JP4241372B2 - ポリオールブレンドの製造方法 - Google Patents

ポリオールブレンドの製造方法 Download PDF

Info

Publication number
JP4241372B2
JP4241372B2 JP2003507170A JP2003507170A JP4241372B2 JP 4241372 B2 JP4241372 B2 JP 4241372B2 JP 2003507170 A JP2003507170 A JP 2003507170A JP 2003507170 A JP2003507170 A JP 2003507170A JP 4241372 B2 JP4241372 B2 JP 4241372B2
Authority
JP
Japan
Prior art keywords
polyether
epoxide
weight
blend
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2003507170A
Other languages
English (en)
Japanese (ja)
Other versions
JP2004530767A (ja
JP2004530767A5 (enExample
Inventor
ジャック・アール・リース
スタンリー・エル・ヘイガー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Antwerpen NV
Original Assignee
Bayer Antwerpen NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Antwerpen NV filed Critical Bayer Antwerpen NV
Publication of JP2004530767A publication Critical patent/JP2004530767A/ja
Publication of JP2004530767A5 publication Critical patent/JP2004530767A5/ja
Application granted granted Critical
Publication of JP4241372B2 publication Critical patent/JP4241372B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2003507170A 2001-06-21 2002-06-13 ポリオールブレンドの製造方法 Expired - Fee Related JP4241372B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/886,510 US6491846B1 (en) 2001-06-21 2001-06-21 Process for the in-situ production of polyol blends, the in-situ produced polyol blends, and their use in the production of viscoelastic foam
PCT/IB2002/003084 WO2003000770A1 (en) 2001-06-21 2002-06-13 Process for the production of polyol blends

Publications (3)

Publication Number Publication Date
JP2004530767A JP2004530767A (ja) 2004-10-07
JP2004530767A5 JP2004530767A5 (enExample) 2006-01-05
JP4241372B2 true JP4241372B2 (ja) 2009-03-18

Family

ID=25389162

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003507170A Expired - Fee Related JP4241372B2 (ja) 2001-06-21 2002-06-13 ポリオールブレンドの製造方法

Country Status (18)

Country Link
US (1) US6491846B1 (enExample)
EP (1) EP1401912B1 (enExample)
JP (1) JP4241372B2 (enExample)
KR (1) KR100852527B1 (enExample)
CN (1) CN1235942C (enExample)
AT (1) ATE296849T1 (enExample)
BR (1) BR0210587A (enExample)
CA (1) CA2450785C (enExample)
CZ (1) CZ20033509A3 (enExample)
DE (1) DE60204461T2 (enExample)
ES (1) ES2242871T3 (enExample)
HU (1) HU229655B1 (enExample)
MX (1) MXPA03011866A (enExample)
PL (1) PL207216B1 (enExample)
PT (1) PT1401912E (enExample)
RU (1) RU2312112C2 (enExample)
TW (1) TW593390B (enExample)
WO (1) WO2003000770A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004051996A (ja) * 2002-07-19 2004-02-19 Bayer Antwerpen Nv 活性化出発混合物およびその関連方法
US7738815B2 (en) 2007-02-20 2010-06-15 Konica Minolta Business Technologies, Inc. Image forming apparatus including a toner discharge operation

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7530127B2 (en) 2002-05-24 2009-05-12 Dan-Foam Aps Pillow and method of manufacturing a pillow
NZ554159A (en) 2002-05-24 2008-10-31 Tempur World Llc Comfort pillow
ITRM20020471A1 (it) * 2002-09-24 2004-03-25 Adler Plastic S P A Composizione poliuretanica fonoassorbente e fonoisolante.
US7078443B2 (en) * 2003-10-22 2006-07-18 Intellectual Property Holdings, Llc Viscoelastic foam layer and composition
US20050107643A1 (en) * 2003-11-13 2005-05-19 Thomas Ostrowski Preparation of polyether alcohols
EP1710268B1 (en) * 2004-01-30 2008-08-27 Kaneka Corporation Method for producing oxyalkylene polymer
EP1710270A4 (en) * 2004-01-30 2007-02-21 Kaneka Medix Corp METHOD FOR PRODUCING HYDROLYZABLE SILICON GROUPS CONTAINING OXYALKYLENE POLYMER AND CURING COMPOSITION THEREOF
KR101292900B1 (ko) * 2005-04-21 2013-08-02 아사히 가라스 가부시키가이샤 저반발성 연질 폴리우레탄폼 및 그 제조 방법
US7469437B2 (en) 2005-06-24 2008-12-30 Tempur-Pedic Management, Inc. Reticulated material body support and method
TW200801060A (en) * 2006-02-28 2008-01-01 Asahi Glass Co Ltd Flexible polyurethane foam and process for producing the same
US8656537B2 (en) 2006-04-20 2014-02-25 Dan Foam Aps Multi-component pillow and method of manufacturing and assembling same
US20070299153A1 (en) * 2006-06-23 2007-12-27 Hager Stanley L Viscoelastic foams with slower recovery and improved tear
JP5228914B2 (ja) 2006-10-25 2013-07-03 旭硝子株式会社 軟質ポリウレタンフォームの製造方法
JP5512283B2 (ja) * 2007-01-30 2014-06-04 ビーエーエスエフ ソシエタス・ヨーロピア ポリエーテルカーボネートポリオールの製造方法
JP5303885B2 (ja) * 2007-09-18 2013-10-02 旭硝子株式会社 軟質ポリウレタンフォームの製造方法および軟質ポリウレタンフォーム
KR20100075825A (ko) * 2007-09-28 2010-07-05 아사히 가라스 가부시키가이샤 연질 폴리우레탄 폼 및 열 프레스 성형품의 제조 방법 그리고 열 프레스 성형품
US20090306235A1 (en) * 2008-06-05 2009-12-10 Wang Jin Quan Memory Foam Pad
CN102149740B (zh) * 2008-07-18 2013-11-13 陶氏环球技术有限责任公司 多孔结构体和粘弹性聚氨酯泡沫体
DE102009053218A1 (de) * 2009-11-06 2011-07-14 Bayer MaterialScience AG, 51373 Verfahren zur Herstellung eines Polyurethanschaums mittels über- oder nahekritischen Treibmittels
US20110230581A1 (en) * 2010-03-17 2011-09-22 Bayer Materialscience Llc Process for the production of polyether polyols with a high ethylene oxide content
GB2482176A (en) 2010-07-23 2012-01-25 Christopher Wickham Noakes Production of polyols for use in low ball rebound polyurethane foams
US8975335B2 (en) * 2011-09-23 2015-03-10 Bayer Materialscience Llc Process for the production of high air flow polyether foams and the foams produced by this process
US10669368B2 (en) 2013-03-15 2020-06-02 Covestro Llc Method to increase the resistance of double metal cyanide catalysts to deactivation
DE102013224708A1 (de) * 2013-12-03 2015-06-03 Evonik Industries Ag Alkoxysilylhaltige Klebdichtstoffe mit intrinsisch reduzierter Viskosität
US20170002128A1 (en) * 2013-12-23 2017-01-05 Shell Oil Company Polyurethanes
US9951174B2 (en) 2015-05-20 2018-04-24 Covestro Llc Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow
EP3317322B1 (en) * 2015-07-02 2019-04-10 Covestro LLC Process for preparing polyether polyol using dmc catalyst and continuous addition of starter
JP7204650B2 (ja) 2017-01-17 2023-01-16 ダウ グローバル テクノロジーズ エルエルシー 粘弾性フォームの製造のために有用なポリオールブレンド
CN110402263B (zh) * 2017-03-15 2022-06-07 科思创有限公司 具有降低的温度敏感性的粘弹性聚氨酯泡沫
US10766998B2 (en) 2017-11-21 2020-09-08 Covestro Llc Flexible polyurethane foams
US10793692B2 (en) 2018-10-24 2020-10-06 Covestro Llc Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers
CN109651609B (zh) * 2018-11-28 2021-04-06 山东蓝星东大有限公司 高eo含量聚醚多元醇的制备方法
EP3741788A1 (de) * 2019-05-24 2020-11-25 Covestro Deutschland AG Verfahren zur herstellung von polyoxyalkylenpolyol-mischungen
CN110922579B (zh) * 2019-12-06 2021-12-03 浙江皇马科技股份有限公司 一种低模量密封胶用聚醚的合成方法
CN112552859B (zh) * 2020-12-29 2022-07-15 烟台信友新材料有限公司 一种高初粘低收缩高强度聚氨酯热熔胶及其制备方法
US11572433B2 (en) 2021-03-12 2023-02-07 Covestro Llc In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
US20230039276A1 (en) 2021-07-28 2023-02-09 Covestro Llc Novel polyether polyol blends, a process for their preparation, foams prepared from these polyether polyol blends and a process for their preparation
US11718705B2 (en) 2021-07-28 2023-08-08 Covestro Llc In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams
CN115181259B (zh) * 2022-08-11 2024-04-09 万华化学集团股份有限公司 一种连续化制备聚醚的方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3457203A (en) * 1966-04-25 1969-07-22 Olin Mathieson Hydrophilic polyurethane foams and a process for preparing them
US4981880A (en) * 1988-09-23 1991-01-01 The Dow Chemical Company Process for making low density flexible polyisocyanurate-polyurethane foams
US5114619A (en) 1989-07-14 1992-05-19 The Dow Chemical Company Production of polyether polyols with reduced unsaturation
US4950695A (en) 1989-03-06 1990-08-21 Pmc, Inc. Reduction of firmness in flexible polyurethane foam by addition of monofunctional alcohols, polyesters, and polyethers
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5777177A (en) 1996-02-07 1998-07-07 Arco Chemical Technology, L.P. Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter
US5689012A (en) 1996-07-18 1997-11-18 Arco Chemical Technology, L.P. Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter
US6077978A (en) * 1997-09-17 2000-06-20 Arco Chemical Technology L.P. Direct polyoxyalkylation of glycerine with double metal cyanide catalysis
US6136879A (en) 1997-10-28 2000-10-24 Tokai Rubber Industries, Ltd. Soft polyurethane foam, method of producing the same and vehicle interior member using the same
US6066683A (en) * 1998-04-03 2000-05-23 Lyondell Chemical Worldwide, Inc. Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof
US6063309A (en) 1998-07-13 2000-05-16 Arco Chemical Technology L.P. Dispersion polyols for hypersoft polyurethane foam
DE19834572A1 (de) * 1998-07-31 2000-02-03 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6391935B1 (en) * 2000-01-31 2002-05-21 Bayer Antwerp, N.V. Viscoelastic polyurethane foams

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004051996A (ja) * 2002-07-19 2004-02-19 Bayer Antwerpen Nv 活性化出発混合物およびその関連方法
US7738815B2 (en) 2007-02-20 2010-06-15 Konica Minolta Business Technologies, Inc. Image forming apparatus including a toner discharge operation

Also Published As

Publication number Publication date
MXPA03011866A (es) 2004-03-26
JP2004530767A (ja) 2004-10-07
PL366781A1 (en) 2005-02-07
DE60204461T2 (de) 2006-04-27
EP1401912A1 (en) 2004-03-31
PL207216B1 (pl) 2010-11-30
CA2450785A1 (en) 2003-01-03
EP1401912B1 (en) 2005-06-01
PT1401912E (pt) 2005-10-31
HU229655B1 (en) 2014-03-28
HUP0400214A2 (hu) 2004-06-28
HUP0400214A3 (en) 2012-05-29
DE60204461D1 (de) 2005-07-07
WO2003000770A1 (en) 2003-01-03
ATE296849T1 (de) 2005-06-15
ES2242871T3 (es) 2005-11-16
CN1235942C (zh) 2006-01-11
RU2004101635A (ru) 2005-06-27
CN1518572A (zh) 2004-08-04
CZ20033509A3 (en) 2004-07-14
US6491846B1 (en) 2002-12-10
KR20040030692A (ko) 2004-04-09
TW593390B (en) 2004-06-21
KR100852527B1 (ko) 2008-08-14
CA2450785C (en) 2011-08-02
BR0210587A (pt) 2004-08-10
HK1068359A1 (en) 2005-04-29
RU2312112C2 (ru) 2007-12-10

Similar Documents

Publication Publication Date Title
KR100852527B1 (ko) 폴리올 배합물의 제조 방법
KR100556181B1 (ko) 이중 금속시아니드 착체-촉매 폴리옥시알킬렌폴리올로부터 제조된 성형 및 슬라브 폴리우레탄 발포체및 그의 제조에 적합한 폴리올
RU2191784C2 (ru) Получение полиолов с помощью двойного металлоцианидного катализатора посредством непрерывного добавления стартера
EP1097179B1 (en) Dispersion polyols for hypersoft polyurethane foam
EP0755955B1 (en) Flexible polyurethane foam on the basis of polyether polyols prepared by co-initiation of aqueous solutions of solid polyhydroxyl initiators
US10793692B2 (en) Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers
MX2007002766A (es) Metodo para producir materiales de espuma suave de poliuretano.
EP4056615B1 (en) Novel in-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
EP3596149A1 (en) Viscoelastic polyurethane foams with reduced temperature sensitivity
US20250019485A1 (en) Novel polyether polyol blends, a process for their preparation, foams prepared from these polyether polyol blends and a process for their preparation
EP4377370B1 (en) In-situ formed polyether polyols, processes for their preparation, and processes for the preparation of polyurethane foams
HK1068359B (en) Process for the production of polyol blends

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050601

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050601

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20080321

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080513

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080813

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20081202

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20081222

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120109

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Ref document number: 4241372

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130109

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140109

Year of fee payment: 5

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees