JP5162567B2 - 高分子マトリクスを有する固体水素燃料およびその製造方法 - Google Patents
高分子マトリクスを有する固体水素燃料およびその製造方法 Download PDFInfo
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- JP5162567B2 JP5162567B2 JP2009283194A JP2009283194A JP5162567B2 JP 5162567 B2 JP5162567 B2 JP 5162567B2 JP 2009283194 A JP2009283194 A JP 2009283194A JP 2009283194 A JP2009283194 A JP 2009283194A JP 5162567 B2 JP5162567 B2 JP 5162567B2
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- 239000007787 solid Substances 0.000 title claims description 79
- 239000001257 hydrogen Substances 0.000 title claims description 77
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 77
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 76
- 239000000446 fuel Substances 0.000 title claims description 76
- 239000011159 matrix material Substances 0.000 title claims description 36
- 229920000642 polymer Polymers 0.000 title claims description 36
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 239000011949 solid catalyst Substances 0.000 claims description 35
- 239000000126 substance Substances 0.000 claims description 32
- 150000004678 hydrides Chemical class 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 13
- 229920002379 silicone rubber Polymers 0.000 claims description 13
- 239000004945 silicone rubber Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 7
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical group C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 239000000806 elastomer Substances 0.000 claims description 6
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229910000104 sodium hydride Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000003456 ion exchange resin Substances 0.000 claims description 5
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 229920001600 hydrophobic polymer Polymers 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 239000012448 Lithium borohydride Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 229910000102 alkali metal hydride Inorganic materials 0.000 claims description 3
- 150000008046 alkali metal hydrides Chemical class 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- BGECDVWSWDRFSP-UHFFFAOYSA-N borazine Chemical compound B1NBNBN1 BGECDVWSWDRFSP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052987 metal hydride Inorganic materials 0.000 claims description 3
- 150000004681 metal hydrides Chemical class 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 3
- 239000012312 sodium hydride Substances 0.000 claims description 3
- 239000011973 solid acid Substances 0.000 claims description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 4
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 4
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 claims 2
- 229910000085 borane Inorganic materials 0.000 claims 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 2
- -1 B A compound Chemical class 0.000 claims 1
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- UWTDFICHZKXYAC-UHFFFAOYSA-N boron;oxolane Chemical compound [B].C1CCOC1 UWTDFICHZKXYAC-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 150000001669 calcium Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical class [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- QVCGXRQVUIKNGS-UHFFFAOYSA-L cobalt(2+);dichloride;hydrate Chemical compound O.Cl[Co]Cl QVCGXRQVUIKNGS-UHFFFAOYSA-L 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
- H01M8/04216—Reactant storage and supply, e.g. means for feeding, pipes characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Energy (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Description
S210〜S250:固体水素燃料の製造工程
Claims (17)
- 高分子マトリクス;および、前記高分子マトリクスに均一に分散させた、固体化学水素化物と固体触媒との破砕混合物;を含み、
前記高分子マトリクスが、疎水性高分子エラストマーとして、シリコーンゴムを含み、前記固体触媒が金属イオンでキレート化されたイオン交換樹脂であり、前記固体触媒の含量が0%〜25%の範囲内であることを特徴とする、高分子マトリクスを有する固体水素燃料。 - 前記固体化学水素化物が、アルカリ金属ホウ化水素化合物、アルカリ金属水素化物、金属ホウ化水素化合物および金属水素化物から選択される請求項1に記載の高分子マトリクスを有する固体水素燃料。
- 前記固体化学水素化物が、水素化ホウ素ナトリウム(NaBH4、略してNBH)、水素化ナトリウム(NaH)、水素化ホウ素リチウム(LiBH4)、水素化リチウム(LiH)、水素化カルシウム(CaH2)、カルシウムホウ化水素(Ca(BH4)2)、マグネシウムホウ化水素(Mg(BH4)2)、水素化ホウ素カリウム(KBH4)およびアルミニウムホウ化水素(Al(BH4)3)から選択される請求項1に記載の高分子マトリクスを有する固体水素燃料。
- 前記固体化学水素化物が、実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物、および、実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物から生じる化合物から選択される請求項1に記載の高分子マトリクスを有する固体水素燃料。
- 前記実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物、および、前記実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物から生じる化合物が、H3BNH3、H2B(NH3)2BH4、ボラジン(B3N3H6)、ボラン−テトラヒドロフラン錯体およびジボラン(B2H6)から選択される請求項4に記載の高分子マトリクスを有する固体水素燃料。
- 前記固体化学水素化物の含量が30%〜70%の範囲内である請求項1〜5のいずれか1項に記載の高分子マトリクスを有する固体水素燃料。
- 前記固体触媒が、固体酸;ルテニウム、コバルト、ニッケル、銅、鉄を含有する金属塩;または、前記金属イオンからなる固体触媒;を含む請求項1〜6のいずれか1項に記載の高分子マトリクスを有する固体水素燃料。
- 高分子マトリクスを有する固体水素燃料の製造方法であって、
固体化学水素化物および固体触媒を破砕/混合機で破砕および混合する工程(ただし、前記固体触媒は金属イオンでキレート化されたイオン交換樹脂である);ならびに、
前記高分子マトリクスを前記固体化学水素化物および前記固体触媒の混合物に加えてフレキシブル固体水素燃料を得る工程(ただし、前記高分子マトリクスは、疎水性高分子エラストマーとして、シリコーンゴムを含み、前記固体触媒の含量は0%〜25%の範囲内である);
を含む製造方法。 - 前記固体水素燃料を成形して容器に入れる工程;ならびに、
前記容器に液体を入れて前記固体水素燃料を前記液体と反応させることにより、安定した水素放出速度を与える工程;
をさらに含む請求項8に記載の製造方法。 - 前記固体化学水素化物が、アルカリ金属ホウ素水素化物、アルカリ金属水素化物、金属ホウ化水素化合物および金属水素化物から選択される請求項8または9に記載の製造方法。
- 前記固体化学水素化物が、水素化ホウ素ナトリウム(NaBH4、略してNBH)、水素化ナトリウム(NaH)、水素化ホウ素リチウム(LiBH4)、水素化リチウム(LiH)、水素化カルシウム(CaH2)、カルシウムホウ化水素(Ca(BH4)2)、マグネシウムホウ化水素(Mg(BH4)2)、水素化ホウ素カリウム(KBH4)およびアルミニウムホウ化水素Al(BH4)3から選択される請求項8または9に記載の製造方法。
- 前記固体化学水素化物が、実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物、および、実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物から生じる化合物から選択される請求項8または9に記載の製造方法。
- 前記実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物、および、実験式BxNyHz(式中、xは0〜10の整数、yは0〜10の整数、および、zは1〜20の整数)で示される化合物から生じる化合物が、H3BNH3、H2B(NH3)2BH4、ボラジン(B3N3H6)、ボラン−テトラヒドロフラン錯体およびジボラン(B2H6)から選択される請求項12に記載の製造方法。
- 前記固体化学水素化物の含量が30%〜70%の範囲内である請求項8〜13のいずれか1項に記載の製造方法。
- 前記固体触媒が、固体酸;ルテニウム、コバルト、ニッケル、銅、鉄を含有する金属塩;および、前記金属イオンからなる固体触媒;から選択される請求項8〜14のいずれか1項に記載の製造方法。
- 前記破砕/混合機が、ジョー・クラッシャー、ジャイレートリークラッシャー、ファイン(fine)コーンクラッシャー、ロールクラッシャー、インパクトクラッシャー、カッティングクラッシャー、複合(complex)カッティングクラッシャー、ボールミル、ロッドミルおよび振動ミルから選択される請求項8〜15のいずれか1項に記載の製造方法。
- 前記液体が水または水溶液を含む請求項9に記載の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW098108205 | 2009-03-13 | ||
TW098108205A TWI371427B (en) | 2009-03-13 | 2009-03-13 | Solid state hydrogen fuel with polymer matrix and fabrication methods thereof |
Publications (2)
Publication Number | Publication Date |
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JP2010215487A JP2010215487A (ja) | 2010-09-30 |
JP5162567B2 true JP5162567B2 (ja) | 2013-03-13 |
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JP2009283194A Expired - Fee Related JP5162567B2 (ja) | 2009-03-13 | 2009-12-14 | 高分子マトリクスを有する固体水素燃料およびその製造方法 |
Country Status (4)
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US (1) | US8658055B2 (ja) |
EP (1) | EP2228338A1 (ja) |
JP (1) | JP5162567B2 (ja) |
TW (1) | TWI371427B (ja) |
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JP5671002B2 (ja) * | 2009-04-09 | 2015-02-18 | カラーマトリックス ホールディングス インコーポレイテッドColormatrix Holdings,Inc. | 酸素を捕捉する組成物を収容する容器、およびクロージャ |
US20110142754A1 (en) * | 2009-12-10 | 2011-06-16 | Jie-Ren Ku | One-off and adjustment method of hydrogen releasing from chemical hydride |
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US20100230636A1 (en) | 2010-09-16 |
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US8658055B2 (en) | 2014-02-25 |
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TW201033116A (en) | 2010-09-16 |
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