JP5269101B2 - 水溶性パウチ - Google Patents
水溶性パウチ Download PDFInfo
- Publication number
- JP5269101B2 JP5269101B2 JP2010545595A JP2010545595A JP5269101B2 JP 5269101 B2 JP5269101 B2 JP 5269101B2 JP 2010545595 A JP2010545595 A JP 2010545595A JP 2010545595 A JP2010545595 A JP 2010545595A JP 5269101 B2 JP5269101 B2 JP 5269101B2
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- JP
- Japan
- Prior art keywords
- pouch
- composition
- acid
- compartment
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
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- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
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- PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
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- ZMRUPTIKESYGQW-UHFFFAOYSA-N propranolol hydrochloride Chemical compound [H+].[Cl-].C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 ZMRUPTIKESYGQW-UHFFFAOYSA-N 0.000 description 1
- 101150002764 purA gene Proteins 0.000 description 1
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- 229910001415 sodium ion Inorganic materials 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
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- 239000003760 tallow Substances 0.000 description 1
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- DCQJDRNKCUQEMA-UHFFFAOYSA-N tetradecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCCCC(=O)OO DCQJDRNKCUQEMA-UHFFFAOYSA-N 0.000 description 1
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- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
- B65D81/3261—Flexible containers having several compartments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Bag Frames (AREA)
- Package Specialized In Special Use (AREA)
- Wrappers (AREA)
Description
任意の従来の洗浄成分を、本発明の多区画パウチの組成物の一部として使用することができる。ここに示す濃度は重量パーセントであり、パウチの全組成物を指す。洗剤組成物は、ビルダーを含む、又は含まない、並びに漂白剤、漂白活性化剤、漂白触媒、界面活性剤、アルカリ源、酵素、ポリマー分散剤、耐食剤(例えば、ケイ酸ナトリウム)及びケア剤から選択され得る1つ以上の洗剤活性成分を含むことができる。極めて好ましい洗剤成分としては、ビルダー化合物、アルカリ源、界面活性剤、酵素及び追加の漂白剤が挙げられる。
