JP5345535B2 - 綿に作用する汚れ分離性セルロース誘導体含有洗濯洗剤 - Google Patents
綿に作用する汚れ分離性セルロース誘導体含有洗濯洗剤 Download PDFInfo
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- JP5345535B2 JP5345535B2 JP2009525995A JP2009525995A JP5345535B2 JP 5345535 B2 JP5345535 B2 JP 5345535B2 JP 2009525995 A JP2009525995 A JP 2009525995A JP 2009525995 A JP2009525995 A JP 2009525995A JP 5345535 B2 JP5345535 B2 JP 5345535B2
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- 239000002537 cosmetic Substances 0.000 description 1
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- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 description 1
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- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- IJFXRHURBJZNAO-UHFFFAOYSA-N meta--hydroxybenzoic acid Natural products OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 125000005527 methyl sulfate group Chemical group 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- BBJRXOJHZTYBJR-UHFFFAOYSA-N molecular hydrogen tetrahydrate Chemical compound O.O.O.O.[H][H] BBJRXOJHZTYBJR-UHFFFAOYSA-N 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- RYMZZMVNJRMUDD-HGQWONQESA-N simvastatin Chemical compound C([C@H]1[C@@H](C)C=CC2=C[C@H](C)C[C@@H]([C@H]12)OC(=O)C(C)(C)CC)C[C@@H]1C[C@@H](O)CC(=O)O1 RYMZZMVNJRMUDD-HGQWONQESA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- AQWHMKSIVLSRNY-UHFFFAOYSA-N trans-Octadec-5-ensaeure Natural products CCCCCCCCCCCCC=CCCCC(O)=O AQWHMKSIVLSRNY-UHFFFAOYSA-N 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Description
で表される四級化脂肪酸トリエタノールアミンエステル塩である。本発明において使用できるエステルクォートの典型例は、ヘキサン酸、オクタン酸、デカン酸、ラウリン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、ステアリン酸、オレイン酸、エライジン酸、アラキン酸、ベヘン酸、エルカ酸、およびそれらの工業用混合物(例えば、天然油脂の高圧分裂時に生じるもの)に基づく生成物である。好ましくは、工業用C12/18ココヤシ油脂肪酸、特に部分的硬化C16/18獣脂またはパーム油脂肪酸、およびエライジン酸リッチC16/18脂肪酸カットを使用する。四級化エステルを製造するため、一般に、脂肪酸およびトリエタノールアミンを、1.1:1〜3:1のモル比で使用できる。エステルクォートの応用工学的性質に関して、1.2:1〜2.2:1、好ましくは1.5:1〜1.9:1の使用比が特に有利であることがわかった。使用するのに好ましいエステルクォートは、1.5〜1.9の平均エステル化度を有するモノ−、ジ−およびトリエステルの工業用混合物に相当し、工業用C16/18獣脂またはパーム脂肪酸(ヨウ素価0〜40)から誘導される。R1COが16〜18個の炭素原子を含有するアシル基を示し、R2がR1COを示し、R3が水素を示し、R4がメチル基を示し、m、nおよびpが0を示し、Xがメチルスルフェートイオンを示す式(I)で表される四級化脂肪酸トリエタノールアミンエステル塩が特に有利であることがわかった。
で表される、カルボン酸とジエタノールアルキルアミンとの四級化エステル塩もエステルクォートとして適している。
で表される、カルボン酸と1,2−ジヒドロキシプロピルジアルキルアミンとの四級化エステル塩である。
下記成分を含有する液体状洗濯洗剤(V1)を、成分の単純混合により製造した。
同様に、水の量を減らして、平均メチル化度1.90および平均カルボキシアルキル化度0.01を有するメチルカルボキシプロピルセルロース1重量%(W1)、平均メチル化度1.90および平均カルボキシアルキル化度0.09を有するメチルカルボキシエチルセルロース1重量%(W2)、または平均メチル化度1.56および平均カルボキシアルキル化度0.03を有するメチルカルボキシエチルセルロース1重量%(W3)を含有する以外は同一成分からなる、洗濯洗剤も製造した。使用したセルロースエーテルは、セルロースとクロロメタンとの反応および続いての対応クロロアルカンカルボン酸との反応により得ることができ、それらの分子量は78,000Dであった。綿布地を以下のように処理した。
洗濯機: Miele W 918 Novotronic(登録商標)
予備洗濯の実施: 一槽式法、通常サイクル
洗濯温度: 40℃
槽容積: 15リットル
水の硬度: 16°dH
洗濯物の量: 3.5kgの清浄な洗濯物
測定数: 3
0.10g 口紅
0.10g 黒色靴クリーム
実施例1に記載したように洗濯実験を実施した。今回は、下記成分を含有する粒状洗濯洗剤V2を使用した。
同様に、硫酸ナトリウムの量を減らして、平均メチル化度1.90および平均カルボキシアルキル化度0.01を有するメチルカルボキシプロピルセルロース1重量%(W4)、平均メチル化度1.90および平均カルボキシアルキル化度0.09を有するメチルカルボキシエチルセルロース1重量%(W5)、または平均メチル化度1.56および平均カルボキシアルキル化度0.03を有するメチルカルボキシエチルセルロース1重量%(W6)を含有する以外は同一成分からなる、洗濯洗剤も使用した。以下の洗濯結果(dde値)を得た。
Claims (13)
- 綿からなるかまたは綿を含有する布地の洗濯に使用する洗濯洗剤の洗浄性能増強剤であって、セルロースのアルキル化およびカルボキシアルキル化により得られ、かつ無水グリコースモノマー単位あたり平均して0.4〜2.7個のアルキル基および0.001〜0.3個の、アルキル基が2または3個の炭素原子を有するカルボキシアルキル基を含有する汚れ分離性セルロース誘導体からなる洗浄性能増強剤。
- 綿からなるかまたは綿を含有し、かつ汚れが付着する前に汚れ分離性セルロース誘導体存在下で既に洗濯および/または後処理した布地の洗濯に使用する洗濯洗剤の洗浄性能増強剤であって、セルロースのアルキル化およびカルボキシアルキル化により得られ、かつ無水グリコースモノマー単位あたり平均して0.4〜2.7個のアルキル基および0.001〜0.3個の、アルキル基が2または3個の炭素原子を有するカルボキシアルキル基を含有する汚れ分離性セルロース誘導体からなる洗浄性能増強剤。
- 布地の洗濯に使用する洗濯洗剤の洗浄性能増強剤であって、セルロースのアルキル化およびカルボキシアルキル化により得られ、かつ無水グリコースモノマー単位あたり平均して0.4〜2.7個のアルキル基および0.001〜0.3個の、アルキル基が2または3個の炭素原子を有するカルボキシアルキル基を含有する汚れ分離性セルロース誘導体と、ジカルボン酸およびジオールから調製されたポリエステル活性汚れ分離性ポリマーとの組み合わせからなる洗浄性能増強剤。
- 該アルキル基およびカルボキシアルキル基を含有する汚れ分離性セルロース誘導体が、C1〜C10 基でアルキル化されている、請求項1〜3のいずれかに記載の洗浄性能増強剤。
- 該アルキル基およびカルボキシアルキル基を含有する汚れ分離性セルロース誘導体中に、無水グリコースモノマー単位あたり平均して、0.5〜2.5個のアルキル基、および0.002〜0.2個のカルボキシアルキル基を含有する、請求項1〜4のいずれかに記載の洗浄性能増強剤。
- 該アルキル基およびカルボキシアルキル基を含有する汚れ分離性セルロース誘導体の平均分子量が10,000D〜150,000Dの範囲である、請求項1〜5のいずれかに記載の洗浄性能増強剤。
- 洗濯洗剤は、5重量%〜70重量%の過酸素系漂白剤を含有する、請求項1〜6のいずれかに記載の洗浄性能増強剤。
- 洗濯洗剤と、セルロースのアルキル化およびカルボキシアルキル化により得られ、かつセルロース誘導体が無水グリコースモノマー単位あたり平均して0.4〜2.7個のアルキル基および0.001〜0.3個の、アルキル基が2または3個の炭素原子を有するカルボキシアルキル基を含有する汚れ分離性セルロース誘導体とを使用して実施する、綿からなるかまたは綿を含有する布地の洗濯方法。
- 漂白剤含有洗濯洗剤を用いて実施する実際の洗濯作業後に、布地をセルロース誘導体含有後処理剤と接触させる、請求項8に記載の方法。
- 汚れ分離性セルロース誘導体およびエステルクォートを含有する洗濯後処理剤を使用する、請求項9に記載の方法。
- 製剤が5重量%〜25重量%の量でエステルクォートを含有する、請求項10に記載の方法。
- 製剤が0.1重量%〜2重量%の量でセルロース誘導体を含有する、請求項8〜11のいずれかに記載の方法。
- セルロースのアルキル化およびカルボキシアルキル化により得られ、かつ無水グリコースモノマー単位あたり平均して0.4〜2.7個のアルキル基および0.001〜0.3個の、アルキル基が2または3個の炭素原子を有するカルボキシアルキル基を有する、汚れ分離性セルロース誘導体を含有する、洗濯洗剤。
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DE102006039873A DE102006039873B4 (de) | 2006-08-25 | 2006-08-25 | Verstärkung der Reinigungsleistung von Waschmitteln durch baumwollaktives schmutzablösevermögendes Cellulosederivat |
DE102006039873.4 | 2006-08-25 | ||
PCT/EP2007/056339 WO2008022827A1 (de) | 2006-08-25 | 2007-06-26 | Waschmittel mit baumwollaktivem schmutzablösevermögendem cellulosederivat |
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JP2010501690A JP2010501690A (ja) | 2010-01-21 |
JP2010501690A5 JP2010501690A5 (ja) | 2011-08-18 |
JP5345535B2 true JP5345535B2 (ja) | 2013-11-20 |
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US (1) | US20090137444A1 (ja) |
EP (1) | EP2054495B1 (ja) |
JP (1) | JP5345535B2 (ja) |
DE (1) | DE102006039873B4 (ja) |
ES (1) | ES2388791T3 (ja) |
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Families Citing this family (12)
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WO2014200656A1 (en) | 2013-06-13 | 2014-12-18 | Danisco Us Inc. | Alpha-amylase from streptomyces umbrinus |
WO2014200657A1 (en) | 2013-06-13 | 2014-12-18 | Danisco Us Inc. | Alpha-amylase from streptomyces xiamenensis |
WO2014200658A1 (en) | 2013-06-13 | 2014-12-18 | Danisco Us Inc. | Alpha-amylase from promicromonospora vindobonensis |
EP3011020A1 (en) | 2013-06-17 | 2016-04-27 | Danisco US Inc. | Alpha-amylase from bacillaceae family member |
EP3052622B1 (en) | 2013-10-03 | 2018-09-19 | Danisco US Inc. | Alpha-amylases from a subset of exiguobacterium, and methods of use, thereof |
WO2015050723A1 (en) | 2013-10-03 | 2015-04-09 | Danisco Us Inc. | Alpha-amylases from exiguobacterium, and methods of use, thereof |
MX2016006489A (es) | 2013-11-20 | 2016-08-03 | Danisco Us Inc | Alfa-amilasas variantes que tienen susceptibilidad reducida a la escision por proteasas y metodos de uso. |
DE102015224954A1 (de) | 2015-12-11 | 2017-06-14 | Henkel Ag & Co. Kgaa | Reinigungsverstärkende Celluloseether |
WO2017173324A2 (en) | 2016-04-01 | 2017-10-05 | Danisco Us Inc. | Alpha-amylases, compositions & methods |
WO2017173190A2 (en) | 2016-04-01 | 2017-10-05 | Danisco Us Inc. | Alpha-amylases, compositions & methods |
JP7149841B2 (ja) * | 2018-12-26 | 2022-10-07 | ライオン株式会社 | トイレ用液体洗浄剤組成物及びトイレ用液体洗浄剤製品 |
DE102019218867A1 (de) * | 2019-12-04 | 2021-06-10 | Henkel Ag & Co. Kgaa | Oberflächenaktive Agentien |
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GB678445A (en) * | 1949-05-27 | 1952-09-03 | Frederick Joseph Pollok | Improvements in or relating to aqueous solutions containing soapless detergents |
US3325414A (en) * | 1963-10-01 | 1967-06-13 | Colgate Palmolive Co | Heavy duty detergent composition containing a quaternary ammonium salt |
US3941771A (en) * | 1973-08-22 | 1976-03-02 | Fmc Corporation | Dextrin carboxylates and their use as detergent builders |
US4029590A (en) * | 1973-08-22 | 1977-06-14 | Fmc Corporation | Dextrin carboxylates and their use as detergent builders |
US4250305A (en) * | 1978-09-01 | 1981-02-10 | Kohjin Co., Ltd. | Process for preparing cellulose ether |
US4230590A (en) * | 1978-12-11 | 1980-10-28 | Colgate Palmolive Company | Detergent softener compositions containing a soap-cellulose ether mixture |
US4311833A (en) * | 1979-03-06 | 1982-01-19 | Daicel Chemical Industries Ltd. | Process for preparing ethylcarboxymethylcellulose |
ATE39126T1 (de) * | 1982-07-27 | 1988-12-15 | Procter & Gamble | Fluessige reinigungsmittelzusammensetzungen, eine koazervatmischung aus alkylcellulose enthaltend und carboxymethylcellulose und verfahren zu deren herstellung. |
DE3329400A1 (de) * | 1983-08-13 | 1985-02-28 | Henkel KGaA, 4000 Düsseldorf | Vergrauungsverhuetender zusatz fuer phosphatfreie und phosphatarme waschmittel |
GB8519046D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent compositions |
DE4134914A1 (de) * | 1991-10-23 | 1993-04-29 | Henkel Kgaa | Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen |
US5837666A (en) * | 1994-06-30 | 1998-11-17 | The Procter & Gamble Company | Detergent compositions comprising methyl cellulose ether |
US5916863A (en) * | 1996-05-03 | 1999-06-29 | Akzo Nobel Nv | High di(alkyl fatty ester) quaternary ammonium compound from triethanol amine |
US6833347B1 (en) * | 1997-12-23 | 2004-12-21 | The Proctor & Gamble Company | Laundry detergent compositions with cellulosic polymers to provide appearance and integrity benefits to fabrics laundered therewith |
DE29905721U1 (de) * | 1999-03-27 | 1999-06-10 | Henkel KGaA, 40589 Düsseldorf | Alkylbenzolsulfonat-Granulate |
GB2351501A (en) * | 1999-07-01 | 2001-01-03 | Procter & Gamble | Detergent compositions or components |
US6861396B2 (en) * | 2000-10-20 | 2005-03-01 | The Procter & Gamble Company | Compositions for pre-treating shoes and methods and articles employing same |
SE520715C2 (sv) * | 2001-12-03 | 2003-08-12 | Akzo Nobel Nv | Förfarande för framställning av metylcellulosaetrar |
ES2309129T3 (es) * | 2002-10-02 | 2008-12-16 | Cognis Ip Management Gmbh | Agente de lavado solidos. |
EP1592764B1 (de) * | 2003-02-10 | 2007-01-03 | Henkel Kommanditgesellschaft auf Aktien | Erhöhung der wasseraufnahmefähigkeit von textilien |
ES2275207T5 (es) * | 2003-02-10 | 2011-12-09 | HENKEL AG & CO. KGAA | Agente de lavado, que contiene agentes de blanqueo, con derivado de la celulosa con capacidad para el desprendimiento de la suciedad, con actividad sobre el algodón. |
DE502004003950D1 (de) * | 2003-02-10 | 2007-07-12 | Henkel Kgaa | Verstärkung der reinigungsleistung von waschmitteln durch cellulosederivat und hygroskopisches polymer |
DE10351321A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch eine Kombination von Cellulosderivaten |
US20070056119A1 (en) * | 2003-06-27 | 2007-03-15 | Gardner Robb R | Method for treating hydrophilic stains in a lipophlic fluid system |
US20050246841A1 (en) * | 2004-05-05 | 2005-11-10 | The Procter & Gamble Company | Textile benefit compositions |
EP1642887A1 (de) * | 2004-09-18 | 2006-04-05 | Cognis IP Management GmbH | Quaternisierte Fettsäureamidoamine |
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2007
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- 2007-06-26 WO PCT/EP2007/056339 patent/WO2008022827A1/de active Application Filing
- 2007-06-26 EP EP07765614A patent/EP2054495B1/de active Active
- 2007-06-26 JP JP2009525995A patent/JP5345535B2/ja not_active Expired - Fee Related
- 2007-06-26 PL PL07765614T patent/PL2054495T3/pl unknown
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PL2054495T3 (pl) | 2012-11-30 |
ES2388791T3 (es) | 2012-10-18 |
WO2008022827A1 (de) | 2008-02-28 |
EP2054495B1 (de) | 2012-06-06 |
JP2010501690A (ja) | 2010-01-21 |
DE102006039873B4 (de) | 2013-10-31 |
DE102006039873A1 (de) | 2008-03-20 |
US20090137444A1 (en) | 2009-05-28 |
EP2054495A1 (de) | 2009-05-06 |
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