JP5414268B2 - リン量を減じた潤滑油組成物 - Google Patents
リン量を減じた潤滑油組成物 Download PDFInfo
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- JP5414268B2 JP5414268B2 JP2008504340A JP2008504340A JP5414268B2 JP 5414268 B2 JP5414268 B2 JP 5414268B2 JP 2008504340 A JP2008504340 A JP 2008504340A JP 2008504340 A JP2008504340 A JP 2008504340A JP 5414268 B2 JP5414268 B2 JP 5414268B2
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- 239000000203 mixture Substances 0.000 title claims description 87
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 49
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 49
- 239000011574 phosphorus Substances 0.000 title claims description 49
- 239000010687 lubricating oil Substances 0.000 title description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 38
- 239000011733 molybdenum Substances 0.000 claims description 38
- 239000011701 zinc Substances 0.000 claims description 37
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 36
- 229910052725 zinc Inorganic materials 0.000 claims description 36
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 33
- 239000002270 dispersing agent Substances 0.000 claims description 33
- 239000003599 detergent Substances 0.000 claims description 32
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 claims description 31
- 239000003963 antioxidant agent Substances 0.000 claims description 30
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 29
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- 230000001050 lubricating effect Effects 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 27
- 230000003078 antioxidant effect Effects 0.000 claims description 24
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 16
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- 229910052717 sulfur Inorganic materials 0.000 description 11
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 10
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid group Chemical group C(CCC(=O)O)(=O)O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 4
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- 239000004215 Carbon black (E152) Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
- 239000004034 viscosity adjusting agent Substances 0.000 description 4
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 description 3
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 3
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
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- 150000003333 secondary alcohols Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
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- CIRMGZKUSBCWRL-LHLOQNFPSA-N (e)-10-[2-(7-carboxyheptyl)-5,6-dihexylcyclohex-3-en-1-yl]dec-9-enoic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(O)=O)C(\C=C\CCCCCCCC(O)=O)C1CCCCCC CIRMGZKUSBCWRL-LHLOQNFPSA-N 0.000 description 2
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- GJKZJNZHHXWKCH-UHFFFAOYSA-N 1-[4-(4-chlorophenyl)-1-[3-(4-methylpiperazin-1-yl)propyl]piperidin-3-yl]ethanone;trihydrochloride Chemical compound Cl.Cl.Cl.C1CN(C)CCN1CCCN1CC(C(C)=O)C(C=2C=CC(Cl)=CC=2)CC1 GJKZJNZHHXWKCH-UHFFFAOYSA-N 0.000 description 2
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- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- ZGVUVKPXCJTREX-UHFFFAOYSA-N 2,6-ditert-butyl-4-(8-methylnonyl)phenol Chemical compound CC(C)CCCCCCCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 ZGVUVKPXCJTREX-UHFFFAOYSA-N 0.000 description 2
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 2
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
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- BOZYIBXVLKRBHX-UHFFFAOYSA-N 2,6-ditert-butyl-4-(5-methylhexyl)phenol Chemical compound CC(C)CCCCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BOZYIBXVLKRBHX-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C—CHEMISTRY; METALLURGY
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- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2030/50—Emission or smoke controlling properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (3)
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| US66596105P | 2005-03-29 | 2005-03-29 | |
| US60/665,961 | 2005-03-29 | ||
| PCT/US2006/011598 WO2006105267A1 (en) | 2005-03-29 | 2006-03-27 | Lubricating oil composition with reduced phosphorus levels |
Publications (3)
| Publication Number | Publication Date |
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| JP2008535965A JP2008535965A (ja) | 2008-09-04 |
| JP2008535965A5 JP2008535965A5 (enExample) | 2009-03-26 |
| JP5414268B2 true JP5414268B2 (ja) | 2014-02-12 |
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| JP5078116B2 (ja) * | 2006-10-20 | 2012-11-21 | Jx日鉱日石エネルギー株式会社 | 長寿命省燃費型エンジン油組成物 |
| US20080202561A1 (en) * | 2007-02-22 | 2008-08-28 | Dumont Richard J | Methods and Compositions for Reducing Deposits In Engines Combusting Alcohol-Containing Fuels |
| US20080216393A1 (en) * | 2007-03-08 | 2008-09-11 | Dumont Richard J | Methods and compositions for reducing corrosion and increasing engine durability in engines combusting alcohol-containing fuels |
| JP2009024123A (ja) * | 2007-07-23 | 2009-02-05 | Showa Shell Sekiyu Kk | バイオ燃料対応ディーゼルエンジン用潤滑油組成物。 |
| US7897552B2 (en) * | 2007-11-30 | 2011-03-01 | Afton Chemical Corporation | Additives and lubricant formulations for improved antioxidant properties |
| US20090163392A1 (en) * | 2007-12-20 | 2009-06-25 | Boffa Alexander B | Lubricating oil compositions comprising a molybdenum compound and a zinc dialkyldithiophosphate |
| US8748357B2 (en) * | 2008-07-15 | 2014-06-10 | Exxonmobil Research And Engineering Company | Method for stabilizing diesel engine lubricating oil against degradation by biodiesel fuel |
| US20100056407A1 (en) * | 2008-08-28 | 2010-03-04 | Afton Chemical Corporation | Lubricant formulations and methods of lubricating a combustion system to achieve improved emmisions catalyst durability |
| ATE551415T1 (de) * | 2008-09-05 | 2012-04-15 | Infineum Int Ltd | Schmierölzusammensetzung |
| KR101790369B1 (ko) | 2010-03-25 | 2017-10-26 | 반더빌트 케미칼스, 엘엘씨 | 초저함량 인 윤활유 조성물 |
| JP6226967B2 (ja) * | 2012-06-06 | 2017-11-08 | ヴァンダービルト ケミカルズ、エルエルシー | 燃費効率がよい潤滑油 |
| US20140020645A1 (en) * | 2012-07-18 | 2014-01-23 | Afton Chemical Corporation | Lubricant compositions for direct injection engines |
| US10113132B2 (en) | 2012-11-19 | 2018-10-30 | The Lubrizol Corporation | Coupled phenols for use in biodiesel engines |
| US10563145B2 (en) * | 2016-09-20 | 2020-02-18 | Lanxess Solutions Us Inc. | Alkylated 3-hydroxydiphenylamine antioxidants |
| RU2630959C1 (ru) * | 2016-12-12 | 2017-09-15 | федеральное государственное автономное образовательное учреждение высшего образования "Южный федеральный университет" | Смазочная композиция |
| EP3585871A1 (en) | 2017-02-21 | 2020-01-01 | Exxonmobil Research And Engineering Company | Lubricating oil compositions and methods of use thereof |
| US11807827B2 (en) * | 2022-01-18 | 2023-11-07 | Afton Chemical Corporation | Lubricating compositions for reduced high temperature deposits |
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| US3211652A (en) * | 1962-12-03 | 1965-10-12 | Ethyl Corp | Phenolic compositions |
| US5523007A (en) * | 1987-07-01 | 1996-06-04 | Ciba-Geigy Corporation | Stabilized diesel engine oil |
| EP0456925B1 (en) * | 1990-05-14 | 1993-10-20 | Ethyl Petroleum Additives Limited | Antioxidant compositions |
| IL107927A0 (en) * | 1992-12-17 | 1994-04-12 | Exxon Chemical Patents Inc | Oil soluble ethylene/1-butene copolymers and lubricating oils containing the same |
| JPH07258671A (ja) * | 1994-03-24 | 1995-10-09 | Lubrizol Corp:The | 無灰の低リン潤滑剤 |
| EP0725129B1 (en) * | 1995-02-01 | 2001-12-12 | The Lubrizol Corporation | Low ash lubricant compositions |
| US5744430A (en) * | 1995-04-28 | 1998-04-28 | Nippon Oil Co., Ltd. | Engine oil composition |
| JP3719266B2 (ja) * | 1995-10-18 | 2005-11-24 | エクソンモービル・ケミカル・パテンツ・インク | 摩擦耐久性が改良された潤滑油 |
| US5650381A (en) * | 1995-11-20 | 1997-07-22 | Ethyl Corporation | Lubricant containing molybdenum compound and secondary diarylamine |
| US5840672A (en) * | 1997-07-17 | 1998-11-24 | Ethyl Corporation | Antioxidant system for lubrication base oils |
| JPH11106776A (ja) * | 1997-10-01 | 1999-04-20 | Oronite Japan Ltd | 潤滑油組成物 |
| US6569818B2 (en) * | 2000-06-02 | 2003-05-27 | Chevron Oronite Company, Llc | Lubricating oil composition |
| JP3722484B2 (ja) * | 2000-06-02 | 2005-11-30 | シェブロンテキサコジャパン株式会社 | 潤滑油組成物 |
| US6408812B1 (en) | 2000-09-19 | 2002-06-25 | The Lubrizol Corporation | Method of operating spark-ignition four-stroke internal combustion engine |
| CA2372755C (en) * | 2001-03-23 | 2011-11-29 | Ethyl Corporation | Hindered phenolic antioxidant compositions |
| US6500786B1 (en) * | 2001-11-26 | 2002-12-31 | Infineum International Ltd. | Lubricating oil composition |
| JP4202636B2 (ja) * | 2001-11-30 | 2008-12-24 | シェブロンジャパン株式会社 | 自動車エンジン用潤滑油組成物 |
| US6730638B2 (en) * | 2002-01-31 | 2004-05-04 | Exxonmobil Research And Engineering Company | Low ash, low phosphorus and low sulfur engine oils for internal combustion engines |
| US6645921B2 (en) * | 2002-02-08 | 2003-11-11 | Ethyl Corporation | Molybdenum-containing lubricant additive compositions, and processes for making and using same |
| AU2003257537A1 (en) * | 2002-08-27 | 2004-03-19 | Nippon Oil Corporation | Lubricating composition |
| US7285516B2 (en) * | 2002-11-25 | 2007-10-23 | The Lubrizol Corporation | Additive formulation for lubricating oils |
| US20040235682A1 (en) * | 2003-05-22 | 2004-11-25 | Chevron Oronite Company Llc | Low emission diesel lubricant with improved corrosion protection |
| JP4955366B2 (ja) * | 2006-10-30 | 2012-06-20 | 株式会社Adeka | リンモリブデン化合物、その製造方法、該化合物を含有する潤滑油添加剤及び潤滑油組成物 |
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- 2006-03-27 KR KR1020077022307A patent/KR101550034B1/ko not_active Expired - Fee Related
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- 2006-03-27 EP EP06740027A patent/EP1871860A1/en not_active Withdrawn
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- 2006-03-27 RU RU2007139717/04A patent/RU2007139717A/ru unknown
Also Published As
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| CN101180385B (zh) | 2012-10-10 |
| CN101180385A (zh) | 2008-05-14 |
| US20060223724A1 (en) | 2006-10-05 |
| EP1871860A1 (en) | 2008-01-02 |
| KR101552612B1 (ko) | 2015-09-11 |
| RU2007139717A (ru) | 2009-05-10 |
| KR101550034B1 (ko) | 2015-09-04 |
| CA2602427A1 (en) | 2006-10-05 |
| JP2008535965A (ja) | 2008-09-04 |
| KR20070116049A (ko) | 2007-12-06 |
| WO2006105267A1 (en) | 2006-10-05 |
| CA2602427C (en) | 2014-03-25 |
| KR20140111027A (ko) | 2014-09-17 |
| BRPI0610408A2 (pt) | 2010-06-22 |
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