JP5296421B2 - 金属製基礎材のための溶射された気密な保護層、保護層を製造するための噴射粉末、保護層の製造方法及び保護層の適用 - Google Patents
金属製基礎材のための溶射された気密な保護層、保護層を製造するための噴射粉末、保護層の製造方法及び保護層の適用 Download PDFInfo
- Publication number
- JP5296421B2 JP5296421B2 JP2008159801A JP2008159801A JP5296421B2 JP 5296421 B2 JP5296421 B2 JP 5296421B2 JP 2008159801 A JP2008159801 A JP 2008159801A JP 2008159801 A JP2008159801 A JP 2008159801A JP 5296421 B2 JP5296421 B2 JP 5296421B2
- Authority
- JP
- Japan
- Prior art keywords
- protective layer
- component
- base material
- powder
- mineral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011241 protective layer Substances 0.000 title claims description 43
- 239000000463 material Substances 0.000 title claims description 42
- 229910052751 metal Inorganic materials 0.000 title claims description 40
- 239000002184 metal Substances 0.000 title claims description 40
- 239000000843 powder Substances 0.000 title claims description 39
- 239000007921 spray Substances 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000010410 layer Substances 0.000 claims description 60
- 239000002585 base Substances 0.000 claims description 37
- 239000002245 particle Substances 0.000 claims description 19
- 230000007797 corrosion Effects 0.000 claims description 16
- 238000005260 corrosion Methods 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 11
- 239000011707 mineral Substances 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 238000010285 flame spraying Methods 0.000 claims description 8
- 238000002347 injection Methods 0.000 claims description 8
- 239000007924 injection Substances 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
- 238000007750 plasma spraying Methods 0.000 claims description 7
- 229910052604 silicate mineral Inorganic materials 0.000 claims description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- 238000007749 high velocity oxygen fuel spraying Methods 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 230000003628 erosive effect Effects 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 4
- 238000004031 devitrification Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000000919 ceramic Substances 0.000 description 10
- 238000002844 melting Methods 0.000 description 10
- 239000011521 glass Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 239000011148 porous material Substances 0.000 description 7
- 230000035939 shock Effects 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 239000004071 soot Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000012447 hatching Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 229910000990 Ni alloy Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- 229910018487 Ni—Cr Inorganic materials 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003139 buffering effect Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 238000007751 thermal spraying Methods 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/129—Flame spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
- Y10T428/12618—Plural oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Laminated Bodies (AREA)
Description
基礎材は鋼鉄あるいはニッケル合金からなる。その上にフレーム溶射、プラズマ溶射、あるいはHVOFによって本発明に係る鉱物−金属噴射粉末を噴射する。その噴射は、砂吹きされ予加熱されていない基礎材上に後溶融せずに実施する。50μm未満の粒子からなる噴射粉末は、噴霧乾燥の後焼結(850℃)したものであり、以下の成分から製造される:
65重量%:ガス霧化された80Ni20Cr(ニッケルクロム)合金からなる金属粉末、25μm未満の粒子;
25重量%:溶融し微細粉砕された人工の黒玄武岩、50重量%のSiO2、20重量%のCaO、15重量%のAl2O3、8重量%のMgO、7重量%のFe2O3、10μm未満の粒子;アルカリ含有率0.5重量%未満;
10重量%:99%超のSiO2純度を有する、粉砕および篩分けされた天然石英あるいはクリストバライト(25ないし50μmの粒子)。
基礎材は鋼鉄、鋳鉄あるいはニッケル合金からなる。その上にフレーム溶射あるいはプラズマ溶射によって本発明に係る二成分の鉱物噴射粉末を噴射する。その噴射は、砂吹きされ約500℃に予加熱された基礎材上に後溶融しながら約1100℃で実施する。100μm未満の粒子からなる噴射粉末は、以下の鉱物成分の混合によって製造される:
67重量%:溶融、粉砕および篩分けされた人工の白玄武岩(25ないし50μm)、54重量%のSiO2、20重量%のCaO、5重量%のMgO、16重量%のAl2O3、5重量%のNa2O;アルカリ含有率5重量%以下;
33重量%:99%超のSiO2純度を有する、粉砕および篩分けされたクリストバライト(25ないし100μmの粒子)。
基礎材はアルミニウムあるいはマグネシウム合金からなる。その上にプラズマ溶射あるいはHVOFによって鉱物−金属噴射粉末を噴射する。その噴射は、砂吹きされ予加熱されていない基礎材上に後溶融せずに実施する。50μm未満の粒子からなる噴射粉末は、噴霧乾燥の後焼結(620℃)したものであり、以下の成分から製造される:
62重量%:ガス霧化された90Cu10Sn合金(錫青銅)からなる金属粉末、25μm未満の粒子;
18重量%:微細粉砕(10μm未満の粒子)された天然の黒玄武岩(玄武粉);アルカリ含有率5重量%未満;
20重量%:99%超のSiO2純度を有する、粉砕および篩分けされた天然石英あるいはクリストバライト(25ないし50μmの粒子)。
基礎材はチタン合金からなる。その上にプラズマ溶射あるいはHVOFによって鉱物−金属噴射粉末を噴射する。その噴射は、砂吹きされ予加熱されていない基礎材上に後溶融せずに実施する。50μm未満の粒子からなる噴射粉末は、噴霧乾燥の後焼結(800℃、保護ガス)したものであり、以下の成分から製造される:
57重量%:ガス霧化された80Ni20Cr(ニッケルクロム)合金からなる金属粉末、25μm未満の粒子;
31重量%:微細粉砕(10μm未満の粒子)された天然の黒玄武岩(玄武粉);
12重量%:95%超のLiAlSi206純度を有する、粉砕および篩分けされた天然の黝輝石(25ないし50μmの粒子)。
Claims (12)
- 金属製の基礎材のための溶射された気密な保護層であり、そのため噴射粉末が第1の成分、第2の成分及び第3の成分を有し、
前記第1の成分は珪酸塩鉱物あるいは鉱石からなる珪酸塩成分であり、
前記第2の成分は珪酸塩鉱物あるいは鉱石からなる珪酸塩成分であり、
前記第3の成分は金属粉であり、
前記噴射粉末中の前記第1の成分と前記第2の成分のいずれかに含まれる珪酸塩鉱物あるいは鉱石の成分が6重量%未満のアルカリ含有量を有することを特徴とする保護層。 - 前記金属製の基礎材がFe、Ni、Al、Mg、および/またはTiに基づいた基礎材である請求項1記載の保護層。
- 前記第3の成分はニッケルあるいは銅ベースの合金からなることを特徴とする請求項1または2記載の保護層。
- 前記噴射粉末の前記第1の成分と前記第2の成分とのうち少なくとも一方が天然あるいは人工の鉱物あるいは鉱石からなることを特徴とする請求項1ないし3のいずれかに記載の保護層。
- 前記噴射粉末が99%超のSiO2含有率を有する前記第1の成分と前記第2の成分とのうちいずれか一方を少なくとも10重量%の比率で含むことを特徴とする請求項1ないし4のいずれかに記載の保護層。
- 前記保護層が100ないし2500μmの層厚を有することを特徴とする請求項1ないし5のいずれかに記載の保護層。
- 前記保護層が2mm超の層厚を有することを特徴とする請求項1ないし6のいずれかに記載の保護層。
- 請求項1ないし7のいずれかに記載の保護層を製造するための前記第1の成分、第2の成分及び第3の成分からなる噴射粉末。
- 金属製の基礎材上への保護層の塗付をフレーム溶射、高速酸素火炎溶射(HVOF)、あるいはプラズマ溶射によって実施する、請求項1ないし7のいずれかに記載の保護層の製造方法であり、前記保護層の塗付に際して噴射粉末の鉱物成分の制御された部分的な脱ガラス化によって層と基礎材との間の熱膨張係数の整合を実施することを特徴とする方法。
- 前記部分的な脱ガラス化は前記噴射粉末の前記第1の成分と前記第2の成分とのうち少なくとも一方の粒径の適宜な選択を介して制御されることを特徴とする請求項9記載の保護層の製造方法。
- 前記保護層はその塗付中における前記少なくとも1つの鉱物成分のグレージングによって裂溝の無い構造ならびに基礎材に対しての良好な付着性を有することを特徴とする請求項9または10に記載の方法。
- 内燃エンジンあるいはガスタービンの燃焼室として機能する基礎材を高温、腐食、および壊食に対して防護するための請求項1ないし7のいずれかに記載の保護層の適用。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007028109.0 | 2007-06-19 | ||
DE102007028109A DE102007028109A1 (de) | 2007-06-19 | 2007-06-19 | Thermisch gespritzte, gasdichte Schutzschicht für metallische Substrate |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009001903A JP2009001903A (ja) | 2009-01-08 |
JP5296421B2 true JP5296421B2 (ja) | 2013-09-25 |
Family
ID=39535282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008159801A Active JP5296421B2 (ja) | 2007-06-19 | 2008-06-18 | 金属製基礎材のための溶射された気密な保護層、保護層を製造するための噴射粉末、保護層の製造方法及び保護層の適用 |
Country Status (6)
Country | Link |
---|---|
US (2) | US8784979B2 (ja) |
EP (1) | EP2006410B1 (ja) |
JP (1) | JP5296421B2 (ja) |
KR (1) | KR20080112099A (ja) |
CN (1) | CN101328569B (ja) |
DE (1) | DE102007028109A1 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009034307A1 (de) * | 2009-07-21 | 2011-01-27 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Hochtemperaturheizung sowie Verfahren zu dessen Herstellung |
DE102011119087B3 (de) * | 2011-11-22 | 2013-03-14 | Märkisches Werk GmbH | Verfahren zum Erzeugen einer Chrom-Schutzschicht und ihre Verwendung |
KR101924810B1 (ko) * | 2012-08-29 | 2018-12-04 | 현대중공업 주식회사 | 디젤엔진용 배기밸브 스핀들의 내부식성 향상을 위한 인코넬-니켈-크롬계 코팅혼합물과, 이를 이용한 배기밸브 스핀들 코팅방법 및 코팅혼합물이 코팅된 배기밸브 스핀들 |
CN103147034A (zh) * | 2013-03-21 | 2013-06-12 | 齐齐哈尔大学 | 用于热喷涂技术的金属/改性玄武岩复合粉末的制备方法 |
DE102013211681A1 (de) | 2013-06-20 | 2014-12-24 | Robert Bosch Gmbh | Brennstoffeinspritzventil und Vorrichtung zur thermischen Sprühbeschichtung |
DE102013108428A1 (de) * | 2013-08-05 | 2015-02-05 | Tenedora Nemak, S.A. De C.V. | Emaillepulver, Metallbauteil mit einem mit einer Emaillebeschichtung versehenen Flächenabschnitt und Verfahren zum Herstellen eines solchen Metallbauteils |
DE102014018693A1 (de) * | 2014-12-18 | 2016-06-23 | Mahle International Gmbh | Verfahren zum Herstellen einer Wärmedämmschicht sowie mittels dieses Verfahrens hergestellte Wärmedämmschicht |
RU2601049C1 (ru) * | 2015-04-29 | 2016-10-27 | Федеральное государственное бюджетное учреждение науки Институт физики твердого тела Российской академии наук (ИФТТ РАН) | Способ нанесения газоплотного покрытия из карбида кремния |
CN106521479A (zh) * | 2016-12-13 | 2017-03-22 | 大连圣洁热处理科技发展有限公司 | 一种复合层钛板的制备方法 |
CN106702368A (zh) * | 2016-12-13 | 2017-05-24 | 大连圣洁热处理科技发展有限公司 | 一种复合层金属板 |
CN107312996A (zh) * | 2017-06-26 | 2017-11-03 | 安徽雷萨重工机械有限公司 | 一种低成本铝合金表面热喷涂方法 |
CN107675161B (zh) * | 2017-09-20 | 2019-05-10 | 兰州理工大学 | 冷气驱动镍包覆超细釉粉制备搪瓷涂层的方法 |
CN115044856B (zh) * | 2022-06-24 | 2024-01-02 | 中国人民解放军陆军装甲兵学院 | 一种磨损自修复密封涂层的制备方法 |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3625773A (en) * | 1969-12-17 | 1971-12-07 | Gen Electric | Method of producing beta-alumina electrolytes |
US4321310A (en) | 1980-01-07 | 1982-03-23 | United Technologies Corporation | Columnar grain ceramic thermal barrier coatings on polished substrates |
US4405659A (en) | 1980-01-07 | 1983-09-20 | United Technologies Corporation | Method for producing columnar grain ceramic thermal barrier coatings |
US4321311A (en) | 1980-01-07 | 1982-03-23 | United Technologies Corporation | Columnar grain ceramic thermal barrier coatings |
US4401697A (en) | 1980-01-07 | 1983-08-30 | United Technologies Corporation | Method for producing columnar grain ceramic thermal barrier coatings |
US4377371A (en) | 1981-03-11 | 1983-03-22 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Laser surface fusion of plasma sprayed ceramic turbine seals |
DE3220185A1 (de) | 1981-06-05 | 1982-12-23 | Sandoz-Patent-GmbH, 7850 Lörrach | 4-amino-benzylamin-derivate, verfahren zu ihrer herstellung, sowie ihre verwendung als pharmazeutica |
FR2508493B1 (fr) | 1981-06-30 | 1989-04-21 | United Technologies Corp | Procede pour appliquer un revetement de barriere thermique en matiere ceramique tolerant aux contraintes sur un substrat metallique |
CA1274859A (en) * | 1987-06-26 | 1990-10-02 | Alcan International Limited | Insulating lightweight refractory materials |
DE3935222A1 (de) | 1989-10-23 | 1991-04-25 | Hoellmueller Maschbau H | Aetzanlage sowie verfahren zum aetzen von gegenstaenden |
JP2937369B2 (ja) * | 1989-12-08 | 1999-08-23 | 株式会社ナカシマ | ガラス被膜形成方法 |
US5122182A (en) * | 1990-05-02 | 1992-06-16 | The Perkin-Elmer Corporation | Composite thermal spray powder of metal and non-metal |
SE9002264L (sv) | 1990-06-27 | 1991-12-28 | Asea Brown Boveri | Kontaktanordning foer elkopplare |
JPH04231452A (ja) * | 1990-12-28 | 1992-08-20 | Nippon Steel Corp | 溶射被覆材料および溶射被覆耐熱部材 |
JPH07122127B2 (ja) * | 1991-03-12 | 1995-12-25 | 秩父小野田株式会社 | セラミックス溶射材料 |
JPH0679982B2 (ja) * | 1991-03-30 | 1994-10-12 | 東邦オリビン工業株式会社 | セラミック溶射材料 |
US5169689A (en) | 1991-10-02 | 1992-12-08 | General Electric Company | Method of producing thermal barrier coatings on a substrate |
JPH0649617A (ja) * | 1992-07-30 | 1994-02-22 | Onoda Cement Co Ltd | セラミックス溶射材料 |
JPH10316477A (ja) * | 1997-05-13 | 1998-12-02 | Chichibu Onoda Cement Corp | 溶射被覆材料及び溶射被覆部材 |
US5989330A (en) * | 1997-12-12 | 1999-11-23 | Barrick Gold Corporation | Acid resistant cement composition |
EP0939142A1 (en) * | 1998-02-27 | 1999-09-01 | Ticona GmbH | Thermal spray powder incorporating an oxidised polyarylene sulfide |
US6069105A (en) * | 1998-07-14 | 2000-05-30 | Ngk Spark Plug Co., Ltd. | Alumina-based sintered materials and process for producing the same |
DE19852285C1 (de) * | 1998-11-13 | 2000-04-27 | Forschungszentrum Juelich Gmbh | Wärmedämmende Glas-Metall/Keramik-Schichten |
US20030165638A1 (en) * | 2001-07-06 | 2003-09-04 | Louks John W. | Inorganic fiber substrates for exhaust systems and methods of making same |
CA2358624C (en) * | 2001-10-10 | 2009-12-22 | The Westaim Corporation | Sprayable composition |
DE10151479A1 (de) * | 2001-10-18 | 2003-05-08 | Wacker Chemie Gmbh | Mikroporöser Wärmedämmformkörper enthaltend Lichtbogenkieselsäure |
US6753299B2 (en) * | 2001-11-09 | 2004-06-22 | Badger Mining Corporation | Composite silica proppant material |
US7175786B2 (en) * | 2003-02-05 | 2007-02-13 | 3M Innovative Properties Co. | Methods of making Al2O3-SiO2 ceramics |
US7197896B2 (en) * | 2003-09-05 | 2007-04-03 | 3M Innovative Properties Company | Methods of making Al2O3-SiO2 ceramics |
JP4412133B2 (ja) * | 2004-09-27 | 2010-02-10 | Jfeスチール株式会社 | 粉末冶金用鉄基混合粉 |
AU2005303131B2 (en) * | 2004-11-09 | 2010-11-11 | Asahi Glass Company, Limited | Fire brick for bottom portion of float bath and method for production thereof |
-
2007
- 2007-06-19 DE DE102007028109A patent/DE102007028109A1/de not_active Withdrawn
-
2008
- 2008-04-11 EP EP08007173.1A patent/EP2006410B1/de active Active
- 2008-05-09 CN CN200810096440.6A patent/CN101328569B/zh not_active Expired - Fee Related
- 2008-05-13 KR KR1020080043973A patent/KR20080112099A/ko active IP Right Grant
- 2008-05-30 US US12/129,872 patent/US8784979B2/en active Active
- 2008-06-18 JP JP2008159801A patent/JP5296421B2/ja active Active
-
2014
- 2014-06-20 US US14/310,411 patent/US20140302299A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
KR20080112099A (ko) | 2008-12-24 |
EP2006410B1 (de) | 2019-04-03 |
EP2006410A3 (de) | 2010-09-01 |
US20080317966A1 (en) | 2008-12-25 |
EP2006410A2 (de) | 2008-12-24 |
US8784979B2 (en) | 2014-07-22 |
US20140302299A1 (en) | 2014-10-09 |
CN101328569A (zh) | 2008-12-24 |
DE102007028109A1 (de) | 2008-12-24 |
JP2009001903A (ja) | 2009-01-08 |
CN101328569B (zh) | 2015-08-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5296421B2 (ja) | 金属製基礎材のための溶射された気密な保護層、保護層を製造するための噴射粉末、保護層の製造方法及び保護層の適用 | |
US20210261465A1 (en) | Ceramic material for high temperature service | |
Ghasemi et al. | The influence of laser treatment on thermal shock resistance of plasma-sprayed nanostructured yttria stabilized zirconia thermal barrier coatings | |
TW467875B (en) | Coated article and method of making | |
US7955708B2 (en) | Optimized high temperature thermal barrier | |
CA2936790C (en) | Thermal barrier coatings and processes | |
US20110171488A1 (en) | Thermal barrier coating systems | |
CN109706418A (zh) | 一种双陶瓷层结构8ysz热障涂层及制备方法 | |
US20150233256A1 (en) | Novel architectures for ultra low thermal conductivity thermal barrier coatings with improved erosion and impact properties | |
CN108264232B (zh) | 抗氧化、耐腐蚀、抗冲击的高温搪瓷涂层及其制备方法 | |
CN107699844B (zh) | 一种热障抗烧蚀复合涂层及其制备方法 | |
JP7232295B2 (ja) | 基材上に高温保護層を接合するための付着促進層、並びにそれの製造方法 | |
KR101681195B1 (ko) | 자가치유능을 갖는 열차폐 코팅 시스템 | |
An et al. | Microstructure and thermal cycle resistance of plasma sprayed mullite coatings made from secondary mullitized natural andalusite powder | |
CN111944334A (zh) | 一种纳米金属陶瓷涂料 | |
Das et al. | Thermal cyclic behavior of glass–ceramic bonded thermal barrier coating on nimonic alloy substrate | |
Sainz et al. | Protective Si–Al–O–Y glass coatings on stainless steel in situ prepared by combustion flame spraying | |
CN105063541A (zh) | 一种具有吸音隔热功能的热障涂层及其制作方法 | |
CN105063544A (zh) | 一种纳米颗粒防电磁干扰的热障涂层及其制作方法 | |
CN101832710A (zh) | 用于熔化钛合金的坩锅 | |
CN105112847A (zh) | 一种抗静电耐氧化的热障涂层及其制作方法 | |
JP2015183195A (ja) | 耐食性被膜、伝熱管及びその製造方法 | |
CN105112842A (zh) | 一种含有隔热陶瓷层的热障涂层及其制作方法 | |
CN105112843A (zh) | 一种耐腐蚀的热障涂层及其制作方法 | |
CN108707897A (zh) | 排气管陶瓷涂层及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090327 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110922 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111007 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120106 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120112 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120206 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120209 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120306 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120926 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130128 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20130322 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130515 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130613 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5296421 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |