JP5137217B2 - 荷電制御されたウレタンフォームおよびそれを用いたトナー搬送ローラ - Google Patents
荷電制御されたウレタンフォームおよびそれを用いたトナー搬送ローラ Download PDFInfo
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- JP5137217B2 JP5137217B2 JP2010519820A JP2010519820A JP5137217B2 JP 5137217 B2 JP5137217 B2 JP 5137217B2 JP 2010519820 A JP2010519820 A JP 2010519820A JP 2010519820 A JP2010519820 A JP 2010519820A JP 5137217 B2 JP5137217 B2 JP 5137217B2
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- urethane foam
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- -1 borate ester compound Chemical class 0.000 claims description 80
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- 239000011230 binding agent Substances 0.000 claims description 31
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- 239000002253 acid Substances 0.000 claims description 22
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910001412 inorganic anion Inorganic materials 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-N iodic acid Chemical class OI(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-N 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- PMHXGHYANBXRSZ-UHFFFAOYSA-N n,n-dimethyl-2-morpholin-4-ylethanamine Chemical compound CN(C)CCN1CCOCC1 PMHXGHYANBXRSZ-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- OOCYPIXCHKROMD-UHFFFAOYSA-M phenyl(propanoyloxy)mercury Chemical compound CCC(=O)O[Hg]C1=CC=CC=C1 OOCYPIXCHKROMD-UHFFFAOYSA-M 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005040 tridecenyl group Chemical group C(=CCCCCCCCCCCC)* 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PPPHYGCRGMTZNA-UHFFFAOYSA-N trifluoromethyl hydrogen sulfate Chemical class OS(=O)(=O)OC(F)(F)F PPPHYGCRGMTZNA-UHFFFAOYSA-N 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-M urea-1-carboxylate Chemical compound NC(=O)NC([O-])=O AVWRKZWQTYIKIY-UHFFFAOYSA-M 0.000 description 1
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- 238000004804 winding Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical group O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description
本発明の荷電制御されたウレタンフォームは、表層中に、基材ウレタンフォームよりも帯電列において負側または正側にある荷電制御剤を含浸してなるものである。これにより、トナー搬送ローラの表層のトナーおよび現像ローラとの摩擦による帯電の影響を十分に防止できる。また、かかる荷電制御剤を含浸することで荷電制御剤の脱離を防止できるため安定して帯電性付与効果を発現することができ、低コストで良好な画像を得ることができる。ここで、表層とは、荷電制御剤が基材ウレタンフォームの全体に含浸せずに、荷電制御剤の含浸量が少なくても十分な本発明の効果を得ることができる範囲を示す。
測定対象材料を23℃、相対湿度55%の雰囲気下に4時間放置する。測定対象材料を除電ブロアSJ−F300(キーエンス社製)にて静電気を除去する。基材として使用するウレタンフォーム(ポリウレタン発泡体)と測定対象材料を擦り、表面電位計(トレック・ジャパン(株)製「MODEL 347」)で測定する。ポリウレタン発泡体および測定対象材料がプラス(正)、マイナス(負)のいずれに帯電するかで判別する。
(上記一般式(1)中、R1およびR2は、水素原子、アルキル基またはアリール基を示し、互いに同一であっても異なっていてもよく、Mは、アルカリ金属またはアルカリ土類金属を示し、nは、整数である)で表されるものが好適に使用できる。
(上記一般式(2)中、Rは−A1−(SO2R3)xを表し、R3は、OH、ハロゲン原子、ONa、OK、OR3aであり、R3a、A1は置換または未置換脂肪族炭化水素基、置換または未置換の芳香族基、置換または未置換の複素環基を表し、mおよびxは1〜8から選ばれた整数であり、複数のユニットが存在する場合、R、R3、R3a、A1、m、xは、各ユニットで独立して上記の意味を表す)で表されるものが好適に使用される。
(上記一般式(3)中、R4は、水素原子、直鎖もしくは分岐鎖のアルキル基、アルコキシ基、ニトロ基、アミノ基、カルボキシル基、アラルキル基、フェニル基、ベンジル基またはハロゲン原子を示し、nは0〜4の整数を示す)で表されるオキシナフトエ酸誘導体と、アルミニウム、クロム、コバルト、鉄、チタン、亜鉛等の金属からなる有機金属化合物が挙げられる。
(上記一般式(4)中、Mは、配位中心金属(クロム、コバルト、ニッケル、マンガン、鉄、チタン、アルミニウム等)を示し、Arは、各種置換基を有してもよいアリール基を示し、X、X1、YおよびY1は、それぞれO、CO、NHまたはNR5(R5は、炭素数1〜4のアルキレン基)を示し、A+は、水素イオン、ナトリウムイオン、カリウムイオン、アンモニウムイオン、脂肪族アンモニウムイオンを示し、A+はこれらのイオンが混合されていてもよい)で表されるものが好適に使用される。
(上記一般式(5)中、R6は、炭素数2〜6のアルキレン基、R7は、水素原子またはメチル基であり、nは、0〜10の整数を表す)
または、下記一般式(6)、
(上記一般式(6)中、R8は、水素原子またはメチル基、R9は、炭素数2〜4のアルキレン基、R10は、エチレン基、ビニレン基、1,2−シクロヘキシレン基、または1,2−フェニレン基を示す)で表されるものが好適に使用される。
(上記一般式(7)中、Mは、ホウ素またはアルミニウムであり、Xは、リチウム、ナトリウムまたはカリウムであり、R11、R12、R13およびR14は、各々独立に、水素原子、炭素数1〜4のアルキル基、炭素数1〜4のアルコキシ基またはハロゲン原子を示し、R11、R12、R13およびR14は複数存在してもよく、これらが複数存在する場合、各々が異なっていても同一であってもよく、nは、1〜5の整数を示す)で表されるものが好適に使用できる。
(上記一般式(8)中、R15は、炭素数4以上のアルキル基を表し、R16は、水素原子またはメチル基を表し、R15は、炭素数6以上のアルキル基であることがより好ましく、炭素数8以上のアルキル基であることがさらに好ましく、さらにまたR15は、炭素数20以下のアルキル基であることが好ましく、R15は直鎖でも分岐していてもよく、環状構造を有していてもよい)で表される(メタ)アクリル酸エステルを主成分とするものが好適に使用できる。
(上記一般式(9)中、R17は、水素原子またはメチル基を示し、R18は、炭素数1〜7の二価の有機基を示し、R19およびR20は、各々独立に、水素原子または炭素数1〜20の有機基、特には炭素数2〜4の有機基が好ましく、あるいは、R19およびR20が化学的に結合した炭素数4〜20の環状構造、またはR19およびR20が化学的に結合した、窒素原子、酸素原子、イオウ原子の少なくとも一種を含む炭素数4〜19の環状構造であってもよい)で表されるアミノ基含有モノマーを主成分とするものが好適に使用できる。
または下記一般式(11)、
(上記一般式(10)および(11)中、R21、R24およびR26は、炭素数1〜8のアルキレン基または繰り返し数が1〜4のエチレンオキシド基であり、R22、R23、R25、R27、R28は、それぞれ炭素数1〜8のアルキル基であり、R22およびR23、R24〜R28は、互いに同一でも異なっていてもよい)で表されるものが好適に使用できる。
(上記一般式(12)中、R29は、水素原子または炭素数1〜17の炭化水素基、R30およびR31は、各々独立に、水素原子または炭素数1〜8の炭化水素基、あるいはR30およびR31は、相互に連結されて環構造を形成していてもよく、R32は、エーテル結合を含んでいてもよい炭素数1〜12のアルキレン基、X−は、アニオン、nは2〜100の整数を示す)で表されるイミダゾリウム塩を主成分とするものが好適に使用できる。
(上記一般式(13)中、R33、R34、R35およびR36は、各々独立して、置換基を有していてもよいアルキル基、置換基を有していてもよい環状アルキル基、置換基を有していてもよいアラルキル基、置換基を有していてもよいアリール基を示し、X−は、アニオンを示す)で表されるものが好適に使用できる。
(上記一般式(14)中、R37およびR39は、各々独立して、アミノ基、炭素数1〜4のアルキル基を有するモノまたはジアルキルアミノ基、炭素数2〜4のアルキル基を有するモノまたはジ−ω−ヒドロキシアルキルアミノ基、無置換またはN−アルキル置換のフェニルアミノ基から選ばれる基であり、R38は、水素原子またはR37およびR39で示した基であり、R40およびR41は、各々独立して、水素原子、ハロゲン原子、スルホン酸基であるか、または両者が縮合したフェニル環を形成し、R42、R43、R45およびR46は、各々独立して、水素原子、メチル基またはエチル基であり、R44は、水素原子またはハロゲン原子であり、X−は、ハロゲンイオン、サルフェート、モリブデート、ホスホロモリブデート、ホウ素アニオンであり、これらのうち、R37およびR39がフェニルアミノ基であり、R38がm−メチルフェニルアミノ基であり、R40〜R46が水素原子である化合物が好ましい)で表されるものが好適に使用できる。
以下に、実施例および比較例で用いた材料を示す。
ウレタンフォームA 株式会社ブリヂストン製(除膜処理なし)
密度 29kg/m3
通気量 196cm3/cm2/sec
硬度 10kgf
平均セル径 280μm
バインダーa エネックス社製「SEバインダー」ウレタン樹脂水分散体
固形分50%
バインダーb 東洋インキ製造(株)製
「TOCRYL BC−X6131」ウレタン樹脂水分散体
固形分50%
荷電制御剤 アクリル酸エステルモノマーの共重合体
エネックス社製「BS−050301−1」
消泡剤 信越シリコーン(株)製「KS−502」
表1の配合量(単位、g)に従って、上記バインダーa、荷電制御剤、消泡剤を混合し、含浸液を調整した。この含浸液を満たした浴中に、ブロック状(16mm×1000mm×2000mm)の除膜処理を施していないウレタンフォームAを浸漬し、2本のロール間で圧縮した後、開放して含浸液にウレタンフォームAを含浸させた。これを浴上に導いて、ニップロールに通して余分な含浸液を絞り、除去した後110℃の熱風炉にて10分間加熱乾燥し、荷電制御されたウレタンフォームを得た。この荷電制御されたウレタンフォームの含浸液の付着量は乾燥質量で8g/Lであった。
含浸液のバインダーとしてバインダーbを使用し、ニップロール間隔を調整し、含浸液付着量(乾燥質量)を11g/Lとした。それ以外は、実施例1と同様にトナー搬送ローラを作製した。
含浸液のバインダーとしてバインダーaを使用し、ニップロール間隔を調整し、含浸液の付着量(乾燥質量)を3.5g/Lにしたこと以外は実施例1と同様にしてトナー搬送ローラを作製した。
上記実施例1,2および比較例1で得られたトナー搬送ローラの物性を以下の通り評価した。結果を表1に併記する。
ウレタンフォームの表面を顕微鏡で撮像し、ウレタンフォームの表面のセル径を測定し、平均を求めた。
剛直な板の上にウレタンフォームを置き、高分子計器製アスカーF硬度計にて測定した。測定は、硬度計を静かに置いた後、10秒後の硬度を測定した。
JIS K 6400に準じて測定した。
JIS K 6400に準じて測定した。
ウレタンフォームの表面を倍率100倍で撮影し、骨格の形状についてエッジの有無(ウレタン骨格が丸みを帯びていないものをエッジ有りとする)を判断した。
市販のプリンタに上記実施例1,2および比較例1で得られたトナー搬送ローラをセットし、下記条件で印刷を行い、印字性能を評価した。
A4用紙に対して4%の印字パターンで20000枚の印刷を行う。20000枚の印刷を行う際に、1000枚おきに3枚連続黒100%パターン印刷を行う。合計20回の3枚連続黒100%パターン印刷を行い、各回下記3段階で評価を行い、20回の平均を算出する(画像平均評価)。また、トナーとして、負帯電性トナーを使用した。
(評価基準)
3枚中1〜2枚目でカスレが生じた場合を×とする。
3枚中3枚目でカスレが生じた場合を△とする。
3枚ともカスレが生じなかった場合を○とする。
(評価基準)
3枚中1〜2枚目でカスレが生じた場合を×とする。
3枚中3枚目でカスレが生じた場合を△とする。
3枚ともカスレが生じなかった場合を○とする。
2 接着層
3 荷電制御されたウレタンフォーム
11 画像形成体
12 現像ローラ
13 トナー搬送ローラ
14 トナー収容部
15 転写ローラ
16 帯電部
17 露光部
18 ブレード
20 トナー
Claims (9)
- 表層中に局所的に、基材ウレタンフォームよりも帯電列において負側または正側にある荷電制御剤とバインダーとを含浸してなることを特徴とする荷電制御されたウレタンフォーム。
- 前記基材ウレタンフォームが、カーボン導電材が含浸された基材ウレタンフォーム、またはカーボン導電材が内部添加された基材ウレタンフォームである請求項1記載の荷電制御されたウレタンフォーム。
- 前記荷電制御剤と前記バインダーとの配合比が、該バインダーの固形分100質量部に対して、該荷電制御剤の固形分が10〜110質量部からなる請求項1または2記載の荷電制御されたウレタンフォーム。
- 前記荷電制御剤が負帯電荷電制御剤であり、該負帯電荷電制御剤が、(A)ホウ素酸塩、(B)ホウ酸エステル化合物、(C)ポリヒドロキシアルカノエート、(D)サリチル酸誘導体の金属化合物、(E)オキシナフトエ酸誘導体の金属化合物、(F)アゾ系金属錯体化合物、(G)芳香族オキシカルボン酸の金属化合物、(H)スルホン酸基を有するモノマーを共重合成分として重合した共重合体、(I)カルボキシル基を有するモノマーを共重合成分として重合した共重合体、(J)ジルコニウムまたはアルミニウムと、亜鉛と、芳香族ジオール、芳香族ヒドロキシカルボン酸、芳香族モノカルボン酸および芳香族ポリカルボン酸からなる群から選択される芳香族化合物とが、配位および/または結合している有機金属化合物、(K)ホウ素またはアルミニウムとベンジル酸誘導体の錯体および(L)含イオウ樹脂よりなる群から選ばれる一種以上である請求項1記載の荷電制御されたウレタンフォーム。
- 前記荷電制御剤が正帯電荷電制御剤であり、該正帯電荷電制御剤が、(a)(メタ)アクリル酸エステルモノマーを共重合成分として重合した共重合体、(b)アミノ基含有モノマーを共重合成分として重合した共重合体、(c)水酸基含有アミノ化合物、(d)イミダゾリウム塩類を構成単位として有する重合体、(e)第4級アンモニウム塩化合物、(f)ニグロシン系化合物および(g)トリフェニルメタン系化合物よりなる群から選ばれる一種以上である請求項1記載の荷電制御されたウレタンフォーム。
- 軸の外周に請求項1記載の荷電制御されたウレタンフォームが担持されてなることを特徴とするトナー搬送ローラ。
- 軸の外周に請求項2記載の荷電制御されたウレタンフォームが担持されてなることを特徴とするトナー搬送ローラ。
- 前記荷電制御剤が、前記基材ウレタンフォームよりも帯電列において負側であり、かつ、正帯電性トナー用である請求項6記載のトナー搬送ローラ。
- 前記荷電制御剤が、前記基材ウレタンフォームよりも帯電列において正側であり、かつ、負帯電性トナー用である請求項6記載のトナー搬送ローラ。
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JP5718180B2 (ja) * | 2011-07-05 | 2015-05-13 | 株式会社ブリヂストン | 現像ローラ |
WO2013065303A1 (ja) * | 2011-10-31 | 2013-05-10 | キヤノン株式会社 | 現像剤担持体及びその製造方法、並びに現像装置 |
WO2013065244A1 (ja) | 2011-10-31 | 2013-05-10 | キヤノン株式会社 | 現像剤担持体及びその製造方法、並びに現像装置 |
JPWO2014136829A1 (ja) * | 2013-03-05 | 2017-02-16 | 株式会社ブリヂストン | ローラ、その製造方法およびそれを用いた画像形成装置 |
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CN108604076B (zh) | 2016-01-27 | 2021-02-12 | 惠普发展公司,有限责任合伙企业 | 液体电子照相墨水显影单元 |
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