JP4362253B2 - 改良された加工性及び物理的性質の改良されたバランスを有する熱可塑性エラストマー - Google Patents
改良された加工性及び物理的性質の改良されたバランスを有する熱可塑性エラストマー Download PDFInfo
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- JP4362253B2 JP4362253B2 JP2001400447A JP2001400447A JP4362253B2 JP 4362253 B2 JP4362253 B2 JP 4362253B2 JP 2001400447 A JP2001400447 A JP 2001400447A JP 2001400447 A JP2001400447 A JP 2001400447A JP 4362253 B2 JP4362253 B2 JP 4362253B2
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- rubber
- polymer
- diene
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- thermoplastic resin
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- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- GUYLTGCUWGGXHD-UHFFFAOYSA-N octadeca-1,17-diene Chemical compound C=CCCCCCCCCCCCCCCC=C GUYLTGCUWGGXHD-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/752,080 US6451915B1 (en) | 2000-12-29 | 2000-12-29 | Thermoplastic elastomers having improved processing and physical property balance |
| US09/752080 | 2000-12-29 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002220493A JP2002220493A (ja) | 2002-08-09 |
| JP2002220493A5 JP2002220493A5 (enExample) | 2005-08-04 |
| JP4362253B2 true JP4362253B2 (ja) | 2009-11-11 |
Family
ID=25024773
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001400447A Expired - Lifetime JP4362253B2 (ja) | 2000-12-29 | 2001-12-28 | 改良された加工性及び物理的性質の改良されたバランスを有する熱可塑性エラストマー |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6451915B1 (enExample) |
| EP (1) | EP1219679B2 (enExample) |
| JP (1) | JP4362253B2 (enExample) |
| KR (1) | KR20020059239A (enExample) |
| DE (1) | DE60108840T3 (enExample) |
| ES (1) | ES2234761T3 (enExample) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE405594T1 (de) | 2002-01-15 | 2008-09-15 | Advanced Elastomer Systems | Thermoplastische elastomere |
| WO2003068859A1 (en) * | 2002-02-11 | 2003-08-21 | Dsm Ip Assets B.V. | Thermoplastic elastomer composition |
| WO2003082971A2 (en) * | 2002-03-22 | 2003-10-09 | Dow Global Technologies Inc. | Thermoplastic vulcanizate composition and method of making same |
| US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7652094B2 (en) * | 2002-08-12 | 2010-01-26 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| EP2083043B1 (en) | 2002-08-12 | 2017-01-18 | ExxonMobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| US7652092B2 (en) | 2002-08-12 | 2010-01-26 | Exxonmobil Chemical Patents Inc. | Articles from plasticized thermoplastic polyolefin compositions |
| US7622523B2 (en) | 2002-08-12 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| US6790911B2 (en) * | 2002-12-26 | 2004-09-14 | Advanvced Elastomer Systems, L.P. | Thermoplastic elastomers having improved adhesive proterties |
| US6780936B1 (en) * | 2003-02-11 | 2004-08-24 | Exxonmobil Chemical Patents Inc. | Diene-modified propylene polymer nucleating agents |
| US7737205B2 (en) * | 2003-07-28 | 2010-06-15 | Dow Global Technologies Inc | Thermoplastic vulcanizates and process to prepare them |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| EP1664189B1 (en) * | 2003-09-17 | 2009-11-18 | ExxonMobil Chemical Patents Inc. | Improved thermoplastic vulcanizates and processes for making the same |
| US7288323B2 (en) * | 2003-11-13 | 2007-10-30 | Fisher Controls International, Llc | Vulcanized rubber composition and articles manufactured therefrom |
| US20060052540A1 (en) | 2004-09-09 | 2006-03-09 | Maria Ellul | Thermoplastic vulcanizates |
| US7193018B2 (en) * | 2004-09-15 | 2007-03-20 | Advanced Elastomer Systems, Lp. | Slip-coat compositions and polymeric laminates |
| US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| US8076416B2 (en) | 2005-02-04 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and their use |
| JP5590517B2 (ja) * | 2005-04-14 | 2014-09-17 | エクソンモービル・ケミカル・パテンツ・インク | 透明ポリオレフィン組成物 |
| US7622528B2 (en) * | 2005-06-27 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Process for preparing thermoplastic elastomers by dynamic vulcanization |
| US8653170B2 (en) * | 2005-06-27 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Dynamic vulcanization process for preparing thermoplastic elastomers |
| ATE555166T1 (de) | 2005-07-15 | 2012-05-15 | Exxonmobil Chem Patents Inc | Elastomere zusammensetzungen |
| US7872075B2 (en) * | 2005-10-07 | 2011-01-18 | Exxonmobil Chemical Patents Inc. | Peroxide-cured thermoplastic vulcanizates and process for making the same |
| US7812093B2 (en) * | 2005-12-19 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Peroxide-cured thermoplastic vulcanizates and medical devices made therewith |
| US7504458B2 (en) * | 2006-04-12 | 2009-03-17 | Advanced Elastomer Systems, Llp | Method for improving compression set in thermoplastic vulcanizates |
| US7413784B2 (en) | 2006-06-19 | 2008-08-19 | Advanced Elastomer Systems, L.P. | Thermoplastic vulcanizates for potable water applications |
| US7625980B2 (en) | 2006-07-11 | 2009-12-01 | Exxonmobil Chemical Patents Inc. | Method for improving extrusion surface smoothness in thermoplastic vulcanizates |
| US8178625B2 (en) * | 2006-08-01 | 2012-05-15 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate composition |
| US7951871B2 (en) * | 2006-11-10 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Curing rubber by hydrosilation |
| US7615589B2 (en) | 2007-02-02 | 2009-11-10 | Exxonmobil Chemical Patents Inc. | Properties of peroxide-cured elastomer compositions |
| DE102007011076B4 (de) * | 2007-03-07 | 2011-06-01 | Teijin Monofilament Germany Gmbh | Antimikrobiell ausgerüstete Fäden, Verfahren zu deren Herstellung und textile Flächengebilde |
| WO2008134173A1 (en) * | 2007-05-01 | 2008-11-06 | Advanced Elastomer Systems, L.P. | Method for preparing thermoplastic vulcanizates |
| US8011913B2 (en) * | 2008-02-29 | 2011-09-06 | Exxonmobil Chemical Patents Inc. | Method of melt blending curable polymer compositions using silicone hydrides |
| US9234093B2 (en) * | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| US10077518B2 (en) * | 2008-10-29 | 2018-09-18 | Mitsui Chemicals, Inc. | Crimped conjugated fiber and nonwoven fabric comprising the same |
| US8877867B2 (en) * | 2008-11-06 | 2014-11-04 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and extruded articles therefrom |
| KR20120099093A (ko) | 2009-12-30 | 2012-09-06 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 열가소성 가황물의 형성 방법 |
| JP5484564B2 (ja) * | 2010-04-16 | 2014-05-07 | 三井化学株式会社 | 捲縮複合繊維、及び当該繊維からなる不織布 |
| US8557906B2 (en) | 2010-09-03 | 2013-10-15 | Exxonmobil Chemical Patents Inc. | Flame resistant polyolefin compositions and methods for making the same |
| ES2613713T3 (es) | 2011-09-15 | 2017-05-25 | Asahi Kasei Kabushiki Kaisha | Composición reticulada, método para producir una composición reticulada y producto moldeado |
| FR2984895B1 (fr) * | 2011-12-21 | 2016-01-01 | Michelin Soc Tech | Pneumatique comprenant une composition essentiellement depourvue de derive guanidique et comprenant un hydroxyde de metal alcalin ou alcalino-terreux |
| JP5966220B2 (ja) | 2012-05-10 | 2016-08-10 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 組成物及びそれらの製造方法 |
| US10836853B2 (en) * | 2012-09-20 | 2020-11-17 | Exxonmobil Chemical Patents Inc. | Crack-resistant polyethylene compositions |
| US10822479B2 (en) * | 2012-09-20 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Foamed polyethylene compositions |
| KR102321541B1 (ko) * | 2014-01-16 | 2021-11-03 | 리서치 파운데이션 오브 더 시티 유니버시티 오브 뉴욕 | 초소수성 표면을 생성하는 중심-측면 방법 |
| WO2015175117A1 (en) | 2014-05-12 | 2015-11-19 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates and method of making the same |
| JP6498760B2 (ja) | 2014-10-24 | 2019-04-10 | エクソンモービル・ケミカル・パテンツ・インク | 熱可塑性加硫物組成物 |
| WO2016085457A1 (en) | 2014-11-25 | 2016-06-02 | Exxonmobil Chemical Patents Inc. | Method of making thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom |
| JP2019513307A (ja) | 2016-03-30 | 2019-05-23 | エクソンモービル・ケミカル・パテンツ・インク | 太陽電池用途向けの熱可塑性加硫物組成物 |
| FR3062446B1 (fr) * | 2017-02-02 | 2020-07-31 | Tristone Flowtech Solutions Tfs | Conduite de circulation de fluide pour vehicule automobile, son procede de fabrication et son utilisation en tant que tuyau de refroidissement de fluide moteur de vehicule automobile |
| WO2019045870A1 (en) | 2017-08-31 | 2019-03-07 | Exxonmobil Chemical Patents Inc. | METHODS OF MANUFACTURING THERMOPLASTIC VULCANISATS (TPV) |
| EP3728458A1 (en) | 2017-12-18 | 2020-10-28 | ExxonMobil Chemical Patents Inc. | Thermoplastic vulcanizate conduits for transporting hydrocarbon fluids |
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| CN114786938A (zh) | 2019-08-26 | 2022-07-22 | 国际人造丝公司 | 作为非柔性管中的绝缘层的热塑性硫化橡胶组合物和热塑性烯烃组合物 |
| US20230133171A1 (en) | 2020-03-18 | 2023-05-04 | Celanese International Corporation | Thermoplastic Elastomer Compositions, Their Preparation and Use in Fiber-Reinforced Spoolable Pipes |
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| US20230272195A1 (en) | 2020-08-25 | 2023-08-31 | Exxonmobil Chemical Patents Inc. | High Density Polyethylene Compositions With Exceptional Physical Properties |
| US20230399426A1 (en) | 2020-12-02 | 2023-12-14 | Exxonmobil Chemical Patents Inc. | Medium density polyethylene compositions with broad orthogonal composition distribution |
| WO2022126068A1 (en) | 2020-12-08 | 2022-06-16 | Exxonmobil Chemical Patents Inc. | High density polyethylene compositions with long-chain branching |
| WO2022132268A1 (en) | 2020-12-16 | 2022-06-23 | Celanese International Corporation | Extrusion molded thermoplastic vulcanizate gaskets and methods of making such gaskets |
| EP4341082A4 (en) | 2021-05-18 | 2025-03-19 | Saint-Gobain Performance Plastics Corporation | A composite tube and method of making |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2972600A (en) | 1957-09-27 | 1961-02-21 | Schenectady Varnish Company In | Substituted phenols |
| NL134120C (enExample) | 1961-11-24 | 1900-01-01 | ||
| US4130535A (en) | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
| US4311628A (en) | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4594390A (en) | 1982-08-23 | 1986-06-10 | Monsanto Company | Process for the preparation of thermoplastic elastomers |
| US4833195A (en) | 1987-07-20 | 1989-05-23 | Bp Performance Polymers, Inc. | High flow drapable polymer compositions |
| US5157081A (en) | 1989-05-26 | 1992-10-20 | Advanced Elastomer Systems, L.P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
| US5100947A (en) | 1989-05-26 | 1992-03-31 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having improved stiffness/impact balance |
| US5196462A (en) | 1991-05-16 | 1993-03-23 | Himont Incorporated | Zinc-salts of certain mercapto compounds as antioxidants for high temperature aging of thermoplastic elastomers |
| US5290886A (en) | 1993-04-20 | 1994-03-01 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved low temperature properties |
| US5656693A (en) | 1995-06-14 | 1997-08-12 | Exxon Chemical Patents Inc. | Thermoplastic elastomers having improved cure |
| US5621045A (en) | 1995-11-13 | 1997-04-15 | Patel; Raman | Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber |
| US5672660A (en) | 1995-12-01 | 1997-09-30 | Advanced Elastomer Systems, L.P. | Hydrosilylation crosslinking |
| US6245856B1 (en) * | 1996-12-17 | 2001-06-12 | Exxon Chemical Patents, Inc. | Thermoplastic olefin compositions |
-
2000
- 2000-12-29 US US09/752,080 patent/US6451915B1/en not_active Expired - Lifetime
-
2001
- 2001-12-21 DE DE60108840.9T patent/DE60108840T3/de not_active Expired - Lifetime
- 2001-12-21 EP EP01130754.3A patent/EP1219679B2/en not_active Expired - Lifetime
- 2001-12-21 ES ES01130754T patent/ES2234761T3/es not_active Expired - Lifetime
- 2001-12-27 KR KR1020010085731A patent/KR20020059239A/ko not_active Withdrawn
- 2001-12-28 JP JP2001400447A patent/JP4362253B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6451915B1 (en) | 2002-09-17 |
| ES2234761T3 (es) | 2005-07-01 |
| DE60108840T3 (de) | 2015-12-17 |
| DE60108840T2 (de) | 2006-02-09 |
| DE60108840D1 (de) | 2005-03-17 |
| EP1219679B1 (en) | 2005-02-09 |
| EP1219679A1 (en) | 2002-07-03 |
| KR20020059239A (ko) | 2002-07-12 |
| US20020128390A1 (en) | 2002-09-12 |
| EP1219679B2 (en) | 2015-08-05 |
| JP2002220493A (ja) | 2002-08-09 |
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