JP5237376B2 - 改良した加工性を有する軟質ポリオレフィン組成物 - Google Patents
改良した加工性を有する軟質ポリオレフィン組成物 Download PDFInfo
- Publication number
- JP5237376B2 JP5237376B2 JP2010521377A JP2010521377A JP5237376B2 JP 5237376 B2 JP5237376 B2 JP 5237376B2 JP 2010521377 A JP2010521377 A JP 2010521377A JP 2010521377 A JP2010521377 A JP 2010521377A JP 5237376 B2 JP5237376 B2 JP 5237376B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- composition
- copolymer
- mfr
- polyolefin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 36
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 23
- 239000004519 grease Substances 0.000 claims abstract description 16
- -1 polypropylene Polymers 0.000 claims abstract description 15
- 239000004743 Polypropylene Substances 0.000 claims abstract description 13
- 229920001155 polypropylene Polymers 0.000 claims abstract description 12
- 238000001746 injection moulding Methods 0.000 claims abstract description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 25
- 229920001577 copolymer Polymers 0.000 claims description 25
- 229920001971 elastomer Polymers 0.000 claims description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
- 239000005977 Ethylene Substances 0.000 claims description 16
- 239000000806 elastomer Substances 0.000 claims description 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000012188 paraffin wax Substances 0.000 claims description 13
- 239000008096 xylene Substances 0.000 claims description 13
- 239000004711 α-olefin Substances 0.000 claims description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 229920001519 homopolymer Polymers 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 229920001384 propylene homopolymer Polymers 0.000 claims description 4
- 229920001748 polybutylene Polymers 0.000 abstract description 16
- 235000019271 petrolatum Nutrition 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- 150000002978 peroxides Chemical class 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 5
- 229920001198 elastomeric copolymer Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000004264 Petrolatum Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229940066842 petrolatum Drugs 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229920005606 polypropylene copolymer Polymers 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 229920006342 thermoplastic vulcanizate Polymers 0.000 description 3
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07114770.6 | 2007-08-22 | ||
| EP07114770 | 2007-08-22 | ||
| US96592507P | 2007-08-23 | 2007-08-23 | |
| US60/965,925 | 2007-08-23 | ||
| PCT/EP2008/059906 WO2009024435A1 (en) | 2007-08-22 | 2008-07-29 | Soft polyolefin compositions with improved processability |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010536967A JP2010536967A (ja) | 2010-12-02 |
| JP2010536967A5 JP2010536967A5 (enExample) | 2011-09-01 |
| JP5237376B2 true JP5237376B2 (ja) | 2013-07-17 |
Family
ID=39832618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010521377A Active JP5237376B2 (ja) | 2007-08-22 | 2008-07-29 | 改良した加工性を有する軟質ポリオレフィン組成物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9029455B2 (enExample) |
| EP (1) | EP2181155B1 (enExample) |
| JP (1) | JP5237376B2 (enExample) |
| KR (1) | KR101499274B1 (enExample) |
| CN (1) | CN101784603B (enExample) |
| AT (1) | ATE496095T1 (enExample) |
| DE (1) | DE602008004668D1 (enExample) |
| WO (1) | WO2009024435A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5608241B2 (ja) | 2009-11-17 | 2014-10-15 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 改善された加工性を有する軟質ポリオレフィン組成物 |
| EP2504393B1 (en) | 2009-11-24 | 2014-04-16 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions having improved sealability |
| WO2012000884A1 (en) * | 2010-06-30 | 2012-01-05 | Basell Poliolefine Italia Srl | Cross-linked polyolefin composition |
| CN104262785B (zh) * | 2014-09-25 | 2016-08-24 | 广东银禧科技股份有限公司 | 一种低气味、高流动性的软触感聚烯烃组合物及其制备方法 |
| JP7700224B2 (ja) * | 2020-10-22 | 2025-06-30 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 射出成形用ポリマー組成物 |
| US20250059362A1 (en) | 2021-12-23 | 2025-02-20 | Basell Poliolefine Italia S.R.L. | Soft polyolefin composition |
| EP4477714A1 (en) * | 2022-02-07 | 2024-12-18 | Sumitomo Bakelite Co.Ltd. | Resin composition for injection molding and method for injection-molding this composition |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3322708A (en) * | 1965-05-17 | 1967-05-30 | Exxon Research Engineering Co | Polypropylene compositions |
| US4078020A (en) * | 1976-04-02 | 1978-03-07 | Ciba-Geigy Corporation | Thermoplastic elastomers comprising ethylene-α-olefin copolymer, polypropylene and polybutene |
| US4677025A (en) * | 1985-08-30 | 1987-06-30 | Shell Oil Company | Unique molecular weight distribution polybutylene blend and film |
| JPH05140384A (ja) * | 1991-11-18 | 1993-06-08 | Chisso Corp | 熱可塑性エラストマー組成物 |
| US5238635A (en) * | 1992-04-16 | 1993-08-24 | Himont Incorporated | Process for treatment of particulate olefin polymer, resulting treated particles and method for using treating particles |
| ES2196241T3 (es) * | 1996-11-26 | 2003-12-16 | Basell North America Inc | Una composicion de poliolefina para la fabricacion de hojas con extrusiones con retencion mejorada de granulacion. |
| IT1292027B1 (it) * | 1997-05-29 | 1999-01-25 | Montell North America Inc | Miscela poliolefinica contenente poli(1-butene) |
| US6277918B1 (en) | 1998-05-06 | 2001-08-21 | Montell Technology Company Bv | Polyolefin compositions and films obtained therefrom |
| US6667364B2 (en) * | 2000-12-29 | 2003-12-23 | Advanced Elastomer Systems Lp | Processable polyethylene/EPDM thermoplastic vulcanizates |
| EP1279699A1 (en) * | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
| ZA200608622B (en) | 2004-05-05 | 2008-06-25 | Dow Global Technologies Inc | Scratch resistant propylene polymer composition |
| WO2006098142A1 (ja) * | 2005-03-15 | 2006-09-21 | Kaneka Corporation | キャップライナー用組成物 |
-
2008
- 2008-07-29 DE DE200860004668 patent/DE602008004668D1/de active Active
- 2008-07-29 AT AT08775367T patent/ATE496095T1/de not_active IP Right Cessation
- 2008-07-29 CN CN2008801039834A patent/CN101784603B/zh not_active Expired - Fee Related
- 2008-07-29 EP EP20080775367 patent/EP2181155B1/en not_active Not-in-force
- 2008-07-29 KR KR1020107003652A patent/KR101499274B1/ko not_active Expired - Fee Related
- 2008-07-29 JP JP2010521377A patent/JP5237376B2/ja active Active
- 2008-07-29 US US12/733,301 patent/US9029455B2/en not_active Expired - Fee Related
- 2008-07-29 WO PCT/EP2008/059906 patent/WO2009024435A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN101784603A (zh) | 2010-07-21 |
| KR20100057814A (ko) | 2010-06-01 |
| US9029455B2 (en) | 2015-05-12 |
| DE602008004668D1 (de) | 2011-03-03 |
| US20100174029A1 (en) | 2010-07-08 |
| EP2181155B1 (en) | 2011-01-19 |
| WO2009024435A1 (en) | 2009-02-26 |
| EP2181155A1 (en) | 2010-05-05 |
| KR101499274B1 (ko) | 2015-03-05 |
| JP2010536967A (ja) | 2010-12-02 |
| CN101784603B (zh) | 2012-11-28 |
| ATE496095T1 (de) | 2011-02-15 |
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