JP5289050B2 - ポリマーによる洗濯洗浄剤の清浄力向上 - Google Patents
ポリマーによる洗濯洗浄剤の清浄力向上 Download PDFInfo
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- JP5289050B2 JP5289050B2 JP2008515077A JP2008515077A JP5289050B2 JP 5289050 B2 JP5289050 B2 JP 5289050B2 JP 2008515077 A JP2008515077 A JP 2008515077A JP 2008515077 A JP2008515077 A JP 2008515077A JP 5289050 B2 JP5289050 B2 JP 5289050B2
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- acid
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- polyethylene glycol
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- XZJZNZATFHOMSJ-KTKRTIGZSA-N cis-3-dodecenoic acid Chemical compound CCCCCCCC\C=C/CC(O)=O XZJZNZATFHOMSJ-KTKRTIGZSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
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- 125000005442 diisocyanate group Chemical group 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
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- ZITKDVFRMRXIJQ-UHFFFAOYSA-N dodecane-1,2-diol Chemical compound CCCCCCCCCCC(O)CO ZITKDVFRMRXIJQ-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
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- 229930182830 galactose Natural products 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000001046 glycoluril group Chemical class [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 1
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- 108010002430 hemicellulase Proteins 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 150000002454 idoses Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- IJFXRHURBJZNAO-UHFFFAOYSA-N meta--hydroxybenzoic acid Natural products OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 125000005527 methyl sulfate group Chemical group 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 229940044652 phenolsulfonate Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical group OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- AQWHMKSIVLSRNY-UHFFFAOYSA-N trans-Octadec-5-ensaeure Natural products CCCCCCCCCCCCC=CCCCC(O)=O AQWHMKSIVLSRNY-UHFFFAOYSA-N 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
Description
に相当する4級化脂肪酸トリエタノールアミンエステル塩である。本発明において利用をみることができる、典型的な例であるエステルクォートは、カプロン酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、ステアリン酸、オレイン酸、エライジン酸、アラキジン酸、ベヘン酸、エルカ酸、ならびに、例えば、天然の脂肪または油の高圧開裂で生じるような、それらの工業用混合物の系の生成物である。工業用C12/18ココナツ脂肪酸および特に部分硬化C16/18獣脂またはパーム脂肪酸ならびに少量のエライジン酸リッチC16/18脂肪酸が用いられる。4級化エステルの調製のため、脂肪酸およびトリエタノールアミンを、一般に1.1:1〜3:1のモル比で一般に使用する。エステルクォートの工業的利用性について、1.2:1〜2.2:1、好ましくは1.5:1〜1.9:1の添加比が特に有利であることが証明された。好ましく組み入れるエステルクォートは、1.5〜1.9の平均エステル化度を有する、モノ−、ジ−およびトリ−エステルの工業用混合物に相当し、工業用C16/18獣脂またはパーム脂肪酸(ヨード価0〜40)から誘導される。R1COは、16〜18個の炭素原子を含有するアシル基を表し、R2はR1COを表し、R3は水素原子を表し、R4はメチル基を表し、m、nおよびpはそれぞれ0を表し、Xはメチルスルフェートを表す式(I)の4級化脂肪酸トリエタノールアミンエステル塩は、特に有利であることが証明された。
のジエタノールアルキルアミンとの4級化エステル塩が、エステルクォートとして適当である。
の1,2−ジヒドロキシプロピルジアルキルアミンとの4級化エステル塩が、適当なエステルクォートのさらなる群として挙げられる。
スチレン、メチルメタクリレートおよびPluriol(登録商標)A2000Eをラジカル重合させた。
洗浄機: Miele W 918 Novotronic
一次洗浄性能: 単一洗浄工程、通常プログラム
洗浄温度: 40℃
測定: 3回
洗浄液容積: 18リットル
水硬度: 16°dH(ドイツ硬度)
総洗濯量: 清潔な洗濯物3.5kg
織布: 綿(1.1.10)
上記の条件で、汚れのない織布を、ポリマーP1を添加した、および添加しない洗浄剤(以下の組成を参照)を用いて3回洗浄し、各洗浄後に乾燥させた。3回の予備洗浄後、織布を、以下の汚れを用いて、手で汚した。
黒い靴墨 0.10g
ほこり/皮脂 0.10g
FAEOS 5%
C12/14 7 EO 12%
APG 2%
脂肪酸 C12−18 5%
グリセリン 5%
Tinopal(登録商標)CBS−X 0.1%
クエン酸塩 1%
ポリアクリレート 2%
プロテアーゼ +
アミラーゼ +
水 100%まで
Claims (12)
- スチレン、メチルメタクリレートおよびメチルポリエチレングリコールのモノマーの重合により得られる汚れ解離性ポリマーの、繊維製品を洗浄する際に洗浄剤の清浄力を強化するための使用。
- スチレン、メチルメタクリレートおよびメチルポリエチレングリコールのモノマーの重合により得られる汚れ解離性ポリマーの、汚れが付く以前に前記ポリマーの存在下で既に洗浄および/または後処理された繊維製品を洗浄する際に、洗浄剤の清浄力を強化するための使用。
- 前記繊維製品が綿からなる、または綿を含んでなる、請求項1または2に記載の使用。
- 前記ポリマーが、スチレン5〜40mol%、メチルメタクリレート20〜40mol%およびメチルポリエチレングリコール25〜65mol%とする分量から得られる、請求項1〜3のいずれかに記載の使用。
- 前記ポリマーがブロックポリマーである、請求項1〜4のいずれかに記載の使用。
- スチレン、メチルメタクリレートおよびメチルポリエチレングリコールのモノマーの重合により得られる汚れ解離性ポリマーと、ジカルボン酸およびポリマージオールまたはモノマージオールとポリマージオールの混合物であってもよいジオールとのポリエステル活性汚れ解離性ポリマーとの組み合わせの、繊維製品を洗浄する際に洗浄剤の清浄力を強化するための使用。
- スチレン、メチルメタクリレートおよびメチルポリエチレングリコールのモノマーの重合により得られる前記ポリマーの平均分子量が、10000D未満である、請求項1〜6のいずれかに記載の使用。
- スチレン、メチルメタクリレートおよびメチルポリエチレングリコールのモノマーから得られる汚れ解離性ポリマーを含んでなる洗浄剤。
- 0.1重量%〜2重量%の汚れ解離性ポリマーを含んでなる、請求項8に記載の洗浄剤。
- 汚れ解離性ポリマーを含んでなる粒子を付加的な固形の洗浄剤成分と混合する、請求項8または9に記載の洗浄剤の製造方法。
- 汚れ解離性ポリマーを含んでなる粒子を製造するために噴霧乾燥工程を用いる、請求項10に記載の製造方法。
- 汚れ解離性ポリマーを含んでなる粒子を製造するために圧縮コンパウンド工程を用いる、請求項10に記載の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005026522A DE102005026522B4 (de) | 2005-06-08 | 2005-06-08 | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
DE102005026522.7 | 2005-06-08 | ||
PCT/EP2006/004707 WO2006131195A1 (de) | 2005-06-08 | 2006-05-18 | Verstärkung der reinigungsleistung von waschmitteln durch polymer |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2008542509A JP2008542509A (ja) | 2008-11-27 |
JP2008542509A5 JP2008542509A5 (ja) | 2009-07-02 |
JP5289050B2 true JP5289050B2 (ja) | 2013-09-11 |
Family
ID=36922047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008515077A Expired - Fee Related JP5289050B2 (ja) | 2005-06-08 | 2006-05-18 | ポリマーによる洗濯洗浄剤の清浄力向上 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7431739B2 (ja) |
EP (1) | EP1888733B1 (ja) |
JP (1) | JP5289050B2 (ja) |
AT (1) | ATE461992T1 (ja) |
DE (2) | DE102005026522B4 (ja) |
ES (1) | ES2341674T3 (ja) |
PL (1) | PL1888733T3 (ja) |
WO (1) | WO2006131195A1 (ja) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
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ES2318622T3 (es) * | 2006-07-06 | 2009-05-01 | Clariant (Brazil) S.A. | Composicion esterquat concentrada. |
ES2360646T3 (es) * | 2006-07-06 | 2011-06-07 | Clariant (Brazil) S.A. | Composición suavizante líquida. |
GB201002245D0 (en) * | 2010-02-10 | 2010-03-31 | Xeros Ltd | Improved cleaning apparatus and method |
US9315621B2 (en) | 2010-03-17 | 2016-04-19 | Croda, Inc. | Polymeric surfactant |
GB201006076D0 (en) | 2010-04-12 | 2010-05-26 | Xeros Ltd | Novel cleaning apparatus and method |
GB201015277D0 (en) | 2010-09-14 | 2010-10-27 | Xeros Ltd | Novel cleaning method |
GB201100627D0 (en) | 2011-01-14 | 2011-03-02 | Xeros Ltd | Improved cleaning method |
GB201100918D0 (en) | 2011-01-19 | 2011-03-02 | Xeros Ltd | Improved drying method |
KR102004562B1 (ko) * | 2011-10-25 | 2019-07-26 | 헨켈 아게 운트 코 카게아아 | 세탁 과정에서의 오염 재부착방지제 및 방오제로서의 빗살형 또는 블록 공중합체의 용도 |
GB201212098D0 (en) | 2012-07-06 | 2012-08-22 | Xeros Ltd | New cleaning material |
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GB201320784D0 (en) | 2013-11-25 | 2014-01-08 | Xeros Ltd | Improved cleaning Apparatus and method |
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-
2005
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- 2006-05-18 WO PCT/EP2006/004707 patent/WO2006131195A1/de not_active Application Discontinuation
- 2006-05-18 ES ES06753699T patent/ES2341674T3/es active Active
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- 2006-05-18 AT AT06753699T patent/ATE461992T1/de active
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EP1888733A1 (de) | 2008-02-20 |
PL1888733T3 (pl) | 2010-08-31 |
ES2341674T3 (es) | 2010-06-24 |
DE102005026522A1 (de) | 2006-12-14 |
WO2006131195A1 (de) | 2006-12-14 |
EP1888733B1 (de) | 2010-03-24 |
ATE461992T1 (de) | 2010-04-15 |
DE502006006514D1 (de) | 2010-05-06 |
JP2008542509A (ja) | 2008-11-27 |
US7431739B2 (en) | 2008-10-07 |
US20080090746A1 (en) | 2008-04-17 |
DE102005026522B4 (de) | 2007-04-05 |
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