JP4498926B2 - 熱交換器を使用して直鎖状α−オレフィンオリゴマーを製造する方法 - Google Patents
熱交換器を使用して直鎖状α−オレフィンオリゴマーを製造する方法 Download PDFInfo
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- JP4498926B2 JP4498926B2 JP2004539030A JP2004539030A JP4498926B2 JP 4498926 B2 JP4498926 B2 JP 4498926B2 JP 2004539030 A JP2004539030 A JP 2004539030A JP 2004539030 A JP2004539030 A JP 2004539030A JP 4498926 B2 JP4498926 B2 JP 4498926B2
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- FCWDPKZMHKLZRU-JCAXBWHZSA-N C/C(/c1nc(/C(/C)=N/c(c(F)ccc2)c2F)ccc1)=N\c(c(F)ccc1)c1F Chemical compound C/C(/c1nc(/C(/C)=N/c(c(F)ccc2)c2F)ccc1)=N\c(c(F)ccc1)c1F FCWDPKZMHKLZRU-JCAXBWHZSA-N 0.000 description 1
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- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
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- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
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- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
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- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
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- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
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- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Description
R1は、HまたはCH3であり、
R2は、H、tert−ブチルまたはフェニルであり、
R3は、H、tert−ブチルまたはOR’(R’はCH3、Si(CH3)3またはエイコシル(C20H41)を表す)である]、および
Claims (10)
- 2,6−ビス(アリールイミノ)ピリジン誘導体の鉄錯体の存在下、熱を放出しながら、エチレンを触媒作用によってオリゴマー化して平均分子量50から350のα−オレフィンオリゴマーにするステップと、少なくとも一部の気相を冷媒として使用して、液相と直接接触していない熱交換器で熱を除去するステップとを含む、液相および気相を含む反応器中で直鎖状α−オレフィンオリゴマーを製造する方法。
- アルミニウムベースの共触媒を液相に添加する請求項1に記載の方法。
- アルミニウムベースの共触媒がメチルアルミノキサンである請求項2に記載の方法。
- 平均分子量が60から280である請求項1から3のいずれか一項に記載の方法。
- 平均分子量が80から210である請求項4に記載の方法。
- 2,6−ビス(アリールイミノ)ピリジン誘導体のアリール部分の1つが、CH2RまたはC2H5R基[Rは、HおよびFから選択される]で2,6−二置換され、他のアリール部分が2,6−非置換であり、または2,6−ビス(アリールイミノ)ピリジン誘導体の両方のアリール部分がFまたはClで2,6−二置換されている請求項1から5のいずれか一項に記載の方法。
- 冷媒が、アルカン、アルケン、および芳香族化合物、ならびにその混合物から選択される請求項1から7のいずれか一項に記載の方法。
- 冷媒が、プロパン、n−ペンタン、イソペンタン、エチレン、1−ブテン、o−、m−、およびp−キシレン、およびトルエン、ならびにその混合物から選択される請求項1から8のいずれか一項に記載の方法。
- 液相(3)、気相(4)、それを介して反応器供給材料(1)を輸送することができる入口(10)、反応器底部出口(9)、および反応器の内部にあり、液相(3)との直接接触を防止するように配置された少なくとも1つの熱交換器(20)、飛沫同伴分離器(13)、さらに場合により気体出口(11)、ポンプ(8)、圧縮機(7a、b)および/または気液分離器(6)を収容することができる反応器(2)を含む請求項1から9のいずれか一項に記載の直鎖状α−オレフィンオリゴマーを製造する方法を実施するための装置。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41327802P | 2002-09-25 | 2002-09-25 | |
PCT/EP2003/010709 WO2004029012A1 (en) | 2002-09-25 | 2003-09-23 | Process for making a linear alpha-olefin oligomer using a heat exchanger |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006500411A JP2006500411A (ja) | 2006-01-05 |
JP4498926B2 true JP4498926B2 (ja) | 2010-07-07 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2004539030A Expired - Fee Related JP4498926B2 (ja) | 2002-09-25 | 2003-09-23 | 熱交換器を使用して直鎖状α−オレフィンオリゴマーを製造する方法 |
Country Status (12)
Country | Link |
---|---|
US (1) | US20040122269A1 (ja) |
EP (1) | EP1546069B1 (ja) |
JP (1) | JP4498926B2 (ja) |
CN (1) | CN100519491C (ja) |
AT (1) | ATE432248T1 (ja) |
AU (1) | AU2003271645A1 (ja) |
CA (1) | CA2499887C (ja) |
DE (1) | DE60327784D1 (ja) |
ES (1) | ES2324030T3 (ja) |
RU (1) | RU2312848C2 (ja) |
WO (1) | WO2004029012A1 (ja) |
ZA (1) | ZA200502082B (ja) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2339604C2 (ru) * | 2002-09-25 | 2008-11-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения линейного альфа-олефинового олигомера с использованием теплообменника |
US7081506B2 (en) * | 2003-10-23 | 2006-07-25 | Fina Technology, Inc. | Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components |
US20050187418A1 (en) | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
US20070043181A1 (en) | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
US20050187098A1 (en) | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
US7384886B2 (en) | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US7129304B1 (en) | 2005-07-21 | 2006-10-31 | Chevron Phillips Chemical Company Lp | Dimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
US7727926B2 (en) * | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
ATE411267T1 (de) * | 2005-07-29 | 2008-10-15 | Linde Ag | Verfahren zur herstellung von linearen olefinen mit verbesserter wärmeabführung |
