JP4574934B2 - オレフィン重合用成分及び触媒 - Google Patents
オレフィン重合用成分及び触媒 Download PDFInfo
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- JP4574934B2 JP4574934B2 JP2001557930A JP2001557930A JP4574934B2 JP 4574934 B2 JP4574934 B2 JP 4574934B2 JP 2001557930 A JP2001557930 A JP 2001557930A JP 2001557930 A JP2001557930 A JP 2001557930A JP 4574934 B2 JP4574934 B2 JP 4574934B2
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- JP
- Japan
- Prior art keywords
- ester
- succinic acid
- polymerization
- catalyst component
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000003054 catalyst Substances 0.000 title claims description 24
- 238000006116 polymerization reaction Methods 0.000 title claims description 22
- 150000001336 alkenes Chemical class 0.000 title claims description 19
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 33
- -1 alkylaluminum compound Chemical class 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 239000011949 solid catalyst Substances 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 150000003891 oxalate salts Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 description 18
- 239000011777 magnesium Substances 0.000 description 13
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 239000010936 titanium Substances 0.000 description 12
- 150000002430 hydrocarbons Chemical group 0.000 description 11
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 10
- 150000003900 succinic acid esters Chemical class 0.000 description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical class OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 238000011282 treatment Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 235000011147 magnesium chloride Nutrition 0.000 description 6
- 150000003609 titanium compounds Chemical class 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000003901 oxalic acid esters Chemical class 0.000 description 5
- 239000002685 polymerization catalyst Substances 0.000 description 5
- 150000003377 silicon compounds Chemical class 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WXUAQHNMJWJLTG-VKHMYHEASA-N (S)-methylsuccinic acid Chemical compound OC(=O)[C@@H](C)CC(O)=O WXUAQHNMJWJLTG-VKHMYHEASA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 235000006408 oxalic acid Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 2
- 238000004438 BET method Methods 0.000 description 2
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229940078552 o-xylene Drugs 0.000 description 2
- 125000005498 phthalate group Chemical class 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- ITMHQIWFDVCNJS-UHFFFAOYSA-N 1-o-ethyl 4-o-(2-methylpropyl) butanedioate Chemical compound CCOC(=O)CCC(=O)OCC(C)C ITMHQIWFDVCNJS-UHFFFAOYSA-N 0.000 description 1
- RGTLSFNPTLNPDZ-UHFFFAOYSA-N 4-(2-methylpropoxy)-4-oxobutanoic acid Chemical compound CC(C)COC(=O)CCC(O)=O RGTLSFNPTLNPDZ-UHFFFAOYSA-N 0.000 description 1
- OGYSYXDNLPNNPW-UHFFFAOYSA-N 4-butoxy-4-oxobutanoic acid Chemical compound CCCCOC(=O)CCC(O)=O OGYSYXDNLPNNPW-UHFFFAOYSA-N 0.000 description 1
- PJOLMBOMBNGLPQ-UHFFFAOYSA-N 4-hexoxy-4-oxobutanoic acid Chemical compound CCCCCCOC(=O)CCC(O)=O PJOLMBOMBNGLPQ-UHFFFAOYSA-N 0.000 description 1
- LWZMWTDHQXTYBH-UHFFFAOYSA-N 4-o-ethyl 1-o-(2-methylpropyl) 2-butylbutanedioate Chemical compound CCOC(=O)CC(CCCC)C(=O)OCC(C)C LWZMWTDHQXTYBH-UHFFFAOYSA-N 0.000 description 1
- MWCBTNNQWBHJGU-UHFFFAOYSA-N 4-o-ethyl 1-o-(2-methylpropyl) 2-hexylbutanedioate Chemical compound CCCCCCC(CC(=O)OCC)C(=O)OCC(C)C MWCBTNNQWBHJGU-UHFFFAOYSA-N 0.000 description 1
- YWNTXVOHFPMHSO-UHFFFAOYSA-N 4-o-ethyl 1-o-(2-methylpropyl) 2-nonylbutanedioate Chemical compound CCCCCCCCCC(CC(=O)OCC)C(=O)OCC(C)C YWNTXVOHFPMHSO-UHFFFAOYSA-N 0.000 description 1
- DLDQMDLNFWKJFC-UHFFFAOYSA-N 4-o-ethyl 1-o-(2-methylpropyl) 2-octylbutanedioate Chemical compound CCCCCCCCC(CC(=O)OCC)C(=O)OCC(C)C DLDQMDLNFWKJFC-UHFFFAOYSA-N 0.000 description 1
- XHUWYFZMERFVCN-UHFFFAOYSA-N 4-o-ethyl 1-o-(2-methylpropyl) 2-pentylbutanedioate Chemical compound CCCCCC(CC(=O)OCC)C(=O)OCC(C)C XHUWYFZMERFVCN-UHFFFAOYSA-N 0.000 description 1
- OTRIFMFAURGFGX-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-decylbutanedioate Chemical compound CCCCCCCCCCC(C(=O)OC)CC(=O)OCC OTRIFMFAURGFGX-UHFFFAOYSA-N 0.000 description 1
- PUJMQOYEVKEVNP-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-dodecylbutanedioate Chemical compound CCCCCCCCCCCCC(C(=O)OC)CC(=O)OCC PUJMQOYEVKEVNP-UHFFFAOYSA-N 0.000 description 1
- HMMXRPIFLVNQGN-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-hexylbutanedioate Chemical compound CCCCCCC(C(=O)OC)CC(=O)OCC HMMXRPIFLVNQGN-UHFFFAOYSA-N 0.000 description 1
- FIQBHLYPHPGRND-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-nonylbutanedioate Chemical compound CCCCCCCCCC(C(=O)OC)CC(=O)OCC FIQBHLYPHPGRND-UHFFFAOYSA-N 0.000 description 1
- BPALWEIADJRBEM-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-octylbutanedioate Chemical compound CCCCCCCCC(C(=O)OC)CC(=O)OCC BPALWEIADJRBEM-UHFFFAOYSA-N 0.000 description 1
- QADFQQDAZIGUGJ-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-pentylbutanedioate Chemical compound CCCCCC(C(=O)OC)CC(=O)OCC QADFQQDAZIGUGJ-UHFFFAOYSA-N 0.000 description 1
- UIYYMFVTSFDNOM-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-tetradecylbutanedioate Chemical compound CCCCCCCCCCCCCCC(C(=O)OC)CC(=O)OCC UIYYMFVTSFDNOM-UHFFFAOYSA-N 0.000 description 1
- DAFRENGHSVIPEF-UHFFFAOYSA-N 4-o-ethyl 1-o-methyl 2-undecylbutanedioate Chemical compound CCCCCCCCCCCC(C(=O)OC)CC(=O)OCC DAFRENGHSVIPEF-UHFFFAOYSA-N 0.000 description 1
- ROYDXBYNOZBQHI-UHFFFAOYSA-N 4-oxo-4-pentoxybutanoic acid Chemical compound CCCCCOC(=O)CCC(O)=O ROYDXBYNOZBQHI-UHFFFAOYSA-N 0.000 description 1
- RKQIRPMWSBEBMA-UHFFFAOYSA-N C1(CCCCC1)[Si](OC)(OC)OC.CO[SiH](OC)OC Chemical compound C1(CCCCC1)[Si](OC)(OC)OC.CO[SiH](OC)OC RKQIRPMWSBEBMA-UHFFFAOYSA-N 0.000 description 1
- LJKOMYSGGJVPAC-UHFFFAOYSA-N CCCCCCCCCCCC(CC(=O)O)C(=O)OCC(C)C Chemical compound CCCCCCCCCCCC(CC(=O)O)C(=O)OCC(C)C LJKOMYSGGJVPAC-UHFFFAOYSA-N 0.000 description 1
- LIXVPCGHBNYHEH-UHFFFAOYSA-N CCCCCCCCCCCCC(CC(=O)O)C(=O)OCC(C)C Chemical compound CCCCCCCCCCCCC(CC(=O)O)C(=O)OCC(C)C LIXVPCGHBNYHEH-UHFFFAOYSA-N 0.000 description 1
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 description 1
- HXXRQBBSGZDQNP-UHFFFAOYSA-N Ethyl methyl_succinate Chemical compound CCOC(=O)CCC(=O)OC HXXRQBBSGZDQNP-UHFFFAOYSA-N 0.000 description 1
