JP5390161B2 - 光電池用途のための反射防止コーティング - Google Patents
光電池用途のための反射防止コーティング Download PDFInfo
- Publication number
- JP5390161B2 JP5390161B2 JP2008265781A JP2008265781A JP5390161B2 JP 5390161 B2 JP5390161 B2 JP 5390161B2 JP 2008265781 A JP2008265781 A JP 2008265781A JP 2008265781 A JP2008265781 A JP 2008265781A JP 5390161 B2 JP5390161 B2 JP 5390161B2
- Authority
- JP
- Japan
- Prior art keywords
- cyclic
- polyunsaturated
- branched
- saturated
- mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006117 anti-reflective coating Substances 0.000 title claims description 41
- 239000000758 substrate Substances 0.000 claims description 73
- 229930195733 hydrocarbon Natural products 0.000 claims description 64
- 125000004122 cyclic group Chemical group 0.000 claims description 59
- 150000002430 hydrocarbons Chemical class 0.000 claims description 58
- 229920006395 saturated elastomer Polymers 0.000 claims description 42
- 239000004215 Carbon black (E152) Substances 0.000 claims description 38
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 33
- 229910052710 silicon Inorganic materials 0.000 claims description 33
- 239000010703 silicon Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 28
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 23
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- -1 acyclic alkylsilane Chemical class 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 7
- 125000003277 amino group Chemical group 0.000 claims description 5
- MEBONNVPKOBPEA-UHFFFAOYSA-N 1,1,2-trimethylcyclohexane Chemical compound CC1CCCCC1(C)C MEBONNVPKOBPEA-UHFFFAOYSA-N 0.000 claims description 4
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 claims description 4
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims description 4
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 4
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 claims description 4
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 claims description 2
- RYOGZVTWMZNTGL-UDRCNDPASA-N (1z,5z)-1,5-dimethylcycloocta-1,5-diene Chemical compound C\C1=C\CC\C(C)=C/CC1 RYOGZVTWMZNTGL-UDRCNDPASA-N 0.000 claims description 2
- TXNWMICHNKMOBR-UHFFFAOYSA-N 1,2-dimethylcyclohexene Chemical compound CC1=C(C)CCCC1 TXNWMICHNKMOBR-UHFFFAOYSA-N 0.000 claims description 2
- SDRZFSPCVYEJTP-UHFFFAOYSA-N 1-ethenylcyclohexene Chemical compound C=CC1=CCCCC1 SDRZFSPCVYEJTP-UHFFFAOYSA-N 0.000 claims description 2
- GQBKAYONUCKYKT-UHFFFAOYSA-N 1-tert-butylcyclohexene Chemical compound CC(C)(C)C1=CCCCC1 GQBKAYONUCKYKT-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 claims description 2
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002619 bicyclic group Chemical group 0.000 claims description 2
- 229930006739 camphene Natural products 0.000 claims description 2
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims description 2
- ZXIJMRYMVAMXQP-UHFFFAOYSA-N cycloheptene Chemical compound C1CCC=CCC1 ZXIJMRYMVAMXQP-UHFFFAOYSA-N 0.000 claims description 2
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004914 cyclooctane Substances 0.000 claims description 2
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 claims description 2
- 239000004913 cyclooctene Substances 0.000 claims description 2
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 claims description 2
- POCNHGFJLGYFIK-UHFFFAOYSA-N methylcyclooctane Chemical compound CC1CCCCCCC1 POCNHGFJLGYFIK-UHFFFAOYSA-N 0.000 claims description 2
- VYIRVGYSUZPNLF-UHFFFAOYSA-N n-(tert-butylamino)silyl-2-methylpropan-2-amine Chemical compound CC(C)(C)N[SiH2]NC(C)(C)C VYIRVGYSUZPNLF-UHFFFAOYSA-N 0.000 claims description 2
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims description 2
- UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 claims description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 claims description 2
- 229930004008 p-menthane Natural products 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- PHICBFWUYUCFKS-UHFFFAOYSA-N spiro[4.4]nonane Chemical compound C1CCCC21CCCC2 PHICBFWUYUCFKS-UHFFFAOYSA-N 0.000 claims description 2
- 239000002019 doping agent Substances 0.000 description 26
- 239000002243 precursor Substances 0.000 description 26
- 239000010408 film Substances 0.000 description 24
- 235000012431 wafers Nutrition 0.000 description 21
- 239000000463 material Substances 0.000 description 20
- 239000006096 absorbing agent Substances 0.000 description 16
- 125000004429 atom Chemical group 0.000 description 14
- 150000001282 organosilanes Chemical class 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000005530 etching Methods 0.000 description 11
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- 238000000151 deposition Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 230000031700 light absorption Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 6
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 229910018540 Si C Inorganic materials 0.000 description 3
- 230000003667 anti-reflective effect Effects 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 238000002161 passivation Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- PHUNDLUSWHZQPF-UHFFFAOYSA-N bis(tert-butylamino)silicon Chemical compound CC(C)(C)N[Si]NC(C)(C)C PHUNDLUSWHZQPF-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000003486 chemical etching Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000013626 chemical specie Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 2
- 238000012876 topography Methods 0.000 description 2
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 2
- MYTCQWNCCJFKNH-UHFFFAOYSA-N (4-diethylsilylcyclohexa-2,5-dien-1-yl)-diethylsilane Chemical compound CC[SiH](CC)C1C=CC(C=C1)[SiH](CC)CC MYTCQWNCCJFKNH-UHFFFAOYSA-N 0.000 description 1
- KNJRBIPCRNZYOH-UHFFFAOYSA-N 3,3-dimethylbutyl-ethyl-ethylsilylsilane Chemical compound CC[SiH2][SiH](CC)CCC(C)(C)C KNJRBIPCRNZYOH-UHFFFAOYSA-N 0.000 description 1
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- LXWPDDYVGZVRSR-UHFFFAOYSA-N N-[tert-butyl(3,3-dimethylbutyl)silyl]-N-methylmethanamine Chemical compound CN(C)[SiH](CCC(C)(C)C)C(C)(C)C LXWPDDYVGZVRSR-UHFFFAOYSA-N 0.000 description 1
- SAJVOSPKIOLXOT-UHFFFAOYSA-N N-[tert-butyl-[tert-butyl-(3,3-dimethylbutyl)-(propylamino)silyl]silyl]propan-1-amine Chemical compound C(CC)N[Si]([SiH](C(C)(C)C)NCCC)(CCC(C)(C)C)C(C)(C)C SAJVOSPKIOLXOT-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- CTCMZLFWDKHYMJ-UHFFFAOYSA-N diethyl(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](CC)(CC)C1=CC=CC=C1 CTCMZLFWDKHYMJ-UHFFFAOYSA-N 0.000 description 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000004943 liquid phase epitaxy Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 239000012686 silicon precursor Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
- H01L31/02168—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02167—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon carbide not containing oxygen, e.g. SiC, SiC:H or silicon carbonitrides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
- H01L21/3148—Silicon Carbide layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0236—Special surface textures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0236—Special surface textures
- H01L31/02363—Special surface textures of the semiconductor body itself, e.g. textured active layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
Landscapes
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Electromagnetism (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Sustainable Energy (AREA)
- Chemical Vapour Deposition (AREA)
- Photovoltaic Devices (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Formation Of Insulating Films (AREA)
Description
例としては、シクロヘキサン、トリメチルシクロヘキサン、1−メチル−4(1−メチルエチル)シクロヘキサン、シクロオクタン、メチルシクロオクタン、シクロオクテン、シクロオクタジエン、シクロヘプテン、シクロペンテン、シクロヘキセン、及び1,5,9−シクロドデカトリエンが挙げられる。
例としては、エチレン、プロピレン、アセチレン、ネオヘキサンなどが挙げられる。
例としては、シクロヘキセン、ビニルシクロヘキサン、ジメチルシクロヘキセン、t−ブチルシクロヘキセン、α−テルピネン、ピネン、1,5−ジメチル−1,5−シクロオクタジエン、ビニル−シクロヘキセンなどが挙げられる。
例としては、ノルボルナン、スピロ−ノナン、デカヒドロナフタレンなどが挙げられる。
例としては、カンフェン、ノルボルネン、ノルボルナジエンなどが挙げられる。
例としては、アダマンタンが挙げられる。
有機シラン、例えば、トリメチルシラン及びテトラメチルシラン(別々に)等を用いてPECVD技術によりシリコンウェハ上に膜を堆積した。ウェハを、約100℃〜約400℃のサセプタ温度を有する200mmのApplied Materials DxZ PECVDチャンバーにおいて処理した。約3torrの圧力を50sccm〜1000sccmの流量とともに用いた。RF出力(13.56MHz)を30〜500秒間にわたり100W〜800Wの間で変化させ、1.5〜2.3の屈折率を得た。図2は、約1200cm-1でのSi−C共有結合を示す非晶質炭化ケイ素膜のIRスペクトルである。
アンモニア(NH3)とともに又はそれなしでビスt−ブチルアミノシラン(BTBAS)を用いてPECVD技術によりシリコンウェハ上に膜を堆積した。ウェハを、約100℃〜約400℃のサセプタ温度を有する200mmのApplied Materials DxZ PECVDチャンバーにおいて処理した。約2.0〜4.0torrの圧力を50sccm〜1000sccmの流量とともに用いた。RF出力(13.56MHz)を30〜500秒間にわたり200W〜800Wの間で変化させ、1.5〜2.0の屈折率を得た。図3は、約1200cm-1でのSi−C共有結合及び3300cm-1での窒素の存在を示す非晶質炭窒化ケイ素膜のIRスペクトルである。
Claims (5)
- p−n接合を含むシリコン基材を含む光起電力素子を製造するための方法であって、
ビス(t−ブチルアミノ)シランを主として含み、
(a)式(NR 1 SiR 1 R 3 ) x の環状シラザン化合物(式中、R 1 及びR 3 は独立してH、直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化されたC 1 〜C 4 であり、xは2〜8の整数である)、
(b)式(CR 1 R 3 SiR 1 R 3 ) x の環状カルボシラン化合物(式中、R 1 及びR 3 は独立してH、直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化されたC 1 〜C 4 であり、xは2〜8の整数である)、
(c)式(R 1n R 2m R 3o R 4p )Si−H 4-t の非環状アルキルシラン(式中、R 1 〜R 4 は直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化されたC 1 〜C 4 であることができ、t=n+m+o+pであり、t=1〜4である)、
(d)式R 1 n (NR 2 ) 4-n Siの化合物(式中、R 1 は独立してH又はC 1 〜C 4 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、R 2 は独立してC 1 〜C 6 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、芳香族の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、nは0〜3である)、
(e)式R 1 n (NR 2 ) 3-n Si−SiR 3 m (NR 4 ) 3-m の化合物(式中、R 1 及びR 3 は独立してH又はC 1 〜C 4 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、R 2 及びR 4 は独立してC 1 〜C 6 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、芳香族の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、nは0〜3であり、mは0〜3である)、
(f)式R 1 n (NR 2 ) 3-n Si−R 5 −SiR 3 m (NR 4 ) m-3 の化合物(式中、R 1 及びR 3 は独立してH又はC 1 〜C 4 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、R 2 、R 4 及びR 5 は独立してC 1 〜C 6 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、芳香族の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、あるいはまた、R 5 はアミン基又は有機アミン基であり、nは0〜3であり、mは0〜3である)、
(g)式(R 1 n (NR 2 ) 3-n Si) t CH 4-t の化合物(式中、R 1 は独立してH又はC 1 〜C 4 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、R 2 は独立してC 1 〜C 6 の直鎖又は分枝の、飽和、単又は複不飽和の、環状の、芳香族の、フッ素化されていないか又は部分的に若しくは完全にフッ素化された炭化水素であり、nは0〜3であり、tは1〜3である)、又は
(h)それらの混合物
をさらに含む組成物をプラズマ化学気相成長させることにより、シリコン基材の少なくとも一方の表面上に非晶質炭化ケイ素の反射防止コーティングを形成する工程を含み、
該非晶質炭化ケイ素の反射防止コーティングが、式SivCxNuHyFzによって表される膜であって、式中、v+x+u+y+z=100%、vが1〜35原子%、xが5〜80原子%、uが0〜50原子%、yが10〜50原子%、及びzが0〜15原子%である、方法。 - 前記基材がテクスチャ処理されている、請求項1に記載の方法。
- 前記組成物が炭化水素をさらに含む、請求項1又は2に記載の方法。
- 前記炭化水素が、
1)一般式CnH2nの環式炭化水素(式中、n=4〜14であり、環式構造中の炭素数は4〜12である)、
2)一般式CnH(2n+2)-2yの直鎖又は分枝の、飽和、単又は複不飽和の炭化水素(式中、n=2〜20であり、y=不飽和の単位である)、
3)一般式CnH2n-2xの単又は複不飽和の環式炭化水素(式中、xは炭化水素分子中の不飽和部位の数であり、n=4〜14であり、環式構造中の炭素数は4〜10である)、
4)一般式CnH2n-2の二環式炭化水素(式中、n=4〜14であり、二環式構造中の炭素数は4〜12である)、
5)一般式CnH2n-(2+2x)の複不飽和の二環式炭化水素(式中、xは分子中の不飽和部位の数であり、n=4〜14であり、二環式構造中の炭素数は4〜12である)、及び
6)一般式CnH2n-4の三環式炭化水素(式中、n=4〜14であり、三環式構造中の炭素数は4〜12である)
からなる群より選択される、請求項3に記載の方法。 - 前記炭化水素が、シクロヘキサン、トリメチルシクロヘキサン、1−メチル−4(1−メチルエチル)シクロヘキサン、シクロオクタン、メチルシクロオクタン、シクロオクテン、シクロオクタジエン、シクロヘプテン、シクロペンテン、シクロヘキセン、1,5,9−シクロドデカトリエン、エチレン、プロピレン、アセチレン、ネオヘキサン、シクロヘキセン、ビニルシクロヘキサン、ジメチルシクロヘキセン、t−ブチルシクロヘキセン、α−テルピネン、ピネン、1,5−ジメチル−1,5−シクロオクタジエン、ビニル−シクロヘキセン、ノルボルナン、スピロ−ノナン、デカヒドロナフタレン、カンフェン、ノルボルネン、ノルボルナジエン、及びアダマンタンからなる群より選択される、請求項4に記載の方法。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US97958507P | 2007-10-12 | 2007-10-12 | |
US60/979585 | 2007-10-12 | ||
US12/244,455 US8987039B2 (en) | 2007-10-12 | 2008-10-02 | Antireflective coatings for photovoltaic applications |
US12/244455 | 2008-10-02 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013171080A Division JP2013238890A (ja) | 2007-10-12 | 2013-08-21 | 光電池用途のための反射防止コーティング |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009099986A JP2009099986A (ja) | 2009-05-07 |
JP2009099986A5 JP2009099986A5 (ja) | 2009-06-18 |
JP5390161B2 true JP5390161B2 (ja) | 2014-01-15 |
Family
ID=40263522
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008265781A Expired - Fee Related JP5390161B2 (ja) | 2007-10-12 | 2008-10-14 | 光電池用途のための反射防止コーティング |
JP2013171080A Pending JP2013238890A (ja) | 2007-10-12 | 2013-08-21 | 光電池用途のための反射防止コーティング |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013171080A Pending JP2013238890A (ja) | 2007-10-12 | 2013-08-21 | 光電池用途のための反射防止コーティング |
Country Status (5)
Country | Link |
---|---|
US (1) | US8987039B2 (ja) |
EP (1) | EP2048699A3 (ja) |
JP (2) | JP5390161B2 (ja) |
KR (1) | KR100986847B1 (ja) |
TW (1) | TWI440197B (ja) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009143618A1 (en) * | 2008-05-28 | 2009-12-03 | Sixtron Advanced Materials, Inc. | Silicon carbide-based antireflective coating |
US20100186811A1 (en) * | 2008-08-26 | 2010-07-29 | Sixtron Advanced Materials, Inc. | Silicon Carbonitride Antireflective Coating |
US20100051096A1 (en) * | 2008-08-26 | 2010-03-04 | Sixtron Advanced Materials, Inc. | Silicon carbonitride antireflective coating |
US8889235B2 (en) * | 2009-05-13 | 2014-11-18 | Air Products And Chemicals, Inc. | Dielectric barrier deposition using nitrogen containing precursor |
FR2949776B1 (fr) | 2009-09-10 | 2013-05-17 | Saint Gobain Performance Plast | Element en couches pour l'encapsulation d'un element sensible |
FR2949775B1 (fr) | 2009-09-10 | 2013-08-09 | Saint Gobain Performance Plast | Substrat de protection pour dispositif collecteur ou emetteur de rayonnement |
US9564542B2 (en) * | 2009-09-17 | 2017-02-07 | Tetrasun, Inc. | Selective transformation in functional films, and solar cell applications thereof |
