JP5199130B2 - トリフェニルアミンレドックスシャトルを有する充電式リチウムイオン電池 - Google Patents
トリフェニルアミンレドックスシャトルを有する充電式リチウムイオン電池 Download PDFInfo
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- JP5199130B2 JP5199130B2 JP2008555268A JP2008555268A JP5199130B2 JP 5199130 B2 JP5199130 B2 JP 5199130B2 JP 2008555268 A JP2008555268 A JP 2008555268A JP 2008555268 A JP2008555268 A JP 2008555268A JP 5199130 B2 JP5199130 B2 JP 5199130B2
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- Japan
- Prior art keywords
- lithium
- shuttle
- potential
- battery
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims description 31
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 31
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 title description 23
- -1 triphenylamine compound Chemical class 0.000 claims description 50
- 239000000126 substance Substances 0.000 claims description 40
- 239000003792 electrolyte Substances 0.000 claims description 38
- 230000003647 oxidation Effects 0.000 claims description 38
- 238000007254 oxidation reaction Methods 0.000 claims description 38
- 229910052744 lithium Inorganic materials 0.000 claims description 34
- 230000014759 maintenance of location Effects 0.000 claims description 21
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 14
- 229910003002 lithium salt Inorganic materials 0.000 claims description 14
- 159000000002 lithium salts Chemical class 0.000 claims description 14
- 229910052731 fluorine Inorganic materials 0.000 claims description 12
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 239000000460 chlorine Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 229910000733 Li alloy Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 239000001989 lithium alloy Substances 0.000 claims description 6
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 5
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 5
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 5
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 5
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 4
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical compound C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 claims description 4
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 229910013375 LiC Inorganic materials 0.000 claims description 4
- 229910013528 LiN(SO2 CF3)2 Inorganic materials 0.000 claims description 4
- 229910013385 LiN(SO2C2F5)2 Inorganic materials 0.000 claims description 4
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 description 29
- 150000001412 amines Chemical class 0.000 description 17
- 239000000463 material Substances 0.000 description 16
- 239000007983 Tris buffer Substances 0.000 description 13
- 125000000217 alkyl group Chemical group 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 9
- 229910011458 Li4/3 Ti5/3O4 Inorganic materials 0.000 description 8
- 125000005843 halogen group Chemical group 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 125000001188 haloalkyl group Chemical group 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 229910052794 bromium Inorganic materials 0.000 description 6
- 239000011888 foil Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- 230000006870 function Effects 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 241000894007 species Species 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 125000004950 trifluoroalkyl group Chemical group 0.000 description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000007774 positive electrode material Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 125000006617 triphenylamine group Chemical class 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- 229910013188 LiBOB Inorganic materials 0.000 description 2
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000001246 bromo group Chemical group Br* 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000011530 conductive current collector Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- ZQBFAOFFOQMSGJ-UHFFFAOYSA-N hexafluorobenzene Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1F ZQBFAOFFOQMSGJ-UHFFFAOYSA-N 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 150000002641 lithium Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- SSIOPLVRUPBGPG-UHFFFAOYSA-N 10-methylphenothiazine 5,5-dioxide Chemical group C1=CC=C2N(C)C3=CC=CC=C3S(=O)(=O)C2=C1 SSIOPLVRUPBGPG-UHFFFAOYSA-N 0.000 description 1
- LUXDKIVXVUWRQB-UHFFFAOYSA-N 10-methylphenothiazine 5-oxide Chemical group C1=CC=C2N(C)C3=CC=CC=C3S(=O)C2=C1 LUXDKIVXVUWRQB-UHFFFAOYSA-N 0.000 description 1
- GVPODVKBTHCGFU-UHFFFAOYSA-N 2,4,6-tribromoaniline Chemical compound NC1=C(Br)C=C(Br)C=C1Br GVPODVKBTHCGFU-UHFFFAOYSA-N 0.000 description 1
- KLOKRJIOLRCMRK-UHFFFAOYSA-N 2,4-dibromo-n,n-bis(2,4-dibromophenyl)aniline Chemical compound BrC1=CC(Br)=CC=C1N(C=1C(=CC(Br)=CC=1)Br)C1=CC=C(Br)C=C1Br KLOKRJIOLRCMRK-UHFFFAOYSA-N 0.000 description 1
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 1
- CEPCPXLLFXPZGW-UHFFFAOYSA-N 2,4-difluoroaniline Chemical compound NC1=CC=C(F)C=C1F CEPCPXLLFXPZGW-UHFFFAOYSA-N 0.000 description 1
- ZRXVCYGHAUGABY-UHFFFAOYSA-N 4-bromo-n,n-bis(4-bromophenyl)aniline Chemical compound C1=CC(Br)=CC=C1N(C=1C=CC(Br)=CC=1)C1=CC=C(Br)C=C1 ZRXVCYGHAUGABY-UHFFFAOYSA-N 0.000 description 1
- 125000004800 4-bromophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Br 0.000 description 1
- XTEJTCSINRHCBZ-UHFFFAOYSA-N 4-fluoro-n,n-bis(4-fluorophenyl)aniline Chemical compound C1=CC(F)=CC=C1N(C=1C=CC(F)=CC=1)C1=CC=C(F)C=C1 XTEJTCSINRHCBZ-UHFFFAOYSA-N 0.000 description 1
- 125000004199 4-trifluoromethylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C(F)(F)F 0.000 description 1
- WWXWRWHYGBFEST-UHFFFAOYSA-N 7-glycidyloxy-9-(2-glycidyloxycarbonylphenyl)-2-xanthone Chemical compound O=C(OCC1CO1)c1ccccc1-c1c2ccc(OCC3CO3)cc2oc2cc(=O)ccc12 WWXWRWHYGBFEST-UHFFFAOYSA-N 0.000 description 1
- 101100502324 Arabidopsis thaliana FAD6 gene Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000002000 Electrolyte additive Substances 0.000 description 1
- 229920006370 Kynar Polymers 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910011281 LiCoPO 4 Inorganic materials 0.000 description 1
- 229910013086 LiNiPO Inorganic materials 0.000 description 1
- 229910012465 LiTi Inorganic materials 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000203482 Polyscias Species 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910020810 Sn-Co Inorganic materials 0.000 description 1
- 229910018757 Sn—Co Inorganic materials 0.000 description 1
- 241000862969 Stella Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 125000004450 alkenylene group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
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- 229910052797 bismuth Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000003085 diluting agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- GZKHDVAKKLTJPO-UHFFFAOYSA-N ethyl 2,2-difluoroacetate Chemical compound CCOC(=O)C(F)F GZKHDVAKKLTJPO-UHFFFAOYSA-N 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
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- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
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- 230000002427 irreversible effect Effects 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- XLDXZSVHMLAQMY-UHFFFAOYSA-N lithium;dioxalooxyborinate Chemical compound [Li+].OC(=O)C(=O)OB([O-])OC(=O)C(O)=O XLDXZSVHMLAQMY-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
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- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- CSSYKHYGURSRAZ-UHFFFAOYSA-N methyl 2,2-difluoroacetate Chemical compound COC(=O)C(F)F CSSYKHYGURSRAZ-UHFFFAOYSA-N 0.000 description 1
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- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 229920000767 polyaniline Polymers 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
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- 238000000926 separation method Methods 0.000 description 1
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- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
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- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000005259 triarylamine group Chemical group 0.000 description 1
- 125000006004 trihaloethyl group Chemical group 0.000 description 1
- 125000004953 trihalomethyl group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74331406P | 2006-02-17 | 2006-02-17 | |
| US60/743,314 | 2006-02-17 | ||
| PCT/US2007/003174 WO2007097912A2 (en) | 2006-02-17 | 2007-02-05 | Rechargeable lithium-ion cell with triphenylamine redox shuttle |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009527096A JP2009527096A (ja) | 2009-07-23 |
| JP2009527096A5 JP2009527096A5 (enExample) | 2010-03-25 |
| JP5199130B2 true JP5199130B2 (ja) | 2013-05-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008555268A Expired - Fee Related JP5199130B2 (ja) | 2006-02-17 | 2007-02-05 | トリフェニルアミンレドックスシャトルを有する充電式リチウムイオン電池 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7585590B2 (enExample) |
| EP (1) | EP1994600A4 (enExample) |
| JP (1) | JP5199130B2 (enExample) |
| KR (1) | KR20080093054A (enExample) |
| CN (1) | CN101385185B (enExample) |
| WO (1) | WO2007097912A2 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US7906238B2 (en) | 2005-12-23 | 2011-03-15 | 3M Innovative Properties Company | Silicon-containing alloys useful as electrodes for lithium-ion batteries |
| WO2008088832A2 (en) * | 2007-01-17 | 2008-07-24 | Enerdel, Inc. | Lithium titanate and lithium cells and batteries including the same |
| EP2250700B1 (en) * | 2008-02-12 | 2014-09-17 | 3M Innovative Properties Company | Redox shuttles for high voltage cathodes |
| US8283074B2 (en) * | 2008-08-15 | 2012-10-09 | Uchicago Argonne, Llc | Electrolyte salts for nonaqueous electrolytes |
| JP5350849B2 (ja) * | 2009-03-23 | 2013-11-27 | 株式会社豊田中央研究所 | リチウム二次電池 |
| JP4934704B2 (ja) * | 2009-07-27 | 2012-05-16 | 株式会社日立製作所 | リチウムイオン二次電池及びリチウムイオン二次電池用過充電抑制剤 |
| GB0913638D0 (en) * | 2009-08-05 | 2009-09-16 | Acal Energy Ltd | Fuel cells |
| EP2494636B1 (de) * | 2009-10-27 | 2018-10-10 | Albemarle Germany GmbH | Stickstoffhaltige hydridanoden und galvanische elemente enthaltend stickstoffhaltige hydridanoden |
| CN103201883B (zh) | 2010-11-09 | 2016-03-02 | 3M创新有限公司 | 高容量合金阳极和包含其的锂离子电化学电池 |
| JP2012138327A (ja) * | 2010-12-28 | 2012-07-19 | Hitachi Ltd | 非水電解液及びこれを用いた非水二次電池 |
| JP6054956B2 (ja) | 2011-06-07 | 2016-12-27 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロカーボン電解質添加剤を含むリチウムイオン電気化学電池 |
| WO2012172592A1 (ja) * | 2011-06-13 | 2012-12-20 | トヨタ自動車株式会社 | 蓄電システムおよび蓄電装置の制御方法 |
| JP2013077424A (ja) * | 2011-09-30 | 2013-04-25 | Fuji Heavy Ind Ltd | リチウムイオン二次電池 |
| WO2013177138A1 (en) * | 2012-05-21 | 2013-11-28 | A123 Systems, LLC | Multi-cell lithium-ion batteries |
| US9853318B2 (en) * | 2012-11-02 | 2017-12-26 | Natron Energy, Inc. | Stabilization of battery electrodes using polymer coatings |
| JP6244623B2 (ja) * | 2012-12-18 | 2017-12-13 | 株式会社Gsユアサ | 非水電解質二次電池の製造方法及び非水電解質二次電池 |
| DE112015003328T5 (de) | 2014-07-18 | 2017-04-13 | Board Of Trustees Of Michigan State University | Wiederaufladbare Lithiumionenzelle mit einem Redox-Shuttle-Additiv |
| KR101786220B1 (ko) * | 2015-11-20 | 2017-10-17 | 현대자동차주식회사 | 리튬-공기 전지용 액상 촉매 |
| CN107026284B (zh) | 2016-01-29 | 2019-10-11 | 比亚迪股份有限公司 | 一种电解液及含有该电解液和/或正极的锂离子电池 |
| US10312523B2 (en) * | 2016-02-25 | 2019-06-04 | Tdk Corporation | Lithium ion secondary battery |
| JP7089295B2 (ja) * | 2016-11-22 | 2022-06-22 | ボード オブ トラスティーズ オブ ミシガン ステイト ユニバーシティ | 充電式電気化学セルおよび酸化還元フロー電池 |