本明細書に使用するのに好適なビルダーとしては、水溶性硬度イオン錯体を形成するビルダー(封鎖性ビルダー)、例えば、シトレート類、及びポリホスフェート類、例えばトリポリリン酸ナトリウム及びトリポリリン酸ナトリウム六水和物、トリポリリン酸カリウム、及び、トリポリリン酸ナトリウムとトリポリリン酸カリウムの混合塩、並びに硬度沈殿物を形成するビルダー(沈殿性ビルダー)、例えばカーボーネート類、例えば炭酸ナトリウムが挙げられる。
好ましいケイ酸塩は、ケイ酸ナトリウム、例えば二ケイ酸ナトリウム、メタケイ酸ナトリウム、及び結晶性フィロケイ酸塩などである。ビルダーは典型的に組成物の約1〜約20重量%、好ましくは約5〜約15重量%の濃度で存在する。
無機及び有機漂白剤は、本明細書に使用するのに適した洗浄活性物質である。無機漂白剤としては、過ホウ酸塩、過炭酸塩、過リン酸塩、過硫酸塩、及び過ケイ酸塩のような過水和物塩が挙げられる。無機過水和物塩は、通常アルカリ金属塩である。無機過水和物塩は、追加的保護なしで、結晶性固体として包含されてもよい。あるいは、塩はコーティングされることができる。
漂白活性化剤は、典型的に、60℃以下の温度で洗浄中に漂白作用を増強する有機過酸前駆体である。本明細書に用いるのに好適な漂白活性化剤としては、過加水分解条件下で好ましくは1〜10個の炭素原子、特に2〜4個の炭素原子を有する脂肪族ペルオキシカルボン酸、及び/又は任意に置換された過安息香酸を与える化合物が挙げられる。好適な物質は、指定された炭素原子数のO−アシル及び/若しくはN−アシル基、並びに/又は任意に置換されたベンゾイル基を有する。好ましいのは、ポリアシル化アルキレンジアミン、特にテトラアセチルエチレンジアミン(TAED)、アシル化トリアジン誘導体、特に1,5−ジアセチル−2,4−ジオキソヘキサヒドロ−1,3,5−トリアジン(DADHT)、アシル化グリコールウリル、特にテトラアセチルグリコールウリル(TAGU)、N−アシルイミド、特にN−ノナノイルスクシンイミド(NOSI)、アシル化フェノールスルホネート、特にn−ノナノイル−又はイソノナノイルオキシベンゼンスルホネート(n−又はイソ−NOBS)、無水カルボン酸、特に無水フタル酸、アシル化多価アルコール、特にトリアセチン、二酢酸エチレングリコール及び2,5−ジアセトキシ−2,5−ジヒドロフラン及び同様にトリエチルアセチルシトレート(TEAC)である。本発明の組成物中に含まれている場合、漂白活性化剤は、組成物の約0.1〜約10重量%、好ましくは約0.5〜約2重量%の濃度である。
本明細書で使用するのに好ましい漂白触媒としては、トリアザシクロノナンのマンガン錯体及び関連する錯体(米国特許第4246612A号、同第5227084A号);ビスピリジルアミンのCo、Cu、Mn、及びFe錯体、並びに関連する錯体(米国特許第5114611A号);並びにペンタミンアセテートのコバルト(III)錯体及び関連する錯体(米国特許第4810410A号)が挙げられる。本明細書に用いるのに好適な漂白触媒の完全な記述は、国際公開第99/06521号、34頁、26行〜40頁、16行に見出すことができる。本発明の組成物中に含まれている場合、漂白活性化剤は、組成物の約0.1〜約10重量%、好ましくは約0.5〜約2重量%の濃度である。
本明細書に用いるのに好ましい界面活性剤は、単独で又は他の成分(即ち、泡抑制剤)と組み合わせて、低起泡性である。本明細書に用いるのに好ましいのは、低及び高曇点非イオン性界面活性剤、並びにこれらの混合物であり、非イオン性アルコキシル化界面活性剤(特にC6〜C18一級アルコールから誘導されるエトキシレート)、エトキシル化−プロポキシル化アルコール(例えば、Olin CorporationのPoly−Tergent(登録商標)SLF18)、エポキシ末端保護ポリ(オキシアルキル化)アルコール(例えば、Olin CorporationのPoly−Tergent(登録商標)SLF18B、国際公開第94/22800A号を参照)、エーテル末端保護ポリ(オキシアルキル化)アルコール界面活性剤、BASF−Wyandotte Corp.(Wyandotte,Michigan)によるPLURONIC(登録商標)、REVERSED PLURONIC(登録商標)、及びTETRONIC(登録商標)のようなブロックポリオキシエチレン−ポリオキシプロピレンポリマー化合物;C12〜C20アルキルアミンオキシド(本明細書に用いるのに好ましいアミンオキシドとしては、ラウリルジメチルアミンオキシド及びヘキサデシルジメチルアミンオキシドが挙げられる)のような両性界面活性剤、並びにMiranol(商標)C2Mのようなアルキルアンフォカルボン酸界面活性剤;ベタイン及びスルタインのような双極性界面活性剤;並びにこれらの混合物が挙げられる。