JP4324257B2 - フッ化アルミニウムの製造方法 - Google Patents
フッ化アルミニウムの製造方法 Download PDFInfo
- Publication number
 - JP4324257B2 JP4324257B2 JP13835098A JP13835098A JP4324257B2 JP 4324257 B2 JP4324257 B2 JP 4324257B2 JP 13835098 A JP13835098 A JP 13835098A JP 13835098 A JP13835098 A JP 13835098A JP 4324257 B2 JP4324257 B2 JP 4324257B2
 - Authority
 - JP
 - Japan
 - Prior art keywords
 - alumina
 - aluminum fluoride
 - alf
 - fluorination
 - producing aluminum
 - Prior art date
 - Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
 - Expired - Fee Related
 
Links
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 title claims description 15
 - IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 title claims description 14
 - 238000004519 manufacturing process Methods 0.000 title claims description 11
 - PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 35
 - VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
 - 229910016569 AlF 3 Inorganic materials 0.000 claims description 20
 - 238000003682 fluorination reaction Methods 0.000 claims description 18
 - 239000011148 porous material Substances 0.000 claims description 13
 - IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
 - 239000013078 crystal Substances 0.000 claims description 5
 - YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
 - 229910052731 fluorine Inorganic materials 0.000 claims description 4
 - 239000011737 fluorine Substances 0.000 claims description 4
 - 229910052757 nitrogen Inorganic materials 0.000 claims description 4
 - 239000011261 inert gas Substances 0.000 claims description 3
 - 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
 - 238000002347 injection Methods 0.000 claims description 2
 - 239000007924 injection Substances 0.000 claims description 2
 - QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
 - 229910052753 mercury Inorganic materials 0.000 claims description 2
 - 239000007789 gas Substances 0.000 claims 1
 - KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 16
 - 238000000034 method Methods 0.000 description 14
 - QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 14
 - 239000000377 silicon dioxide Substances 0.000 description 11
 - 238000006243 chemical reaction Methods 0.000 description 4
 - XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
 - 241000640882 Condea Species 0.000 description 3
 - VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 3
 - 239000003054 catalyst Substances 0.000 description 3
 - 230000000694 effects Effects 0.000 description 3
 - 239000000203 mixture Substances 0.000 description 3
 - 239000007787 solid Substances 0.000 description 3
 - 238000011282 treatment Methods 0.000 description 3
 - XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
 - 238000001354 calcination Methods 0.000 description 2
 - 230000003197 catalytic effect Effects 0.000 description 2
 - 239000013065 commercial product Substances 0.000 description 2
 - 230000000052 comparative effect Effects 0.000 description 2
 - 239000002638 heterogeneous catalyst Substances 0.000 description 2
 - 150000002894 organic compounds Chemical class 0.000 description 2
 - 239000000047 product Substances 0.000 description 2
 - 230000008929 regeneration Effects 0.000 description 2
 - 238000011069 regeneration method Methods 0.000 description 2
 - 239000000126 substance Substances 0.000 description 2
 - ZZBAGJPKGRJIJH-UHFFFAOYSA-N 7h-purine-2-carbaldehyde Chemical compound O=CC1=NC=C2NC=NC2=N1 ZZBAGJPKGRJIJH-UHFFFAOYSA-N 0.000 description 1
 - VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
 - DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
 - NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
 - 238000002441 X-ray diffraction Methods 0.000 description 1
 - HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
 - 229910052782 aluminium Inorganic materials 0.000 description 1
 - -1 aluminum halide Chemical class 0.000 description 1
 - 238000004458 analytical method Methods 0.000 description 1
 - 230000015572 biosynthetic process Effects 0.000 description 1
 - 238000012512 characterization method Methods 0.000 description 1
 - 229910052804 chromium Inorganic materials 0.000 description 1
 - 239000011651 chromium Substances 0.000 description 1
 - 229910017052 cobalt Inorganic materials 0.000 description 1
 - 239000010941 cobalt Substances 0.000 description 1
 - GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
 - 150000001875 compounds Chemical class 0.000 description 1
 - 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
 - 239000012467 final product Substances 0.000 description 1
 - 239000008246 gaseous mixture Substances 0.000 description 1
 - 230000036571 hydration Effects 0.000 description 1
 - 238000006703 hydration reaction Methods 0.000 description 1
 - 229910001026 inconel Inorganic materials 0.000 description 1
 - 229910001055 inconels 600 Inorganic materials 0.000 description 1
 - 229910003480 inorganic solid Inorganic materials 0.000 description 1
 - 229910052742 iron Inorganic materials 0.000 description 1
 - 239000011159 matrix material Substances 0.000 description 1
 - 229910052751 metal Inorganic materials 0.000 description 1
 - 239000002184 metal Substances 0.000 description 1
 - 150000002815 nickel Chemical class 0.000 description 1
 - TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
 - 239000002245 particle Substances 0.000 description 1
 - 239000002243 precursor Substances 0.000 description 1
 - 238000000197 pyrolysis Methods 0.000 description 1
 - 239000000376 reactant Substances 0.000 description 1
 - 150000003839 salts Chemical class 0.000 description 1
 - 229910052708 sodium Inorganic materials 0.000 description 1
 - 239000011734 sodium Substances 0.000 description 1
 - 238000001179 sorption measurement Methods 0.000 description 1
 - 238000001694 spray drying Methods 0.000 description 1
 - 229910052717 sulfur Inorganic materials 0.000 description 1
 - 239000011593 sulfur Substances 0.000 description 1
 - 238000004876 x-ray fluorescence Methods 0.000 description 1
 
Classifications
- 
        
- C—CHEMISTRY; METALLURGY
 - C01—INORGANIC CHEMISTRY
 - C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
 - C01F7/00—Compounds of aluminium
 - C01F7/48—Halides, with or without other cations besides aluminium
 - C01F7/50—Fluorides
 
 - 
        
- B—PERFORMING OPERATIONS; TRANSPORTING
 - B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
 - B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
 - B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
 - B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
 - B01J21/04—Alumina
 
 - 
        
- B—PERFORMING OPERATIONS; TRANSPORTING
 - B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
 - B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
 - B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
 - B01J27/06—Halogens; Compounds thereof
 - B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
 
 - 
        
- B—PERFORMING OPERATIONS; TRANSPORTING
 - B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
 - B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
 - B01J35/00—Catalysts, in general, characterised by their form or physical properties
 - B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
 - B01J35/61—Surface area
 - B01J35/613—10-100 m2/g
 
 - 
        
- B—PERFORMING OPERATIONS; TRANSPORTING
 - B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
 - B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
 - B01J35/00—Catalysts, in general, characterised by their form or physical properties
 - B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
 - B01J35/61—Surface area
 - B01J35/615—100-500 m2/g
 
 - 
        
- B—PERFORMING OPERATIONS; TRANSPORTING
 - B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
 - B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
 - B01J35/00—Catalysts, in general, characterised by their form or physical properties
 - B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
 - B01J35/63—Pore volume
 - B01J35/633—Pore volume less than 0.5 ml/g
 
 - 
        
- B—PERFORMING OPERATIONS; TRANSPORTING
 - B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
 - B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
 - B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
 - B01J37/22—Halogenating
 - B01J37/26—Fluorinating
 
 - 
        
- C—CHEMISTRY; METALLURGY
 - C01—INORGANIC CHEMISTRY
 - C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
 - C01P2006/00—Physical properties of inorganic compounds
 - C01P2006/12—Surface area
 
 - 
        
- C—CHEMISTRY; METALLURGY
 - C01—INORGANIC CHEMISTRY
 - C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
 - C01P2006/00—Physical properties of inorganic compounds
 - C01P2006/14—Pore volume
 
 
Landscapes
- Chemical & Material Sciences (AREA)
 - Organic Chemistry (AREA)
 - Engineering & Computer Science (AREA)
 - Materials Engineering (AREA)
 - Chemical Kinetics & Catalysis (AREA)
 - Life Sciences & Earth Sciences (AREA)
 - Geology (AREA)
 - Inorganic Chemistry (AREA)
 - Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
 - Catalysts (AREA)
 - Glass Compositions (AREA)
 
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| IT97A001195 | 1997-05-22 | ||
| IT97MI001195A IT1291758B1 (it) | 1997-05-22 | 1997-05-22 | Processo per la preparazione di fluoruro di alluminio | 
Publications (2)
| Publication Number | Publication Date | 
|---|---|
| JPH1111940A JPH1111940A (ja) | 1999-01-19 | 
| JP4324257B2 true JP4324257B2 (ja) | 2009-09-02 | 
Family
ID=11377188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| JP13835098A Expired - Fee Related JP4324257B2 (ja) | 1997-05-22 | 1998-05-20 | フッ化アルミニウムの製造方法 | 
Country Status (5)
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| IT1303073B1 (it) * | 1998-05-07 | 2000-10-23 | Ausimont Spa | Processo per la preparazione di fluoruro di alluminio | 
| IT1307755B1 (it) | 1999-02-05 | 2001-11-19 | Ausimont Spa | Processo per la dimerizzazione di (cfc-113a). | 
| ITMI20010287A1 (it) | 2001-02-13 | 2002-08-13 | Ausimont Spa | Procedimento per ottenere cfc 113a da cfc 113 | 
| US7316838B2 (en) * | 2001-02-15 | 2008-01-08 | Integral Technologies, Inc. | Low cost electrically conductive carpeting manufactured from conductive loaded resin-based materials | 
| US7485598B2 (en) * | 2006-06-21 | 2009-02-03 | Arkema Inc. | High pressure catalyst activation method and catalyst produced thereby | 
| US20060116537A1 (en) * | 2003-01-03 | 2006-06-01 | Solvay Solexis S.P.A. | Aluminium fluoride | 
| RU2237020C1 (ru) * | 2003-03-19 | 2004-09-27 | Федеральное государственное унитарное предприятие УРАЛЬСКИЙ ЭЛЕКТРОХИМИЧЕСКИЙ КОМБИНАТ | Способ получения гранулированного фторида алюминия для улавливания газообразного соединения рутения-106 | 
| EP1502906A1 (en) * | 2003-07-31 | 2005-02-02 | Solvay Solexis S.p.A. | Process for activation of AIF3 based catalysts and process for isomerising hydrochlorofluorocarbons | 
| EP2172441A1 (en) | 2008-10-02 | 2010-04-07 | Solvay Fluor GmbH | Process for the manufacture of hydrochlorofluorocarbons using trifluoromethane as fluorinating agent | 
| US8580342B2 (en) * | 2009-02-27 | 2013-11-12 | Applied Nanostructured Solutions, Llc | Low temperature CNT growth using gas-preheat method | 
| CN106277004A (zh) * | 2015-06-23 | 2017-01-04 | 中南大学 | 两种高催化活性氟化铝的制备方法及在全氟卤代烃合成中的应用 | 
| CN112042018B (zh) * | 2018-03-27 | 2023-11-07 | 本田技研工业株式会社 | 氟化物离子二次电池用负极活性物质、使用了该活性物质的负极、及氟化物离子二次电池、以及该活性物质的制造方法 | 
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| FR1209223A (fr) * | 1958-07-03 | 1960-02-29 | Pechiney | Procédé de récupération de gaz fluorhydrique par l'alumine | 
| GB1000485A (en) | 1962-02-07 | 1965-08-04 | Sicedison Spa | Improvements in or relating to the fluorination of halo-olefines | 
| GB1026131A (en) * | 1962-02-16 | 1966-04-14 | Imp Smelting Corp Ltd | Improvements in or relating to the production of aluminium fluoride | 
| DE1224732B (de) | 1962-11-08 | 1966-09-15 | Du Pont | Verfahren zur Herstellung von Vinylfluorid und 1, 1-Difluoraethan | 
| US3473887A (en) * | 1968-02-21 | 1969-10-21 | Allied Chem | Aluminum fluoride production | 
| JPS4823797B1 (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) * | 1968-08-14 | 1973-07-16 | ||
| SE366722B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) * | 1970-01-27 | 1974-05-06 | Montedison Spa | |
| GB1290749A (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) * | 1970-05-04 | 1972-09-27 | ||
| JPS5033992B1 (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) * | 1970-12-23 | 1975-11-05 | ||
| DE2106306C3 (de) * | 1971-02-10 | 1974-12-19 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Aluminiumfluorid | 
| US4275046A (en) * | 1978-01-16 | 1981-06-23 | Exxon Research & Engineering Co. | Preparation of high surface area metal fluorides and metal oxyfluorides, especially aluminum fluoride extrudates | 
| FR2590251B1 (fr) * | 1985-11-15 | 1988-10-14 | Atochem | Procede de synthese du chloropentafluoroethane a partir de dichlorotetrafluoroethane et d'acide fluorhydrique | 
| IT1202652B (it) | 1987-03-09 | 1989-02-09 | Ausimont Spa | Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori | 
| US4754084A (en) * | 1987-04-01 | 1988-06-28 | E. I. Du Pont De Nemours And Company | Preparation of substituted fluorobenzenes | 
| US5008475A (en) | 1987-07-07 | 1991-04-16 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process | 
| JPH02116618A (ja) * | 1988-10-26 | 1990-05-01 | Central Glass Co Ltd | フッ化アルミニウムの製造方法 | 
| CN1041804C (zh) * | 1995-09-13 | 1999-01-27 | 西安近代化学研究所 | 氟化卤代烃的氟化催化剂 | 
- 
        1997
        
- 1997-05-22 IT IT97MI001195A patent/IT1291758B1/it active IP Right Grant
 
 - 
        1998
        
- 1998-05-14 EP EP98108740A patent/EP0879790B1/en not_active Expired - Lifetime
 - 1998-05-14 DE DE69832325T patent/DE69832325D1/de not_active Expired - Lifetime
 - 1998-05-20 US US09/081,294 patent/US6187280B1/en not_active Expired - Fee Related
 - 1998-05-20 JP JP13835098A patent/JP4324257B2/ja not_active Expired - Fee Related
 
 - 
        2000
        
- 2000-12-21 US US09/740,963 patent/US20010038819A1/en not_active Abandoned
 
 
Also Published As
| Publication number | Publication date | 
|---|---|
| ITMI971195A0 (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) | 1997-05-22 | 
| JPH1111940A (ja) | 1999-01-19 | 
| EP0879790A1 (en) | 1998-11-25 | 
| DE69832325D1 (de) | 2005-12-22 | 
| IT1291758B1 (it) | 1999-01-21 | 
| ITMI971195A1 (it) | 1998-11-22 | 
| US20010038819A1 (en) | 2001-11-08 | 
| EP0879790B1 (en) | 2005-11-16 | 
| US6187280B1 (en) | 2001-02-13 | 
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