| JP2019003928A (ja) * | 2017-06-16 | 2019-01-10 | パナソニックIpマネジメント株式会社 | フロー電池 |
| WO2019018741A1 (en) | 2017-07-20 | 2019-01-24 | Board Of Trustees Of Michigan State University | REDOX FLOW BATTERY |
| KR102328258B1 (ko) * | 2017-10-17 | 2021-11-18 | 주식회사 엘지에너지솔루션 | 리튬 금속 전지용 전해질 및 이를 포함하는 리튬 금속 전지 |
| US20240122065A1 (en) * | 2020-08-12 | 2024-04-11 | Tosoh Corporation | Metal patterning material, amine compound, electronic device, and method for forming metal pattern |
| RU2752762C1 (ru) * | 2020-10-26 | 2021-08-02 | Автономная некоммерческая образовательная организация высшего образования "Сколковский институт науки и технологий" (Сколковский институт науки и технологий) | Высокорастворимый католит на основе трифениламина и электрохимический источник тока на его основе |
| CN113860280B (zh) * | 2021-09-24 | 2023-02-10 | 惠州亿纬锂能股份有限公司 | 一种磷酸锰铁锂正极材料及其制备方法与应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS61279061A (ja) | 1985-06-04 | 1986-12-09 | Showa Denko Kk | 二次電池 |
| JPS6282649A (ja) | 1985-10-04 | 1987-04-16 | Showa Denko Kk | 二次電池 |
| JPS6338347A (ja) | 1986-08-01 | 1988-02-18 | Fujitsu Ltd | 信号線の反転切替方式 |
| JPS6355861A (ja) | 1986-08-26 | 1988-03-10 | Showa Denko Kk | 二次電池 |
| JPS6355868A (ja) | 1986-08-27 | 1988-03-10 | Showa Denko Kk | 二次電池の運転方法 |
| US4670363A (en) | 1986-09-22 | 1987-06-02 | Duracell Inc. | Non-aqueous electrochemical cell |
| JPH065903B2 (ja) * | 1987-06-24 | 1994-01-19 | 株式会社メディア | 入出力組合せパタ−ンのプリセット、記憶及び切換機能を備えたマトリクススイッチャ− |
| JPH04246745A (ja) * | 1991-02-01 | 1992-09-02 | Canon Inc | 情報処理装置及びその方法 |
| JPH0536439A (ja) | 1991-07-31 | 1993-02-12 | Sony Corp | 非水電解液二次電池 |
| EP0614239A3 (en) * | 1993-03-01 | 1996-10-16 | Tadiran Ltd | Non-aqueous secondary battery with safety device. |
| JPH06333598A (ja) * | 1993-05-26 | 1994-12-02 | Tokin Corp | リチウム2次電池用電解液 |
| JP3809657B2 (ja) | 1994-03-07 | 2006-08-16 | ソニー株式会社 | 非水電解液二次電池 |
| JPH07320778A (ja) * | 1994-05-20 | 1995-12-08 | Sanyo Electric Co Ltd | 非水電解液電池 |
| JPH08236155A (ja) * | 1995-02-27 | 1996-09-13 | Sanyo Electric Co Ltd | リチウム二次電池 |
| JP3756232B2 (ja) | 1996-01-17 | 2006-03-15 | 宇部興産株式会社 | 非水電解質二次電池 |
| DE69736970T2 (de) | 1996-09-03 | 2007-09-13 | Ube Industries, Ltd., Ube | Nichtwässrige Lithium-Ion Sekundärbatterie |
| US6004698A (en) | 1997-08-21 | 1999-12-21 | The United States Of America As Represented By The United States Department Of Energy | Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection |
| JP3635884B2 (ja) * | 1997-09-03 | 2005-04-06 | 宇部興産株式会社 | 非水電解液二次電池 |
| JPH11219730A (ja) * | 1998-02-03 | 1999-08-10 | Fuji Photo Film Co Ltd | 非水電解液二次電池 |
| US20010004507A1 (en) | 1998-10-22 | 2001-06-21 | Hong Gan | Organic carbonate additives for nonaqueous electrolyte rechargeable electrochemical cells |
| EP1361622B1 (en) | 2001-01-24 | 2008-06-04 | Ube Industries, Ltd. | Nonaqueous electrolytic solution and lithium secondary batteries |
| KR100558847B1 (ko) | 2003-08-19 | 2006-03-10 | 에스케이씨 주식회사 | 전해질 조성물 및 이를 채용한 리튬 전지와 그의 제조방법 |
-
2007
- 2007-02-05 KR KR1020087019935A patent/KR20080093054A/ko not_active Abandoned
- 2007-02-05 JP JP2008555268A patent/JP5199130B2/ja not_active Expired - Fee Related
- 2007-02-05 CN CN2007800059003A patent/CN101385185B/zh not_active Expired - Fee Related
- 2007-02-05 WO PCT/US2007/003174 patent/WO2007097912A2/en not_active Ceased
- 2007-02-05 US US11/671,128 patent/US7585590B2/en not_active Expired - Fee Related
- 2007-02-05 EP EP07750059A patent/EP1994600A4/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US7585590B2 (en) | 2009-09-08 |
| CN101385185A (zh) | 2009-03-11 |
| KR20080093054A (ko) | 2008-10-17 |
| WO2007097912A3 (en) | 2007-11-08 |
| US20070196727A1 (en) | 2007-08-23 |
| EP1994600A2 (en) | 2008-11-26 |
| WO2007097912A2 (en) | 2007-08-30 |
| EP1994600A4 (en) | 2012-04-04 |
| JP2009527096A (ja) | 2009-07-23 |
| CN101385185B (zh) | 2011-05-04 |
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