- JKRZOJADNVOXPM-UHFFFAOYSA-N Oxalic acid dibutyl ester Chemical compound CCCCOC(=O)C(=O)OCCCC JKRZOJADNVOXPM-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WQDHBPALGQOBHN-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-butylbutanedioate Chemical compound CC(C)(C)COC(=O)C(CCCC)CC(=O)OCC(C)(C)C WQDHBPALGQOBHN-UHFFFAOYSA-N 0.000 description 1
- XHWLITAQNBYUHT-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-decylbutanedioate Chemical compound CCCCCCCCCCC(C(=O)OCC(C)(C)C)CC(=O)OCC(C)(C)C XHWLITAQNBYUHT-UHFFFAOYSA-N 0.000 description 1
- JQZLXMJMIWWFIH-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-dodecylbutanedioate Chemical class CCCCCCCCCCCCC(C(=O)OCC(C)(C)C)CC(=O)OCC(C)(C)C JQZLXMJMIWWFIH-UHFFFAOYSA-N 0.000 description 1
- LTKXZVRZFQUAGD-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-hexylbutanedioate Chemical compound CCCCCCC(C(=O)OCC(C)(C)C)CC(=O)OCC(C)(C)C LTKXZVRZFQUAGD-UHFFFAOYSA-N 0.000 description 1
- SCXGVLZPAHSQTJ-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-nonylbutanedioate Chemical compound CCCCCCCCCC(C(=O)OCC(C)(C)C)CC(=O)OCC(C)(C)C SCXGVLZPAHSQTJ-UHFFFAOYSA-N 0.000 description 1
- BZTGKYJFVFYORX-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-pentylbutanedioate Chemical compound CCCCCC(C(=O)OCC(C)(C)C)CC(=O)OCC(C)(C)C BZTGKYJFVFYORX-UHFFFAOYSA-N 0.000 description 1
- HOJONPHBVHKRAW-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-undecylbutanedioate Chemical compound CCCCCCCCCCCC(C(=O)OCC(C)(C)C)CC(=O)OCC(C)(C)C HOJONPHBVHKRAW-UHFFFAOYSA-N 0.000 description 1
- UKMWFJSTYVOROV-UHFFFAOYSA-N bis(2,2-dimethylpropyl) butanedioate Chemical compound CC(C)(C)COC(=O)CCC(=O)OCC(C)(C)C UKMWFJSTYVOROV-UHFFFAOYSA-N 0.000 description 1
- LHNGTRIMEXLPNE-UHFFFAOYSA-N bis(2-methylpropyl) 2-butylbutanedioate Chemical compound CC(C)COC(=O)C(CCCC)CC(=O)OCC(C)C LHNGTRIMEXLPNE-UHFFFAOYSA-N 0.000 description 1
- ILRLITALONRWJO-UHFFFAOYSA-N bis(2-methylpropyl) 2-decylbutanedioate Chemical compound CCCCCCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C ILRLITALONRWJO-UHFFFAOYSA-N 0.000 description 1
- JZLAYFJLZUHYQJ-UHFFFAOYSA-N bis(2-methylpropyl) 2-dodecylbutanedioate Chemical compound CCCCCCCCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C JZLAYFJLZUHYQJ-UHFFFAOYSA-N 0.000 description 1
- SMIXDCNLTTUKNX-UHFFFAOYSA-N bis(2-methylpropyl) 2-heptylbutanedioate Chemical compound CCCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C SMIXDCNLTTUKNX-UHFFFAOYSA-N 0.000 description 1
- YONSTJLJDXVRIZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-hexylbutanedioate Chemical compound CCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C YONSTJLJDXVRIZ-UHFFFAOYSA-N 0.000 description 1
- YFUUKAUIQFLBLB-UHFFFAOYSA-N bis(2-methylpropyl) 2-nonylbutanedioate Chemical compound CCCCCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C YFUUKAUIQFLBLB-UHFFFAOYSA-N 0.000 description 1
- OVONPYGMFZFTDN-UHFFFAOYSA-N bis(2-methylpropyl) 2-octylbutanedioate Chemical compound CCCCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C OVONPYGMFZFTDN-UHFFFAOYSA-N 0.000 description 1
- VMXFQGODSNTIIZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-pentylbutanedioate Chemical compound CCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C VMXFQGODSNTIIZ-UHFFFAOYSA-N 0.000 description 1
- XLFLAWSRNYBFTF-UHFFFAOYSA-N bis(2-methylpropyl) 2-undecylbutanedioate Chemical compound CCCCCCCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C XLFLAWSRNYBFTF-UHFFFAOYSA-N 0.000 description 1
- QCOAPBRVQHMEPF-UHFFFAOYSA-N bis(2-methylpropyl) butanedioate Chemical compound CC(C)COC(=O)CCC(=O)OCC(C)C QCOAPBRVQHMEPF-UHFFFAOYSA-N 0.000 description 1
- GJRRTUSXQPXVES-UHFFFAOYSA-N bis(2-methylpropyl) oxalate Chemical compound CC(C)COC(=O)C(=O)OCC(C)C GJRRTUSXQPXVES-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- YCHPAFWBCSNTIL-UHFFFAOYSA-N dibutyl 2-butylbutanedioate Chemical compound CCCCOC(=O)CC(CCCC)C(=O)OCCCC YCHPAFWBCSNTIL-UHFFFAOYSA-N 0.000 description 1
- AOJZNVYSFRUQSI-UHFFFAOYSA-N dibutyl 2-decylbutanedioate Chemical compound CCCCCCCCCCC(C(=O)OCCCC)CC(=O)OCCCC AOJZNVYSFRUQSI-UHFFFAOYSA-N 0.000 description 1
- PLGGSEZFWVZNBC-UHFFFAOYSA-N dibutyl 2-dodecylbutanedioate Chemical compound CCCCCCCCCCCCC(C(=O)OCCCC)CC(=O)OCCCC PLGGSEZFWVZNBC-UHFFFAOYSA-N 0.000 description 1
- AFJMHJCQXZVKKD-UHFFFAOYSA-N dibutyl 2-hexylbutanedioate Chemical compound CCCCCCC(C(=O)OCCCC)CC(=O)OCCCC AFJMHJCQXZVKKD-UHFFFAOYSA-N 0.000 description 1
- LYMPHIFOCXZLLM-UHFFFAOYSA-N dibutyl 2-nonylbutanedioate Chemical compound CCCCCCCCCC(C(=O)OCCCC)CC(=O)OCCCC LYMPHIFOCXZLLM-UHFFFAOYSA-N 0.000 description 1
- QYXDVOKUQRHMBL-UHFFFAOYSA-N dibutyl 2-octylbutanedioate Chemical compound CCCCCCCCC(C(=O)OCCCC)CC(=O)OCCCC QYXDVOKUQRHMBL-UHFFFAOYSA-N 0.000 description 1
- QBLHSCOGUYLFOX-UHFFFAOYSA-N dibutyl 2-pentylbutanedioate Chemical compound CCCCOC(=O)C(CCCCC)CC(=O)OCCCC QBLHSCOGUYLFOX-UHFFFAOYSA-N 0.000 description 1
- SGTUFZBFFLXNLS-UHFFFAOYSA-N dibutyl 2-tetradecylbutanedioate Chemical compound CCCCCCCCCCCCCCC(C(=O)OCCCC)CC(=O)OCCCC SGTUFZBFFLXNLS-UHFFFAOYSA-N 0.000 description 1
- RKEFLLNMAAMEGX-UHFFFAOYSA-N dibutyl 2-undecylbutanedioate Chemical compound CCCCCCCCCCCC(C(=O)OCCCC)CC(=O)OCCCC RKEFLLNMAAMEGX-UHFFFAOYSA-N 0.000 description 1
- QFPQXFREXONVSL-UHFFFAOYSA-N dicyclohexylmethoxy-methoxy-pentylsilane Chemical compound C1(CCCCC1)C(O[SiH](OC)CCCCC)C1CCCCC1 QFPQXFREXONVSL-UHFFFAOYSA-N 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- YAEKQEGHOYSBCP-UHFFFAOYSA-N diethyl 2-butylbutanedioate Chemical compound CCCCC(C(=O)OCC)CC(=O)OCC YAEKQEGHOYSBCP-UHFFFAOYSA-N 0.000 description 1
- OOIAZKGZMYMYEC-UHFFFAOYSA-N diethyl 2-decylbutanedioate Chemical compound CCCCCCCCCCC(C(=O)OCC)CC(=O)OCC OOIAZKGZMYMYEC-UHFFFAOYSA-N 0.000 description 1
- OBFIDAIVFBXWTB-UHFFFAOYSA-N diethyl 2-dodecylbutanedioate Chemical compound CCCCCCCCCCCCC(C(=O)OCC)CC(=O)OCC OBFIDAIVFBXWTB-UHFFFAOYSA-N 0.000 description 1
- DZKVMOJBGDUQGT-UHFFFAOYSA-N diethyl 2-hexylbutanedioate Chemical compound CCCCCCC(C(=O)OCC)CC(=O)OCC DZKVMOJBGDUQGT-UHFFFAOYSA-N 0.000 description 1
- ZKZOYTZHXSTDSV-UHFFFAOYSA-N diethyl 2-nonylbutanedioate Chemical compound CCCCCCCCCC(C(=O)OCC)CC(=O)OCC ZKZOYTZHXSTDSV-UHFFFAOYSA-N 0.000 description 1
- HWQGPEHOHZHKKB-UHFFFAOYSA-N diethyl 2-octylbutanedioate Chemical compound CCCCCCCCC(C(=O)OCC)CC(=O)OCC HWQGPEHOHZHKKB-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- DIJRHOZMLZRNLM-UHFFFAOYSA-N dimethoxy-methyl-(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](C)(OC)CCC(F)(F)F DIJRHOZMLZRNLM-UHFFFAOYSA-N 0.000 description 1
- FUUSMEUQTOULKC-UHFFFAOYSA-N dimethyl 2-decylbutanedioate Chemical compound CCCCCCCCCCC(C(=O)OC)CC(=O)OC FUUSMEUQTOULKC-UHFFFAOYSA-N 0.000 description 1
- HZKZKJNBPVNYJN-UHFFFAOYSA-N dimethyl 2-dodecylbutanedioate Chemical compound CCCCCCCCCCCCC(C(=O)OC)CC(=O)OC HZKZKJNBPVNYJN-UHFFFAOYSA-N 0.000 description 1
- BUOQXQXEXKAKJK-UHFFFAOYSA-N dimethyl 2-nonylbutanedioate Chemical compound CCCCCCCCCC(C(=O)OC)CC(=O)OC BUOQXQXEXKAKJK-UHFFFAOYSA-N 0.000 description 1
- RPVIZIOEDKZTNQ-UHFFFAOYSA-N dimethyl 2-undecylbutanedioate Chemical compound CCCCCCCCCCCC(C(=O)OC)CC(=O)OC RPVIZIOEDKZTNQ-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- QGGUMTNPIYCTSF-UHFFFAOYSA-N hexylsilane Chemical compound CCCCCC[SiH3] QGGUMTNPIYCTSF-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NIOVJFCCEONHGJ-UHFFFAOYSA-N tert-butyl-(2-ethylpiperidin-1-yl)-dimethoxysilane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)(C)C NIOVJFCCEONHGJ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00200342 | 2000-02-02 | ||
| EP00200342.4 | 2000-02-02 | ||
| PCT/EP2001/000828 WO2001057099A1 (en) | 2000-02-02 | 2001-01-25 | Components and catalysts for the polymerization of olefins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003522231A JP2003522231A (ja) | 2003-07-22 |
| JP2003522231A5 JP2003522231A5 (https=) | 2008-03-21 |
| JP4574934B2 true JP4574934B2 (ja) | 2010-11-04 |
Family
ID=8170966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001557930A Expired - Fee Related JP4574934B2 (ja) | 2000-02-02 | 2001-01-25 | オレフィン重合用成分及び触媒 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6716939B2 (https=) |
| EP (1) | EP1165633B1 (https=) |
| JP (1) | JP4574934B2 (https=) |
| AU (1) | AU2849701A (https=) |
| DE (1) | DE60104238T2 (https=) |
| ES (1) | ES2223887T3 (https=) |
| WO (1) | WO2001057099A1 (https=) |
Families Citing this family (97)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2334743C (en) * | 1999-04-15 | 2010-01-12 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| RU2325404C2 (ru) | 2002-08-01 | 2008-05-27 | Базелль Полиолефин Италия С.П.А. | Высокостереорегулярный полипропилен с улучшенными свойствами |
| TW200427763A (en) | 2003-04-03 | 2004-12-16 | Basell Poliolefine Spa | Impact resistant polyolefin compositions |
| RU2371458C2 (ru) | 2004-05-21 | 2009-10-27 | Базелль Полиолефин Италия С.Р.Л. | Ударопрочные полиолефиновые композиции |
| AU2005291326A1 (en) | 2004-10-04 | 2006-04-13 | Basell Poliolefine Italia S.R.L. | Elastomeric polyolefin compositions |
| CN101084268B (zh) | 2004-12-23 | 2011-09-14 | 巴塞尔聚烯烃意大利有限责任公司 | 具有优良抗发白性能的聚烯烃组合物 |
| US7888438B2 (en) | 2005-01-19 | 2011-02-15 | Mitsui Chemicals, Inc. | Catalyst for olefin polymerization and process for olefin polymerization |
| KR100918546B1 (ko) | 2005-01-19 | 2009-09-21 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체의 제조방법 및 고체상 티탄 촉매성분 |
| JP4632299B2 (ja) * | 2005-01-26 | 2011-02-16 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法および触媒 |
| CA2610030A1 (en) | 2005-05-27 | 2006-11-30 | Basell Poliolefine Italia S.R.L. | Polyolefinic compositions having good whitening resistance |
| CN101490101B (zh) | 2006-07-18 | 2011-11-02 | 三井化学株式会社 | 固态钛催化剂成分、烯烃聚合用催化剂及烯烃聚合方法 |
| WO2008061843A1 (en) * | 2006-11-23 | 2008-05-29 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions |
| BRPI0815890A2 (pt) * | 2007-08-29 | 2015-02-24 | Basell Poliolefine Srl | Catalisador para a polimerização de olefinas |
| US8507628B2 (en) | 2007-10-02 | 2013-08-13 | Fina Technology, Inc. | Propylene based polymers for injection stretch blow molding |
| FR2922548B1 (fr) * | 2007-10-22 | 2012-11-30 | Rhodia Operations | Diesters d'acides dicarboxyliques,procedes de preparation et utilisations |
| CN101423571B (zh) * | 2007-11-01 | 2010-09-01 | 中国石油天然气股份有限公司 | 烯烃聚合催化组分及其催化剂 |
| WO2009069483A1 (ja) | 2007-11-27 | 2009-06-04 | Mitsui Chemicals, Inc. | 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| EP2070954A1 (en) * | 2007-12-14 | 2009-06-17 | Total Petrochemicals Research Feluy | Process for the production of a propylene polymer having a broad molecular weight distribution and a low ash content |
| BRPI0821410A2 (pt) * | 2007-12-20 | 2015-06-16 | Basell Poliolefine Srl | Componentes catalisadores para a polimerização de olefinas |
| US9090000B2 (en) * | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
| CN102459453B (zh) | 2009-06-26 | 2013-07-31 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃组合物 |
| BR112012002281B1 (pt) | 2009-07-31 | 2019-05-28 | Basell Poliolefine Italia S.R.L. | Composição polimérica e processo de polimerização para sua preparação |
| KR101765960B1 (ko) | 2009-07-31 | 2017-08-07 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀계 조성물 |
| EP2480597A1 (en) | 2009-09-24 | 2012-08-01 | Basell Poliolefine Italia S.r.l. | Heat-sealable polyolefin films |
| WO2011039314A1 (en) | 2009-09-29 | 2011-04-07 | Basell Poliolefine Italia Srl | Heat-sealable polyolefin films |
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| EP2463413B1 (en) | 2010-12-07 | 2014-01-29 | Basell Poliolefine Italia S.r.l. | Polyolefin fibres |
| WO2012076447A1 (en) | 2010-12-07 | 2012-06-14 | Basell Poliolefine Italia S.R.L. | Polyolefin based corrugated boards |
| US20130316213A1 (en) | 2011-01-18 | 2013-11-28 | Baseell Poliolefine Italia S.r.l. | Polyolefin composition |
| US9000097B2 (en) | 2011-07-07 | 2015-04-07 | Basell Poliolefine Italia S.R.L. | Polypropylene composition |
| EP2583999A1 (en) | 2011-10-20 | 2013-04-24 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions |
| US9677178B2 (en) | 2012-01-27 | 2017-06-13 | Versum Materials Us, Llc | Alkoxyaminosilane compounds and applications thereof |
| US9200167B2 (en) * | 2012-01-27 | 2015-12-01 | Air Products And Chemicals, Inc. | Alkoxyaminosilane compounds and applications thereof |
| CN103665199B (zh) * | 2012-09-06 | 2015-11-25 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的固体催化剂组分、催化剂及应用 |
| CN104583219B (zh) * | 2012-09-24 | 2018-03-16 | 印度石油有限公司 | 固体形式的有机金属化合物，其制造方法，及其用途 |
| US9453093B2 (en) | 2012-10-31 | 2016-09-27 | Exxonmobil Chemical Patents Inc. | Broad molecular weight distribution polypropylene resins |
| US9464178B2 (en) | 2012-10-31 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Articles comprising broad molecular weight distribution polypropylene resins |
| EP2743307A1 (en) | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Polyolefin composition |
| EP2829397A1 (en) | 2013-07-22 | 2015-01-28 | Basell Poliolefine Italia S.r.l. | Heat sealable polyolefin films and sheets |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| US10233403B2 (en) | 2016-11-03 | 2019-03-19 | EXXONMOBiL RESEARCH AND ENGiNEERENG COMPANY | High viscosity index monomethyl ester lubricating oil base stocks and methods of making and use thereof |
| US10077409B2 (en) | 2015-12-28 | 2018-09-18 | Exxonmobil Research And Engineering Company | Low viscosity low volatility lubricating oil base stocks and methods of use thereof |
| US9976099B2 (en) | 2015-12-28 | 2018-05-22 | Exxonmobil Research And Engineering Company | Low viscosity low volatility lubricating oil base stocks and methods of use thereof |
| US10316265B2 (en) | 2015-12-28 | 2019-06-11 | Exxonmobil Research And Engineering Company | Low viscosity low volatility lubricating oil base stocks and methods of use thereof |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| RU2757372C2 (ru) | 2016-09-23 | 2021-10-14 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора для полимеризации олефина, катализатор и их применение |
| RU2758673C2 (ru) | 2016-09-23 | 2021-11-01 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора для полимеризации олефина, катализатор и их применение |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| CN112062884B (zh) * | 2019-06-10 | 2022-07-05 | 中国石油天然气股份有限公司 | 一种丙烯聚合催化剂体系及其应用 |
| US20230250266A1 (en) | 2020-06-30 | 2023-08-10 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| WO2022002601A1 (en) | 2020-06-30 | 2022-01-06 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
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| US20240417555A1 (en) | 2021-12-22 | 2024-12-19 | Basell Poliolefine Italia S.R.L. | Compositions obtained from recycled polyolefins |
| JP2023132923A (ja) * | 2022-03-11 | 2023-09-22 | 東邦チタニウム株式会社 | オレフィン類重合用触媒、オレフィン類重合体の製造方法及びプロピレン単独重合体 |
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| WO2024028191A1 (en) | 2022-08-04 | 2024-02-08 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions obtained from recycled polyolefins |
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| CN119161511A (zh) * | 2023-06-20 | 2024-12-20 | 中国科学院大连化学物理研究所 | 一种烯烃聚合用固体催化剂 |
| WO2025021459A1 (en) | 2023-07-27 | 2025-01-30 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions obtained from recycled polyolefins |
| CN121443683A (zh) | 2023-08-03 | 2026-01-30 | 巴塞尔聚烯烃意大利有限公司 | 含有再循环材料的软聚丙烯组合物 |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
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| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| IT202300025932A1 (it) | 2023-12-05 | 2025-06-05 | Basell Poliolefine Italia Srl | Composizioni polipropileniche con proprietà meccaniche migliorate |
| WO2025125124A1 (en) | 2023-12-14 | 2025-06-19 | Basell Poliolefine Italia S.R.L. | Polypropylene composition for wire and cable applications |
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| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
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| EP4636027A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefins compositions obtained from recycled polyolefins |
| EP4636026A1 (en) | 2024-04-19 | 2025-10-22 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions obtained from recycled polyolefins |
| EP4660239A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing recycled polyolefins |
| EP4660237A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polyolefin compositions comprising recycled polyolefins and propylene homopolymer |
| EP4660238A1 (en) | 2024-06-06 | 2025-12-10 | Basell Poliolefine Italia S.r.l. | Polypropylene compositions containing recycled polyolefin |
| EP4667525A1 (en) | 2024-06-19 | 2025-12-24 | Basell Poliolefine Italia S.r.l. | Transparent recycled polypropylene composition |
| EP4667218A1 (en) | 2024-06-20 | 2025-12-24 | Basell Poliolefine Italia S.r.l. | Recycled polyolefin composition having improoved impact properties |
| EP4667524A1 (en) | 2024-06-20 | 2025-12-24 | Basell Poliolefine Italia S.r.l. | Recycled polyolefin composition having improved impact properties |
| WO2026008347A1 (en) | 2024-07-01 | 2026-01-08 | Basell Poliolefine Italia S.R.L. | Process for improving melt flow rate of a polyolefin recyclate composition |
| EP4685277A1 (en) | 2024-07-25 | 2026-01-28 | Basell Poliolefine Italia S.r.l. | Fiber comprising a propylene based polymers composition |
| WO2026063967A1 (en) | 2024-09-19 | 2026-03-26 | Formosa Plastics Corporation, Usa | Olefin polymerization ziegler-natta catalyst components and process for the production of olefin polymers therewith |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE363977B (https=) | 1968-11-21 | 1974-02-11 | Montedison Spa | |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS58138709A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| JPS58138705A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフイン系重合体の製造方法 |
| JPS59207904A (ja) | 1983-05-11 | 1984-11-26 | Mitsui Petrochem Ind Ltd | オレフイン重合体の製造方法 |
| KR920000173B1 (ko) | 1986-10-09 | 1992-01-09 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체 |
| JPS63122710A (ja) * | 1986-11-12 | 1988-05-26 | Nippon Petrochem Co Ltd | ポリオレフインの製造方法 |
| JPH0733407B2 (ja) * | 1988-12-26 | 1995-04-12 | 台湾塑膠工業股▲ひん▼有限公司 | ポリオレフィンの製造方法 |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1256648B (it) | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| JP3529894B2 (ja) * | 1994-05-19 | 2004-05-24 | 三井化学株式会社 | オレフィン重合用固体状チタン触媒成分、これを含むオレフィン重合用触媒およびオレフィンの重合方法 |
| IL127230A (en) | 1997-03-29 | 2004-07-25 | Montell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| CA2334743C (en) | 1999-04-15 | 2010-01-12 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
-
2001
- 2001-01-25 DE DE60104238T patent/DE60104238T2/de not_active Expired - Lifetime
- 2001-01-25 JP JP2001557930A patent/JP4574934B2/ja not_active Expired - Fee Related
- 2001-01-25 US US09/937,884 patent/US6716939B2/en not_active Expired - Fee Related
- 2001-01-25 WO PCT/EP2001/000828 patent/WO2001057099A1/en not_active Ceased
- 2001-01-25 AU AU28497/01A patent/AU2849701A/en not_active Abandoned
- 2001-01-25 ES ES01948988T patent/ES2223887T3/es not_active Expired - Lifetime
- 2001-01-25 EP EP01948988A patent/EP1165633B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1165633A1 (en) | 2002-01-02 |
| US20020183575A1 (en) | 2002-12-05 |
| JP2003522231A (ja) | 2003-07-22 |
| DE60104238D1 (de) | 2004-08-19 |
| WO2001057099A1 (en) | 2001-08-09 |
| ES2223887T3 (es) | 2005-03-01 |
| DE60104238T2 (de) | 2005-07-28 |
| EP1165633B1 (en) | 2004-07-14 |
| AU2849701A (en) | 2001-08-14 |
| US6716939B2 (en) | 2004-04-06 |
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