JP4833717B2 - 接触燃焼式ガスセンサとその検知素子および補償素子 - Google Patents
接触燃焼式ガスセンサとその検知素子および補償素子 Download PDFInfo
- Publication number
- JP4833717B2 JP4833717B2 JP2006100258A JP2006100258A JP4833717B2 JP 4833717 B2 JP4833717 B2 JP 4833717B2 JP 2006100258 A JP2006100258 A JP 2006100258A JP 2006100258 A JP2006100258 A JP 2006100258A JP 4833717 B2 JP4833717 B2 JP 4833717B2
- Authority
- JP
- Japan
- Prior art keywords
- gas sensor
- layer
- compensation
- fired
- type gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002485 combustion reaction Methods 0.000 title claims description 68
- 239000007789 gas Substances 0.000 claims description 95
- 238000001514 detection method Methods 0.000 claims description 75
- 239000000463 material Substances 0.000 claims description 69
- 239000003054 catalyst Substances 0.000 claims description 37
- 238000007084 catalytic combustion reaction Methods 0.000 claims description 25
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 25
- 229910001887 tin oxide Inorganic materials 0.000 claims description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 21
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 19
- 239000000843 powder Substances 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052763 palladium Inorganic materials 0.000 claims description 10
- 239000000567 combustion gas Substances 0.000 claims description 9
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 8
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 238000010304 firing Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000009833 condensation Methods 0.000 description 12
- 230000005494 condensation Effects 0.000 description 12
- 230000008014 freezing Effects 0.000 description 8
- 238000007710 freezing Methods 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 230000035945 sensitivity Effects 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 239000000470 constituent Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910000629 Rh alloy Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000010485 coping Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/14—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature
- G01N27/16—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature caused by burning or catalytic oxidation of surrounding material to be tested, e.g. of gas
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/005—H2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006100258A JP4833717B2 (ja) | 2006-03-31 | 2006-03-31 | 接触燃焼式ガスセンサとその検知素子および補償素子 |
| US12/295,177 US7947226B2 (en) | 2006-03-31 | 2007-03-29 | Catalytic combustion type gas sensor, sensing element and compensating element for the same |
| PCT/JP2007/056902 WO2007114267A1 (ja) | 2006-03-31 | 2007-03-29 | 接触燃焼式ガスセンサとその検知素子および補償素子 |
| EP07740340A EP2009433B1 (en) | 2006-03-31 | 2007-03-29 | Catalytic combustion type gas sensor, detection device and compensating device |
| CN2007800111106A CN101410711B (zh) | 2006-03-31 | 2007-03-29 | 接触燃烧式气体传感器及其探测元件以及补偿元件 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006100258A JP4833717B2 (ja) | 2006-03-31 | 2006-03-31 | 接触燃焼式ガスセンサとその検知素子および補償素子 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007271556A JP2007271556A (ja) | 2007-10-18 |
| JP2007271556A5 JP2007271556A5 (enExample) | 2009-04-09 |
| JP4833717B2 true JP4833717B2 (ja) | 2011-12-07 |
Family
ID=38563535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006100258A Expired - Fee Related JP4833717B2 (ja) | 2006-03-31 | 2006-03-31 | 接触燃焼式ガスセンサとその検知素子および補償素子 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7947226B2 (enExample) |
| EP (1) | EP2009433B1 (enExample) |
| JP (1) | JP4833717B2 (enExample) |
| CN (1) | CN101410711B (enExample) |
| WO (1) | WO2007114267A1 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5307588B2 (ja) | 2009-03-11 | 2013-10-02 | アイシン・エーアイ株式会社 | 車両の動力伝達制御装置 |
| JP5307589B2 (ja) | 2009-03-11 | 2013-10-02 | アイシン・エーアイ株式会社 | 車両の動力伝達制御装置 |
| JP2010208521A (ja) | 2009-03-11 | 2010-09-24 | Aisin Ai Co Ltd | 車両の動力伝達制御装置 |
| JP2010208523A (ja) | 2009-03-11 | 2010-09-24 | Aisin Ai Co Ltd | 車両の動力伝達制御装置 |
| JP5307587B2 (ja) | 2009-03-11 | 2013-10-02 | アイシン・エーアイ株式会社 | 車両の動力伝達制御装置 |
| JP5307604B2 (ja) | 2009-04-08 | 2013-10-02 | アイシン・エーアイ株式会社 | 車両の動力伝達制御装置 |
| JP5340790B2 (ja) | 2009-04-08 | 2013-11-13 | アイシン・エーアイ株式会社 | 車両の動力伝達制御装置 |
| US10578573B2 (en) * | 2013-03-12 | 2020-03-03 | Msa Technology, Llc | Diagnostics for catalytic structures and combustible gas sensors including catalytic structures |
| JP6146271B2 (ja) * | 2013-11-20 | 2017-06-14 | 株式会社デンソー | ガスセンサ |
| WO2015123499A1 (en) * | 2014-02-14 | 2015-08-20 | Rosemount Analytical Inc. | Solid state gas detection sensor diagnostic |
| JP6472168B2 (ja) * | 2014-03-25 | 2019-02-20 | 新コスモス電機株式会社 | 接触燃焼式ガスセンサ |
| JP6512701B2 (ja) * | 2015-05-12 | 2019-05-15 | 理研計器株式会社 | 接触燃焼式ガスセンサー |
| US9759699B1 (en) * | 2015-05-22 | 2017-09-12 | Council On Postsecondary Education | Systems and methods for the detection of compounds |
| US10041898B2 (en) * | 2015-12-01 | 2018-08-07 | International Business Machines Corporation | 3D micro and nanoheater design for ultra-low power gas sensors |
| CN105572170B (zh) * | 2015-12-10 | 2017-12-29 | 郑州大学 | 具有环境温、湿度自补偿能力的SnO2基热线型半导体气体传感器 |
| CN107228927B (zh) * | 2017-06-22 | 2019-08-13 | 云南大学 | 一种高灵敏度甲烷气体敏感材料及其制备方法与应用 |
| JP7046509B2 (ja) * | 2017-07-10 | 2022-04-04 | 新コスモス電機株式会社 | 接触燃焼式ガスセンサ |
| EP3848702A4 (en) * | 2018-09-05 | 2022-04-20 | Osaka Gas Co., Ltd. | Gas detection device |
| US11703471B1 (en) | 2018-12-20 | 2023-07-18 | University Of Rhode Island Board Of Trustees | Trace detection of chemical compounds via catalytic decomposition and redox reactions |
| WO2022150229A2 (en) | 2020-11-06 | 2022-07-14 | Pgr Holdings, Llc | Decoupled thermodynamic sensing system |
| US12188914B2 (en) | 2020-11-06 | 2025-01-07 | Trace Sensing Technologies Inc. | Decoupled thermodynamic sensing system |
| US11340183B1 (en) | 2021-06-23 | 2022-05-24 | Pgr Holdings, Llc | Ultrasensitive, ultrathin vapor sensors and arrays |
| US12405238B2 (en) | 2021-06-23 | 2025-09-02 | Trace Sensing Technologies Inc. | Ultrasensitive, ultrathin vapor sensors and arrays |
| JP7671223B2 (ja) * | 2021-10-05 | 2025-05-01 | 新コスモス電機株式会社 | Mems型接触燃焼式ガスセンサ |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2125554B (en) * | 1982-08-16 | 1985-12-24 | Sieger J & S Ltd | Catalytic gas detector |
| GB8516389D0 (en) | 1985-06-28 | 1985-07-31 | Coles G S V | Gas sensors |
| JPH03162658A (ja) | 1989-11-21 | 1991-07-12 | Fuji Electric Co Ltd | ガス検知素子 |
| US5739742A (en) * | 1995-08-31 | 1998-04-14 | Matsushita Electric Industrial Co., Ltd. | Zinc oxide ceramics and method for producing the same and zinc oxide varistors |
| JP3624928B2 (ja) * | 1997-09-11 | 2005-03-02 | 富士電機機器制御株式会社 | ガスセンサ用触媒の製造方法 |
| JP3919306B2 (ja) * | 1997-10-31 | 2007-05-23 | 新コスモス電機株式会社 | 炭化水素ガス検知素子 |
| JP3812215B2 (ja) * | 1999-04-02 | 2006-08-23 | 富士電機機器制御株式会社 | 薄膜ガスセンサ |
| JP2002139469A (ja) * | 2000-11-02 | 2002-05-17 | Yazaki Corp | ガス検知素子及びそれを有するガス検知装置 |
| JP3844723B2 (ja) | 2002-08-05 | 2006-11-15 | 本田技研工業株式会社 | ガスセンサの結露防止構造 |
| JP4724426B2 (ja) | 2004-03-30 | 2011-07-13 | シチズンホールディングス株式会社 | ガスセンサ用検知素子および接触燃焼式ガスセンサ |
-
2006
- 2006-03-31 JP JP2006100258A patent/JP4833717B2/ja not_active Expired - Fee Related
-
2007
- 2007-03-29 CN CN2007800111106A patent/CN101410711B/zh not_active Expired - Fee Related
- 2007-03-29 WO PCT/JP2007/056902 patent/WO2007114267A1/ja not_active Ceased
- 2007-03-29 US US12/295,177 patent/US7947226B2/en not_active Expired - Fee Related
- 2007-03-29 EP EP07740340A patent/EP2009433B1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2009433A1 (en) | 2008-12-31 |
| CN101410711B (zh) | 2012-11-21 |
| JP2007271556A (ja) | 2007-10-18 |
| EP2009433A4 (en) | 2009-05-27 |
| US20090249859A1 (en) | 2009-10-08 |
| US7947226B2 (en) | 2011-05-24 |
| CN101410711A (zh) | 2009-04-15 |
| EP2009433B1 (en) | 2011-05-18 |
| WO2007114267A1 (ja) | 2007-10-11 |
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