JP4749544B2 - 安定な酸化性の臭素製剤、その製造方法および微生物汚損の制御のために使用する方法 - Google Patents
安定な酸化性の臭素製剤、その製造方法および微生物汚損の制御のために使用する方法 Download PDFInfo
- Publication number
- JP4749544B2 JP4749544B2 JP2000545793A JP2000545793A JP4749544B2 JP 4749544 B2 JP4749544 B2 JP 4749544B2 JP 2000545793 A JP2000545793 A JP 2000545793A JP 2000545793 A JP2000545793 A JP 2000545793A JP 4749544 B2 JP4749544 B2 JP 4749544B2
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- Prior art keywords
- solution
- stable
- bromine compound
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- adjusting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 230000001590 oxidative effect Effects 0.000 title claims description 66
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title claims description 62
- 229910052794 bromium Inorganic materials 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 52
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title claims description 31
- 230000000813 microbial effect Effects 0.000 title claims description 8
- 239000000203 mixture Substances 0.000 title description 10
- 238000009472 formulation Methods 0.000 title description 5
- 238000002360 preparation method Methods 0.000 title description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 55
- 239000007800 oxidant agent Substances 0.000 claims description 41
- -1 bromine compound Chemical class 0.000 claims description 39
- 239000008235 industrial water Substances 0.000 claims description 22
- 229910001616 alkaline earth metal bromide Inorganic materials 0.000 claims description 15
- 150000002367 halogens Chemical class 0.000 claims description 14
- 239000003381 stabilizer Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000003513 alkali Substances 0.000 claims description 13
- 230000003115 biocidal effect Effects 0.000 claims description 13
- 239000003139 biocide Substances 0.000 claims description 13
- 229910052736 halogen Inorganic materials 0.000 claims description 13
- 229910001513 alkali metal bromide Inorganic materials 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 8
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 230000001954 sterilising effect Effects 0.000 claims description 4
- 235000013361 beverage Nutrition 0.000 claims description 3
- 229940124530 sulfonamide Drugs 0.000 claims description 2
- 150000003456 sulfonamides Chemical class 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 34
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 10
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical group [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 10
- 235000011121 sodium hydroxide Nutrition 0.000 description 8
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 5
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- FJWLWIRHZOHPIY-UHFFFAOYSA-N potassium;hydroiodide Chemical compound [K].I FJWLWIRHZOHPIY-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- YIROYDNZEPTFOL-UHFFFAOYSA-N 5,5-Dimethylhydantoin Chemical compound CC1(C)NC(=O)NC1=O YIROYDNZEPTFOL-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- SNCZNSNPXMPCGN-UHFFFAOYSA-N butanediamide Chemical compound NC(=O)CCC(N)=O SNCZNSNPXMPCGN-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical compound BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002455 scale inhibitor Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- QDWYPRSFEZRKDK-UHFFFAOYSA-M sodium;sulfamate Chemical compound [Na+].NS([O-])(=O)=O QDWYPRSFEZRKDK-UHFFFAOYSA-M 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
- C02F1/766—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/069,653 | 1998-04-29 | ||
| US09/069,653 US6007726A (en) | 1998-04-29 | 1998-04-29 | Stable oxidizing bromine formulations, methods of manufacture thereof and methods of use for microbiofouling control |
| PCT/US1999/008549 WO1999055627A1 (en) | 1998-04-29 | 1999-04-26 | Stable oxidizing bromine formulations, methods of manufacture thereof and methods of use for microbiofouling control |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002512885A JP2002512885A (ja) | 2002-05-08 |
| JP2002512885A5 JP2002512885A5 (enExample) | 2005-12-22 |
| JP4749544B2 true JP4749544B2 (ja) | 2011-08-17 |
Family
ID=22090378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000545793A Expired - Lifetime JP4749544B2 (ja) | 1998-04-29 | 1999-04-26 | 安定な酸化性の臭素製剤、その製造方法および微生物汚損の制御のために使用する方法 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6007726A (enExample) |
| EP (1) | EP1094987A4 (enExample) |
| JP (1) | JP4749544B2 (enExample) |
| KR (1) | KR20010034832A (enExample) |
| CN (1) | CN1298370A (enExample) |
| AR (1) | AR016240A1 (enExample) |
| AU (1) | AU745642B2 (enExample) |
| BR (1) | BR9910011A (enExample) |
| CA (1) | CA2329896A1 (enExample) |
| CO (1) | CO5050388A1 (enExample) |
| ID (1) | ID27578A (enExample) |
| NO (1) | NO20005421L (enExample) |
| NZ (1) | NZ507736A (enExample) |
| WO (1) | WO1999055627A1 (enExample) |
| ZA (1) | ZA200005916B (enExample) |
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| US6352725B1 (en) | 1998-06-01 | 2002-03-05 | Albemarle Corporation | Continuous processes for preparing concentrated aqueous liquid biocidal composition |
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| US6511682B1 (en) | 1998-06-01 | 2003-01-28 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
| US8293795B1 (en) | 1998-06-01 | 2012-10-23 | Albemarle Corporation | Preparation of concentrated aqueous bromine solutions and biocidal applications thereof |
| US6299909B1 (en) | 1998-06-01 | 2001-10-09 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
| US6068861A (en) | 1998-06-01 | 2000-05-30 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
| US8414932B2 (en) | 1998-06-01 | 2013-04-09 | Albemarie Corporation | Active bromine containing biocidal compositions and their preparation |
| US6156229A (en) * | 1998-06-29 | 2000-12-05 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
| US6123870A (en) * | 1998-06-29 | 2000-09-26 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
| US6287473B1 (en) * | 1998-06-29 | 2001-09-11 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
| US6270722B1 (en) * | 1999-03-31 | 2001-08-07 | Nalco Chemical Company | Stabilized bromine solutions, method of manufacture and uses thereof for biofouling control |
| US6669904B1 (en) * | 1999-03-31 | 2003-12-30 | Ondeo Nalco Company | Stabilized bromine solutions, method of making and uses thereof for biofouling control |
| US6110387A (en) * | 1999-04-22 | 2000-08-29 | Albemarle Corporation | Sulfamate stabilization of a bromine biocide in water |
| US6506418B1 (en) | 1999-09-24 | 2003-01-14 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
| JP2001104971A (ja) * | 1999-10-07 | 2001-04-17 | Nec Corp | 廃水処理方法および装置 |
| KR100339129B1 (ko) * | 1999-12-13 | 2002-05-31 | 심상희 | 알칼리 금속 또는 알칼리 토금속의 차아브롬산염을 이용한미생물 오염제어방법 및 이에 사용되는 오염제어시스템 |
| US7371397B2 (en) | 2000-01-18 | 2008-05-13 | Albemarle Corporation | Methods for microbiological control in aqueous systems |
| US6375991B1 (en) | 2000-09-08 | 2002-04-23 | Albemarle Corporation | Production of concentrated biocidal solutions |
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| US6908636B2 (en) | 2001-06-28 | 2005-06-21 | Albermarle Corporation | Microbiological control in poultry processing |
| JP2003142445A (ja) * | 2001-11-08 | 2003-05-16 | Mitsubishi Electric Corp | 洗浄装置及び洗浄方法 |
| KR100465046B1 (ko) * | 2001-11-23 | 2005-01-13 | 애큐랩주식회사 | 알칼리금속 또는 알칼리토금속의 차아할로겐산염을 함유한미생물 성장억제 조성물 및 이를 이용한 미생물 제어방법 |
| US6749758B2 (en) * | 2001-12-05 | 2004-06-15 | Albemarle Corporation | Methods and systems for uniform-control of bromine concentrations in water |
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| US20040120853A1 (en) * | 2002-12-20 | 2004-06-24 | Carpenter Joel F. | Biocidal control in recovery of oil by water injection |
| US7901276B2 (en) | 2003-06-24 | 2011-03-08 | Albemarle Corporation | Microbiocidal control in the processing of meat-producing four-legged animals |
| US7455859B2 (en) * | 2003-06-27 | 2008-11-25 | Enviro Tech Chemical Services, Inc. | Highly concentrated bromine compositions and methods of preparation |
| EP1638394A4 (en) * | 2003-06-27 | 2009-11-11 | Enviro Tech Chemical Services | HIGHLY CONCENTRATED BROMA COMPOSITIONS AND METHOD FOR THE PRODUCTION THEREOF |
| US7883622B1 (en) * | 2003-09-23 | 2011-02-08 | Barnes Ronald L | Water treatment methods and systems using combinations of ozone and chlorine generators |
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| US7309503B2 (en) * | 2004-05-10 | 2007-12-18 | Enviro Tech Chemical Services, Inc. | Methods for the preparation of concentrated aqueous bromine solutions and high activity bromine-containing solids |
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| US20060029680A1 (en) * | 2004-08-06 | 2006-02-09 | Harvey Michael S | Methods of preparing highly concentrated aqueous bromine solutions |
| EP1786266B1 (en) * | 2004-09-07 | 2014-12-03 | Albemarle Corporation | Concentrated aqueous bromine solutions and their preparation |
| US9452229B2 (en) | 2005-06-10 | 2016-09-27 | Albemarle Corporation | Highly concentrated, biocidally active compositions and aqueous mixtures and methods of making the same |
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| CN107205401A (zh) | 2015-01-23 | 2017-09-26 | 雅宝公司 | 家禽加工中的杀微生物控制 |
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| US5683654A (en) * | 1996-03-22 | 1997-11-04 | Nalco Chemical Co | Process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling |
| EP0912695A1 (en) * | 1996-05-15 | 1999-05-06 | The Procter & Gamble Company | Process for manufacturing bleaching compositions comprising chlorine and bromine sources and product thereof |
-
1998
- 1998-04-29 US US09/069,653 patent/US6007726A/en not_active Expired - Lifetime
-
1999
- 1999-04-19 KR KR1020007011935A patent/KR20010034832A/ko not_active Withdrawn
- 1999-04-26 CN CN99805518A patent/CN1298370A/zh active Pending
- 1999-04-26 EP EP19990918668 patent/EP1094987A4/en not_active Withdrawn
- 1999-04-26 WO PCT/US1999/008549 patent/WO1999055627A1/en not_active Ceased
- 1999-04-26 NZ NZ507736A patent/NZ507736A/xx unknown
- 1999-04-26 JP JP2000545793A patent/JP4749544B2/ja not_active Expired - Lifetime
- 1999-04-26 BR BR9910011-8A patent/BR9910011A/pt not_active IP Right Cessation
- 1999-04-26 AU AU36527/99A patent/AU745642B2/en not_active Ceased
- 1999-04-26 CA CA002329896A patent/CA2329896A1/en not_active Abandoned
- 1999-04-26 ID IDW20002172A patent/ID27578A/id unknown
- 1999-04-28 CO CO99025512A patent/CO5050388A1/es unknown
- 1999-04-29 AR ARP990101991A patent/AR016240A1/es not_active Application Discontinuation
-
2000
- 2000-10-23 ZA ZA200005916A patent/ZA200005916B/en unknown
- 2000-10-27 NO NO20005421A patent/NO20005421L/no not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3558503A (en) * | 1968-07-22 | 1971-01-26 | Dow Chemical Co | Stable bromo-sulfamate composition |
| US5603840A (en) * | 1995-05-15 | 1997-02-18 | Nalco Chemical Company | Method of achieving microbiological control in open recirculating cooling water |
Also Published As
| Publication number | Publication date |
|---|---|
| NO20005421D0 (no) | 2000-10-27 |
| US6007726A (en) | 1999-12-28 |
| BR9910011A (pt) | 2001-01-09 |
| ZA200005916B (en) | 2001-05-22 |
| WO1999055627A9 (en) | 2000-03-02 |
| CO5050388A1 (es) | 2001-06-27 |
| CA2329896A1 (en) | 1999-11-04 |
| EP1094987A4 (en) | 2002-11-04 |
| EP1094987A1 (en) | 2001-05-02 |
| NO20005421L (no) | 2000-12-19 |
| AU3652799A (en) | 1999-11-16 |
| WO1999055627A1 (en) | 1999-11-04 |
| KR20010034832A (ko) | 2001-04-25 |
| WO1999055627A8 (en) | 2000-01-27 |
| NZ507736A (en) | 2002-11-26 |
| JP2002512885A (ja) | 2002-05-08 |
| AR016240A1 (es) | 2001-06-20 |
| ID27578A (id) | 2001-04-12 |
| CN1298370A (zh) | 2001-06-06 |
| AU745642B2 (en) | 2002-03-28 |
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