本明細書で好適な界面活性剤は、例えば、米国特許第3,929,678A号、同第4,259,217A号、欧州特許第0414 549A号、国際公開第93/08876A号、及び同第93/08874A号に開示されている。界面活性剤は、典型的に洗剤組成物の約0.2重量%〜約30重量%、より好ましくは約0.5重量%〜約10重量%、最も好ましくは約1重量%〜約5重量%の濃度で存在する。
(式中、R3は8〜26個の炭素原子、好ましくは8〜18個の炭素原子を含有する、アルキル、ヒドロキシアルキル、アシルアミドプロピル及びアルキルフェニル基、又はこれらの混合物から選択され、R4は2〜3個の炭素原子、好ましくは2個の炭素原子を含有するアルキレン又はヒドロキシアルキレン基、又はこれらの混合物であり、xは0〜5、好ましくは0〜3であり、各R5は1〜3個、好ましくは1〜2個の炭素原子を含有するアルキル又はヒドロキシアルキル基、又は1〜3個、好ましくは1個のエチレンオキシド基を含有するポリエチレンオキシド基である)。R5基は、例えば酸素原子又は窒素原子を介して互いに結合させ、環状構造を形成できる。
好適なプロテアーゼとしては、サブチリシン(EC 3.4.21.62)のような、中性又はアルカリ性の微生物セリンプロテアーゼなどの、メタロプロテアーゼ及びセリンプロテアーゼが挙げられる。好適なプロテアーゼには、動物、植物、又は微生物起源のプロテアーゼが挙げられる。微生物起源が好ましい。化学操作された又は遺伝子操作された突然変異体が含まれる。プロテアーゼはセリンプロテアーゼ、好ましくは、アルカリ性微生物プロテアーゼ又はキモトリプシン若しくはトリプシン様プロテアーゼである。中性又はアルカリ性のプロテアーゼには以下のものが挙げられる:
(a)サブチリシン(EC 3.4.21.62)、特にバチルスから誘導されたもの、例えば米国特許第6,312,936B1号、同第5,679,630号、同第4,760,025号、DEA6022216A1号、及び同第6022224A1号に記載されているバチルス・レンタス、B.アルカロフィルス、B.サブチリス、B.アミロリケファシエンス、バチルス・プミラス、及びバチルス・ギブソニィなど。
(a)国際公開第94/02597号、同第94/18314号、同第96/23874号、及び同第97/43424号に記載の変異体、特に、国際公開第96/23874号のSEQ ID No.2としてリストされた酵素に対して、以下の位置:15、23、105、106、124、128、133、154、156、181、188、190、197、202、208、209、243、264、304、305、391、408及び444のうちの1つ以上が置換された変異体。
26、30、33、82、37、106、118、128、133、149、150、160、178、182、186、193、203、214、231、256、257、258、269、270、272、283、295、296、298、299、303、304、305、311、314、315、318、319、339、345、361、378、383、419、421、437、441、444、445、446、447、450、461、471、482、484のうちの1つ以上が置換された変異体であって、また、好ましくはD183*及びG184*の欠損を含有する変異体。
本明細書で使用するのに好適な泡抑制剤は、低曇点を有する非イオン性界面活性剤を含む。「低曇点」非イオン性界面活性剤とは、本明細書で使用するとき、30℃未満、好ましくは約20℃未満、更に好ましくは約10℃未満、最も好ましくは約7.5℃未満の曇点を有する非イオン性界面活性剤系成分として定義される。典型的な低曇点の非イオン性界面活性剤としては、非イオン性アルコキシル化界面活性剤、特に一級アルコールから誘導されるエトキシレート、及びポリオキシプロピレン/ポリオキシエチレン/ポリオキシプロピレン(PO/EO/PO)リバースブロックポリマーが挙げられる。また、このような低曇点の非イオン性界面活性剤としては、例えば、エトキシル化−プロポキシル化アルコール(例えば、BASFのPoly−Tergent(登録商標)SLF18)及びエポキシ末端保護されたポリ(オキシアルキル化)アルコール(例えば、米国特許第5,576,281A号に記載されているような非イオン性物質のBASFのPoly−Tergent(登録商標)SLF18Bシリーズ)が挙げられる。
(式中、R1は平均約7〜約12個の炭素原子を有する直鎖アルキル炭化水素であり、R2は約1〜約4個の炭素原子を有する直鎖アルキル炭化水素であり、R3は約1〜約4個の炭素原子を有する直鎖アルキル炭化水素であり、xは約1〜約6の整数であり、yは約4〜約15の整数であり、zは約4〜約25の整数である)。
RIO(RIIO)nCH(CH3)ORIII
を有するエーテル末端処理されたポリ(オキシアルキル化)である
(式中、RIは約7〜約12個の炭素原子を有する、直鎖又は分枝状、飽和又は不飽和、置換又は非置換、脂肪族又は芳香族の炭化水素ラジカルからなる群から選択され、RIIは同じでも又は異なってもよく、任意の所与の分子中で分枝状又は直鎖C2〜C7アルキレンからなる群から独立に選択され;nは1〜約30の数であり);RIIIは、
(i)1〜3のヘテロ原子を含有する、4〜8員の置換又は非置換の複素環、及び
(ii)約1〜約30の炭素原子を有する直鎖又は分枝鎖、飽和又は不飽和、置換又は非置換、環式又は非環式、脂肪族又は芳香族の炭化水素ラジカル;からなる群から選択され、
(b)ただし、R2が(ii)の場合、(A)R1の少なくとも1つがC2〜C3アルキレン以外であるか、又は(B)R2が6〜30の炭素原子を有し、更にR2が8〜18の炭素原子を有するときには、RはC1〜C5アルキル以外である。
ポリマーが使用される場合、組成物の約0.1重量%〜約50重量%、好ましくは1重量%〜約20重量%、より好ましくは2重量%〜10重量%の任意の好適な量で使用される。スルホン化/カルボキシル化ポリマーは、本発明のパウチに含有される組成物に特に好適である。
実施例では、略された成分の識別表示は、次の意味を有する。
Claims (5)
- 複数の水溶性フィルムを有する洗剤多区画パウチであって、少なくとも2つの前記フィルムが異なる溶解度を有し、複数の区画を形成し、前記パウチは、他の区画の上に重ねて置かれた、2つの並んだ区画を含み、少なくとも2つの異なる区画は2つの異なる組成物を含有し、
前記区画の1つは酵素及び60℃より高い曇点を有する非イオン性界面活性剤を含む液体形態の組成物0.5gから4gを含有し、他の区画は漂白剤を含む固体形態の組成物10gから26gを含有し、
前記酵素含有組成物を含有する前記区画を形成する前記フィルムの1つが、前記漂白剤含有組成物を含有する前記区画を形成する前記フィルムに先立ってその内容物を放出するような溶解度を有し、
前記パウチは5,000から45,000ダルトンの分子量を有するスルホン化/カルボキシル化ポリマーを含有し、前記ポリマーは前記パウチ内に含有された全組成物の2重量%から10重量%で含まれる
洗剤多区画パウチ。 - 前記パウチが約10mL〜約30mLの容積を有する、請求項1に記載の洗剤パウチ。
- 前記液体組成物の少なくとも1つが、すすぎ補助剤組成物であり、前記すすぎ補助剤を含有する前記区画を形成する前記フィルムが、本洗い中に不溶性であり、自動食器洗浄機のすすぎサイクル中にその内容物を放出するような溶解度を有する、請求項1又は2に記載の洗剤パウチ。
- 請求項1に記載の洗剤パウチを使用して、自動食器洗浄機で食器を洗浄する方法であって、
a)前記パウチを前記ディスペンサーの中に配置し、それを前記本洗いサイクル中に放出する工程と、
b)少なくとも1つの酵素含有組成物を、前記漂白剤含有組成物の送達に先立って洗浄溶液の中に放出する工程と、を含む、方法。 - 請求項3に記載の洗剤パウチを使用して、自動食器洗浄機で食器を洗浄する方法であって、
c)前記パウチを前記ディスペンサーの中に配置し、それを前記本洗いサイクル中に放出する工程と、
d)組成物を、前記本洗いサイクル中に前記洗浄液の中に、かつ少なくとも1つの液体組成物を、前記すすぎサイクル中にすすぎ溶液の中に放出する工程と、を含む、方法。
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HUE031196T2 (en) | 2017-07-28 |
JP2011510880A (ja) | 2011-04-07 |
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PL2345599T3 (pl) | 2017-01-31 |
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