JP4511926B2 - ケイ素／酸化ケイ素の面平行な構造 - Google Patents

ケイ素／酸化ケイ素の面平行な構造 Download PDF

Info

Publication number
JP4511926B2
JP4511926B2 JP2004513386A JP2004513386A JP4511926B2 JP 4511926 B2 JP4511926 B2 JP 4511926B2 JP 2004513386 A JP2004513386 A JP 2004513386A JP 2004513386 A JP2004513386 A JP 2004513386A JP 4511926 B2 JP4511926 B2 JP 4511926B2
Authority
JP
Japan
Prior art keywords
silicon
sio
layer
oxygen
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2004513386A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005529835A5 (https=
JP2005529835A (ja
Inventor
ブヤルト，パトリーチェ
レイバッハ，ホルガー
ヴァイネルト，ヒルマール
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
Publication of JP2005529835A publication Critical patent/JP2005529835A/ja
Publication of JP2005529835A5 publication Critical patent/JP2005529835A5/ja
Application granted granted Critical
Publication of JP4511926B2 publication Critical patent/JP4511926B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0018—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings uncoated and unlayered plate-like particles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0024—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0024—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index
    • C09C1/003—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index comprising at least one light-absorbing layer
    • C09C1/0039—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index comprising at least one light-absorbing layer consisting of at least one coloured inorganic material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10—Interference pigments characterized by the core material
    • C09C2200/1037—Interference pigments characterized by the core material the core consisting of an inorganic suboxide or a mixture thereof, e.g. SiOx or TiOx
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/301—Thickness of the core
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/302—Thickness of a layer with high refractive material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/308—Total thickness of the pigment particle
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2220/00—Methods of preparing the interference pigments
    • C09C2220/20—PVD, CVD methods or coating in a gas-phase using a fluidized bed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Silicon Compounds (AREA)
JP2004513386A 2002-06-18 2003-06-16 ケイ素／酸化ケイ素の面平行な構造 Expired - Fee Related JP4511926B2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10227229 2002-06-18
EP03405017 2003-01-17
EP03100548 2003-03-06
PCT/EP2003/050229 WO2003106569A1 (en) 2002-06-01 2003-06-16 Plane-parallel structures of silicon/silicon oxide

Publications (3)

Publication Number Publication Date
JP2005529835A JP2005529835A (ja) 2005-10-06
JP2005529835A5 JP2005529835A5 (https=) 2006-08-10
JP4511926B2 true JP4511926B2 (ja) 2010-07-28

Family

ID=29740364

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004513386A Expired - Fee Related JP4511926B2 (ja) 2002-06-18 2003-06-16 ケイ素／酸化ケイ素の面平行な構造

Country Status (8)

Country Link
US (1) US7273522B2 (https=)
EP (1) EP1517964A1 (https=)
JP (1) JP4511926B2 (https=)
CN (1) CN1662613A (https=)
AU (1) AU2003250247A1 (https=)
CA (1) CA2489874A1 (https=)
MX (1) MXPA04012887A (https=)
WO (1) WO2003106569A1 (https=)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004035693A1 (en) 2002-10-16 2004-04-29 Ciba Specialty Chemicals Holding Inc. Interference pigments on the basis of silicon oxides
US7452597B2 (en) * 2002-11-13 2008-11-18 Ciba Specialty Chemicals Corporation Interference pigments comprising a layer of silicon oxide
JP4620469B2 (ja) * 2002-11-21 2011-01-26 チバ ホールディング インコーポレーテッド 非対称層構造を有する光学的に可変性の顔料
EP1585703A1 (en) * 2003-01-17 2005-10-19 Ciba SC Holding AG A process for the production of porous inorganic materials or a matrix material containing nanoparticles
EP1585792B1 (en) * 2003-01-23 2007-04-11 Ciba SC Holding AG Platelet-shaped pigments
DE102004014020A1 (de) * 2004-03-19 2005-10-06 Eckart Gmbh & Co. Kg Kosmetisches Präparat mit UV-Schutz und Verwendung von Effektpigmenten
EP1755381A2 (en) * 2004-05-12 2007-02-28 CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement Antimicrobial silicon oxide flakes
JP2008506801A (ja) * 2004-07-16 2008-03-06 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 発光性シリコン酸化物フレーク
EP1769025A1 (en) * 2004-07-16 2007-04-04 Ciba SC Holding AG Porous inorganic materials containing polymer additives
EP1784355A2 (en) * 2004-07-26 2007-05-16 CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement Reactive silicon suboxide flakes
DE602005026820D1 (de) 2004-08-23 2011-04-21 Basf Se Verfahren zur herstellung von blättchenförmigen pi0)
GB0502166D0 (en) * 2005-02-02 2005-03-09 Effectology Ltd Ink-jet printing process
JP2009504909A (ja) * 2005-08-12 2009-02-05 ダンウィルコ（１１９８）リミテッド 金属フレーク製造方法
GB0516968D0 (en) * 2005-08-18 2005-09-28 Dunwilco 1198 Ltd Process
US20070256782A1 (en) * 2006-05-02 2007-11-08 Haldeman Steven V Multiple Layer Glazing Bilayer Comprising Cesium Tungsten Oxide
GB2440140A (en) * 2006-07-17 2008-01-23 Dunwilco Method of making flakes
BRPI0807590B8 (pt) 2007-02-20 2019-08-13 Microban Products composição de esmalte cerâmico antimicrobiano, substrato cerâmico esmaltado, e, métodos para fabricação de um substrato cerâmico esmaltado e de uma composição de esmalte cerâmico antimicrobiano
US8216683B2 (en) * 2007-08-03 2012-07-10 Solutia Inc. Interlayers comprising stabilized tungsten oxide agents
US10159255B2 (en) 2008-02-16 2018-12-25 Microban Products Company Biocidal glazing composition, method, and article
CN102234198B (zh) * 2011-04-18 2012-12-26 西峡县新锦耐化有限责任公司 热反射节能涂料
US9320687B2 (en) 2013-03-13 2016-04-26 Johnson & Johnson Consumer Inc. Pigmented skin-care compositions
US9168209B2 (en) 2013-03-13 2015-10-27 Johnson & Johnson Consumer Inc. Pigmented skin-care compositions
US9168394B2 (en) 2013-03-13 2015-10-27 Johnson & Johnson Consumer Inc. Pigmented skin-care compositions
US9168393B2 (en) 2013-03-13 2015-10-27 Johnson & Johnson Consumer Inc. Pigmented skin-care compositions
JP6407887B2 (ja) 2013-11-26 2018-10-17 日本碍子株式会社 多孔質材料及び断熱膜
US9974310B2 (en) 2016-03-09 2018-05-22 Microban Products Company Ceramic additive formulation and method of making
US10899657B1 (en) 2016-03-09 2021-01-26 Microban Products Company Ceramic additive formulation and method of making
US11844351B2 (en) 2016-10-31 2023-12-19 Microban Products Company Method of treating a glazed ceramic article
CN109485252B (zh) * 2018-06-19 2021-09-28 原思平 一种高透可见光和吸收近红外线的功能玻璃的着色添加剂、应用及功能玻璃
JP7079503B6 (ja) * 2019-11-29 2022-08-15 尾池工業株式会社 金色顔料、分散液、インク、並びに塗膜及びその製造方法
BE1031181B1 (fr) * 2022-12-22 2024-07-22 Materia Nova Asbl Revêtement muticouche de couleur réglable

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL104714C (https=) * 1955-12-22
US3438796A (en) * 1967-02-02 1969-04-15 Du Pont Aluminum-silica-aluminum flake pigments
DE59704636D1 (de) * 1996-04-25 2001-10-25 Ciba Sc Holding Ag Farbige Glanzpigmente
ES2234170T3 (es) * 1997-12-25 2005-06-16 Nippon Steel Corporation Procedimiento para la preparacion de si de alta pureza y equipo para el procedimiento.
DK1153088T3 (da) * 1999-01-25 2004-09-20 Ciba Sc Holding Ag Farveeffekt-pigmenter og fremgangsmåde til deres fremstilling
DE10004888A1 (de) * 2000-02-04 2001-08-09 Eckart Standard Bronzepulver Glanzpigment und Verfahren zu seiner Herstellung
US6586098B1 (en) * 2000-07-27 2003-07-01 Flex Products, Inc. Composite reflective flake based pigments comprising reflector layers on bothside of a support layer
US6569529B1 (en) * 2000-10-10 2003-05-27 Flex Product, Inc. Titanium-containing interference pigments and foils with color shifting properties
MXPA04007992A (es) * 2002-02-18 2004-11-26 Ciba Sc Holding Ag Metodos para producir estructuras de caras planas paralelas de suboxido de silicio, dioxido de silicio y/o carburo de silicio, estructura de caras planas paralelas obtenibles por esos metodos, y el uso de los mismos.
WO2004035693A1 (en) * 2002-10-16 2004-04-29 Ciba Specialty Chemicals Holding Inc. Interference pigments on the basis of silicon oxides
EP1585703A1 (en) 2003-01-17 2005-10-19 Ciba SC Holding AG A process for the production of porous inorganic materials or a matrix material containing nanoparticles
CA2527763A1 (en) * 2003-06-17 2004-12-29 Ciba Specialty Chemicals Holding Inc. A process for the preparation of a pigment comprising a core material and at least one dielectric layer

Also Published As

Publication number Publication date
EP1517964A1 (en) 2005-03-30
MXPA04012887A (es) 2005-03-31
US7273522B2 (en) 2007-09-25
AU2003250247A1 (en) 2003-12-31
WO2003106569A1 (en) 2003-12-24
CN1662613A (zh) 2005-08-31
JP2005529835A (ja) 2005-10-06
CA2489874A1 (en) 2003-12-24
US20050252410A1 (en) 2005-11-17

Similar Documents

Publication Publication Date Title
JP4511926B2 (ja) ケイ素／酸化ケイ素の面平行な構造
JP4777066B2 (ja) 新規な干渉顔料
JP4476629B2 (ja) 亜酸化ケイ素、二酸化ケイ素及び／又は炭化ケイ素の面平行な構造を製造する方法、当該方法によって得られる面平行な構造ならびにその使用
JP4820549B2 (ja) 還元顔料
JP5234960B2 (ja) ガラスフレークに基づく干渉顔料
KR101015031B1 (ko) 규소 산화물을 기본으로 하는 간섭 안료
JP2006509088A (ja) アルミニウムをベースとするフレーク状顔料
KR101057964B1 (ko) 작은판 형상의 안료
JP2008511704A (ja) アルミニウムおよびＳｉＯｚ（ｚ＝０．７〜２．０）をベースとするフレーク状顔料を製造する方法
JP2010532808A (ja) パーライトフレークを基礎とする干渉顔料
JP2010525125A (ja) 効果顔料のための強化金属酸化物フレーク
JP4620469B2 (ja) 非対称層構造を有する光学的に可変性の顔料

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060616

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060616

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090512

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090805

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100413

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100507

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130514

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees