JP4299141B2 - 押出可能なポリカーボネート成形組成物 - Google Patents
押出可能なポリカーボネート成形組成物 Download PDFInfo
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- JP4299141B2 JP4299141B2 JP2003554793A JP2003554793A JP4299141B2 JP 4299141 B2 JP4299141 B2 JP 4299141B2 JP 2003554793 A JP2003554793 A JP 2003554793A JP 2003554793 A JP2003554793 A JP 2003554793A JP 4299141 B2 JP4299141 B2 JP 4299141B2
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- ASURBSPIYIISGI-UHFFFAOYSA-N 4-(3,3,5-trimethylcyclohexyl)phenol Chemical compound C1C(C)(C)CC(C)CC1C1=CC=C(O)C=C1 ASURBSPIYIISGI-UHFFFAOYSA-N 0.000 description 1
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- CUAUDSWILJWDOD-UHFFFAOYSA-N 4-(3,5-dimethylheptyl)phenol Chemical compound CCC(C)CC(C)CCC1=CC=C(O)C=C1 CUAUDSWILJWDOD-UHFFFAOYSA-N 0.000 description 1
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
- KJWMCPYEODZESQ-UHFFFAOYSA-N 4-Dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=C(O)C=C1 KJWMCPYEODZESQ-UHFFFAOYSA-N 0.000 description 1
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 1
- XJGTVJRTDRARGO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)(C)C1=CC=C(O)C=C1 XJGTVJRTDRARGO-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- NIRYBKWMEWFDPM-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)-3-methylbutyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)CCC1=CC=C(O)C=C1 NIRYBKWMEWFDPM-UHFFFAOYSA-N 0.000 description 1
- XHDKBYRAWKLXGE-UHFFFAOYSA-N 4-[4,6-bis(4-hydroxyphenyl)-4,6-dimethylhept-1-en-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)CC(C)(C=1C=CC(O)=CC=1)CC(=C)C1=CC=C(O)C=C1 XHDKBYRAWKLXGE-UHFFFAOYSA-N 0.000 description 1
- LIDWAYDGZUAJEG-UHFFFAOYSA-N 4-[bis(4-hydroxyphenyl)-phenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=CC=C1 LIDWAYDGZUAJEG-UHFFFAOYSA-N 0.000 description 1
- BOCLKUCIZOXUEY-UHFFFAOYSA-N 4-[tris(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 BOCLKUCIZOXUEY-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- DNSAZEFZWVPMDT-UHFFFAOYSA-N CC1(C=CC([N](C)(NC)NC)=CC=C1)[N](C)(NC)NC Chemical compound CC1(C=CC([N](C)(NC)NC)=CC=C1)[N](C)(NC)NC DNSAZEFZWVPMDT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- UWCPYKQBIPYOLX-UHFFFAOYSA-N benzene-1,3,5-tricarbonyl chloride Chemical compound ClC(=O)C1=CC(C(Cl)=O)=CC(C(Cl)=O)=C1 UWCPYKQBIPYOLX-UHFFFAOYSA-N 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical class OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 125000002256 xylenyl group Chemical group C1(C(C=CC=C1)C)(C)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
成分A)40〜99.99、好ましくは50〜99、特に好ましくは60〜95重量部、
少なくとも1つのリン化合物B)0.01〜60、好ましくは0.01〜30、特に好ましくは0.05〜20重量部、極めて特に好ましくは0.1〜15重量部、最も好ましくは2〜15重量部、
ゴム−変性ビニル(コ)ポリマーC)0〜60、好ましくは0.5〜50、特に1〜30重量部、特に好ましくは2〜25重量部、極めて特に好ましくは3〜15重量部
を含有する。
成分Aに該当する本発明による好適な直鎖および分岐芳香族ポリカーボネートおよび/または芳香族ポリエステルカーボネートは、文献公知または文献公知のプロセスによって調製することができる(芳香族ポリカーボネートの調製は、例えばシュネル(Schnell),「ポリカーボネートの化学と物理(“Chemistry and Physics of Polycarbonates”)」,インタ−サイエンス パブリッシャ−ズ(Interscience Publishers),1964年、およびDE−AS 1,495,626、DE−A 2,232,877、DE−A 2,703,376、DE−A 2,714,544、DE−A 3,000,610、DE−A 3,832,396;例えばDE−A 3,077,934に記載された芳香族ポリエステルカーボネートの調製)。
または式(II)または(III)の基:
xは各々独立し、0、1または2であることを示し、
pは0または1であり、および
R5およびR6は、各X1ごとに独立に選択されることができ、互いに独立して水素またはC1〜C6−アルキル、好ましくは水素、メチルまたはエチルを示し、
X1は炭素を示し、および
mは4〜7の整数、好ましくは4または5であるが、少なくとも1つのX1原子上で、R5およびR6は同時にアルキル基である。]
を有する化合物である。
さらに、組成物は少なくとも1つのリン化合物を含有する。リン化合物はポリカーボネート組成物中でさまざまな機能を発揮することができる。リンベース(P-based)難燃性添加物およびリンベース安定剤を例として記載することができる。リン含有化合物の例は、オリゴマーおよびモノマーホスフェイトおよびホスホネート、ホスホネートアミン、無機リン酸塩、酸化リンオキサイド、ホスファイトおよびホスファゼンであり、それらの2またはそれ以上の成分の混合物を用いてもよい。
nは互いに独立して0または1を示し、
qは0〜30、および
Xは6〜30の炭素原子を有する単核または多核の芳香族基、または2〜30の炭素原子を有する直鎖または分岐脂肪族基であって、それらがOH置換されてもよく、および8個以下のエーテル結合を含んでもよい。]
で表されるホスフェートまたはホスホネートである。
mは互いに独立して、0,1,2,3または4であり、
R5およびR6は独立して、C1〜C4アルキル、好ましくはメチルまたはエチルを示し、および
YはC1〜C7アルキリデン、C1−C7アルキレン、C5〜C12シクロアルキレン、C5〜C12シクロアルキリデン、−O−、−S−、−SO2−または−CO−、好ましくはイソプロピリデンまたはメチレンを示す。]
本発明による成形組成物はまた、グラフト基材としてガラス転移温度<10℃を有する少なくとも1つのゴム上での少なくとも1つのビニルモノマーのグラフトポリマーC1からなる成分Cを包含する。
1. ビニル芳香族化合物および/または環−置換ビニル芳香族化合物(例えば、スチレン、α−メチルスチレン、p−メチルスチレン、p−クロロスチレン)および/またはメタクリル酸(C1−C8)−アルキル(例えばメタクリル酸メチル、メタクリル酸エチル)50〜99重量%、特に50〜90、より好ましくは55〜85、極めて特に好ましくは60〜80重量%および
2. ビニルシアニド(不飽和ニトリル、例えばアクリロニトリルおよびメタクリロニトリル)および/または(C1−C8)−アルキル(メタ)アクリレート(例えばメタクリル酸メチル、n−ブチルアクリレート、t−ブチルアクリレート)および/または不飽和カルボン酸(例えば無水マレイン酸およびN−フェニルマレイン酸イミド)の誘導体(例えば無水物およびイミド)1〜50重量%、特に10〜50、より好ましくは15〜45、極めて特に好ましくは20〜40重量%
の混合物5〜95重量%、好ましくは20〜90重量%の1またはそれ以上のグラフトポリマーである。
もし、リンベースFR添加剤が成分B)として使用されるなら、それらは燃焼の際に燃焼液滴を形成する物質を分解する性質がある、いわゆるアンチ−ドリップ剤(anti-drip agents)との組合せでしばしば使用される。例示として、フッ素化ポリオレフィン、シリコーンおよびアラミド繊維からなる物質のクラスからなる化合物が挙げられる。それらは本発明の組成物中で用いてもよい。フッ素化ポリオレフィンがアンチドリップ剤として好ましく用いられる。
本発明による組成物はまた、20重量部以下、好ましくは0.1〜10重量部の少なくとも1つの常套のポリマー添加剤、例えば潤滑剤および成形離型剤、具体的にはテトラステアリン酸ペンタエリスリトールまたはポリオレフィン、成核剤、静電防止剤、安定剤、リンフリーFR添加剤、FR相乗剤、例えばナノスケールの無機物質、または充填剤および強化剤、例えばガラスおよびカーボンファイバーまたは無機物、具体的にはタルク、マイカ、カオリンまたは珪灰石(wollastonite)、または着色剤および顔料を含んでもよい。
列車車両、船舶、エアロプレーン(aeroplanes)、バスおよび自動車の内部部品、ハブキャップ(hub caps)、小さな変圧器を含む電気設備のためのハウジング、情報の配電(distribution)および送電(transmission)設備のためのハウジング、医療目的のためのハウジングおよびカバーリング、マッサージ機器およびそのためのハウジング、子供用玩具、二次元壁成分(two-dimentional wall elements)、安全装置のためのハウジング、リアスポイラー(rear spoilers)、自動車の車体部品、熱的に絶縁である輸送用コンテナ、小動物の捕獲および飼育のための装置、洗面所および浴室の備品のための成形部品、換気扇のための塵除けカバー、庭および物置小屋のための成形部品、庭設備のためのハウジングである。
表1に記載し、以下に簡単に説明する成分を、ZSK−25上で260℃での溶融コンパウンドする。試験体は射出成形機Arburg270Eタイプを使用して260℃で製造する。
(成分A1)
ビスフェノールAおよびイサチンビスクレゾールの総量に基づいて、イサチンビスクレゾール0.3モル%の使用によって分岐された25℃で濃度0.5g/100mlのCH2Cl2溶媒中で測定した相対溶液粘度ηrel=1.31を有するビスフェノールAをベースにした分岐ポリカーボネート。
25℃で濃度0.5g/100mlのCH2Cl2溶媒中で測定した相対溶液粘度ηrel=1.31を有するビスフェノールAをベースにした直鎖ポリカーボネート。
オリゴホスフェイトベースのビスフェノールA:
カラムタイプ:LiChrosorp RP−8
溶離剤濃度勾配(Eluant in gradients):アセトニトリル/水 50:50〜100:0
濃度:5mg/ml
加重平均数qは次いで公知の方法で個々の成分(モノおよびオリゴホスフェイト)の比率から算出。
粒子状架橋剤であるポリブタジエンゴム(平均粒径d50=0.3μm)60重量部上へのスチレン/アクリロニトリルの比率が73:27である混合物40重量部のグラフトによって調製したエマルジョンポリマー。
上記成分Cによる水中でのグラフトポリマーエマルジョンおよび水中でのテトラフルオロエチレンポリマーエマルジョンの凝集混合物としてはテトラフルオロエチレンポリマー(PTFE)である。DにおけるグラフトポリマーC/テトラフルオロエチレンポリマーとの重量比は90重量%〜10重量%である。テトラフルオロエチレンポリマーエマルジョンは固形分含量60重量%を有する。グラフトポリマーエマルジョンは固形分含量34重量%を有する。
ホスファイト安定剤。
離型剤および潤滑剤としてテトラステアリン酸ペンタエリスリトール(PETS)。
白色顔料として二酸化チタン。
熱寸法安定性は大きさ80mm×10mm×4mmのロッドを用いてDIN 53,460(ISO 306)に該当するビカーB(Vicat B)によって測定する。
Claims (6)
- A)60〜95重量部のポリカーボネートおよび/またはポリエステルカーボネート、
B)式(IV):
R1、R2、R3およびR4は、互いに独立して、要すればハロゲン化されたC1〜C8アルキルを示すか、あるいは、各々が要すればアルキルおよび/またはハロゲンによって置換されてもよい、C5〜C6シクロアルキル、C6〜C20アリールまたはC7〜C12アラルキルを示し、
nは、互いに独立して、0または1を示し、
qは、0〜30であり、および
Xは、6〜30の炭素原子を有する単核または多核の芳香族基、または2〜30の炭素原子を有する直鎖または分岐脂肪族基を示し、これらは、OH置換されてもよく、そして8個以下のエーテル結合を含んでもよい。]
のホスフェートおよびホスホネートから選択される、0.05〜20重量部の少なくとも1つのリン化合物、
C)1〜30重量部のグラフトポリマーC1および要すればグラフトポリマーC1に分散して存在する熱可塑性ビニル(コ)ポリマーC2であって、
グラフトポリマーC1は、グラフト基材として10℃未満のガラス転移温度を有する1またはそれ以上のゴム95〜5重量%上での、
1. ビニル芳香族化合物および/または環−置換ビニル芳香族化合物50〜99重量%、および
2. ビニルシアニドならびに/あるいは無水物およびイミドからなる群から選択される不飽和カルボン酸の誘導体1〜50重量%
の混合物5〜95重量%の1またはそれ以上のグラフトポリマーであり、
D)0〜1重量部のフッ素化ポリオレフィン、および
E)潤滑剤および成形離型剤、成核剤、静電防止剤、安定剤、リンフリーFR添加剤、FR相乗剤、充填剤および強化剤、着色剤および顔料からなる群から選択される、0〜20重量部の少なくとも1つの添加剤、
からなる組成物であって、成分(A)が分岐ポリカーボネートおよび/またはポリエステルカーボネートA.1)95〜70重量%および直鎖ポリカーボネートおよび/またはポリエステルカーボネートA.2)5〜30重量%(それぞれ成分A)に基づく)の混合物であり、成分A)〜E)の重量部合計が100である、組成物。 - グラフト基材がジエン、EP(D)M、アクリレートまたはシリコーンゴムまたはそれらの成分の2またはそれ以上を含有するコンポジットゴムである請求項1記載の組成物。
- 成形品を製造するための請求項1〜3のいずれか1項に記載の組成物の使用。
- 請求項1〜3のいずれか1項に記載の組成物から得られ得る成形品または成形体。
- 請求項1〜3のいずれか1項に記載の組成物から得られ得る押出板材および押出シート。
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DE10162747A DE10162747A1 (de) | 2001-12-20 | 2001-12-20 | Extrudierbare Polycarbonat-Formmassen |
PCT/EP2002/013906 WO2003054085A1 (de) | 2001-12-20 | 2002-12-09 | Extrudierbare polycarbonat-formmassen |
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DE10256316A1 (de) * | 2002-12-03 | 2004-06-24 | Bayer Ag | Polycarbonat-Formmassen |
US7939591B2 (en) | 2005-05-19 | 2011-05-10 | Teijin Chemicals, Ltd. | Polycarbonate resin composition |
DE102005050956A1 (de) * | 2005-10-25 | 2007-04-26 | Lanxess Deutschland Gmbh | Halogenfreie flammgeschützte thermoplastische Polyester |
DE102006012990A1 (de) * | 2006-03-22 | 2007-09-27 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
DE102006012988A1 (de) * | 2006-03-22 | 2007-09-27 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
US20080118729A1 (en) * | 2006-11-16 | 2008-05-22 | General Electric Company | Thermoplastic composition, method of making, and articles formed therefrom |
US7829632B2 (en) * | 2007-04-30 | 2010-11-09 | Sabic Innovative Plastics Ip B.V. | Polyester polycarbonate compositions, methods of making, and articles formed therefrom |
US7691950B2 (en) * | 2007-04-30 | 2010-04-06 | Sabic Innovative Plastics Ip B.V. | Polyester polycarbonate compositions, methods of making, and articles formed therefrom |
US7687583B2 (en) * | 2007-04-30 | 2010-03-30 | Sabic Innovative Plastics Ip B.V. | Polyester polycarbonate compositions, methods of making, and articles formed therefrom |
US20090186966A1 (en) * | 2008-01-22 | 2009-07-23 | Sabic Innovative Plastics Ip B.V. | Thermoplastic polyestercarbonate composition |
KR101077842B1 (ko) * | 2008-12-17 | 2011-10-28 | 제일모직주식회사 | 난연성 폴리카보네이트 수지 조성물 |
KR101138797B1 (ko) * | 2008-12-23 | 2012-04-26 | 제일모직주식회사 | 투명 난연 필름용 수지 조성물 및 이를 이용한 폴리카보네이트 투명 난연 필름 제조 방법 |
KR101256262B1 (ko) * | 2009-12-16 | 2013-04-18 | 주식회사 삼양사 | 난연성 열가소성 수지 조성물 및 이를 이용한 성형품 |
KR101240320B1 (ko) * | 2009-12-29 | 2013-03-07 | 제일모직주식회사 | 투명성과 난연성이 우수한 폴리카보네이트 수지 조성물 |
JP5422444B2 (ja) * | 2010-03-01 | 2014-02-19 | 三菱エンジニアリングプラスチックス株式会社 | 芳香族ポリカーボネート樹脂組成物および成形体 |
KR101378865B1 (ko) * | 2010-12-13 | 2014-03-28 | 주식회사 삼양사 | 난연성 및 내충격성이 모두 우수한 폴리카보네이트 수지 조성물 및 이의 성형품 |
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DE3149812A1 (de) | 1981-12-16 | 1983-07-21 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmassen |
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US6649677B2 (en) * | 1998-11-03 | 2003-11-18 | General Electric Company | Polycarbonate sheet with improved fire retardant performance |
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BR0215259B1 (pt) | 2012-07-24 |
KR100869028B1 (ko) | 2008-11-17 |
DE10162747A1 (de) | 2003-07-03 |
WO2003054085A1 (de) | 2003-07-03 |
BR0215259A (pt) | 2004-12-07 |
CN100415830C (zh) | 2008-09-03 |
ES2302863T3 (es) | 2008-08-01 |
KR20040071738A (ko) | 2004-08-12 |
DE50211986D1 (de) | 2008-05-08 |
CA2471492C (en) | 2011-09-20 |
US20030153658A1 (en) | 2003-08-14 |
JP2005513233A (ja) | 2005-05-12 |
ATE390462T1 (de) | 2008-04-15 |
TW200305611A (en) | 2003-11-01 |
TWI302160B (en) | 2008-10-21 |
MXPA04005820A (es) | 2004-11-10 |
US6838518B2 (en) | 2005-01-04 |
CA2471492A1 (en) | 2003-07-03 |
AU2002358109A1 (en) | 2003-07-09 |
CN1620479A (zh) | 2005-05-25 |
EP1458813B1 (de) | 2008-03-26 |
AR037879A1 (es) | 2004-12-09 |
EP1458813A1 (de) | 2004-09-22 |
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