JP5401094B2 - 熱可塑性エラストマーを生成するための動的加硫方法 - Google Patents

熱可塑性エラストマーを生成するための動的加硫方法 Download PDF

Info

Publication number
JP5401094B2
JP5401094B2 JP2008519275A JP2008519275A JP5401094B2 JP 5401094 B2 JP5401094 B2 JP 5401094B2 JP 2008519275 A JP2008519275 A JP 2008519275A JP 2008519275 A JP2008519275 A JP 2008519275A JP 5401094 B2 JP5401094 B2 JP 5401094B2
Authority
JP
Japan
Prior art keywords
thermoplastic
elastomer
thermoplastic polymer
oil
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2008519275A
Other languages
English (en)
Japanese (ja)
Other versions
JP2008544076A (ja
JP2008544076A5 (https=
Inventor
ナデラ、ハリー・プラサド
デ・ヤング、ロナルド
チェング、ジアンヤ
Original Assignee
アドバンスド エラストマー システムズ，エル．ピー．
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/167,339 external-priority patent/US7655728B2/en
Application filed by アドバンスド エラストマー システムズ，エル．ピー． filed Critical アドバンスド エラストマー システムズ，エル．ピー．
Publication of JP2008544076A publication Critical patent/JP2008544076A/ja
Publication of JP2008544076A5 publication Critical patent/JP2008544076A5/ja
Application granted granted Critical
Publication of JP5401094B2 publication Critical patent/JP5401094B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
JP2008519275A 2005-06-27 2006-04-24 熱可塑性エラストマーを生成するための動的加硫方法 Expired - Fee Related JP5401094B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US11/167,339 2005-06-27
US11/167,339 US7655728B2 (en) 2005-06-27 2005-06-27 Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders
US11/375,737 US8653170B2 (en) 2005-06-27 2006-03-15 Dynamic vulcanization process for preparing thermoplastic elastomers
US11/375,737 2006-03-15
PCT/US2006/015240 WO2007001601A1 (en) 2005-06-27 2006-04-24 Dynamic vulcanization process for preparing thermoplastic elastomers

Publications (3)

Publication Number Publication Date
JP2008544076A JP2008544076A (ja) 2008-12-04
JP2008544076A5 JP2008544076A5 (https=) 2011-07-14
JP5401094B2 true JP5401094B2 (ja) 2014-01-29

Family

ID=36763818

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008519275A Expired - Fee Related JP5401094B2 (ja) 2005-06-27 2006-04-24 熱可塑性エラストマーを生成するための動的加硫方法

Country Status (4)

Country Link
US (1) US8653170B2 (https=)
EP (1) EP1896540B1 (https=)
JP (1) JP5401094B2 (https=)
WO (1) WO2007001601A1 (https=)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7625980B2 (en) * 2006-07-11 2009-12-01 Exxonmobil Chemical Patents Inc. Method for improving extrusion surface smoothness in thermoplastic vulcanizates
US8557393B2 (en) * 2006-10-31 2013-10-15 Exxonmobil Chemical Patents Inc. Adhesive thermoplastic vulcanizates
US7951871B2 (en) 2006-11-10 2011-05-31 Exxonmobil Chemical Patents Inc. Curing rubber by hydrosilation
WO2008134173A1 (en) * 2007-05-01 2008-11-06 Advanced Elastomer Systems, L.P. Method for preparing thermoplastic vulcanizates
US7803875B2 (en) * 2007-06-27 2010-09-28 Exxonmobil Chemical Patents Inc. Curing of rubbers and thermoplastic vulcanizates in the absence of halogen donors
US8158721B2 (en) * 2008-06-13 2012-04-17 Exxonmobil Chemical Patents Inc. Process for preparing dynamically vulcanized alloys
US20090309252A1 (en) * 2008-06-17 2009-12-17 Century, Inc. Method of controlling evaporation of a fluid in an article
US7793703B2 (en) * 2008-06-17 2010-09-14 Century Inc. Method of manufacturing a metal matrix composite
US8877867B2 (en) * 2008-11-06 2014-11-04 Exxonmobil Chemical Patents Inc. Process for forming thermoplastic vulcanizates and extruded articles therefrom
US8247494B2 (en) 2009-11-23 2012-08-21 Exxonmobil Chemical Patents Inc. Thermoset compositions with dispersed thermoplastic resin therein and process for making them
IT1396617B1 (it) 2009-11-25 2012-12-14 Pirelli Metodo per controllare selettivamente la capacita' auto-sigillante di un pneumatico e pneumatico auto-sigillante per ruote di veicoli
US9283734B2 (en) 2010-05-28 2016-03-15 Gunite Corporation Manufacturing apparatus and method of forming a preform
FR2963624B1 (fr) * 2010-08-04 2014-02-21 Hutchinson Procede de preparation d'une composition thermoplastique renforcee et reactive, cette composition et son utilisation
US20150065625A1 (en) * 2011-03-11 2015-03-05 Exxonmobil Chemical Patents Inc. Method of Forming Dynamically Vulcanized Thermoplastic Elastomer Films and Films Formed Therefrom
US20130041090A1 (en) * 2011-06-14 2013-02-14 Sumitomo Chemical Company, Limited Method for producing thermoplastic elastomer composition
EP2935409B1 (en) 2012-12-20 2023-12-20 ExxonMobil Chemical Patents Inc. Process for preparing dynamically vulcanized alloys
US10240008B2 (en) * 2014-05-12 2019-03-26 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and method of making the same
SG11201609150RA (en) * 2014-07-01 2016-12-29 Halliburton Energy Services Inc Improved high temperature mechanical properties of elastomers with semi-crystalline polymers for downhole applications
EP3209724B1 (en) 2014-10-24 2022-08-17 ExxonMobil Chemical Patents Inc. Thermoplastic vulcanizate compositions
CN104513434B (zh) * 2014-11-27 2017-02-01 北京化工大学 一种丁基橡胶/长碳链聚酰胺热塑性硫化胶及其制备方法
CN107429019B (zh) * 2015-04-02 2020-09-25 埃克森美孚化学专利公司 制备热塑性硫化橡胶材料的方法及其制备的热塑性硫化橡胶材料
WO2016190981A1 (en) * 2015-05-22 2016-12-01 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates comprising propylene-based elastomers and methods for making the same
CN105330952A (zh) * 2015-11-18 2016-02-17 安徽雄亚塑胶科技有限公司 一种汽车线束热缩套管料用tpv
MX2018006256A (es) 2015-11-25 2018-09-07 Gen Cable Technologies Corp Reticulacion por hidrosililacion de componentes de cable de poliolefina.
JP6869333B2 (ja) 2016-09-02 2021-05-12 株式会社ブリヂストン ポリマーセメントのその場ヒドロシリル化により調製される複数のシラン官能基を有するシス−１，４−ポリジエンの製造
JP7033843B2 (ja) * 2016-10-12 2022-03-11 株式会社Adeka ポリオレフィン系樹脂組成物およびこれを用いた成形品
WO2018108228A1 (de) 2016-12-13 2018-06-21 Actega Ds Gmbh Thermoplastische vulkanisate
CN114846074A (zh) 2019-10-22 2022-08-02 国际人造丝公司 热塑性硫化橡胶组合物及其生产工艺
WO2023076448A1 (en) * 2021-10-29 2023-05-04 Celanese International Corporation Extruder systems and processes thereof
CN113980477B (zh) * 2021-11-15 2023-01-10 中国人民解放军66350部队 一种高压闭气膜材料及其制备方法

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2631727A (en) * 1949-12-27 1953-03-17 Gulf Research Development Co Adsorption process and apparatus
US2765282A (en) * 1952-03-18 1956-10-02 Socony Mobil Oil Co Inc Method for the regeneration of adsorbent contact material
US2859170A (en) * 1955-03-09 1958-11-04 Texas Co Method of treating hydrocarbons
US4130535A (en) * 1975-07-21 1978-12-19 Monsanto Company Thermoplastic vulcanizates of olefin rubber and polyolefin resin
DE2726962C2 (de) * 1977-06-15 1982-09-02 Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover Vorrichtung zum Aufbereiten und Strangpressen von plastischen Massen, insbesondere Kunststoff oder Kautschuk
US4311628A (en) * 1977-11-09 1982-01-19 Monsanto Company Thermoplastic elastomeric blends of olefin rubber and polyolefin resin
JPS5825340A (ja) 1981-08-07 1983-02-15 Mitsui Petrochem Ind Ltd 部分架橋ゴム−樹脂組成物の製造法
US4594390A (en) * 1982-08-23 1986-06-10 Monsanto Company Process for the preparation of thermoplastic elastomers
US4480074A (en) 1982-10-20 1984-10-30 Monsanto Company Process for preparing elastoplastic compositions
US4594391A (en) * 1984-05-21 1986-06-10 The Dow Chemical Company Impact-modified monovinylidene aromatic polymer injection molding resins
DE3541414A1 (de) 1985-11-23 1987-05-27 Zimmermann Azo Maschf Verfahren und vorrichtung zum regenerieren von rieselfaehigen adsorbentien waehrend des adsorptionsprozesses
CA1333308C (en) 1987-07-08 1994-11-29 Tadashi Hikasa Olefinic thermoplastic elastomer composition
JPH07103274B2 (ja) * 1987-07-08 1995-11-08 住友化学工業株式会社 オレフィン系熱可塑性エラストマー組成物
IT1223262B (it) 1987-12-11 1990-09-19 Himont Inc Composizioni elasto plastiche e procedimento per la loro preparazione
US4940830A (en) * 1988-09-26 1990-07-10 Uop Rejective separation of para-xylene from xylene isomers and ethylbenzene with zeolites
JP2798303B2 (ja) * 1989-07-10 1998-09-17 三井化学株式会社 熱可塑性エラストマー組成物の製造方法および熱可塑性エラストマー組成物
WO1991000890A1 (en) 1989-07-10 1991-01-24 Mitsui Petrochemical Industries, Ltd. Method of producing thermoplastic elastomer composition and thermoplastic elastomer composition produced thereby
DE4001986C1 (https=) * 1990-01-24 1991-09-19 Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover, De
JP2837741B2 (ja) * 1990-06-12 1998-12-16 アドバンスド・エラストマー・システムズ・エルピー 熱可塑性エラストマー組成物
US5349005A (en) * 1990-06-12 1994-09-20 Advanced Elastomer Systems, L.P. Thermoplastic elastomer composition
JP3027429B2 (ja) 1991-02-12 2000-04-04 昭和電工株式会社 熱可塑性エラストマーの製造法
US5158725A (en) * 1991-04-29 1992-10-27 The Goodyear Tire & Rubber Company Continuous mixing of elastomeric compounds
JP3031022B2 (ja) 1991-12-19 2000-04-10 住友化学工業株式会社 熱可塑性エラストマー組成物の製造方法
EP0757077A1 (en) * 1995-08-01 1997-02-05 Advanced Elastomer Systems, L.P. Very soft thermoplastic elastomer compositions
DE19536289C2 (de) * 1995-09-29 1999-01-07 Krupp Werner & Pfleiderer Gmbh Verfahren zur Durchführung von kontinuierlichen Aufbereitungsprozessen mit gleichsinnig drehenden, dicht kämmenden Doppelschneckenextrudern
US6150464A (en) * 1995-12-01 2000-11-21 Advanced Elastomer Systems, L.P. Preferred process for silicon hydride addition and preferred degree of polymerization for silicon hydride for thermoplastic vulcanizates
US5672660A (en) * 1995-12-01 1997-09-30 Advanced Elastomer Systems, L.P. Hydrosilylation crosslinking
WO1997039059A1 (en) 1996-04-12 1997-10-23 Dsm N.V. Thermoplastic elastomer
CN1176877A (zh) * 1997-09-03 1998-03-25 青岛化工学院 挤出机螺旋啮合喂料方法
JP3704948B2 (ja) * 1997-09-30 2005-10-12 三井化学株式会社 熱可塑性エラストマーおよび製造方法
US6210030B1 (en) * 1999-06-15 2001-04-03 Jean-Pierre Ibar Method and apparatus to control viscosity of molten plastics prior to a molding operation
US6437030B1 (en) * 2000-05-24 2002-08-20 Advanced Elastomer Systems, L.P. Thermoplastic vulcanizates and process for making the same
DE10050295A1 (de) * 2000-10-10 2002-04-11 Buehler Ag Mehrwellen-Extruder und Verfahren zur Aufbereitung und/oder Vorarbeitung von mit Füllstoff versetzten Elastomeren
DE10055772A1 (de) * 2000-11-10 2002-05-29 Buehler Ag Ring-Extruder-Einzug
JP3575426B2 (ja) 2000-12-28 2004-10-13 Ｊｓｒ株式会社 熱可塑性エラストマー組成物及びその製造方法
US6451915B1 (en) * 2000-12-29 2002-09-17 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved processing and physical property balance
DE10122462C1 (de) * 2001-05-09 2002-10-10 3 & Extruder Gmbh Vorrichtung mit Schnecken zum Homogenisieren und/oder Dispergieren eines viskosen Stoffes und eines Feststoffes und/oder eines anderen Stoffes unterschiedlicher Viskosität
DE50208613D1 (de) * 2001-09-14 2006-12-14 Buehler Ag Verfahren und vorrichtung zur herstellung von elastomermischungen für die gummiherstellung
WO2003031150A1 (en) 2001-10-11 2003-04-17 Dsm Ip Assets B.V. Process for the preparation of a dynamically vulcanized thermoplastic elastomer
US6646056B2 (en) * 2001-10-16 2003-11-11 Solvay Engineered Polymers Thermoplastic elastomer compositions
US20030144415A1 (en) * 2002-01-29 2003-07-31 Dsm N.V. Process for the preparation of a thermoplastic elastomer comprising a partially vulcanized rubber concentrate
DE10233214B4 (de) 2002-07-22 2005-01-27 3+Extruder Gmbh Extruder zum kontinuierlichen Bearbeiten und/oder Verarbeiten von fließfähigen Materialien
US6890990B2 (en) * 2003-05-30 2005-05-10 Solvay Engineered Polymers, Inc. Co-agents for the preparation of thermoplastic elastomeric blends of rubber and polyolefins
US7737205B2 (en) * 2003-07-28 2010-06-15 Dow Global Technologies Inc Thermoplastic vulcanizates and process to prepare them
KR101059056B1 (ko) 2003-07-29 2011-08-24 테크너 아펙스 컴퍼니 중합체 조성물
EP1664189B1 (en) * 2003-09-17 2009-11-18 ExxonMobil Chemical Patents Inc. Improved thermoplastic vulcanizates and processes for making the same
US7622528B2 (en) * 2005-06-27 2009-11-24 Exxonmobil Chemical Patents Inc. Process for preparing thermoplastic elastomers by dynamic vulcanization

Also Published As

Publication number Publication date
JP2008544076A (ja) 2008-12-04
WO2007001601A1 (en) 2007-01-04
EP1896540B1 (en) 2016-08-10
EP1896540A1 (en) 2008-03-12
US8653170B2 (en) 2014-02-18
US20060293454A1 (en) 2006-12-28

Similar Documents

Publication Publication Date Title
JP5401094B2 (ja) 熱可塑性エラストマーを生成するための動的加硫方法
JP5002593B2 (ja) 多軸スクリュー押出機における動的加硫による熱可塑性エラストマーの生成方法
US7622528B2 (en) Process for preparing thermoplastic elastomers by dynamic vulcanization
US9296885B2 (en) Thermoplastic vulcanizates and processes for making the same
JP5216182B2 (ja) 熱可塑性エラストマーの製造方法
US20110028637A1 (en) Method for Preparing Thermoplastic Vulcanizates
JP2005068430A (ja) 熱可塑性エラストマー組成物及びその製造方法
EP1940945B1 (en) Peroxide-cured thermoplastic vulcanizates and process for making the same
JP2001524563A (ja) エチレンの熱可塑性ランダムコポリマーによる熱可塑性加硫ゴムの改良
US10240008B2 (en) Thermoplastic vulcanizates and method of making the same
WO2008008129A1 (en) Method for improving extrusion surface smoothness in thermoplastic vulcanizates
JP3575426B2 (ja) 熱可塑性エラストマー組成物及びその製造方法
WO2007067245A1 (en) Method for preparing thermoplastic vulcanizates with improved extrusion surfaces

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110215

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110222

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110523

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20110523

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120214

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120511

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20130226

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130626

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20130704

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20131001

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20131028

R150 Certificate of patent or registration of utility model

Ref document number: 5401094

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees