JP4938457B2 - ポリマー電解質膜および製造方法 - Google Patents

ポリマー電解質膜および製造方法 Download PDF

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Publication number
JP4938457B2
JP4938457B2 JP2006538036A JP2006538036A JP4938457B2 JP 4938457 B2 JP4938457 B2 JP 4938457B2 JP 2006538036 A JP2006538036 A JP 2006538036A JP 2006538036 A JP2006538036 A JP 2006538036A JP 4938457 B2 JP4938457 B2 JP 4938457B2
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typically
polymer
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membrane
polymers
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Japanese (ja)
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JP2007511047A5 (OSRAM
JP2007511047A (ja
Inventor
ジェイ． ハムロック，スティーブン
エム． リバード，リンダ
エー． ヤンドラシッツ，マイケル
エム． ピアーポント，ダニエル
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/109—After-treatment of the membrane other than by polymerisation thermal other than drying, e.g. sintering
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Development (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
JP2006538036A 2003-10-30 2004-10-08 ポリマー電解質膜および製造方法 Expired - Fee Related JP4938457B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/697,831 2003-10-30
US10/697,831 US7285349B2 (en) 2003-10-30 2003-10-30 Polymer electrolyte membrane and method of making
PCT/US2004/033299 WO2005045978A2 (en) 2003-10-30 2004-10-08 Polymer electrolyte membrane and method of making

Publications (3)

Publication Number Publication Date
JP2007511047A JP2007511047A (ja) 2007-04-26
JP2007511047A5 JP2007511047A5 (OSRAM) 2007-11-22
JP4938457B2 true JP4938457B2 (ja) 2012-05-23

Family

ID=34550459

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006538036A Expired - Fee Related JP4938457B2 (ja) 2003-10-30 2004-10-08 ポリマー電解質膜および製造方法

Country Status (7)

Country Link
US (1) US7285349B2 (OSRAM)
EP (1) EP1683224B1 (OSRAM)
JP (1) JP4938457B2 (OSRAM)
KR (1) KR20060120172A (OSRAM)
CN (1) CN100448087C (OSRAM)
CA (1) CA2544054A1 (OSRAM)
WO (1) WO2005045978A2 (OSRAM)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040116742A1 (en) * 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US7610582B2 (en) * 2003-04-18 2009-10-27 Sap Ag Managing a computer system with blades
EP1667265B1 (en) * 2003-09-17 2011-03-23 Asahi Kasei Kabushiki Kaisha Membrane-electrode assembly for solid polymer fuel cell
US8465858B2 (en) * 2004-07-28 2013-06-18 University Of South Carolina Development of a novel method for preparation of PEMFC electrodes
US8247135B2 (en) * 2004-09-14 2012-08-21 Case Western Reserve University Light-weight, flexible edge collected fuel cells
US20060141138A1 (en) * 2004-12-29 2006-06-29 3M Innovative Properties Company Microwave annealing of membranes for use in fuel cell assemblies
US20070214962A1 (en) * 2006-03-16 2007-09-20 Kozak Paul D Fluorination of a porous hydrocarbon-based polymer for use as composite membrane
EP3012895A3 (en) * 2007-11-09 2016-06-01 3M Innovative Properties Company Polymer electrolytes including heteropolyacids
EP2062933A1 (en) 2007-11-26 2009-05-27 Solvay Solexis S.p.A. Fluoroionomer liquid composition
CN103788280B (zh) 2008-04-24 2016-08-17 3M创新有限公司 质子传导材料
EP2374180A1 (en) * 2008-12-22 2011-10-12 3M Innovative Properties Company Fuel cell membrane electrode assembly with multilayer cathode
US9893373B2 (en) 2010-05-25 2018-02-13 3M Innovative Properties Company Reinforced electrolyte membrane
CN103403936B (zh) 2011-03-11 2016-08-17 奥迪股份公司 具有高当量重量离子交联聚合物的单元化电极组件
CN103547915B (zh) * 2011-06-08 2015-11-25 3M创新有限公司 湿度传感器及其传感器元件
US9663600B2 (en) 2012-12-21 2017-05-30 Audi Ag Method of fabricating an electrolyte material
EP2956979B1 (en) 2012-12-21 2019-02-20 Toyota Jidosha Kabushiki Kaisha Proton exchange material and method therefor
US9923223B2 (en) 2012-12-21 2018-03-20 Audi Ag Electrolyte membrane, dispersion and method therefor
CN109690695B (zh) * 2016-09-08 2021-01-08 旭化成株式会社 固体高分子电解质膜及其制造方法
EP3473659A1 (de) 2017-10-17 2019-04-24 Evonik Degussa GmbH Polymere anionen leitende membrane
PT3770201T (pt) 2019-07-22 2023-08-18 Evonik Operations Gmbh Membrana polimérica condutora de aniões
EP4127002A1 (en) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
KR102699314B1 (ko) * 2022-02-11 2024-08-30 상명대학교 천안산학협력단 높은 함수율과 이온전도도를 갖는 고분자전해질 막
GB2641268A (en) * 2024-05-23 2025-11-26 Johnson Matthey Hydrogen Technologies Ltd Water electrolyser membrane

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06231778A (ja) * 1993-01-29 1994-08-19 Asahi Glass Co Ltd 固体高分子電解質型燃料電池
JPH11204119A (ja) * 1997-12-26 1999-07-30 E I Du Pont De Nemours & Co 固体高分子電解質型燃料電池およびその製造方法
JPH11329062A (ja) * 1998-05-13 1999-11-30 Daikin Ind Ltd 燃料電池に使用するのに適した固体高分子電解質用材料
JP2006511919A (ja) * 2002-12-19 2006-04-06 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化主鎖ポリマー電解質膜

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6026496B2 (ja) * 1980-04-18 1985-06-24 旭化成株式会社 改良された陽イオン交換膜
US4417969A (en) * 1980-06-11 1983-11-29 The Dow Chemical Co. Sulfonic acid electrolytic cell membranes
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
JPS5893728A (ja) 1981-12-01 1983-06-03 Tokuyama Soda Co Ltd イオン交換膜
AU570847B2 (en) 1985-05-17 1988-03-24 Dow Chemical Company, The Electrochemical cell component, process for preparing same and processes utilising the component
JPS6461507A (en) * 1987-08-26 1989-03-08 Asahi Chemical Ind Production of fiber composed of fluorocarbon polymer
US5302269A (en) * 1990-06-11 1994-04-12 The Dow Chemical Company Ion exchange membrane/electrode assembly having increased efficiency in proton exchange processes
US6277521B1 (en) * 1997-05-15 2001-08-21 Fmc Corporation Lithium metal oxide containing multiple dopants and method of preparing same
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
US6649299B2 (en) * 2000-02-11 2003-11-18 The Texas A&M University System Gas diffusion electrode with nanosized pores and method for making same
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06231778A (ja) * 1993-01-29 1994-08-19 Asahi Glass Co Ltd 固体高分子電解質型燃料電池
JPH11204119A (ja) * 1997-12-26 1999-07-30 E I Du Pont De Nemours & Co 固体高分子電解質型燃料電池およびその製造方法
JPH11329062A (ja) * 1998-05-13 1999-11-30 Daikin Ind Ltd 燃料電池に使用するのに適した固体高分子電解質用材料
JP2006511919A (ja) * 2002-12-19 2006-04-06 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化主鎖ポリマー電解質膜

Also Published As

Publication number Publication date
KR20060120172A (ko) 2006-11-24
CN1886857A (zh) 2006-12-27
EP1683224B1 (en) 2019-01-23
US7285349B2 (en) 2007-10-23
CA2544054A1 (en) 2005-05-19
WO2005045978A3 (en) 2006-02-02
US20050095487A1 (en) 2005-05-05
JP2007511047A (ja) 2007-04-26
CN100448087C (zh) 2008-12-31
WO2005045978A2 (en) 2005-05-19
EP1683224A2 (en) 2006-07-26

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