JP4960242B2 - 低揮発性イソシアネートモノマー含有ポリウレタンプレポリマー及び接着剤システム - Google Patents

低揮発性イソシアネートモノマー含有ポリウレタンプレポリマー及び接着剤システム Download PDF

Info

Publication number
JP4960242B2
JP4960242B2 JP2007535918A JP2007535918A JP4960242B2 JP 4960242 B2 JP4960242 B2 JP 4960242B2 JP 2007535918 A JP2007535918 A JP 2007535918A JP 2007535918 A JP2007535918 A JP 2007535918A JP 4960242 B2 JP4960242 B2 JP 4960242B2
Authority
JP
Japan
Prior art keywords
isocyanate
prepolymer
adhesive
composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2007535918A
Other languages
English (en)
Japanese (ja)
Other versions
JP2008516057A5 (https=
JP2008516057A (ja
Inventor
ディー． ツー，フイデ
アール． ニーセル，アンドリュー
ゼット． マーディ，サイド
ダブリュ． サラクサン，ジェフリー
Original Assignee
ダウ グローバル テクノロジーズ エルエルシー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ダウ グローバル テクノロジーズ エルエルシー filed Critical ダウ グローバル テクノロジーズ エルエルシー
Publication of JP2008516057A publication Critical patent/JP2008516057A/ja
Publication of JP2008516057A5 publication Critical patent/JP2008516057A5/ja
Application granted granted Critical
Publication of JP4960242B2 publication Critical patent/JP4960242B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • C09J201/02—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C09J201/025—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polyurethanes Or Polyureas (AREA)
JP2007535918A 2004-10-08 2005-10-11 低揮発性イソシアネートモノマー含有ポリウレタンプレポリマー及び接着剤システム Expired - Fee Related JP4960242B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US96164304A 2004-10-08 2004-10-08
US10/961,643 2004-10-08
PCT/US2005/036831 WO2006042305A1 (en) 2004-10-08 2005-10-11 Low volatile isocyanate monomer containing polyurethane prepolymer and adhesive system

Publications (3)

Publication Number Publication Date
JP2008516057A JP2008516057A (ja) 2008-05-15
JP2008516057A5 JP2008516057A5 (https=) 2008-11-27
JP4960242B2 true JP4960242B2 (ja) 2012-06-27

Family

ID=35735126

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007535918A Expired - Fee Related JP4960242B2 (ja) 2004-10-08 2005-10-11 低揮発性イソシアネートモノマー含有ポリウレタンプレポリマー及び接着剤システム

Country Status (4)

Country Link
US (2) US20060079661A1 (https=)
EP (1) EP1799738B1 (https=)
JP (1) JP4960242B2 (https=)
WO (1) WO2006042305A1 (https=)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070048504A1 (en) * 2005-08-25 2007-03-01 Dimario Joseph Methods for applying sound dampening and/or aesthetic coatings and articles made thereby
US7658967B2 (en) 2005-08-25 2010-02-09 Pittsburgh Glass Works, Llc Methods for applying sound dampening and/or aesthetic coatings and articles made thereby
CN101522746B (zh) * 2006-10-05 2012-09-26 陶氏环球技术公司 用于玻璃接合的底漆组合物
WO2008077060A1 (en) 2006-12-19 2008-06-26 Dow Global Technologies, Inc. Improved composites and methods for conductive transparent substrates
EP2094463B1 (en) 2006-12-19 2016-07-27 Dow Global Technologies LLC Encapsulated panel assemblies and method for making same
CN101563412B (zh) 2006-12-19 2014-07-16 陶氏环球技术公司 用于改进涂料组合物的促粘添加剂和方法
EP1947126A1 (de) * 2007-01-17 2008-07-23 Sika Technology AG Haftvermittlerzusammensetzung für Polymere Substrate
WO2008097852A1 (en) * 2007-02-02 2008-08-14 Dow Global Technologies Inc. Adhesive useful for installing vehicle windows
CA2662947C (en) 2007-04-24 2013-03-26 Dow Global Technologies Inc. One component glass primer including oxazoladine
JP5666294B2 (ja) * 2007-04-24 2015-02-12 ダウ グローバル テクノロジーズ エルエルシー 一般的なプライマー組成物及び方法
WO2009009159A1 (en) 2007-07-12 2009-01-15 Dow Global Technologies, Inc. Colored primer compositions and methods
WO2009061580A1 (en) * 2007-11-07 2009-05-14 Dow Global Technologies Inc. Polyurethane adhesive compositions having high filler levels
KR101587666B1 (ko) 2007-12-18 2016-01-21 다우 글로벌 테크놀로지스 엘엘씨 유리 결합용 접착제에 대한 접착성이 개선된 창 유리용 보호 코팅
WO2009086459A1 (en) * 2007-12-28 2009-07-09 Bostik, Inc. A continuous process for the production of moisture-cure, polyurethane sealants and adhesives
DE102008025793A1 (de) * 2008-05-29 2009-12-03 Henkel Ag & Co. Kgaa Reaktive Klebstoffe mit sehr geringem Gehalt an monomeren Diisocyanaten
JP5312602B2 (ja) * 2008-10-29 2013-10-09 ダウ グローバル テクノロジーズ エルエルシー 長いオープンタイムを有するプライマーを含有する低エネルギー表面接着システム
DE102009005017A1 (de) * 2009-01-17 2010-07-22 Bayer Materialscience Ag Reaktive Polyurethan Zusammensetzungen
JP2011068806A (ja) * 2009-09-28 2011-04-07 Auto Kagaku Kogyo Kk 硬化性組成物
DE102009046050A1 (de) 2009-10-27 2011-04-28 Henkel Ag & Co. Kgaa PU-Klebstoff mit Viskositätsregler
WO2011090627A1 (en) 2009-12-29 2011-07-28 Dow Global Technologies Inc. Fire-resistant polyurethane foam for sound and vibration absorption
DE102010028269A1 (de) * 2010-04-27 2011-10-27 Henkel Ag & Co. Kgaa PU-Klebstoff mit Fließgrenze
EP2481764A1 (en) 2011-01-27 2012-08-01 de Schrijver, Aster Composition for one-component polyurethane foams having low free monomeric MDI content
CN103370350B (zh) 2011-02-17 2015-05-27 陶氏环球技术有限责任公司 含有碳酸钙的含烷氧基硅烷的聚氨酯粘合剂组合物
PL2780384T5 (pl) 2011-11-16 2020-11-02 Soudal Ulepszona kompozycja pianki poliuretanowej
JP6196297B2 (ja) * 2012-05-22 2017-09-13 ダウ グローバル テクノロジーズ エルエルシー 高弾性ウレタン接着剤組成物、それらの製造および使用
CN105764949B (zh) * 2013-12-09 2019-05-31 陶氏环球技术有限责任公司 具有极少或无塑化剂的改进的聚氨基甲酸酯预聚物和其在车辆玻璃粘合剂中的用途
CN104449534B (zh) * 2014-11-21 2016-08-24 济南汉斯曼时代技术有限公司 一种免底涂聚氨酯玻璃胶及其制备方法
MX2017006889A (es) 2014-12-01 2017-09-01 Dow Global Technologies Llc Películas de contracción, y métodos para su fabricación.
JP6480176B2 (ja) 2014-12-19 2019-03-06 ヘンケルジャパン株式会社 ウレタン粘着剤
WO2018061335A1 (ja) * 2016-09-28 2018-04-05 横浜ゴム株式会社 １液湿気硬化型ウレタン組成物
KR20200105483A (ko) 2018-01-10 2020-09-07 헌트스만 인터내셔날, 엘엘씨 이소시아네이트 관능성을 갖는 제제를 포함하는 폴리우레탄
CN114364766B (zh) * 2019-10-09 2023-05-23 Sika技术股份公司 用于低温应用的单组分聚氨酯密封剂
AU2024362835A1 (en) * 2023-10-16 2026-03-26 Henkel Ag & Co. Kgaa Liquid, one component, moisture curable polyurethane for bonding untreated metals
GB202317086D0 (en) * 2023-11-07 2023-12-20 Sylmasta Ltd Bandages
BE1032362B1 (nl) * 2024-01-31 2025-09-01 Soudal N V Reactieve polyurethaanformulering met een laag monomeer gehalte

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3391101A (en) * 1964-08-10 1968-07-02 Jefferson Chem Co Inc Pipe sealant compositions
US3779794A (en) * 1970-03-05 1973-12-18 Essex Chemical Corp Polyurethane sealant-primer system
US3707521A (en) * 1970-03-05 1972-12-26 Essex Chemical Corp Polyurethane sealant-primer system isocyanate-reactive surface primer composition for polyurethane sealants
US3933725A (en) * 1974-09-26 1976-01-20 General Motors Corporation Preparation of isocyanate terminated prepolymer
GB2137638A (en) * 1983-04-05 1984-10-10 Bostik Ltd Adhesive compositions
DE3401129A1 (de) * 1984-01-14 1985-07-18 Henkel KGaA, 4000 Düsseldorf Verfahren zur herstellung gemischter polyurethan-prepolymerer
US4525511A (en) * 1984-04-06 1985-06-25 Essex Specialty Products, Inc. Method and compositions for improving bonding to painted surfaces
WO1991015530A1 (en) * 1990-03-30 1991-10-17 H.B. Fuller Licensing & Financing Inc. Hot melt moisture-cure polyurethane adhesive
DE4210277C5 (de) * 1992-03-28 2009-02-26 Henkel Ag & Co. Kgaa Kleb- und Dichtstoff und dessen Verwendung
MX9701338A (es) * 1994-08-22 1997-05-31 Henkel Kgaa Composiciones de poliuretano con bajo contenido endiisocianatos monomeros.
US5922809A (en) * 1996-01-11 1999-07-13 The Dow Chemical Company One-part moisture curable polyurethane adhesive
CA2214311A1 (en) * 1996-09-06 1998-03-06 Air Products And Chemicals, Inc. Hot melt adhesives comprising low free monomer, low oligomer isocyanate prepolymers
DE19700014A1 (de) * 1997-01-02 1998-07-09 Henkel Kgaa Monomerenarmes PU-Prepolymer
US5852137A (en) * 1997-01-29 1998-12-22 Essex Specialty Products Polyurethane sealant compositions
JP3881083B2 (ja) * 1997-05-14 2007-02-14 横浜ゴム株式会社 湿気硬化型一液ウレタンシーリング材組成物の製造方法及びその組成物
BR9815177B1 (pt) * 1997-12-18 2008-11-18 mÉtodo para tratamento de uma superfÍcie pintada e composiÇço de prÉ-revestimento.
US5817860A (en) * 1998-03-20 1998-10-06 Essex Specialty Products, Inc. Polyurethane prepolymer compositions, foams made therefrom and methods of making each thereof
ES2205812T3 (es) * 1998-04-27 2004-05-01 Essex Specialty Products, Inc. Metodo para unir un vidrio de ventana a un sustrato utilizando una composicion adhesiva con funcionalidad silano.
US6255433B1 (en) * 1998-06-19 2001-07-03 Takeda Chemical Industries, Ltd. One-package thixotropic polyurethane resin composition
US6809171B2 (en) * 1998-07-20 2004-10-26 Henkel Kommanditgesellschaft Auf Aktien Monomer-poor polyurethane bonding agent having an improved lubricant adhesion
US6866743B2 (en) * 2001-04-12 2005-03-15 Air Products And Chemicals, Inc. Controlled structure polyurethane prepolymers for polyurethane structural adhesives
US6884904B2 (en) * 2001-04-12 2005-04-26 Air Products And Chemicals, Inc. MDI-based polyurethane prepolymer with low monomeric MDI content
US20030092848A1 (en) * 2001-09-11 2003-05-15 Ashok Sengupta Sprayable liner for supporting the rock surface of a mine
KR20030057384A (ko) * 2001-12-27 2003-07-04 요코하마 고무 가부시키가이샤 폴리우레탄 조성물

Also Published As

Publication number Publication date
US20060079661A1 (en) 2006-04-13
EP1799738B1 (en) 2017-05-03
WO2006042305A1 (en) 2006-04-20
EP1799738A1 (en) 2007-06-27
JP2008516057A (ja) 2008-05-15
US20080041522A1 (en) 2008-02-21

Similar Documents

Publication Publication Date Title
JP4960242B2 (ja) 低揮発性イソシアネートモノマー含有ポリウレタンプレポリマー及び接着剤システム
KR101359140B1 (ko) 자동차 창문 설치용 접착제로서 유용한 조성물
KR101226337B1 (ko) 자동차 창문을 설치하기에 유용한 고탄성률, 비전도성의폴리우레탄 프리폴리머계 접착제
JP5669735B2 (ja) 大質量部品を構造体に接着するのに適応した接着剤組成物
CN104672413B (zh) 在固化状态下具有改进的耐久性的含异氰酸酯官能组分的可固化组合物
CN102869695B (zh) 改进的交通工具玻璃粘合剂和粘合所述玻璃的方法
EP2207830B1 (en) Polyurethane adhesive compositions having high filler levels
JP4673306B2 (ja) 車両窓の取付用接着剤として有用な組成物
JP7333314B2 (ja) シラン化アクリルポリオールに基づくコーティングにプライマーレスで結合するイソシアネート官能性接着剤
JP6336381B2 (ja) 迅速な走行可能時間を提供する車輌窓装着において有用な接着剤
JP2001511216A (ja) ポリウレタンシーラント組成物
CN106257984B (zh) 可用于粘结玻璃的可湿致固化聚氨酯粘合剂组合物的加速固化
CN104968698A (zh) 适用于粘合到玻璃的快速固化粘合剂
JP7313357B2 (ja) 車両窓を設置するために有用な接着剤

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20081010

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20081010

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110809

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20111109

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20111116

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111205

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120221

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120322

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150330

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees