation Effects 0.000 description 25
- 238000000034 method Methods 0.000 description 25
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000000295 emission spectrum Methods 0.000 description 23
- 238000005259 measurement Methods 0.000 description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 19
- 229910052710 silicon Inorganic materials 0.000 description 19
- 238000007789 sealing Methods 0.000 description 18
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 18
- 229910052727 yttrium Inorganic materials 0.000 description 18
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 17
- 230000006870 function Effects 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 229910052771 Terbium Inorganic materials 0.000 description 16
- 239000000049 pigment Substances 0.000 description 16
- 238000010521 absorption reaction Methods 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 15
- 238000005481 NMR spectroscopy Methods 0.000 description 14
- 229910052782 aluminium Inorganic materials 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 14
- 239000013078 crystal Substances 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 229910002601 GaN Inorganic materials 0.000 description 13
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 13
- 239000004065 semiconductor Substances 0.000 description 13
- 239000010703 silicon Substances 0.000 description 13
- 239000002210 silicon-based material Substances 0.000 description 13
- 229910052684 Cerium Inorganic materials 0.000 description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 229910004283 SiO 4 Inorganic materials 0.000 description 12
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 239000000758 substrate Substances 0.000 description 12
- 238000010992 reflux Methods 0.000 description 11
- 150000004760 silicates Chemical class 0.000 description 11
- 0 Cc(c(C)c1*)c(*)c(*)c1C#C[Al]C#Cc1c(C)c(*)c(*)c(*)c1C Chemical compound Cc(c(C)c1*)c(*)c(*)c1C#C[Al]C#Cc1c(C)c(*)c(*)c(*)c1C 0.000 description 10
- 150000004645 aluminates Chemical class 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 10
- 238000001723 curing Methods 0.000 description 10
- 125000001624 naphthyl group Chemical group 0.000 description 10
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 238000000746 purification Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 10
- 125000004104 aryloxy group Chemical group 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000005286 illumination Methods 0.000 description 9
- 229910052746 lanthanum Inorganic materials 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 150000003220 pyrenes Chemical class 0.000 description 9
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 229910052688 Gadolinium Inorganic materials 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 8
- 238000009833 condensation Methods 0.000 description 8
- 230000005494 condensation Effects 0.000 description 8
- 230000001771 impaired effect Effects 0.000 description 8
- 239000004973 liquid crystal related substance Substances 0.000 description 8
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 8
- 229910052763 palladium Inorganic materials 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 230000001747 exhibiting effect Effects 0.000 description 7
- 230000010354 integration Effects 0.000 description 7
- 229910052748 manganese Inorganic materials 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- 238000001953 recrystallisation Methods 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 7
- 238000000967 suction filtration Methods 0.000 description 7
- 230000001629 suppression Effects 0.000 description 7
- ZKBKRTZIYOKNRG-UHFFFAOYSA-N 1,3,6,8-tetrabromopyrene Chemical compound C1=C2C(Br)=CC(Br)=C(C=C3)C2=C2C3=C(Br)C=C(Br)C2=C1 ZKBKRTZIYOKNRG-UHFFFAOYSA-N 0.000 description 6
- JRCJYPMNBNNCFE-UHFFFAOYSA-N 1,6-dibromopyrene Chemical compound C1=C2C(Br)=CC=C(C=C3)C2=C2C3=C(Br)C=CC2=C1 JRCJYPMNBNNCFE-UHFFFAOYSA-N 0.000 description 6
- JBLQSCAVCHTKPV-UHFFFAOYSA-N 1,8-dibromopyrene Chemical compound C1=C2C(Br)=CC=C(C=C3)C2=C2C3=CC=C(Br)C2=C1 JBLQSCAVCHTKPV-UHFFFAOYSA-N 0.000 description 6
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 229910052794 bromium Inorganic materials 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 125000004093 cyano group Chemical group *C#N 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 125000005843 halogen group Chemical group 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 150000004767 nitrides Chemical class 0.000 description 6
- 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 description 6
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 6
- 229910020068 MgAl Inorganic materials 0.000 description 5
- 229910052772 Samarium Inorganic materials 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000005859 coupling reaction Methods 0.000 description 5
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 5
- 229910052733 gallium Inorganic materials 0.000 description 5
- 230000003993 interaction Effects 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 238000001782 photodegradation Methods 0.000 description 5
- 230000001443 photoexcitation Effects 0.000 description 5
- 238000001308 synthesis method Methods 0.000 description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- 125000001544 thienyl group Chemical group 0.000 description 5
- 150000003606 tin compounds Chemical class 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- FZUWXBIQCCJYAR-UHFFFAOYSA-N 1,6-bis[4-(trifluoromethyl)phenyl]pyrene Chemical compound C1=CC(C(F)(F)F)=CC=C1C1=CC=C(C=C2)C3=C4C2=C(C=2C=CC(=CC=2)C(F)(F)F)C=CC4=CC=C13 FZUWXBIQCCJYAR-UHFFFAOYSA-N 0.000 description 4
- IGTQPXMEWQTTBJ-UHFFFAOYSA-N 2,7-dibromopyrene Chemical compound C1=C(Br)C=C2C=CC3=CC(Br)=CC4=CC=C1C2=C43 IGTQPXMEWQTTBJ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910017639 MgSi Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 125000004196 benzothienyl group Chemical group S1C(=CC2=C1C=CC=C2)* 0.000 description 4
- 125000006267 biphenyl group Chemical group 0.000 description 4
- 230000005587 bubbling Effects 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
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- 229910010272 inorganic material Inorganic materials 0.000 description 4
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 4
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- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 4
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- 125000005561 phenanthryl group Chemical group 0.000 description 4
- 125000004076 pyridyl group Chemical group 0.000 description 4
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- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 238000000859 sublimation Methods 0.000 description 4
- 230000008022 sublimation Effects 0.000 description 4
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 4
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- SIJHJHYRYHIWFW-UHFFFAOYSA-N 1,3,6,8-tetraphenylpyrene Chemical compound C1=CC=CC=C1C(C1=CC=C23)=CC(C=4C=CC=CC=4)=C(C=C4)C1=C2C4=C(C=1C=CC=CC=1)C=C3C1=CC=CC=C1 SIJHJHYRYHIWFW-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229910052765 Lutetium Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- VKIJXFIYBAYHOE-VOTSOKGWSA-N [(e)-2-phenylethenyl]boronic acid Chemical compound OB(O)\C=C\C1=CC=CC=C1 VKIJXFIYBAYHOE-VOTSOKGWSA-N 0.000 description 3
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 3
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
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- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 3
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- 125000005620 boronic acid group Chemical class 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 3
- 229910000024 caesium carbonate Inorganic materials 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
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- 239000012043 crude product Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 125000004987 dibenzofuryl group Chemical group C1(=CC=CC=2OC3=C(C21)C=CC=C3)* 0.000 description 3
- 125000004988 dibenzothienyl group Chemical group C1(=CC=CC=2SC3=C(C21)C=CC=C3)* 0.000 description 3
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- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 3
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
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- WCPAKWJPBJAGKN-UHFFFAOYSA-N oxadiazole Chemical group C1=CON=N1 WCPAKWJPBJAGKN-UHFFFAOYSA-N 0.000 description 3
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- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 3
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
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- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 3
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical class [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 3
- YWKONAIFFYXFIU-UHFFFAOYSA-N 1,3,6,8-tetrakis[4-(trifluoromethyl)phenyl]pyrene Chemical compound C1=CC(C(F)(F)F)=CC=C1C(C1=CC=C23)=CC(C=4C=CC(=CC=4)C(F)(F)F)=C(C=C4)C1=C2C4=C(C=1C=CC(=CC=1)C(F)(F)F)C=C3C1=CC=C(C(F)(F)F)C=C1 YWKONAIFFYXFIU-UHFFFAOYSA-N 0.000 description 2
- QKLPIYTUUFFRLV-YTEMWHBBSA-N 1,4-bis[(e)-2-(2-methylphenyl)ethenyl]benzene Chemical compound CC1=CC=CC=C1\C=C\C(C=C1)=CC=C1\C=C\C1=CC=CC=C1C QKLPIYTUUFFRLV-YTEMWHBBSA-N 0.000 description 2
- DLCSQWPISJODNM-UHFFFAOYSA-N 1,4-dimethyl-2,5-bis(2-phenylethenyl)benzene Chemical compound CC=1C=C(C=CC=2C=CC=CC=2)C(C)=CC=1C=CC1=CC=CC=C1 DLCSQWPISJODNM-UHFFFAOYSA-N 0.000 description 2
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 2
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/49—Structure, shape, material or disposition of the wire connectors after the connecting process of a plurality of wire connectors
- H01L2224/491—Disposition
- H01L2224/49105—Connecting at different heights
- H01L2224/49107—Connecting at different heights on the semiconductor or solid-state body
Landscapes
- Electroluminescent Light Sources (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Led Device Packages (AREA)
- Led Devices (AREA)
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KR100974562B1 (ko) * | 2007-12-31 | 2010-08-06 | 다우어드밴스드디스플레이머티리얼 유한회사 | 신규한 유기 발광 화합물 및 이를 발광재료로서 채용하고있는 유기 발광 소자 |
JP5805361B2 (ja) * | 2009-03-24 | 2015-11-04 | 林テレンプ株式会社 | 発光性材料および発光素子の作成方法 |
EP2442621A4 (en) * | 2009-06-11 | 2013-10-09 | Sharp Kk | ORGANIC EL DISPLAY DEVICE AND MANUFACTURING METHOD THEREFOR |
WO2011077690A1 (ja) | 2009-12-21 | 2011-06-30 | 出光興産株式会社 | ピレン誘導体及びそれを用いた有機エレクトロルミネッセンス素子 |
BR112012022991A8 (pt) * | 2010-03-16 | 2018-04-03 | Koninklijke Philips Electronics Nv | Aparelho de iluminação, método de fabricação para fabricar um aparelho de iluminação e método de iluminação |
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TW201213502A (en) | 2010-08-05 | 2012-04-01 | Idemitsu Kosan Co | Organic electroluminescent element |
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WO2006069028A2 (en) * | 2004-12-20 | 2006-06-29 | Performance Indicator L.L.C. | High-intensity, persistent photoluminescent formulations and objects, and methods for creating the same |
KR20080031872A (ko) * | 2005-06-24 | 2008-04-11 | 이데미쓰 고산 가부시키가이샤 | 벤조싸이오펜 유도체 및 그것을 이용한 유기 전기발광 소자 |
JP2007077185A (ja) * | 2005-09-12 | 2007-03-29 | Toray Ind Inc | ピレン化合物を用いた発光素子材料および発光素子 |
JP2007088299A (ja) * | 2005-09-22 | 2007-04-05 | Mitsubishi Chemicals Corp | 発光装置並びにそれを用いた照明装置及び画像表示装置 |
JP5093879B2 (ja) * | 2006-03-20 | 2012-12-12 | 国立大学法人京都大学 | ピレン系有機化合物、トランジスタ材料及び発光トランジスタ素子 |
US8729530B2 (en) * | 2006-06-15 | 2014-05-20 | Toray Industries, Inc. | Material for light-emitting device and light-emitting device |
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