JP5041354B2 - 反応性蒸留によるフェノールの製法 - Google Patents

反応性蒸留によるフェノールの製法 Download PDF

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JP5041354B2
JP5041354B2 JP2001546616A JP2001546616A JP5041354B2 JP 5041354 B2 JP5041354 B2 JP 5041354B2 JP 2001546616 A JP2001546616 A JP 2001546616A JP 2001546616 A JP2001546616 A JP 2001546616A JP 5041354 B2 JP5041354 B2 JP 5041354B2
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JP
Japan
Prior art keywords
cumene hydroperoxide
catalyst bed
acetone
distillation column
overhead product
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Expired - Fee Related
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JP2001546616A
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English (en)
Japanese (ja)
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JP2003518047A5 (https=
JP2003518047A (ja
Inventor
レビン、ドロン
サンティステバン、ジョージ・ジー
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エクソンモービル・オイル・コーポレイション
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/06—Reactor-distillation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
JP2001546616A 1999-12-21 2000-12-20 反応性蒸留によるフェノールの製法 Expired - Fee Related JP5041354B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/468,465 US6410804B1 (en) 1999-12-21 1999-12-21 Production of phenol using reactive distillation
US09/468,465 1999-12-21
PCT/US2000/034843 WO2001046102A1 (en) 1999-12-21 2000-12-20 Production of phenol using reactive distillation

Publications (3)

Publication Number Publication Date
JP2003518047A JP2003518047A (ja) 2003-06-03
JP2003518047A5 JP2003518047A5 (https=) 2008-01-17
JP5041354B2 true JP5041354B2 (ja) 2012-10-03

Family

ID=23859932

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001546616A Expired - Fee Related JP5041354B2 (ja) 1999-12-21 2000-12-20 反応性蒸留によるフェノールの製法

Country Status (8)

Country Link
US (2) US6410804B1 (https=)
EP (1) EP1242348B1 (https=)
JP (1) JP5041354B2 (https=)
AT (1) ATE331702T1 (https=)
AU (1) AU2447701A (https=)
DE (1) DE60029132T2 (https=)
ES (1) ES2267600T3 (https=)
WO (1) WO2001046102A1 (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10036959A1 (de) * 2000-07-28 2002-02-07 Basf Ag Verfahren zur Herstellung von tert.-Butylestern aliphatischer C1-C4-Carbonsäuren
US8252961B2 (en) 2002-04-22 2012-08-28 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US7663004B2 (en) 2002-04-22 2010-02-16 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US8017816B2 (en) 2002-04-22 2011-09-13 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US6984761B2 (en) * 2002-12-16 2006-01-10 Exxonmobil Chemical Patents Inc. Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor
US20040249229A1 (en) * 2003-06-06 2004-12-09 Gee Jeffery C. Isomerization of olefins with carboxylic acid
ES2501391T3 (es) * 2004-03-25 2014-10-01 Galen J. Suppes Procedimiento para producir una composición anticongelante que contiene alcoholes inferiores y glicerol a través de alcohólisis de un glicérido
US7109385B2 (en) 2004-03-31 2006-09-19 General Electric Company Process for producing phenol
TWI376361B (en) * 2004-08-13 2012-11-11 Exxonmobil Chem Patents Inc Process for producing phenol and methyl ethyl ketone
JP2007099746A (ja) * 2005-09-06 2007-04-19 Ube Ind Ltd フェノールおよびシクロアルカノンの製造方法
US7326815B2 (en) * 2005-12-27 2008-02-05 Exxonmobil Chemical Patents Inc. Selective oxidation of alkylbenzenes
WO2007137021A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Catalysts comprising a combination of oxidized metals and a method for cleaving phenylalkyl hydroperoxides using the catalysts
WO2007137020A2 (en) * 2006-05-16 2007-11-29 Shell Oil Company Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts
US20080116053A1 (en) * 2006-11-20 2008-05-22 Abb Lummus Global Inc. Non-refluxing reactor stripper
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
US7888537B2 (en) * 2006-12-29 2011-02-15 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
KR20100044900A (ko) * 2007-08-22 2010-04-30 엑손모빌 케미칼 패턴츠 인코포레이티드 2급 부틸벤젠의 제조 방법
EP2098498A1 (en) 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Selective oligomerization of isobutene
US20110092742A1 (en) * 2008-08-26 2011-04-21 Dakka Jihad M Process for Producing Alkylbenzene Hydroperoxides
WO2010042269A1 (en) 2008-10-10 2010-04-15 Exxonmobil Chemical Patents Inc. Process for producing phenol and methyl ethyl ketone
US8440864B2 (en) * 2008-10-10 2013-05-14 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
KR20140015548A (ko) 2008-12-15 2014-02-06 엑손모빌 케미칼 패턴츠 인코포레이티드 알킬방향족 화합물의 산화
CN102161616A (zh) * 2011-03-11 2011-08-24 北京化工大学 一种过氧化氢烷基苯分解制备酚和酮的方法
KR101732771B1 (ko) 2014-06-16 2017-05-04 주식회사 엘지화학 탈거 장치
CN106866379B (zh) * 2017-03-23 2020-11-10 中石化上海工程有限公司 反应精馏分解chp制备苯酚丙酮的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55153730A (en) * 1979-04-20 1980-11-29 Ici Ltd Manufacture of phenol and acetone
DE3063046D1 (en) 1979-04-20 1983-06-16 Ici Plc Process for the production of phenol, acetone and alpha methylstyrene
US5055627A (en) * 1985-01-07 1991-10-08 Chemical Research & Licensing Company Process for the preparation of cumene
US4935577A (en) * 1988-07-15 1990-06-19 Mobil Oil Corp. Hydrocarbon processes comprised of catalytic distillation using Lewis acid promoted inorganic oxide catalyst systems
US4870217A (en) * 1988-10-24 1989-09-26 Texaco Chemical Company Method for production of phenol/acetone from cumene hydroperoxide
EP0367408A3 (en) * 1988-10-24 1991-06-12 Texaco Development Corporation Method for production of phenol/acetone from cumene hydroperoxide
US5118872A (en) * 1989-03-10 1992-06-02 Chemical Research & Licensing Company Process for conducting heterogeneous chemical reactions
DE4322712A1 (de) * 1993-07-08 1995-01-12 Huels Chemische Werke Ag Verfahren zur Durchführung chemischer Reaktionen in Reaktionsdestillationskolonnen
JPH08119892A (ja) * 1994-10-26 1996-05-14 Mitsui Petrochem Ind Ltd ヒドロキシ芳香族化合物の製造方法
US5463136A (en) 1994-12-22 1995-10-31 Shell Oil Company Cumene hydroperoxide cleavage process
US5705711A (en) * 1995-08-17 1998-01-06 Huntsman Specialty Chemicals Corporation Manufacture of methyl tertiary butyl ether in reactive distillation column
US5905178A (en) * 1998-04-20 1999-05-18 Catalytic Distillation Technologies Removal of α-methyl styrene from cumene

Also Published As

Publication number Publication date
DE60029132D1 (de) 2006-08-10
AU2447701A (en) 2001-07-03
US6410804B1 (en) 2002-06-25
US6441252B1 (en) 2002-08-27
EP1242348A1 (en) 2002-09-25
ES2267600T3 (es) 2007-03-16
DE60029132T2 (de) 2006-12-21
JP2003518047A (ja) 2003-06-03
ATE331702T1 (de) 2006-07-15
EP1242348B1 (en) 2006-06-28
WO2001046102A1 (en) 2001-06-28
US20020058845A1 (en) 2002-05-16

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