US20120222741A1 (en) * | 2009-09-18 | 2012-09-06 | L'air Liquide, Societe Anonyme Pour I'etude Et I'exploitation Des Procedes Georges Claude | Solar cell with improved performance |
US20110094574A1 (en) * | 2009-10-27 | 2011-04-28 | Calisolar Inc. | Polarization Resistant Solar Cell Design Using SiCN |
KR20110088172A (ko) * | 2010-01-28 | 2011-08-03 | 삼성전자주식회사 | 태양 전지 모듈 및 그 제조 방법 |
JPWO2012002440A1 (ja) * | 2010-06-29 | 2013-08-29 | 京セラ株式会社 | 半導体基板の表面処理方法、半導体基板、および太陽電池の製造方法 |
US8852848B2 (en) * | 2010-07-28 | 2014-10-07 | Z Electronic Materials USA Corp. | Composition for coating over a photoresist pattern |
WO2012024676A2 (en) * | 2010-08-20 | 2012-02-23 | First Solar, Inc. | Anti-reflective photovoltaic module |
JP5490031B2 (ja) * | 2011-02-04 | 2014-05-14 | 三菱電機株式会社 | 光起電力装置および光起電力モジュール |
FR2973939A1 (fr) | 2011-04-08 | 2012-10-12 | Saint Gobain | Element en couches pour l’encapsulation d’un element sensible |
US20130247967A1 (en) * | 2012-03-23 | 2013-09-26 | Scott Harrington | Gaseous ozone (o3) treatment for solar cell fabrication |
CN104769726B (zh) * | 2012-09-05 | 2018-10-09 | 兹尼亚泰克有限公司 | 具有三维表面特征的光伏设备及制造该光伏设备的方法 |
US9401450B2 (en) * | 2013-12-09 | 2016-07-26 | Sunpower Corporation | Solar cell emitter region fabrication using ion implantation |
KR101867855B1 (ko) * | 2014-03-17 | 2018-06-15 | 엘지전자 주식회사 | 태양 전지 |
US9837259B2 (en) | 2014-08-29 | 2017-12-05 | Sunpower Corporation | Sequential etching treatment for solar cell fabrication |
CN109072426B (zh) * | 2016-02-26 | 2021-12-03 | 弗萨姆材料美国有限责任公司 | 组合物和使用其沉积含硅膜的方法 |
KR102105977B1 (ko) * | 2017-03-29 | 2020-05-04 | (주)디엔에프 | 실릴아민 화합물, 이를 포함하는 실리콘 함유 박막증착용 조성물 및 이를 이용하는 실리콘 함유 박막의 제조방법 |
KR20180110612A (ko) | 2017-03-29 | 2018-10-10 | (주)디엔에프 | 비스(아미노실릴)알킬아민 화합물을 포함하는 실리콘 함유 박막증착용 조성물 및 이를 이용하는 실리콘 함유 박막의 제조방법 |
US11105960B2 (en) | 2017-12-19 | 2021-08-31 | Canon Kabushiki Kaisha | Optical element and method of producing the element, and optical instrument |
JP2021013044A (ja) * | 2020-11-06 | 2021-02-04 | シャープ株式会社 | 光電変換素子 |
CN118043288A (zh) * | 2021-10-07 | 2024-05-14 | 康宁股份有限公司 | 作为光学和保护性涂层的具有可调离子渗透性的氧化物涂层及其制造方法 |
CN114203840A (zh) * | 2021-11-15 | 2022-03-18 | 一道新能源科技(衢州)有限公司 | 一种改善硼掺杂对绒面金字塔损伤的方法及装置 |
Family Cites Families (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5895873A (ja) | 1981-12-02 | 1983-06-07 | Konishiroku Photo Ind Co Ltd | アモルフアスシリコン太陽電池 |
JPS6067901A (ja) | 1983-09-24 | 1985-04-18 | Agency Of Ind Science & Technol | 水素化及び弗素化した非晶質炭化ケイ素薄膜を用いた光学素子 |
JP2897569B2 (ja) | 1991-12-30 | 1999-05-31 | ソニー株式会社 | レジストパターン形成時に用いる反射防止膜の条件決定方法と、レジストパターン形成方法 |
US5472827A (en) | 1991-12-30 | 1995-12-05 | Sony Corporation | Method of forming a resist pattern using an anti-reflective layer |
US6541695B1 (en) | 1992-09-21 | 2003-04-01 | Thomas Mowles | High efficiency solar photovoltaic cells produced with inexpensive materials by processes suitable for large volume production |
KR0134942B1 (ko) | 1993-06-11 | 1998-06-15 | 이다가끼 유끼오 | 비정질 경질 탄소막 및 그 제조 방법 |
TW362118B (en) | 1995-10-30 | 1999-06-21 | Dow Corning | Method for depositing amorphous SiNC coatings |
JPH10190031A (ja) | 1996-12-20 | 1998-07-21 | Tdk Corp | 太陽電池およびその製造方法 |
US6020458A (en) | 1997-10-24 | 2000-02-01 | Quester Technology, Inc. | Precursors for making low dielectric constant materials with improved thermal stability |
US6303523B2 (en) | 1998-02-11 | 2001-10-16 | Applied Materials, Inc. | Plasma processes for depositing low dielectric constant films |
US6054379A (en) | 1998-02-11 | 2000-04-25 | Applied Materials, Inc. | Method of depositing a low k dielectric with organo silane |
US6159871A (en) | 1998-05-29 | 2000-12-12 | Dow Corning Corporation | Method for producing hydrogenated silicon oxycarbide films having low dielectric constant |
US6054206A (en) | 1998-06-22 | 2000-04-25 | Novellus Systems, Inc. | Chemical vapor deposition of low density silicon dioxide films |
US6316167B1 (en) | 2000-01-10 | 2001-11-13 | International Business Machines Corporation | Tunabale vapor deposited materials as antireflective coatings, hardmasks and as combined antireflective coating/hardmasks and methods of fabrication thereof and application thereof |
US6635583B2 (en) | 1998-10-01 | 2003-10-21 | Applied Materials, Inc. | Silicon carbide deposition for use as a low-dielectric constant anti-reflective coating |
US6974766B1 (en) | 1998-10-01 | 2005-12-13 | Applied Materials, Inc. | In situ deposition of a low κ dielectric layer, barrier layer, etch stop, and anti-reflective coating for damascene application |
US6171945B1 (en) | 1998-10-22 | 2001-01-09 | Applied Materials, Inc. | CVD nanoporous silica low dielectric constant films |
MXPA01006925A (es) | 1999-01-06 | 2003-06-04 | Union Carbide Chem Plastic | Composiciones de limpieza acuosas. |
US6828289B2 (en) | 1999-01-27 | 2004-12-07 | Air Products And Chemicals, Inc. | Low surface tension, low viscosity, aqueous, acidic compositions containing fluoride and organic, polar solvents for removal of photoresist and organic and inorganic etch residues at room temperature |
KR100307629B1 (ko) | 1999-04-30 | 2001-09-26 | 윤종용 | 하이드로 카본계의 가스를 이용한 반사방지막의 형성 및 적용방법 |
US6312793B1 (en) | 1999-05-26 | 2001-11-06 | International Business Machines Corporation | Multiphase low dielectric constant material |
US6875687B1 (en) | 1999-10-18 | 2005-04-05 | Applied Materials, Inc. | Capping layer for extreme low dielectric constant films |
US6936405B2 (en) | 2000-02-22 | 2005-08-30 | Brewer Science Inc. | Organic polymeric antireflective coatings deposited by chemical vapor deposition |
EP1127929B1 (en) | 2000-02-28 | 2009-04-15 | JSR Corporation | Composition for film formation, method of film formation, and silica-based film |
US6441491B1 (en) | 2000-10-25 | 2002-08-27 | International Business Machines Corporation | Ultralow dielectric constant material as an intralevel or interlevel dielectric in a semiconductor device and electronic device containing the same |
US6583048B2 (en) | 2001-01-17 | 2003-06-24 | Air Products And Chemicals, Inc. | Organosilicon precursors for interlayer dielectric films with low dielectric constants |
US20030022800A1 (en) | 2001-06-14 | 2003-01-30 | Peters Darryl W. | Aqueous buffered fluoride-containing etch residue removers and cleaners |
US6627546B2 (en) | 2001-06-29 | 2003-09-30 | Ashland Inc. | Process for removing contaminant from a surface and composition useful therefor |
DE10131680A1 (de) | 2001-06-29 | 2003-01-23 | Voith Paper Patent Gmbh | Auftragsvorrichtung |
US6943142B2 (en) | 2002-01-09 | 2005-09-13 | Air Products And Chemicals, Inc. | Aqueous stripping and cleaning composition |
US6846515B2 (en) | 2002-04-17 | 2005-01-25 | Air Products And Chemicals, Inc. | Methods for using porogens and/or porogenated precursors to provide porous organosilica glass films with low dielectric constants |
US7122880B2 (en) | 2002-05-30 | 2006-10-17 | Air Products And Chemicals, Inc. | Compositions for preparing low dielectric materials |
US7307343B2 (en) | 2002-05-30 | 2007-12-11 | Air Products And Chemicals, Inc. | Low dielectric materials and methods for making same |
US6677286B1 (en) | 2002-07-10 | 2004-01-13 | Air Products And Chemicals, Inc. | Compositions for removing etching residue and use thereof |
US7166419B2 (en) | 2002-09-26 | 2007-01-23 | Air Products And Chemicals, Inc. | Compositions substrate for removing etching residue and use thereof |
WO2004044025A2 (en) | 2002-11-12 | 2004-05-27 | Honeywell International Inc | Anti-reflective coatings for photolithography and methods of preparation thereof |
KR20040060331A (ko) | 2002-12-30 | 2004-07-06 | 주식회사 하이닉스반도체 | 반도체소자의 금속배선 형성방법 |
US6855645B2 (en) | 2002-12-30 | 2005-02-15 | Novellus Systems, Inc. | Silicon carbide having low dielectric constant |
US7402448B2 (en) | 2003-01-31 | 2008-07-22 | Bp Corporation North America Inc. | Photovoltaic cell and production thereof |
US6869542B2 (en) | 2003-03-12 | 2005-03-22 | International Business Machines Corporation | Hard mask integrated etch process for patterning of silicon oxide and other dielectric materials |
US8137764B2 (en) | 2003-05-29 | 2012-03-20 | Air Products And Chemicals, Inc. | Mechanical enhancer additives for low dielectric films |
US20050067702A1 (en) | 2003-09-30 | 2005-03-31 | International Business Machines Corporation | Plasma surface modification and passivation of organo-silicate glass films for improved hardmask adhesion and optimal RIE processing |
US20050287747A1 (en) | 2004-06-29 | 2005-12-29 | International Business Machines Corporation | Doped nitride film, doped oxide film and other doped films |
US20060045986A1 (en) | 2004-08-30 | 2006-03-02 | Hochberg Arthur K | Silicon nitride from aminosilane using PECVD |
JP4540447B2 (ja) | 2004-10-27 | 2010-09-08 | シャープ株式会社 | 太陽電池および太陽電池の製造方法 |
US20060183055A1 (en) | 2005-02-15 | 2006-08-17 | O'neill Mark L | Method for defining a feature on a substrate |
JP2006265530A (ja) | 2005-02-28 | 2006-10-05 | Toray Ind Inc | コーティング材料およびそれを用いた光学物品 |
US7554031B2 (en) | 2005-03-03 | 2009-06-30 | Sunpower Corporation | Preventing harmful polarization of solar cells |
US7875556B2 (en) | 2005-05-16 | 2011-01-25 | Air Products And Chemicals, Inc. | Precursors for CVD silicon carbo-nitride and silicon nitride films |
US20060286774A1 (en) | 2005-06-21 | 2006-12-21 | Applied Materials. Inc. | Method for forming silicon-containing materials during a photoexcitation deposition process |
US7718888B2 (en) | 2005-12-30 | 2010-05-18 | Sunpower Corporation | Solar cell having polymer heterojunction contacts |
-
2008
- 2008-10-02 US US12/244,455 patent/US8987039B2/en not_active Expired - Fee Related
- 2008-10-13 KR KR1020080100360A patent/KR100986847B1/ko not_active IP Right Cessation
- 2008-10-13 EP EP08166488A patent/EP2048699A3/en not_active Withdrawn
- 2008-10-13 TW TW097139271A patent/TWI440197B/zh not_active IP Right Cessation
- 2008-10-14 JP JP2008265781A patent/JP5390161B2/ja not_active Expired - Fee Related
-
2013
- 2013-08-21 JP JP2013171080A patent/JP2013238890A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
TWI440197B (zh) | 2014-06-01 |
US8987039B2 (en) | 2015-03-24 |
EP2048699A3 (en) | 2010-11-03 |
TW200917510A (en) | 2009-04-16 |
US20090095346A1 (en) | 2009-04-16 |
KR100986847B1 (ko) | 2010-10-08 |
JP2013238890A (ja) | 2013-11-28 |
JP2009099986A (ja) | 2009-05-07 |
KR20090037842A (ko) | 2009-04-16 |
EP2048699A2 (en) | 2009-04-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5390161B2 (ja) | 光電池用途のための反射防止コーティング | |
EP2471111B1 (fr) | Procede de nettoyage de la surface d'un substrat de silicium | |
EP2833391A1 (en) | Semiconductor laminate and method for manufacturing same, method for manufacturing semiconductor device, semiconductor device, dopant composition, dopant injection layer, and method for forming doped layer | |
CN101425551B (zh) | 用于光伏应用的抗反射涂层 | |
US20130220410A1 (en) | Precursors for Photovoltaic Passivation | |
WO2016019396A2 (en) | Solar cell surface passivation using photo-anneal | |
US20130247971A1 (en) | Oxygen Containing Precursors for Photovoltaic Passivation | |
US10276732B2 (en) | Solar cell element and method of manufacturing solar cell element | |
US8980737B2 (en) | Methods of forming contact regions using sacrificial layers | |
Jeong et al. | Preparation of born-doped a-SiC: H thin films by ICP-CVD method and to the application of large-area heterojunction solar cells | |
EP2993699B1 (en) | Method for fabricating crystalline photovoltaic cells | |
CN103000755A (zh) | 用于光伏钝化的前体 | |
KR101198930B1 (ko) | 질화규소 반사방지막의 제조 방법 및 이를 이용한 실리콘 태양전지 | |
Cho et al. | Effects of plasma-enhanced chemical vapor deposition (PECVD) on the carrier lifetime of Al 2 O 3 passivation stack | |
EP4162534A1 (en) | Methodology for efficient hole transport layer using transition metal oxides | |
KR101375233B1 (ko) | 광전 패시베이션용 산소 함유 전구체 | |
Kang et al. | A Study of Blister Control of AL2O3 Thin Film Deposited by Plasma-assisted Atomic Layer Deposition after Firing Process | |
JP4237435B2 (ja) | 太陽電池の製造方法および太陽電池 | |
KR101554565B1 (ko) | ZnO:Al:Ag 패시베이션 층의 제조방법 및 이에 따라 제조되는 ZnO:Al:Ag 패시베이션 층 | |
JP3487580B2 (ja) | 堆積膜形成方法および堆積膜形成装置 | |
Janz et al. | Passivation mechanisms of amorphous SixC1-x layers on highly doped and textured Si surfaces | |
Shin et al. | Electrical and chemical characterization of Al 2 O 3 passivation layer deposited by plasma-assisted atomic layer deposition in c-Si solar cells | |
Kang et al. | Silane-free PECVD silicon carbon nitride (SiC x N y) passivation and anti-reflection coatings for high efficiency silicon solar cells | |
JPH08181079A (ja) | 非晶質半導体薄膜形成方法 | |
Matsumura et al. | Highly moisture-resistive SiN/sub x/films by catalytic chemical vapor deposition and their application to passivation and antireflection coating for crystalline Si solar cells |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090303 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090303 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110721 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110802 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20111101 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20111107 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120403 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120801 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20120808 |
|
A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20121130 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130315 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130321 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130821 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20131010 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |