JP5037942B2 - ゴム、炭化水素樹脂および溶剤を含有する組成物の改良された連続製造方法 - Google Patents
ゴム、炭化水素樹脂および溶剤を含有する組成物の改良された連続製造方法 Download PDFInfo
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- JP5037942B2 JP5037942B2 JP2006530038A JP2006530038A JP5037942B2 JP 5037942 B2 JP5037942 B2 JP 5037942B2 JP 2006530038 A JP2006530038 A JP 2006530038A JP 2006530038 A JP2006530038 A JP 2006530038A JP 5037942 B2 JP5037942 B2 JP 5037942B2
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- 239000002904 solvent Substances 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 20
- 229920001971 elastomer Polymers 0.000 title claims abstract description 12
- 239000005060 rubber Substances 0.000 title claims abstract description 12
- 239000013032 Hydrocarbon resin Substances 0.000 title claims abstract description 11
- 229920006270 hydrocarbon resin Polymers 0.000 title claims abstract description 11
- 238000010924 continuous production Methods 0.000 title abstract description 3
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 4
- 229920003052 natural elastomer Polymers 0.000 claims description 4
- 229920001194 natural rubber Polymers 0.000 claims description 4
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/487—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws with consecutive casings or screws, e.g. for feeding, discharging, mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
- B29B7/007—Methods for continuous mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/94—Liquid charges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/375—Plasticisers, homogenisers or feeders comprising two or more stages
- B29C48/38—Plasticisers, homogenisers or feeders comprising two or more stages using two or more serially arranged screws in the same barrel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
- B29C48/404—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders the screws having non-intermeshing parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Apparatuses For Bulk Treatment Of Fruits And Vegetables And Apparatuses For Preparing Feeds (AREA)
- Nonmetallic Welding Materials (AREA)
Description
10b … 第2押出機
20 … ゴム
22 … 炭化水素樹脂
26 … 溶剤
Claims (12)
- ゴム(20)と、炭化水素樹脂(22)と、溶剤(26)とを含む接着性組成物の連続製造方法であって、
少なくとも、複数の区画からなる第1の2軸押出機(10a)と、複数の区画からなる第2の2軸押出機(10b)とを連続して配置し、
前記ゴム(20)を、前記第1の2軸押出機(10a)の最初の1番目の区画で加え、
前記樹脂(22)を、前記第1の2軸押出機(10a)の最初の1番目の区画で加え、そして、
前記第1の2軸押出機(10a)の最初の1番目の区画から下流の少なくとも1つの地点に、前記溶剤(26)を加え、
各2軸押出機の出口の温度は、前記溶剤(26)の沸点未満の温度であり、前記溶剤(26)中に、前記ゴム(20)および前記炭化水素樹脂(22)が溶解している、
製造方法。 - 前記溶剤(26)を分けて、第1の2軸押出機(10a)の最初の1番目の区画から下流の多数の地点および第2の2軸押出機(10b)に沿って配置された多数の地点で加える請求項1記載の製造方法。
- 前記組成物に溶剤(26)の画分を加えた後、前記組成物が、前記第1の2軸押出機(10a)を出て、前記第2の2軸押出機(10b)に入る、請求項2記載の製造方法。
- 前記樹脂(22)の画分を、前記第1の2軸押出機(10a)の最初の1番目の区画で加え、残りの画分を前記第1の2軸押出機(10a)の最初の1番目の区画から下流の地点で加える請求項1〜3のいずれか1項記載の製造方法。
- 前記第1の2軸押出機(10a)のスクリューの回転速度が20〜300rpmであり、前記第2の2軸押出機(10b)のスクリューの回転速度が60〜600rpmである請求項1〜4のいずれか1項記載の製造方法。
- 前記ゴム(20)が、天然ゴム、合成ゴムおよびそれらの混合物から成る群から選択される請求項1〜5のいずれか1項記載の製造方法。
- 前記炭化水素樹脂(22)が粘着性付与性を有する請求項1〜6のいずれか1項記載の製造方法。
- 前記溶剤(26)が、ペンタン、ヘキサン、ヘプタン、ジクロロプロパンおよびそれらの混合物から成る群から選択される請求項1〜7のいずれか1項記載の製造方法。
- 前記少なくとも2つの2軸押出機(10a、10b)が同方向回転型である請求項1〜8のいずれか1項記載の製造方法。
- 前記少なくとも2つの2軸押出機(10a、10b)の内の少なくとも1つが、スクリューの外径および内径の比が1.4〜2.0である請求項1〜9のいずれか1項記載の製造方法。
- 前記第2の2軸押出機(10b)中の前記組成物の温度が、前記第1の2軸押出機(10a)中の前記組成物の温度より低い請求項1〜10のいずれか1項記載の製造方法。
- 前記比が1.55〜1.8である、請求項10記載の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO2003A000764 | 2003-10-01 | ||
IT000764A ITTO20030764A1 (it) | 2003-10-01 | 2003-10-01 | Procedimento perfezionato di produzione in continuo di |
PCT/EP2004/010874 WO2005030457A1 (en) | 2003-10-01 | 2004-09-29 | Improved process for the continuous production of a composition comprising rubber, hydrocarbon resin and solvent |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2007507367A JP2007507367A (ja) | 2007-03-29 |
JP2007507367A5 JP2007507367A5 (ja) | 2010-10-28 |
JP5037942B2 true JP5037942B2 (ja) | 2012-10-03 |
Family
ID=34385839
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006530038A Expired - Fee Related JP5037942B2 (ja) | 2003-10-01 | 2004-09-29 | ゴム、炭化水素樹脂および溶剤を含有する組成物の改良された連続製造方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US7641832B2 (ja) |
EP (1) | EP1670626B1 (ja) |
JP (1) | JP5037942B2 (ja) |
CN (1) | CN100594107C (ja) |
AT (1) | ATE555885T1 (ja) |
BR (1) | BRPI0415153B1 (ja) |
IT (1) | ITTO20030764A1 (ja) |
RU (1) | RU2372359C2 (ja) |
WO (1) | WO2005030457A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11314139B2 (en) * | 2009-12-22 | 2022-04-26 | View, Inc. | Self-contained EC IGU |
CN102173003B (zh) * | 2010-12-24 | 2013-12-18 | 佛山市金银河智能装备股份有限公司 | 热硫化硅橡胶的自动生产线 |
CN102357935A (zh) * | 2011-08-30 | 2012-02-22 | 佛山市金银河机械设备有限公司 | 液体硅橡胶的自动连续生产线 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5936861B2 (ja) * | 1977-05-25 | 1984-09-06 | 日立電線株式会社 | 流体状添加剤を押出成型品中に添加する方法 |
US4687794A (en) * | 1986-08-01 | 1987-08-18 | The Kendall Company | Novel system for preparing rubber compositions employing a cavity transfer mixer |
DE3702833A1 (de) * | 1987-01-30 | 1988-08-11 | Peter Julius | Verfahren und vorrichtung zur herstellung von kautschukmischungen |
US4906421A (en) * | 1987-07-01 | 1990-03-06 | Avery International Corporation | Process for making high performance pressure sensitive adhesive tapes |
US4816101A (en) | 1987-08-27 | 1989-03-28 | The Uniroyal Goodrich Tire Company | Process for extruding a puncture sealant and forming an elastomeric laminate |
JPH089709B2 (ja) * | 1990-11-09 | 1996-01-31 | 積水化学工業株式会社 | 溶剤型天然ゴム系粘着剤の製造方法 |
DE4039943A1 (de) * | 1990-12-14 | 1992-06-17 | Berstorff Gmbh Masch Hermann | Verfahren und vorrichtung zur einstufigen, kontinuierlichen herstellung einer kautschaukgrund- und fertigmischung fuer fahrzeugreifen, antriebsriemen, transportbaender sowie fuer technische gummiartikel in nur einer mischvorrichtung |
US5539033A (en) * | 1992-11-06 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Solventless compounding and coating of non-thermoplastic hydrocarbon elastomers |
FR2698820A1 (fr) * | 1992-12-07 | 1994-06-10 | Sedepro | Procédé et appareil de mélangeage en continu de caoutchouc. |
JPH06322333A (ja) * | 1993-05-12 | 1994-11-22 | Sekisui Chem Co Ltd | 溶剤型ゴム系粘着剤の製造方法 |
JPH08245799A (ja) | 1995-03-08 | 1996-09-24 | Tonen Chem Corp | ポリオレフィン溶液の製造方法 |
CN1114669C (zh) | 2000-06-19 | 2003-07-16 | 黄世德 | 常温固化输送带接头氯丁橡胶粘合剂 |
TWI296635B (ja) * | 2000-09-08 | 2008-05-11 | Asahi Kasei Chemicals Corp | |
JP3868757B2 (ja) * | 2001-04-25 | 2007-01-17 | 株式会社神戸製鋼所 | ゴム系組成物の混練装置および混練方法 |
JP2002337139A (ja) * | 2001-05-17 | 2002-11-27 | Dainippon Ink & Chem Inc | 熱可塑性樹脂組成物の連続押出法 |
EP1419044B1 (en) * | 2001-07-25 | 2012-12-12 | Pirelli Tyre S.p.A. | Process for continuously producing an elastomeric composition |
DE10162076B4 (de) * | 2001-12-07 | 2009-03-05 | Kraussmaffei Berstorff Gmbh | Mehrfach-Extruderanordnung |
ITTO20020578A1 (it) * | 2002-07-03 | 2004-01-05 | Maris Spa Flli | Procedimento di produzione in continuo di una composizione comprendente gomma resina idrocarbonica e solvente |
-
2003
- 2003-10-01 IT IT000764A patent/ITTO20030764A1/it unknown
-
2004
- 2004-09-29 EP EP04765678A patent/EP1670626B1/en active Active
- 2004-09-29 BR BRPI0415153-4A patent/BRPI0415153B1/pt not_active IP Right Cessation
- 2004-09-29 RU RU2006114351/04A patent/RU2372359C2/ru not_active IP Right Cessation
- 2004-09-29 AT AT04765678T patent/ATE555885T1/de active
- 2004-09-29 US US10/574,481 patent/US7641832B2/en not_active Expired - Fee Related
- 2004-09-29 WO PCT/EP2004/010874 patent/WO2005030457A1/en active Application Filing
- 2004-09-29 CN CN200480028611A patent/CN100594107C/zh not_active Expired - Fee Related
- 2004-09-29 JP JP2006530038A patent/JP5037942B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1670626B1 (en) | 2012-05-02 |
CN1860011A (zh) | 2006-11-08 |
BRPI0415153B1 (pt) | 2015-04-07 |
EP1670626A1 (en) | 2006-06-21 |
JP2007507367A (ja) | 2007-03-29 |
US20080023876A1 (en) | 2008-01-31 |
ATE555885T1 (de) | 2012-05-15 |
CN100594107C (zh) | 2010-03-17 |
WO2005030457A1 (en) | 2005-04-07 |
ITTO20030764A1 (it) | 2005-04-02 |
RU2006114351A (ru) | 2007-11-20 |
BRPI0415153A (pt) | 2006-11-28 |
RU2372359C2 (ru) | 2009-11-10 |
US7641832B2 (en) | 2010-01-05 |
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