JP4246281B2 - 難燃性ポリアミド組成物 - Google Patents
難燃性ポリアミド組成物 Download PDFInfo
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- JP4246281B2 JP4246281B2 JP01087798A JP1087798A JP4246281B2 JP 4246281 B2 JP4246281 B2 JP 4246281B2 JP 01087798 A JP01087798 A JP 01087798A JP 1087798 A JP1087798 A JP 1087798A JP 4246281 B2 JP4246281 B2 JP 4246281B2
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- Prior art keywords
- flame retardant
- weight
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- flame
- molded
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- 239000003063 flame retardant Substances 0.000 title claims description 36
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
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- 125000003277 amino group Chemical group 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
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- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/790012 | 1997-01-28 | ||
| US08/790,012 US5863974A (en) | 1997-01-28 | 1997-01-28 | Flame retardant polyamide composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH10273589A JPH10273589A (ja) | 1998-10-13 |
| JPH10273589A5 JPH10273589A5 (enExample) | 2005-08-11 |
| JP4246281B2 true JP4246281B2 (ja) | 2009-04-02 |
Family
ID=25149388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP01087798A Expired - Fee Related JP4246281B2 (ja) | 1997-01-28 | 1998-01-23 | 難燃性ポリアミド組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5863974A (enExample) |
| EP (1) | EP0855421B1 (enExample) |
| JP (1) | JP4246281B2 (enExample) |
| DE (1) | DE69823245T2 (enExample) |
| ES (1) | ES2218765T3 (enExample) |
| SG (1) | SG65728A1 (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3016344B2 (ja) * | 1994-12-19 | 2000-03-06 | 三菱電機株式会社 | 開閉器 |
| NL1008443C2 (nl) * | 1998-03-02 | 1999-09-03 | Dsm Nv | Hoogsmeltende polyamidesamenstelling voor electronicatoepassingen. |
| US6308142B1 (en) | 1999-02-12 | 2001-10-23 | General Electric Company | Method for determining flame retardance of polymer compositions |
| US20020086927A1 (en) * | 1999-07-23 | 2002-07-04 | De Schryver Daniel A. | Flame retardant compositions |
| US6753367B2 (en) | 2001-08-20 | 2004-06-22 | General Electric Company | Flame retardant polycarbonate compositions with improved weathering performance containing cyanoacrylic esters |
| US7166243B2 (en) * | 2003-08-16 | 2007-01-23 | General Electric Company | Reinforced poly(arylene ether)/polyamide composition |
| US20060205872A1 (en) * | 2003-08-16 | 2006-09-14 | General Electric Company | Reinforced Poly(Arylene Ether)/Polyamide Composition and Articles Thereof |
| CN101128541B (zh) * | 2005-02-23 | 2010-08-11 | 宝理塑料株式会社 | 阻燃性树脂组合物 |
| EP1719796A1 (en) * | 2005-05-03 | 2006-11-08 | DSM IP Assets B.V. | A polyester moulding composition for use in electrical devices |
| CN101218305B (zh) * | 2005-07-08 | 2011-03-23 | 宝理塑料株式会社 | 阻燃性树脂组合物 |
| JP5179731B2 (ja) * | 2005-08-11 | 2013-04-10 | ポリプラスチックス株式会社 | 難燃性樹脂組成物 |
| JP4953669B2 (ja) * | 2006-03-15 | 2012-06-13 | 旭化成ケミカルズ株式会社 | ポリアミド樹脂組成物およびその製造方法 |
| CN101490472B (zh) * | 2006-07-11 | 2016-08-17 | 帝斯曼知识产权资产管理有限公司 | 灯座 |
| WO2008006443A1 (en) * | 2006-07-11 | 2008-01-17 | Dsm Ip Assets B.V. | Lamp sockets |
| DE102008016436A1 (de) * | 2008-03-31 | 2009-10-01 | Ems-Patent Ag | Polyamidformmasse für lackfreie, zähe Gehäuse mit Hochglanz-Oberfläche |
| TWI379860B (en) | 2008-06-24 | 2012-12-21 | Univ Chung Yuan Christian | Modified clay and clay-polymer composite |
| US8991321B2 (en) | 2009-12-24 | 2015-03-31 | Bromine Compounds Ltd. | Flame retarded compositions |
| US20130197150A1 (en) * | 2010-10-13 | 2013-08-01 | Solvay Specialty Polymers Usa, Llc | Stain-resistant articles |
| KR20130140697A (ko) * | 2010-10-13 | 2013-12-24 | 솔베이 스페셜티 폴리머즈 유에스에이, 엘.엘.씨. | 내오염성 물품 |
| KR101333579B1 (ko) * | 2010-12-15 | 2013-11-28 | 제일모직주식회사 | 반사성, 내열성 및 내습성이 우수한 폴리아마이드 수지 조성물. |
| CN102911480A (zh) * | 2011-08-05 | 2013-02-06 | 鸿富锦精密工业(深圳)有限公司 | 树脂组合物及应用该树脂组合物所制得的复合体 |
| US8865807B2 (en) | 2011-12-29 | 2014-10-21 | Cheil Industries Inc. | Polyamide resin composition having improved physical properties including thin-wall moldability |
| CN102618026B (zh) * | 2012-04-25 | 2014-07-02 | 中国科学院宁波材料技术与工程研究所 | 一种高cti值的无卤阻燃尼龙母料及制备方法 |
| JP6095799B2 (ja) * | 2012-12-28 | 2017-03-15 | コーロン プラスティックス,インク | ポリアミド樹脂組成物 |
| KR101566063B1 (ko) | 2012-12-31 | 2015-11-04 | 제일모직주식회사 | 표면광택도, 반사성, 내황변성 및 성형성이 우수한 열가소성 수지 조성물 |
| CN103102680B (zh) * | 2013-02-20 | 2017-08-01 | 合肥杰事杰新材料股份有限公司 | 一种低成本阻燃耐磨高抗冲聚酰胺6复合材料及制备方法 |
| CN105873742B (zh) | 2013-11-21 | 2017-10-17 | 沙特基础工业全球技术有限公司 | 密度减小的制品 |
| US10301449B2 (en) | 2013-11-29 | 2019-05-28 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition having excellent light stability at high temperature |
| KR101685771B1 (ko) * | 2013-12-10 | 2016-12-13 | 주식회사 엘지화학 | 할로겐계 난연 유리섬유 강화 폴리아미드 수지 조성물, 및 제조방법 |
| KR101690829B1 (ko) | 2013-12-30 | 2016-12-28 | 롯데첨단소재(주) | 내충격성 및 내광성이 우수한 열가소성 수지 조성물 |
| CN106068177B (zh) | 2014-03-06 | 2017-12-19 | 沙特基础工业全球技术有限公司 | 增材制造的具有阻燃性的制品、制成方法及测试它们的阻燃性的方法 |
| US10636951B2 (en) | 2014-06-27 | 2020-04-28 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition having excellent reflectivity |
| US9840610B2 (en) | 2014-09-30 | 2017-12-12 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and molded article using the same |
| KR101793319B1 (ko) | 2014-12-17 | 2017-11-03 | 롯데첨단소재(주) | 폴리에스테르 수지 조성물 및 이로부터 제조된 성형품 |
| US10457809B2 (en) | 2015-02-23 | 2019-10-29 | Sabic Global Technologies B.V. | Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof |
| US10294367B2 (en) * | 2015-02-23 | 2019-05-21 | Sabic Global Technologies B.V. | Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof |
| US20180044521A1 (en) * | 2015-02-23 | 2018-02-15 | Sabic Global Technologies B.V. | Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof |
| WO2016137852A1 (en) | 2015-02-23 | 2016-09-01 | Sabic Global Technologies B.V. | Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof |
| KR101849830B1 (ko) | 2015-06-30 | 2018-04-18 | 롯데첨단소재(주) | 내충격성 및 광신뢰성이 우수한 폴리에스테르 수지 조성물 및 이를 이용한 성형품 |
| BR112019020703A8 (pt) * | 2017-04-07 | 2023-02-28 | Imerys Talc America Inc | Composição polimérica retardante de chama |
| GB201809830D0 (en) * | 2018-06-15 | 2018-08-01 | Hexcel Composties Ltd | Epoxy resin formulations |
| KR20240019760A (ko) * | 2021-06-11 | 2024-02-14 | 이메리스 유에스에이, 인크. | 난연제 폴리머 조성물 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2465319A (en) * | 1941-07-29 | 1949-03-22 | Du Pont | Polymeric linear terephthalic esters |
| US3047539A (en) * | 1958-11-28 | 1962-07-31 | Goodyear Tire & Rubber | Production of polyesters |
| BE608862A (enExample) * | 1960-10-06 | 1900-01-01 | ||
| US3425986A (en) * | 1965-07-28 | 1969-02-04 | Firestone Tire & Rubber Co | Process and composition of matter |
| FR1464645A (fr) * | 1965-08-25 | 1967-01-06 | Firestone Tire & Rubber Co | Composition de résines de polyamide stabilisée à l'égard de la chaleur et de la lumière |
| FR1545754A (fr) * | 1966-09-22 | 1968-11-15 | Perfectionnements apportés aux procédés de stabilisation de polyamides linéairessynthétiques et produits ainsi obtenus | |
| US3479319A (en) * | 1967-09-19 | 1969-11-18 | Firestone Tire & Rubber Co | Polyethylene terephthalate stabilized with sodium pyrophosphate |
| US3808180A (en) * | 1970-04-13 | 1974-04-30 | Rohm & Haas | Composite interpolymer and low haze impact resistant thermoplastic compositions thereof |
| GB1485271A (en) * | 1974-08-05 | 1977-09-08 | Ici Ltd | Thermoplastic polyester composition |
| CH595416A5 (enExample) * | 1975-04-18 | 1978-02-15 | Ciba Geigy Ag | |
| DE2524121C2 (de) * | 1975-05-30 | 1986-02-06 | Basf Ag, 6700 Ludwigshafen | Verwendung von Polybutylenterephthalat-Formmassen zur Herstellung von Formteilen durch Spritzguß |
| US4096202A (en) * | 1976-06-09 | 1978-06-20 | Rohm And Haas Company | Impact modified poly(alkylene terephthalates) |
| US4296021A (en) * | 1976-12-06 | 1981-10-20 | General Electric Company | Reinforced thermoplastic polyester compositions having improved high voltage breakdown resistance |
| US4180494A (en) * | 1977-08-15 | 1979-12-25 | Rohm And Haas Company | Thermoplastic polyesters |
| DE2905253C3 (de) * | 1979-02-12 | 1986-01-09 | Chemische Fabrik Kalk GmbH, 5000 Köln | Brandschutzkomponenten für thermoplastische Kunststoffe |
| DE2927576A1 (de) * | 1979-07-07 | 1981-01-15 | Bayer Ag | Hochschlagzaehes polybutylenterephthalat |
| US4260693A (en) * | 1979-08-27 | 1981-04-07 | General Electric Company | Polycarbonate compositions |
| US4376188A (en) * | 1980-03-10 | 1983-03-08 | Allied Corporation | High melt strength composition comprising modified polycaprolactam and impact modifier |
| DE3267383D1 (en) * | 1981-05-25 | 1985-12-19 | Ciba Geigy Ag | Thermoplastic polyester moulding masses and their use |
| US4456723A (en) * | 1981-10-28 | 1984-06-26 | Ciba-Geigy Corporation | Thermoplastic moulding composition and the use thereof |
| DE3150272A1 (de) * | 1981-12-18 | 1983-06-30 | Bayer Ag, 5090 Leverkusen | Polyamidformmassen |
| US4421888A (en) * | 1982-03-30 | 1983-12-20 | Celanese Corporation | Sustained high arc resistant polyester composition |
| FR2553783B1 (fr) * | 1983-10-21 | 1986-01-17 | Rhone Poulenc Spec Chim | Compositions a base de polyamide ignifuge |
| US4544695A (en) * | 1984-09-13 | 1985-10-01 | The B. F. Goodrich Company | Low melting phosphate-sulfate glasses as intumescent flame and/or smoke retardants for polymers |
| DE3443154A1 (de) * | 1984-11-27 | 1986-05-28 | Basf Ag, 6700 Ludwigshafen | Selbstverloeschende thermoplastische polyamid-formmassen |
| US4636544A (en) * | 1985-02-25 | 1987-01-13 | General Electric Company | Flame retarded polyester molding composition with improved electrical performance |
| US4687802A (en) * | 1985-02-25 | 1987-08-18 | General Electric Company | Glass fiber reinforced polyester molding compositions containing metal salts |
| US4717751A (en) * | 1985-03-29 | 1988-01-05 | General Electric Company | Linear polyester resin blends with high impact resistance |
| GB8725745D0 (en) * | 1987-11-03 | 1987-12-09 | Du Pont Canada | High viscosity nylon |
| GB8725744D0 (en) * | 1987-11-03 | 1987-12-09 | Du Pont Canada | Dual-ovenable nylon container |
| US4981898A (en) * | 1987-12-31 | 1991-01-01 | General Electric Company | Polycarbonate-polyester blends |
| US4981897A (en) * | 1989-06-28 | 1991-01-01 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Aromatic polyester film containing orthophosphate powder |
| US5149734A (en) * | 1989-10-20 | 1992-09-22 | General Electric Company | Highly filled thermoplastic polyester molding compositions |
| US5026760A (en) * | 1989-11-02 | 1991-06-25 | General Electric Company | Warpage controlled polyesters |
| US5162412A (en) * | 1991-07-26 | 1992-11-10 | General Electric Company | Polyester compositions having improved wear characteristics |
| CA2103420A1 (en) * | 1992-12-22 | 1994-06-23 | Eileen B. Walsh | Stabilization of low molecular weight polybutylene terephthalate/polyester blends with phosphorus compounds |
| US5441997A (en) * | 1992-12-22 | 1995-08-15 | General Electric Company | High density polyester-polycarbonate molding composition |
| US5554674A (en) * | 1995-04-07 | 1996-09-10 | General Electric Company | Flame retardant molding thermoplastics |
-
1997
- 1997-01-28 US US08/790,012 patent/US5863974A/en not_active Expired - Fee Related
-
1998
- 1998-01-23 SG SG1998000168A patent/SG65728A1/en unknown
- 1998-01-23 JP JP01087798A patent/JP4246281B2/ja not_active Expired - Fee Related
- 1998-01-28 ES ES98300624T patent/ES2218765T3/es not_active Expired - Lifetime
- 1998-01-28 DE DE69823245T patent/DE69823245T2/de not_active Expired - Fee Related
- 1998-01-28 EP EP98300624A patent/EP0855421B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| SG65728A1 (en) | 1999-06-22 |
| ES2218765T3 (es) | 2004-11-16 |
| EP0855421A1 (en) | 1998-07-29 |
| JPH10273589A (ja) | 1998-10-13 |
| US5863974A (en) | 1999-01-26 |
| DE69823245T2 (de) | 2005-04-14 |
| EP0855421B1 (en) | 2004-04-21 |
| DE69823245D1 (de) | 2004-05-27 |
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