JP4494010B2 - 実質的に亜塩素酸塩フリーで、安定した水性塩素酸素溶液の製造方法、この方法により得られる塩素酸素溶液、ならびにその利用 - Google Patents
実質的に亜塩素酸塩フリーで、安定した水性塩素酸素溶液の製造方法、この方法により得られる塩素酸素溶液、ならびにその利用 Download PDFInfo
- Publication number
- JP4494010B2 JP4494010B2 JP2003501791A JP2003501791A JP4494010B2 JP 4494010 B2 JP4494010 B2 JP 4494010B2 JP 2003501791 A JP2003501791 A JP 2003501791A JP 2003501791 A JP2003501791 A JP 2003501791A JP 4494010 B2 JP4494010 B2 JP 4494010B2
- Authority
- JP
- Japan
- Prior art keywords
- solution
- chlorite
- aqueous
- oxygen
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 26
- WGKMWBIFNQLOKM-UHFFFAOYSA-N [O].[Cl] Chemical compound [O].[Cl] WGKMWBIFNQLOKM-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000000243 solution Substances 0.000 claims abstract description 42
- -1 hydrogen sulfate compound Chemical class 0.000 claims abstract description 20
- 229910001919 chlorite Inorganic materials 0.000 claims abstract description 18
- 229910052619 chlorite group Inorganic materials 0.000 claims abstract description 18
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 7
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000012467 final product Substances 0.000 claims abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 11
- 238000004659 sterilization and disinfection Methods 0.000 claims description 9
- 238000000746 purification Methods 0.000 claims description 7
- 239000003814 drug Substances 0.000 claims description 5
- VOWOEBADKMXUBU-UHFFFAOYSA-J molecular oxygen;tetrachlorite;hydrate Chemical compound O.O=O.[O-]Cl=O.[O-]Cl=O.[O-]Cl=O.[O-]Cl=O VOWOEBADKMXUBU-UHFFFAOYSA-J 0.000 claims description 5
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 5
- 229960002218 sodium chlorite Drugs 0.000 claims description 5
- 230000009182 swimming Effects 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 229940079593 drug Drugs 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000003651 drinking water Substances 0.000 claims description 3
- 235000020188 drinking water Nutrition 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 12
- 239000004155 Chlorine dioxide Substances 0.000 description 6
- 235000019398 chlorine dioxide Nutrition 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000010253 intravenous injection Methods 0.000 description 2
- 150000002926 oxygen Chemical class 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000035473 Communicable disease Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000204031 Mycoplasma Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004973 alkali metal peroxides Chemical class 0.000 description 1
- 150000004974 alkaline earth metal peroxides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000001990 intravenous administration Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- QEHKBHWEUPXBCW-UHFFFAOYSA-N nitrogen trichloride Chemical class ClN(Cl)Cl QEHKBHWEUPXBCW-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- VISKNDGJUCDNMS-UHFFFAOYSA-M potassium;chlorite Chemical compound [K+].[O-]Cl=O VISKNDGJUCDNMS-UHFFFAOYSA-M 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10127729A DE10127729C2 (de) | 2001-06-07 | 2001-06-07 | Stabile wäßrige Chlorsauerstofflösung, die im wesentlichen chloritfrei ist, Verfahren zu deren Herstellung sowie deren Verwendung |
| PCT/EP2002/006178 WO2002098791A1 (de) | 2001-06-07 | 2002-06-05 | Verfahren zur herstellung einer im wesentlichen chloritfreien, stabilen wässrigen chlorsauerstofflösung, die mit dem verfahren erhältliche chlorsauerstofflösung sowie deren verwendung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004529058A JP2004529058A (ja) | 2004-09-24 |
| JP2004529058A5 JP2004529058A5 (https=) | 2010-04-08 |
| JP4494010B2 true JP4494010B2 (ja) | 2010-06-30 |
Family
ID=7687557
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003501791A Expired - Lifetime JP4494010B2 (ja) | 2001-06-07 | 2002-06-05 | 実質的に亜塩素酸塩フリーで、安定した水性塩素酸素溶液の製造方法、この方法により得られる塩素酸素溶液、ならびにその利用 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US7252772B2 (https=) |
| EP (1) | EP1392599B1 (https=) |
| JP (1) | JP4494010B2 (https=) |
| CN (1) | CN100396597C (https=) |
| AT (1) | ATE342228T1 (https=) |
| AU (1) | AU2002328285B2 (https=) |
| CA (1) | CA2449974C (https=) |
| CZ (1) | CZ299317B6 (https=) |
| DE (2) | DE10127729C2 (https=) |
| DK (1) | DK1392599T3 (https=) |
| ES (1) | ES2272760T3 (https=) |
| HR (1) | HRP20031004B1 (https=) |
| HU (1) | HU226415B1 (https=) |
| NZ (1) | NZ530173A (https=) |
| PL (1) | PL203372B1 (https=) |
| PT (1) | PT1392599E (https=) |
| WO (1) | WO2002098791A1 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1971426A1 (de) * | 2006-01-11 | 2008-09-24 | P & W Invest Vermögensverwaltungsgesellschaft mbH | Hüllenmembran zur abgabe eines eingeschlossenen wirkstoffs, ein verfahren zur herstellung sowie deren verwendung |
| DE102006001481A1 (de) * | 2006-01-11 | 2007-07-12 | P & W Invest Vermögensverwaltungsgesellschaft mbH | Kapseln zur dosierten Abgabe eines eingeschlossenen Wirkstoffs, ein Verfahren zu deren Herstellung und deren Verwendung |
| BRPI0902987A2 (pt) * | 2009-08-12 | 2011-04-12 | Multclor Quimica Imp Adora E Exportadora Ltda | cloro oxigenado para tratamento de águas e seu respectivo processo de obtenção e aplicação |
| JP6310745B2 (ja) * | 2014-03-26 | 2018-04-11 | 保土谷化学工業株式会社 | 殺菌組成物 |
| WO2016080243A1 (ja) * | 2014-11-17 | 2016-05-26 | 日本曹達株式会社 | 屋内プール用水の処理方法 |
| WO2021189103A1 (en) * | 2020-03-23 | 2021-09-30 | Waterco Limited | Water sanitisation device, system and method |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE464370A (https=) | 1943-08-13 | |||
| US4296103A (en) | 1980-08-08 | 1981-10-20 | Felipe Laso | Stabilized solution of chlorine oxides |
| DE3403631A1 (de) | 1983-02-25 | 1984-08-30 | Peter 6900 Heidelberg Berger | Verfahren zur herstellung einer modifizierten waessrigen chloritloesung, die danach hergestellte loesung sowie deren verwendung |
| WO1984003274A1 (fr) * | 1983-02-25 | 1984-08-30 | Peter Berger | Procede de fabrication d'une solution aqueuse modifiee de chlorite, la solution produite par la suite et son utilisation |
| US4574084A (en) * | 1983-02-25 | 1986-03-04 | Peter Berger | Process for the preparation of a modified aqueous chlorite solution, the solution prepared by this process and the use thereof |
| DE3515749A1 (de) * | 1985-05-02 | 1986-11-06 | Oxo Chemie GmbH, 6900 Heidelberg | Verwendung einer stabilisierten chloritmatrixloesung bei infektioesen zustaenden |
| DE3515745A1 (de) | 1985-05-02 | 1986-11-06 | Oxo Chemie GmbH, 6900 Heidelberg | Waessrige chloritmatrix-loesung |
| DE3515748A1 (de) | 1985-05-02 | 1986-11-06 | Oxo Chemie GmbH, 6900 Heidelberg | Verwendung einer isotonen chloritmatrix-loesung bei der behandlung von tumoren |
| JP2638611B2 (ja) * | 1988-06-17 | 1997-08-06 | 紀久雄 及川 | 安定化二酸化塩素水溶液の製造法 |
| US5009875A (en) * | 1988-08-03 | 1991-04-23 | International Dioxcide, Inc. | Process of preparing clorine dioxide and apparatus therefor |
| JPH0446003A (ja) * | 1990-06-11 | 1992-02-17 | Japan Carlit Co Ltd:The | 安定化二酸化塩素水溶液の製造法 |
| US5575945A (en) * | 1994-09-14 | 1996-11-19 | Brandeis University | Chemical treatment system for producing odor and taste-free potable water |
| CZ281460B6 (cs) * | 1994-12-01 | 1996-10-16 | Jindřich Sznapka | Způsob úpravy vody a zapojení k provádění tohoto způsobu |
| DE19514612A1 (de) * | 1995-04-25 | 1996-10-31 | Fritz Dr Kueke | Verfahren zur Herstellung einer wässrigen Chlordioxid-Lösung |
| DE19529504C2 (de) * | 1995-08-10 | 1998-03-26 | Manfred Prof Dr Rer Na Rimpler | Verfahren zur Herstellung wäßriger Chlordioxid-Lösungen |
| GB2304706B (en) * | 1995-09-01 | 1999-06-30 | Feedwater Treatment Services L | Preparation and use of novel biocidal solutions |
| US6051135A (en) * | 1996-02-23 | 2000-04-18 | Water Technologies Limited | Apparatus for making aqueous chlorine dioxide and apparatus for treating water with aqueous chlorine dioxide |
| US5855861A (en) * | 1996-02-23 | 1999-01-05 | Water Technologies Limited | Method and apparatus for making aqueous chlorine dioxide |
| JPH09268002A (ja) * | 1996-04-02 | 1997-10-14 | Akira Yoshikawa | 二酸化塩素の発生方法 |
-
2001
- 2001-06-07 DE DE10127729A patent/DE10127729C2/de not_active Expired - Lifetime
-
2002
- 2002-06-05 JP JP2003501791A patent/JP4494010B2/ja not_active Expired - Lifetime
- 2002-06-05 NZ NZ530173A patent/NZ530173A/xx not_active IP Right Cessation
- 2002-06-05 PL PL367845A patent/PL203372B1/pl unknown
- 2002-06-05 DE DE50208422T patent/DE50208422D1/de not_active Expired - Lifetime
- 2002-06-05 ES ES02762281T patent/ES2272760T3/es not_active Expired - Lifetime
- 2002-06-05 HU HU0400173A patent/HU226415B1/hu unknown
- 2002-06-05 CA CA2449974A patent/CA2449974C/en not_active Expired - Lifetime
- 2002-06-05 US US10/480,009 patent/US7252772B2/en not_active Expired - Lifetime
- 2002-06-05 AU AU2002328285A patent/AU2002328285B2/en not_active Ceased
- 2002-06-05 CN CNB02812507XA patent/CN100396597C/zh not_active Expired - Fee Related
- 2002-06-05 WO PCT/EP2002/006178 patent/WO2002098791A1/de not_active Ceased
- 2002-06-05 AT AT02762281T patent/ATE342228T1/de active
- 2002-06-05 PT PT02762281T patent/PT1392599E/pt unknown
- 2002-06-05 CZ CZ20033313A patent/CZ299317B6/cs not_active IP Right Cessation
- 2002-06-05 EP EP02762281A patent/EP1392599B1/de not_active Expired - Lifetime
- 2002-06-05 HR HR20031004A patent/HRP20031004B1/xx not_active IP Right Cessation
- 2002-06-05 DK DK02762281T patent/DK1392599T3/da active
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0400173A3 (en) | 2005-11-28 |
| CZ299317B6 (cs) | 2008-06-18 |
| CA2449974C (en) | 2010-08-10 |
| HRP20031004A2 (en) | 2005-08-31 |
| ES2272760T3 (es) | 2007-05-01 |
| NZ530173A (en) | 2006-03-31 |
| PL367845A1 (en) | 2005-03-07 |
| AU2002328285B2 (en) | 2007-03-22 |
| PL203372B1 (pl) | 2009-09-30 |
| CN1537074A (zh) | 2004-10-13 |
| CZ20033313A3 (en) | 2004-03-17 |
| DE10127729A1 (de) | 2002-12-19 |
| EP1392599B1 (de) | 2006-10-11 |
| JP2004529058A (ja) | 2004-09-24 |
| PT1392599E (pt) | 2007-01-31 |
| HK1068863A1 (en) | 2005-07-29 |
| HRP20031004B1 (hr) | 2010-04-30 |
| DK1392599T3 (da) | 2007-02-19 |
| HU226415B1 (en) | 2008-11-28 |
| DE50208422D1 (de) | 2006-11-23 |
| CA2449974A1 (en) | 2002-12-12 |
| DE10127729C2 (de) | 2003-05-28 |
| US7252772B2 (en) | 2007-08-07 |
| US20040206707A1 (en) | 2004-10-21 |
| ATE342228T1 (de) | 2006-11-15 |
| EP1392599A1 (de) | 2004-03-03 |
| CN100396597C (zh) | 2008-06-25 |
| HUP0400173A2 (hu) | 2004-07-28 |
| WO2002098791A1 (de) | 2002-12-12 |
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