JP5216577B2 - Ｖｉｉｉ族金属触媒錯体混合物からのトリアリールホスフィンの回収方法 - Google Patents

Ｖｉｉｉ族金属触媒錯体混合物からのトリアリールホスフィンの回収方法 Download PDF

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JP5216577B2
JP5216577B2 JP2008507676A JP2008507676A JP5216577B2 JP 5216577 B2 JP5216577 B2 JP 5216577B2 JP 2008507676 A JP2008507676 A JP 2008507676A JP 2008507676 A JP2008507676 A JP 2008507676A JP 5216577 B2 JP5216577 B2 JP 5216577B2
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triarylphosphine
group viii
end component
viii metal
condensate
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JP2008536683A (ja
JP2008536683A5 (cg-RX-API-DMAC10.html
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シャー・ベイクレッシュ・エヌ
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オクセア・コーポレイション
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5095—Separation; Purification; Stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP2008507676A 2005-04-21 2006-03-22 Ｖｉｉｉ族金属触媒錯体混合物からのトリアリールホスフィンの回収方法 Expired - Fee Related JP5216577B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/112,402 US7667079B2 (en) 2005-04-21 2005-04-21 Processes for recovery of a triarylphosphine from a group VIII metal catalyst complex mixture
US11/112,402 2005-04-21
PCT/US2006/010413 WO2006115644A2 (en) 2005-04-21 2006-03-22 Processes for recovery of a triarylphosphine from a group viii metal catalyst complex mixture

Publications (3)

Publication Number Publication Date
JP2008536683A JP2008536683A (ja) 2008-09-11
JP2008536683A5 JP2008536683A5 (cg-RX-API-DMAC10.html) 2012-06-14
JP5216577B2 true JP5216577B2 (ja) 2013-06-19

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JP2008507676A Expired - Fee Related JP5216577B2 (ja) 2005-04-21 2006-03-22 Ｖｉｉｉ族金属触媒錯体混合物からのトリアリールホスフィンの回収方法

Country Status (10)

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US (1) US7667079B2 (cg-RX-API-DMAC10.html)
EP (1) EP1883471B1 (cg-RX-API-DMAC10.html)
JP (1) JP5216577B2 (cg-RX-API-DMAC10.html)
KR (1) KR101243618B1 (cg-RX-API-DMAC10.html)
CN (1) CN101163549B (cg-RX-API-DMAC10.html)
BR (1) BRPI0610595A2 (cg-RX-API-DMAC10.html)
MX (1) MX2007013055A (cg-RX-API-DMAC10.html)
TW (1) TWI366568B (cg-RX-API-DMAC10.html)
WO (1) WO2006115644A2 (cg-RX-API-DMAC10.html)
ZA (1) ZA200707303B (cg-RX-API-DMAC10.html)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100843424B1 (ko) * 2006-07-06 2008-07-03 삼성전기주식회사 스퍼터링 공정을 이용한 필름형 안테나 제조 방법
CN105441681B (zh) * 2014-09-26 2018-03-02 中国石油化工股份有限公司 一种从包含铑膦络合催化剂的废液中回收铑的方法
EP3374340B1 (en) * 2015-11-10 2021-12-29 Dow Technology Investments LLC Process for producing aldehydes
CN107955038A (zh) * 2017-12-19 2018-04-24 天津渤化永利化工股份有限公司 一种丙烯羰基化中的催化剂母液综合回收利用方法及装置

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO156742C (no) * 1979-03-28 1987-11-18 Union Carbide Corp Fremgangsmaate for fremstilling av et hydroformyleringsmedium, og fremgangsmaate for fremstilling av aldehyder.
DE2912230B1 (de) * 1979-03-28 1980-10-09 Union Carbide Corp Verfahren zur Rueckgewinnung und Reaktivierung gebrauchter Rhodium- und Phosphin-enthaltender Katalysatoren aus Reaktionsprodukten der Rhodium-katalysierten Oxosynthese
GB2048862B (en) 1979-05-11 1983-06-15 Mitsubishi Chem Ind Process for the hydroformylation of olefins
JPS5822132B2 (ja) * 1980-01-18 1983-05-06 三菱化学株式会社 オレフインのヒドロホルミル化方法
JPS584690B2 (ja) * 1979-05-11 1983-01-27 三菱化学株式会社 オレフインのヒドロホルミル化方法
JPS5645436A (en) 1979-09-21 1981-04-25 Mitsubishi Chem Ind Ltd Hydroformylation of olefin
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
US4528404A (en) 1983-03-16 1985-07-09 Exxon Research And Engineering Co. High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
CA1259331A (en) * 1984-03-30 1989-09-12 Gregory J. Dembowski Process for recovery of phosphorus ligand from vaporized aldehyde
US4871879A (en) 1987-10-27 1989-10-03 Hoechst Celanese Corporation Rhodium recovery from hydroformylation reaction product
JP3758226B2 (ja) * 1996-02-13 2006-03-22 三菱化学株式会社 ルテニウム錯体の分離回収方法
JPH10291996A (ja) 1997-04-22 1998-11-04 Mitsubishi Chem Corp ロジウム錯体溶液の調製方法
JP3888008B2 (ja) * 1999-10-12 2007-02-28 三菱化学株式会社 第８族貴金属及び／又は有機ホスファイト化合物の回収方法
US6335415B1 (en) * 2001-01-30 2002-01-01 Council Of Scientific & Industrial Research Process for the preparation of a polyester
US7196227B2 (en) * 2002-12-23 2007-03-27 Eastman Chemical Company Process for the recovery of phosphorus and iodine containing catalyst components
WO2004065007A1 (en) 2003-01-17 2004-08-05 Sasol Technology (Proprietary) Limited Recovery of an active catalyst component from a process stream

Also Published As

Publication number Publication date
ZA200707303B (en) 2008-07-30
TW200643025A (en) 2006-12-16
US20060241322A1 (en) 2006-10-26
WO2006115644A3 (en) 2007-03-15
EP1883471A2 (en) 2008-02-06
KR101243618B1 (ko) 2013-03-14
MX2007013055A (es) 2008-01-14
EP1883471B1 (en) 2018-10-10
TWI366568B (en) 2012-06-21
KR20080023286A (ko) 2008-03-13
WO2006115644A2 (en) 2006-11-02
CN101163549A (zh) 2008-04-16
JP2008536683A (ja) 2008-09-11
CN101163549B (zh) 2012-02-29
US7667079B2 (en) 2010-02-23
BRPI0610595A2 (pt) 2010-07-06
HK1121708A1 (en) 2009-04-30

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