JP4281953B2 - 調湿性、ホルムアルデヒド吸着性塗材 - Google Patents
調湿性、ホルムアルデヒド吸着性塗材 Download PDFInfo
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- JP4281953B2 JP4281953B2 JP2003329414A JP2003329414A JP4281953B2 JP 4281953 B2 JP4281953 B2 JP 4281953B2 JP 2003329414 A JP2003329414 A JP 2003329414A JP 2003329414 A JP2003329414 A JP 2003329414A JP 4281953 B2 JP4281953 B2 JP 4281953B2
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- formaldehyde
- humidity
- humidity control
- glass transition
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims description 71
- 239000011248 coating agent Substances 0.000 title claims description 39
- 238000000576 coating method Methods 0.000 title claims description 39
- 239000000463 material Substances 0.000 title claims description 33
- 239000003463 adsorbent Substances 0.000 title claims description 5
- 239000000839 emulsion Substances 0.000 claims description 21
- 239000010410 layer Substances 0.000 claims description 15
- 239000004925 Acrylic resin Substances 0.000 claims description 14
- 229920000178 Acrylic resin Polymers 0.000 claims description 14
- 230000009477 glass transition Effects 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 claims description 11
- 239000012792 core layer Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000011258 core-shell material Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000178 monomer Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- XDQWJFXZTAWJST-UHFFFAOYSA-N 3-triethoxysilylpropyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C=C XDQWJFXZTAWJST-UHFFFAOYSA-N 0.000 description 6
- GULAMJIQWGAUGT-UHFFFAOYSA-N 5-hydrazinyl-5-oxopentane-1,2,3-tricarboxylic acid Chemical compound NNC(=O)CC(C(O)=O)C(C(O)=O)CC(O)=O GULAMJIQWGAUGT-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- -1 amine compound Chemical class 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000005909 Kieselgur Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- 229920000142 Sodium polycarboxylate Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 229910052624 sepiolite Inorganic materials 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- HORQAOAYAYGIBM-UHFFFAOYSA-N 2,4-dinitrophenylhydrazine Chemical compound NNC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HORQAOAYAYGIBM-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- CUXGDKOCSSIRKK-UHFFFAOYSA-N 7-methyloctyl prop-2-enoate Chemical compound CC(C)CCCCCCOC(=O)C=C CUXGDKOCSSIRKK-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010003645 Atopy Diseases 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 108010082455 Sebelipase alfa Proteins 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052956 cinnabar Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229940041615 kanuma Drugs 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide group Chemical group NNC(=O)N DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
分散剤としては、例えばポリカルボン酸ナトリウム、ポリカルボン酸アンモニウム、有機酸エステル系、エーテル系若しくは反応系界面活性剤、アルコールエトキシ系若しくはナフタレン系無機塩などが使用されるが、中でも分散が良好で環境汚染にならないポリカルボン酸ナトリウムが好ましい。
調湿性能の評価方法/日本仕上工業会の規定の測定方法に準じる。
イ.試験体の調整
厚さ9.5mm、縦300mm、横300mmの石膏ボードに実施例、比較例の調湿塗材を2kg/m2塗布し、養生室に12日間静置し、側面及び裏面をシリコーン樹脂シーリング材で塗り込んでシールし、温度20±2℃、湿度45±5%の恒温恒湿室内に48時間静置したものを試験体とする。
ロ.試験方法
予め試験体の重量を測定したのち、温度20±2℃、湿度90±5%に調整した恒温恒湿器に24時間静置し、重量を測定する。次いで温度20±2℃、湿度45±5%に調整した恒温恒室器に24時間静置したのち重量を測定する。
この操作を2回繰り返し、吸放湿特性値を算出する。
5Lの二方コックテドラーバックに塗布試験体(有効面積100cm2)を挿入し、熱シールで密封した後、バック内の残空気を吸引した後、窒素ベースのホルムアルデヒドガス(約16ppm)を注入。ガス検知管{ガステック(株)社製No.91L}を用いて、バック内の残存ガス濃度を経時的に測定。
1Lの二方コックテドラーバックに塗布試験体(有効面積100cm2)を挿入し、熱シールで密封した後、バック内の残空気を吸引した後、窒素ベースのホルムアルデヒドガス(約15ppm)を注入し、室温で60時間保存。バック内の残存ガスを吸引置換し、新たに窒素ガスを封入して40℃、3時間加熱後、バック内の気体をDNPH捕集管に通過させてカルボニル化合物の誘導化を行い、アセトニトリルを用いて誘導体の抽出を行いHPLCにて定量分析を行った。
コア・シェル構造を持ち、コア層のガラス転移点が0℃、シェル層のガラス転移点が20℃の樹脂固形分50%のアクリル樹脂エマルジョン(透湿度200g/m2・24h以上、以下AE1)、含水非晶質二酸化ケイ素{塩野義製薬(株)、カープレックス(登録商標)}、キャッチャー剤として1,2,3,4−ブタンテトラカルボン酸ヒドラジド、水を表1に示す配合で混合容器中に投入し完全に混合して調湿性ホルムアルデヒド吸着性塗材を調製した。
実施例1配合より、キャッチャー剤を含まない塗材を調製した。
実施例1の配合より、含水非晶質二酸化ケイ素を含まない塗材を調製した。
実施例1の配合より、含水非晶質二酸化ケイ素とキャッチャー剤を含まず、代わりにケイ藻土を混合容器中投入し完全に混合して塗材を調製した。
実施例1配合より、含水非晶質二酸化ケイ素、キャッチャー剤を含まない汎用塗材{透湿度150g/m 2 ・24h以上、アイカ工業(株)製JQ−20}を配合して塗材を調製した。
Claims (4)
- バインダーとしてコア・シェル構造からなるアクリル樹脂系エマルジョンと、含水非晶質二酸化ケイ素、ホルムアルデヒド吸着剤を含むことを特徴とする調湿性、ホルムアルデヒド吸着性塗材。
- 前記アクリル樹脂系エマルジョンがコア層のガラス転移点が0℃以下、シェル層のガラス転移点が20℃以上であることを特徴とする請求項1記載の調湿性、ホルムアルデヒド吸着性塗材。
- 前記含水非晶質二酸化ケイ素の配合率が固形分中に5〜15重量%配合されていることを特徴とする請求項1乃至2いすれか記載の調湿性、ホルムアルデヒド吸着性塗材。
- 前記ホルムアルデヒド吸着剤の配合率が固形分中に0.05〜0.5重量%配合されている請求項1乃至3いずれか記載の調湿性、ホルムアルデヒド吸着性塗材。
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JP2003329414A JP4281953B2 (ja) | 2003-09-22 | 2003-09-22 | 調湿性、ホルムアルデヒド吸着性塗材 |
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JP2003329414A JP4281953B2 (ja) | 2003-09-22 | 2003-09-22 | 調湿性、ホルムアルデヒド吸着性塗材 |
Publications (2)
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JP2005097337A JP2005097337A (ja) | 2005-04-14 |
JP4281953B2 true JP4281953B2 (ja) | 2009-06-17 |
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JP2003329414A Expired - Lifetime JP4281953B2 (ja) | 2003-09-22 | 2003-09-22 | 調湿性、ホルムアルデヒド吸着性塗材 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5393942B2 (ja) * | 2005-04-08 | 2014-01-22 | アイカ工業株式会社 | 水性塗料組成物及び壁面 |
JP5044152B2 (ja) * | 2005-06-24 | 2012-10-10 | 日本化成株式会社 | コーティング用組成物及びその製造方法、並びに樹脂成形体及びその製造方法 |
JP5127021B2 (ja) * | 2006-07-11 | 2013-01-23 | 特種東海製紙株式会社 | 調湿性塗料 |
FR2952067B1 (fr) * | 2009-11-03 | 2012-05-25 | Saint Gobain Technical Fabrics | Composition filmogene renfermant un agent apte a pieger le formaldehyde |
WO2015048797A1 (en) | 2013-09-30 | 2015-04-02 | Certainteed Corporation | Stain repellent and voc eliminating coatings and use thereof |
EP3851208A4 (en) * | 2018-09-14 | 2022-06-08 | Aisin Seiki Kabushiki Kaisha | DEFINED WATER DISPENSER |
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2003
- 2003-09-22 JP JP2003329414A patent/JP4281953B2/ja not_active Expired - Lifetime
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