JP4332454B2 - 芳香族ポリカーボネート共重合体、及びそれより形成された光ディスク基板 - Google Patents
芳香族ポリカーボネート共重合体、及びそれより形成された光ディスク基板 Download PDFInfo
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- JP4332454B2 JP4332454B2 JP2004066823A JP2004066823A JP4332454B2 JP 4332454 B2 JP4332454 B2 JP 4332454B2 JP 2004066823 A JP2004066823 A JP 2004066823A JP 2004066823 A JP2004066823 A JP 2004066823A JP 4332454 B2 JP4332454 B2 JP 4332454B2
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- Prior art keywords
- optical disk
- substrate
- bis
- disk substrate
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000758 substrate Substances 0.000 title claims description 86
- 230000003287 optical effect Effects 0.000 title claims description 77
- 125000003118 aryl group Chemical group 0.000 title claims description 25
- 229920000515 polycarbonate Polymers 0.000 title claims description 19
- 239000004417 polycarbonate Substances 0.000 title claims description 19
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000004431 polycarbonate resin Substances 0.000 claims description 19
- 229920005668 polycarbonate resin Polymers 0.000 claims description 19
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- 239000012778 molding material Substances 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 claims description 5
- XXHIPRDUAVCXHW-UHFFFAOYSA-N 4-[2-ethyl-1-(4-hydroxyphenyl)hexyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C(CC)CCCC)C1=CC=C(O)C=C1 XXHIPRDUAVCXHW-UHFFFAOYSA-N 0.000 claims description 5
- 238000004581 coalescence Methods 0.000 claims description 2
- 229920005989 resin Polymers 0.000 description 42
- 239000011347 resin Substances 0.000 description 42
- 238000000034 method Methods 0.000 description 31
- -1 3-methyl-4-hydroxyphenyl Chemical group 0.000 description 27
- 238000000465 moulding Methods 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000010521 absorption reaction Methods 0.000 description 16
- 238000012546 transfer Methods 0.000 description 16
- 239000010410 layer Substances 0.000 description 15
- 238000001746 injection moulding Methods 0.000 description 14
- 150000002989 phenols Chemical class 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 230000008859 change Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
- 229910052698 phosphorus Inorganic materials 0.000 description 10
- 239000011574 phosphorus Substances 0.000 description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 230000009477 glass transition Effects 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000000748 compression moulding Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 5
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 239000001294 propane Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000012792 core layer Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- BJRHKGAIKFIDMH-UHFFFAOYSA-N methyl 2-phenoxycarbonyloxybenzoate Chemical compound COC(=O)C1=CC=CC=C1OC(=O)OC1=CC=CC=C1 BJRHKGAIKFIDMH-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- GEPJYVPWXSKFIT-UHFFFAOYSA-N (2-chlorophenyl) phenyl carbonate Chemical compound ClC1=CC=CC=C1OC(=O)OC1=CC=CC=C1 GEPJYVPWXSKFIT-UHFFFAOYSA-N 0.000 description 2
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 238000012695 Interfacial polymerization Methods 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- MUCRFDZUHPMASM-UHFFFAOYSA-N bis(2-chlorophenyl) carbonate Chemical compound ClC1=CC=CC=C1OC(=O)OC1=CC=CC=C1Cl MUCRFDZUHPMASM-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000007791 dehumidification Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LGXOQPZYEAYMIG-UHFFFAOYSA-N ethyl 2-phenoxycarbonyloxybenzoate Chemical compound CCOC(=O)C1=CC=CC=C1OC(=O)OC1=CC=CC=C1 LGXOQPZYEAYMIG-UHFFFAOYSA-N 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- PXDJXZJSCPSGGI-UHFFFAOYSA-N palmityl palmitate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- FEODVXCWZVOEIR-UHFFFAOYSA-N (2,4-ditert-butylphenyl) octyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C FEODVXCWZVOEIR-UHFFFAOYSA-N 0.000 description 1
- VUSLNLODSKMXDY-UHFFFAOYSA-N (2-bromophenyl) phenyl carbonate Chemical compound BrC1=CC=CC=C1OC(=O)OC1=CC=CC=C1 VUSLNLODSKMXDY-UHFFFAOYSA-N 0.000 description 1
- RLHUAUAFOKFLOH-UHFFFAOYSA-N (2-nitrophenyl) phenyl carbonate Chemical compound [O-][N+](=O)C1=CC=CC=C1OC(=O)OC1=CC=CC=C1 RLHUAUAFOKFLOH-UHFFFAOYSA-N 0.000 description 1
- LKKLDKBWCWESPV-UHFFFAOYSA-N (2-phenylphenyl) hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC=C1C1=CC=CC=C1 LKKLDKBWCWESPV-UHFFFAOYSA-N 0.000 description 1
- WXENKXQUTQFQIP-PLKIVWSFSA-N (2e,4e)-hexa-2,4-dienoic acid;octadecanoic acid Chemical compound C\C=C\C=C\C(O)=O.CCCCCCCCCCCCCCCCCC(O)=O WXENKXQUTQFQIP-PLKIVWSFSA-N 0.000 description 1
- GPFJHNSSBHPYJK-UHFFFAOYSA-N (3-methylphenyl) hydrogen carbonate Chemical compound CC1=CC=CC(OC(O)=O)=C1 GPFJHNSSBHPYJK-UHFFFAOYSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 1
- WZUNUACWCJJERC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)(CO)CO WZUNUACWCJJERC-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- FDIPWBUDOCPIMH-UHFFFAOYSA-N 2-decylphenol Chemical compound CCCCCCCCCCC1=CC=CC=C1O FDIPWBUDOCPIMH-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- HMWIHOZPGQRZLR-UHFFFAOYSA-N 2-hexadecylphenol Chemical compound CCCCCCCCCCCCCCCCC1=CC=CC=C1O HMWIHOZPGQRZLR-UHFFFAOYSA-N 0.000 description 1
- WCRKLZYTQVZTMM-UHFFFAOYSA-N 2-octadecylphenol Chemical compound CCCCCCCCCCCCCCCCCCC1=CC=CC=C1O WCRKLZYTQVZTMM-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- JOONSONEBWTBLT-UHFFFAOYSA-N 2-tetradecylphenol Chemical compound CCCCCCCCCCCCCCC1=CC=CC=C1O JOONSONEBWTBLT-UHFFFAOYSA-N 0.000 description 1
- OREKREJVUNVFJP-UHFFFAOYSA-N 2-triacontylphenol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC1=CC=CC=C1O OREKREJVUNVFJP-UHFFFAOYSA-N 0.000 description 1
- RKSBPFMNOJWYSB-UHFFFAOYSA-N 3,3-Bis(4-hydroxyphenyl)pentane Chemical compound C=1C=C(O)C=CC=1C(CC)(CC)C1=CC=C(O)C=C1 RKSBPFMNOJWYSB-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- SSADPHQCUURWSW-UHFFFAOYSA-N 3,9-bis(2,6-ditert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(C)=CC=3C(C)(C)C)C(C)(C)C)OC2)CO1 SSADPHQCUURWSW-UHFFFAOYSA-N 0.000 description 1
- ZGZVGZCIFZBNCN-UHFFFAOYSA-N 4,4'-(2-Methylpropylidene)bisphenol Chemical compound C=1C=C(O)C=CC=1C(C(C)C)C1=CC=C(O)C=C1 ZGZVGZCIFZBNCN-UHFFFAOYSA-N 0.000 description 1
- RXNYJUSEXLAVNQ-UHFFFAOYSA-N 4,4'-Dihydroxybenzophenone Chemical compound C1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1 RXNYJUSEXLAVNQ-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- RQCACQIALULDSK-UHFFFAOYSA-N 4-(4-hydroxyphenyl)sulfinylphenol Chemical compound C1=CC(O)=CC=C1S(=O)C1=CC=C(O)C=C1 RQCACQIALULDSK-UHFFFAOYSA-N 0.000 description 1
- HHMYOZSUJUQIRL-UHFFFAOYSA-N 4-[1-(4-hydroxy-3-phenylphenyl)-3,3,5-trimethylcyclohexyl]-2-phenylphenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=C(C(O)=CC=1)C=1C=CC=CC=1)C1=CC=C(O)C(C=2C=CC=CC=2)=C1 HHMYOZSUJUQIRL-UHFFFAOYSA-N 0.000 description 1
- UJCYBTZHUJWCMB-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-4-propan-2-ylcyclohexyl]phenol Chemical compound C1CC(C(C)C)CCC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UJCYBTZHUJWCMB-UHFFFAOYSA-N 0.000 description 1
- VGFSOACUVJLBAA-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-3,3-dimethylbutan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C(C)(C)C)C1=CC=C(O)C=C1 VGFSOACUVJLBAA-UHFFFAOYSA-N 0.000 description 1
- KANXFMWQMYCHHH-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-3-methylbutan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C(C)C)C1=CC=C(O)C=C1 KANXFMWQMYCHHH-UHFFFAOYSA-N 0.000 description 1
- VHLLJTHDWPAQEM-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-4-methylpentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CC(C)C)C1=CC=C(O)C=C1 VHLLJTHDWPAQEM-UHFFFAOYSA-N 0.000 description 1
- WCUDAIJOADOKAW-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)pentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CCC)C1=CC=C(O)C=C1 WCUDAIJOADOKAW-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Optical Record Carriers And Manufacture Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
(B)下記式[2]
(B)下記式[2]
[η]=1.23×10-4 M0.83
c=0.7
塩化メチレン100mlにポリカーボネート樹脂0.7gを溶解し、その溶液の20℃における比粘度(ηsp)を次式に挿入して求めた。
[η]=1.23×10-4 M0.83
c=0.7
TAインスツルメント社製の熱分析システム DSC−2910を使用して、窒素雰囲気下(窒素流量:40ml/min)、昇温速度:20℃/minの条件下で測定した。
ASTM D−570に従い、φ45mm成形プレートを水中浸漬し重量変化率(重量%)により求めた。
塩化メチレン100mlにポリカーボネート樹脂5.0gを溶解させ、その溶液をシャーレに一晩放置し、キャストフィルムを作成した。該フィルムを60℃、2時間乾燥させた後、5cm×2cmの大きさに切り取り、日本分光社製エリプソメータM−220にて測定を行った。
TAインスツルメント社製の動的粘弾性測定装置RDAIIIを使用して、周波数89.7rad/sec,降温速度20℃/minの条件下で、ゴム域〜ガラス域におけるずり貯蔵弾性率の温度依存性を測定した。表1に記載の値は、該温度依存性曲線からTg’−5℃における値を読み取ったものである。ここで、「Tg’−5℃」の「Tg’」はずり貯蔵弾性率(G’)と同時に測定されるずり損失弾性率(G”)の温度依存性曲線から得た力学的ガラス転移温度を示す。
真空理工社製のTC−7000においてレーザーフラッシュ法にて熱拡散率を測定した。照射光はルビーレーザー、真空中、温度はTg−20℃にて測定した。ここで「Tg」とは上記(2)のガラス転移温度のことを示す。
名機製作所製の射出成形機 M35B−D−DM、深さ200nm、間隔0.5μm、幅0.2μmの溝が刻まれたスタンパーを用いて、直径120mm、厚さ1.2mmの光ディスク基板を成形した。なお、シリンダー温度は360℃、型締め力は30トン一定とし、金型温度を表1に記載の通り各樹脂に設定した。
転写率(%)=100×ディスクの溝深さ/スタンパーの溝深さ
名機製作所製の射出成形機 M35B−D−DMを用いて、直径120mm、厚さ1.2mmの光ディスク基板を成形した。その後、射出成形により得られたディスク基板の信号面側に反射膜、誘電体層1、相変化記録膜、誘電体層2をスパッタ蒸着させ、その上にポリカーボネート製薄膜カバー層を貼りあわせ光ディスクを作成した。続いて、ディスクが互いに接触しないようスペーサーを挟み、温度23℃、湿度50%RH環境に2日間以上放置した。熱収縮および環境変化に対するtiltの変化が安定した時点でジャパン・イー・エム(株)製3次元形状測定器DLD−3000Uによりtiltの評価を行い、初期機械特性とした。
初期機械特性を評価した基板を30℃、湿度90%RHの恒温恒湿機に72hr放置した後、このディスクを23℃、湿度50%RHの環境下に移し、その後のディスクの反り変形量の最大値(ΔR−tiltmax)をジャパン・イー・エム(株)製3次元形状測定器DLD−3000Uにより評価した。
オーク社製エリプソメータADR−200B自動複屈折測定装置を用い、入射角30度で測定した。
温度計、撹拌機および還流冷却器の付いた反応器に、48%水酸化ナトリウム水溶液62.8部およびイオン交換水313.3部を仕込み、これに1,1−ビス(4−ヒドロキシフェニル)−3,3,5−トリメチルシクロヘキサン13.5部、1,1−ビス(4−ヒドロキシフェニル)−2−エチルヘキサン51.8部およびハイドロサルファイト0.13部を溶解した後、塩化メチレン184.9部を加え、撹拌下、15〜25℃でホスゲン28.0部を約60分かけて吹き込んだ。ホスゲンの吹き込み終了後、48%水酸化ナトリウム水溶液9.0部およびp−tert−ブチルフェノール1.31部を加え、撹拌を再開、乳化後トリエチルアミン0.08部を加え、さらに28〜33℃で1時間撹拌して反応を終了した。反応終了後生成物を塩化メチレンで希釈して水洗した後、塩酸酸性にして水洗し、さらに水相の導電率がイオン交換水とほぼ同じになるまで水洗を繰り返し、ポリカーボネート樹脂の塩化メチレン溶液を得た。次いで、この溶液を目開き0.3μmのフィルターに通過させ、さらに軸受け部に異物取出口を有する隔離室付きニーダー中の温水に滴下、塩化メチレンを留去しながらポリカーボネート樹脂をフレーク化し、引続き該含液フレークを粉砕・乾燥してパウダーを得た。その後、該パウダーにトリス(2,4−di−tert−ブチルフェニル)ホスファイトを0.0025重量%、ステアリン酸モノグリセリドを0.05重量%添加し、均一に混合した後、かかるパウダーをベント式二軸押出機[神戸製鋼(株)製KTX−46]により脱気しながら溶融混錬し、ポリカーボネート樹脂のペレットを得た。該ペレットの粘度平均分子量、ガラス転移温度、吸水率、光弾性定数、貯蔵弾性率、熱拡散率を表1に掲載した。該ペレットから、射出成形機(名機製作所製M35B−D−DM)、キャビティ厚0.6mmt、直径120mmの金型、深さ200nm、間隔0.5μm、幅0.2μmの溝が刻まれたスタンパーを用い、シリンダー設定温度360℃、金型温度116℃、充填時間0.2秒、冷却時間15秒、型締力30トンの条件で光ディスク基板を成形した。この時の転写性評価結果も表1に併記した。
1,1−ビス(4−ヒドロキシフェニル)−3,3,5−トリメチルシクロヘキサン27.0部、1,1−ビス(4−ヒドロキシフェニル)−2−エチルヘキサン38.9部とした以外は全て実施例1と同様にし、表1に記載の特性を有するポリカーボネート樹脂のペレットを得た。さらに、金型温度を138℃とした以外は実施例1と同様にして光ディスク基板の成形を行い、該基板の転写性を評価した。この時の転写性評価結果も表1に併記した。
1,1−ビス(4−ヒドロキシフェニル)−3,3,5−トリメチルシクロヘキサン53.9部、1,1−ビス(4−ヒドロキシフェニル)−2−エチルヘキサン12.9部とした以外は全て実施例1と同様にし、表1に記載の特性を有するポリカーボネート樹脂のペレットを得た。さらに、金型温度を182℃とした以外は実施例1と同様にして光ディスク基板の成形を行い、該基板の転写性を評価した。この時の転写性評価結果も表1に併記した。
2,2−ビス(4−ヒドロキシフェニル)プロパンより得られたポリカーボネート樹脂(帝人化成製パンライトAD−5503)を用い、金型温度を125℃とした以外は実施例1と同様にして基板成形を行い、該基板の転写性を評価した。この時の転写性評価結果を樹脂物性とともに表1に記載した。
Claims (9)
- (A)下記式[1]
で表される二価フェノール成分と
(B)下記式[2]
で表される二価フェノール成分から実質的に構成され、(A)成分と(B)成分のモル比が(A):(B)=10:90〜70:30である芳香族ポリカーボネート共重合体。 - (A)成分と(B)成分のモル比が(A):(B)=10:90〜40:60である請求項1記載の芳香族ポリカーボネート共重合体。
- (A)成分が1,1−ビス(4−ヒドロキシフェニル)−3,3,5−トリメチルシクロヘキサンであり、(B)成分が1,1−ビス(4−ヒドロキシフェニル)−2−エチルヘキサンである請求項1記載の芳香族ポリカーボネート共重合体。
- ポリカーボネート樹脂は、20℃の塩化メチレン溶液で測定された粘度平均分子量が10,000〜30,000の範囲内にある請求項1記載の芳香族ポリカーボネート共重合体。
- 請求項1〜4記載のいずれかのポリカーボネート共重合体よりなる光学用成形材料。
- 請求項5記載の光学用成形材料を用いて成形された光ディスク基板。
- 請求項5記載の光学用成形材料を用いて成形されたグルーブ列もしくはピット列の間隔が0.1μm〜0.8μmである光ディスク基板。
- 請求項5記載の光学用成形材料を用いて成形されたグルーブもしくはピットの光学的深さが、記録再生に使われるレーザー光の波長λと基板の屈折率nに対してλ/8n〜λ/2nの範囲である光ディスク基板。
- 請求項6〜8記載のいずれかの光ディスク基板を用いた光学記録媒体。
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