US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
CN101906009B (zh) * | 2010-07-29 | 2013-02-13 | 浙江大学 | 一种制备线性α-烯烃的方法 |
US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
WO2016047558A1 (ja) | 2014-09-22 | 2016-03-31 | 三菱化学株式会社 | α-オレフィン低重合体の製造方法及び製造装置 |
US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
FR3083235B1 (fr) * | 2018-06-29 | 2021-12-03 | Ifp Energies Now | Procede d'oligomerisation en cascade de reacteurs gaz liquide agites avec injection etagee d'ethylene |
CN113045691B (zh) * | 2021-03-23 | 2022-08-05 | 中国科学院青岛生物能源与过程研究所 | 一种铁催化剂配位聚合制备低分子量聚异丁烯的方法 |
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US2978441A (en) * | 1957-05-23 | 1961-04-04 | Phillips Petroleum Co | Polyolefin reactor control |
US3461109A (en) * | 1964-11-09 | 1969-08-12 | Phillips Petroleum Co | Process for the polymerization of conjugated dienes |
US3565873A (en) * | 1967-09-25 | 1971-02-23 | Copolymer Rubber & Chem Corp | Method and apparatus for polymerizing monomeric materials |
DE2461104C3 (de) * | 1973-12-28 | 1980-09-18 | Mitsubishi Rayon Co. Ltd., Tokio | Verfahren zum Abführen von Wärme während der Methylmethacrylat-Massepolymerisation und Vorrichtung zur Durchführung des Verfahrens |
US4709111A (en) * | 1987-02-27 | 1987-11-24 | Uop Inc. | Oligomerization process with integrated heat utilization |
US5198563A (en) * | 1989-08-10 | 1993-03-30 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5550305A (en) * | 1991-10-16 | 1996-08-27 | Amoco Corporation | Ethylene trimerization |
US5438027A (en) * | 1991-12-13 | 1995-08-01 | Phillips Petroleum Company | Chromium compounds and uses thereof |
ZA943399B (en) * | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
GB9819847D0 (en) * | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
US6825297B1 (en) * | 1999-05-14 | 2004-11-30 | The Dow Chemical Company | Transition metal complexes and olefin polymerization process |
GC0000291A (en) * | 2000-06-30 | 2006-11-01 | Shell Int Research | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
US6534691B2 (en) * | 2000-07-18 | 2003-03-18 | E. I. Du Pont De Nemours And Company | Manufacturing process for α-olefins |
RU2339604C2 (ru) * | 2002-09-25 | 2008-11-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения линейного альфа-олефинового олигомера с использованием теплообменника |
ATE327826T1 (de) * | 2002-09-25 | 2006-06-15 | Shell Int Research | Katalysatorsysteme für die ethylen- oligomerisierung zu linearen alpha-olefinen |
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2003
- 2003-09-23 EP EP03753462A patent/EP1546069B1/en not_active Revoked
- 2003-09-23 CA CA2499887A patent/CA2499887C/en not_active Expired - Fee Related
- 2003-09-23 CN CNB038229943A patent/CN100519491C/zh not_active Expired - Fee Related
- 2003-09-23 ES ES03753462T patent/ES2324030T3/es not_active Expired - Lifetime
- 2003-09-23 RU RU2005112253/04A patent/RU2312848C2/ru not_active IP Right Cessation
- 2003-09-23 DE DE60327784T patent/DE60327784D1/de not_active Expired - Lifetime
- 2003-09-23 AU AU2003271645A patent/AU2003271645A1/en not_active Abandoned
- 2003-09-23 AT AT03753462T patent/ATE432248T1/de not_active IP Right Cessation
- 2003-09-23 JP JP2004539030A patent/JP4498926B2/ja not_active Expired - Fee Related
- 2003-09-23 WO PCT/EP2003/010709 patent/WO2004029012A1/en active Application Filing
- 2003-09-23 US US10/668,933 patent/US20040122269A1/en not_active Abandoned
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2005
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Publication number | Publication date |
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CN1735576A (zh) | 2006-02-15 |
CA2499887A1 (en) | 2004-04-08 |
WO2004029012A1 (en) | 2004-04-08 |
ES2324030T3 (es) | 2009-07-29 |
ATE432248T1 (de) | 2009-06-15 |
ZA200502082B (en) | 2005-11-30 |
RU2312848C2 (ru) | 2007-12-20 |
DE60327784D1 (de) | 2009-07-09 |
CN100519491C (zh) | 2009-07-29 |
CA2499887C (en) | 2011-08-16 |
EP1546069B1 (en) | 2009-05-27 |
EP1546069A1 (en) | 2005-06-29 |
AU2003271645A1 (en) | 2004-04-19 |
US20040122269A1 (en) | 2004-06-24 |
JP2006500411A (ja) | 2006-01-05 |
RU2005112253A (ru) | 2005-09-10 |
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