JP4208714B2 - フラーレンの燃焼合成のための方法 - Google Patents
フラーレンの燃焼合成のための方法 Download PDFInfo
- Publication number
- JP4208714B2 JP4208714B2 JP2003525713A JP2003525713A JP4208714B2 JP 4208714 B2 JP4208714 B2 JP 4208714B2 JP 2003525713 A JP2003525713 A JP 2003525713A JP 2003525713 A JP2003525713 A JP 2003525713A JP 4208714 B2 JP4208714 B2 JP 4208714B2
- Authority
- JP
- Japan
- Prior art keywords
- fullerene
- zone
- combustion
- fuel
- oxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 title claims description 146
- 229910003472 fullerene Inorganic materials 0.000 title claims description 143
- 238000000034 method Methods 0.000 title claims description 45
- 238000005049 combustion synthesis Methods 0.000 title description 8
- 238000002485 combustion reaction Methods 0.000 claims description 177
- 239000000047 product Substances 0.000 claims description 170
- 239000000446 fuel Substances 0.000 claims description 155
- 239000007800 oxidant agent Substances 0.000 claims description 97
- 230000001590 oxidative effect Effects 0.000 claims description 85
- 239000000543 intermediate Substances 0.000 claims description 50
- 238000006243 chemical reaction Methods 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 41
- 238000002156 mixing Methods 0.000 claims description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 35
- 229910052799 carbon Inorganic materials 0.000 claims description 34
- 239000000654 additive Substances 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 30
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 27
- 238000004064 recycling Methods 0.000 claims description 21
- 230000000996 additive effect Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000006227 byproduct Substances 0.000 claims description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 3
- 229920001197 polyacetylene Polymers 0.000 claims description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 description 59
- 238000005755 formation reaction Methods 0.000 description 51
- 238000007254 oxidation reaction Methods 0.000 description 21
- 150000003254 radicals Chemical class 0.000 description 19
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 18
- 230000003647 oxidation Effects 0.000 description 16
- 238000010438 heat treatment Methods 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 230000006641 stabilisation Effects 0.000 description 11
- 238000011105 stabilization Methods 0.000 description 11
- 239000003085 diluting agent Substances 0.000 description 10
- 238000011084 recovery Methods 0.000 description 10
- 239000004071 soot Substances 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 238000007796 conventional method Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- 230000037361 pathway Effects 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- -1 carbon fullerenes Chemical class 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthene Chemical compound C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000001737 promoting effect Effects 0.000 description 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 3
- 238000001308 synthesis method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000009841 combustion method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 239000002109 single walled nanotube Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QEJQAPYSVNHDJF-UHFFFAOYSA-N $l^{1}-oxidanylethyne Chemical compound [O]C#C QEJQAPYSVNHDJF-UHFFFAOYSA-N 0.000 description 1
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- ATLMFJTZZPOKLC-UHFFFAOYSA-N C70 fullerene Chemical compound C12=C(C3=C4C5=C67)C8=C9C%10=C%11C%12=C%13C(C%14=C%15C%16=%17)=C%18C%19=C%20C%21=C%22C%23=C%24C%21=C%21C(C=%25%26)=C%20C%18=C%12C%26=C%10C8=C4C=%25C%21=C5C%24=C6C(C4=C56)=C%23C5=C5C%22=C%19C%14=C5C=%17C6=C5C6=C4C7=C3C1=C6C1=C5C%16=C3C%15=C%13C%11=C4C9=C2C1=C34 ATLMFJTZZPOKLC-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 description 1
- HXGDTGSAIMULJN-UHFFFAOYSA-N acetnaphthylene Natural products C1=CC(C=C2)=C3C2=CC=CC3=C1 HXGDTGSAIMULJN-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- YAVVGPBYBUYPSR-UHFFFAOYSA-N benzene;oxygen Chemical class [O].C1=CC=CC=C1 YAVVGPBYBUYPSR-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229940087654 iron carbonyl Drugs 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000004767 rumen Anatomy 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/02—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in parallel arrangement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/152—Fullerenes
- C01B32/154—Preparation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C99/00—Subject-matter not provided for in other groups of this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00157—Controlling the temperature by means of a burner
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/842—Manufacture, treatment, or detection of nanostructure for carbon nanotubes or fullerenes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31655001P | 2001-08-31 | 2001-08-31 | |
| PCT/US2002/027838 WO2003021018A1 (en) | 2001-08-31 | 2002-08-31 | Method for combustion synthesis of fullerenes |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008209984A Division JP5226428B2 (ja) | 2001-08-31 | 2008-08-18 | フラーレンの燃焼合成のための方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005501794A JP2005501794A (ja) | 2005-01-20 |
| JP2005501794A5 JP2005501794A5 (https=) | 2008-10-02 |
| JP4208714B2 true JP4208714B2 (ja) | 2009-01-14 |
Family
ID=23229513
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003525713A Expired - Lifetime JP4208714B2 (ja) | 2001-08-31 | 2002-08-31 | フラーレンの燃焼合成のための方法 |
| JP2008209984A Expired - Lifetime JP5226428B2 (ja) | 2001-08-31 | 2008-08-18 | フラーレンの燃焼合成のための方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008209984A Expired - Lifetime JP5226428B2 (ja) | 2001-08-31 | 2008-08-18 | フラーレンの燃焼合成のための方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US7396520B2 (https=) |
| EP (1) | EP1423561B1 (https=) |
| JP (2) | JP4208714B2 (https=) |
| CN (1) | CN1556876B (https=) |
| AU (1) | AU2002326799B2 (https=) |
| CA (1) | CA2458223C (https=) |
| WO (1) | WO2003021018A1 (https=) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7279137B2 (en) * | 2001-08-30 | 2007-10-09 | Tda Research, Inc. | Burners and combustion apparatus for carbon nanomaterial production |
| EP1423561B1 (en) | 2001-08-31 | 2018-06-27 | Nano-C, Inc. | Method for combustion synthesis of fullerenes |
| JP4711680B2 (ja) | 2002-07-03 | 2011-06-29 | ナノ−シー,インク. | フラーレンの分離と精製 |
| US7335344B2 (en) * | 2003-03-14 | 2008-02-26 | Massachusetts Institute Of Technology | Method and apparatus for synthesizing filamentary structures |
| JP2005074557A (ja) * | 2003-08-29 | 2005-03-24 | Japan Science & Technology Agency | ナノスケール物質の構造制御方法 |
| US20060078488A1 (en) * | 2004-01-14 | 2006-04-13 | Frontier Carbon Corporation | Carbon material and process for producing the same |
| FI120195B (fi) * | 2005-11-16 | 2009-07-31 | Canatu Oy | Hiilinanoputket, jotka on funktionalisoitu kovalenttisesti sidotuilla fullereeneilla, menetelmä ja laitteisto niiden tuottamiseksi ja niiden komposiitit |
| CN103227289B (zh) | 2006-06-13 | 2016-08-17 | 索尔维美国有限公司 | 包含富勒烯及其衍生物的有机光伏器件 |
| CN101516765B (zh) | 2006-08-31 | 2012-03-28 | Nano-C公司 | 富勒烯材料的直接液相收集和加工 |
| CN100436313C (zh) * | 2007-01-26 | 2008-11-26 | 厦门大学 | 碳簇的燃烧合成装置 |
| WO2009086210A2 (en) | 2007-12-21 | 2009-07-09 | Plextronics, Inc. | Organic photovoltaic devices comprising fullerenes and derivatives thereof and improved methodes of making fullerene derivatives |
| JP2009203098A (ja) * | 2008-02-26 | 2009-09-10 | Mitsubishi Heavy Ind Ltd | フラーレン類似構造体の製造方法及びフラーレン類似構造体 |
| US20100249447A1 (en) * | 2009-03-17 | 2010-09-30 | Nano-C, Inc. | Purification of fullerene derivatives from various impurities |
| CN101597052B (zh) * | 2009-07-06 | 2011-06-15 | 中国科学院化学研究所 | 一种利用煤或石墨燃烧法大规模生产富勒烯的方法 |
| US9340697B2 (en) | 2009-08-14 | 2016-05-17 | Nano-C, Inc. | Solvent-based and water-based carbon nanotube inks with removable additives |
| EP2464698B1 (en) * | 2009-08-14 | 2021-12-01 | Nano-C, Inc. | Solvent-based and water-based carbon nanotube inks with removable additives |
| US8564954B2 (en) | 2010-06-15 | 2013-10-22 | Chipmos Technologies Inc. | Thermally enhanced electronic package |
| WO2012116286A1 (en) | 2011-02-25 | 2012-08-30 | Rutgers, The State University Of New Jersey | Scalable multiple-inverse diffusion flame burner for synthesis and processing of carbon-based and other nanostructured materials and films and fuels |
| EP2615356B1 (en) * | 2012-01-13 | 2016-05-25 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Method for the preparation of compressed oxidant-fuel gas mixtures |
| KR101939874B1 (ko) | 2012-12-21 | 2019-01-17 | 나노-씨, 인크. | 제거가능한 첨가제를 사용한 용매계 및 수계 탄소 나노튜브 잉크 |
| WO2015036075A1 (en) * | 2013-09-11 | 2015-03-19 | Merck Patent Gmbh | Cyclohexadiene fullerene derivatives |
| US9550907B2 (en) | 2015-02-27 | 2017-01-24 | Gates Corporation | Carbon nanostructure preblends and their applications |
| CN105540565A (zh) * | 2016-01-17 | 2016-05-04 | 河南科技学院 | 一种富勒烯的制备方法 |
| WO2018195272A1 (en) | 2017-04-20 | 2018-10-25 | Lanahan Samuel J | Truncated icosahedra assemblies |
| US11235977B2 (en) | 2017-12-21 | 2022-02-01 | Rutgers, The State University Of New Jersey | Flame-synthesis of monolayer and nano-defective graphene |
| CN109467075B (zh) * | 2018-12-24 | 2020-04-24 | 厦门大学 | 一种合成吨级富勒烯的连续燃烧生产设备及其合成方法 |
| CN110342499B (zh) * | 2019-07-26 | 2022-05-27 | 广西科学院 | 一种生物质高温碳化末端微氧烧蚀制备类富勒烯碳球的方法 |
| EP4225700A4 (en) | 2020-10-06 | 2025-04-23 | Nano-C, Inc. | PURIFICATION OF CARBON NANORETUBE ACID |
| CN112265980B (zh) * | 2020-10-18 | 2022-05-24 | 中国人民解放军陆军工程大学 | 富勒烯c60的配料及其制备方法 |
| CN112557578B (zh) * | 2020-12-11 | 2025-06-17 | 中国华能集团清洁能源技术研究院有限公司 | 一种研究水蒸气浓度对煤粉燃烧特性影响的装置及方法 |
| CN116601112B (zh) * | 2020-12-17 | 2025-10-10 | 三菱商事株式会社 | 富勒烯的制造装置及制造方法 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US393494A (en) | 1888-11-27 | whipple | ||
| US4089637A (en) | 1977-05-20 | 1978-05-16 | Combustion Engineering, Inc. | Control of air flow in a burner for a tangentially fired boiler |
| US5211932A (en) | 1989-07-06 | 1993-05-18 | Cabot Corporation | Carbon black process control system |
| US5199357A (en) | 1991-03-25 | 1993-04-06 | Foster Wheeler Energy Corporation | Furnace firing apparatus and method for burning low volatile fuel |
| US5076779A (en) | 1991-04-12 | 1991-12-31 | Union Carbide Industrial Gases Technology Corporation | Segregated zoning combustion |
| US5273729A (en) | 1991-05-24 | 1993-12-28 | Massachusetts Institute Of Technology | Combustion method for producing fullerenes |
| US5209656A (en) | 1991-08-29 | 1993-05-11 | Praxair Technology, Inc. | Combustion system for high velocity gas injection |
| US5227038A (en) | 1991-10-04 | 1993-07-13 | William Marsh Rice University | Electric arc process for making fullerenes |
| US5300203A (en) | 1991-11-27 | 1994-04-05 | William Marsh Rice University | Process for making fullerenes by the laser evaporation of carbon |
| US5304366A (en) | 1991-12-24 | 1994-04-19 | Sri International | Process and apparatus for producing and separating fullerenes |
| DE59301138D1 (de) | 1992-05-06 | 1996-01-25 | Hoechst Ag | Abtrennung von Fullerenen |
| US5662876A (en) | 1992-06-10 | 1997-09-02 | University Of South Carolina | Purification of fullerenes |
| WO1995026925A1 (en) * | 1994-03-30 | 1995-10-12 | Massachusetts Institute Of Technology | Production of fullerenic nanostructures in flames |
| US6083469A (en) | 1998-04-10 | 2000-07-04 | Leftin; Harry Paul | Pyrolysis process for making fullerenes |
| US6089855A (en) * | 1998-07-10 | 2000-07-18 | Thermo Power Corporation | Low NOx multistage combustor |
| EP0987493B1 (de) * | 1998-09-16 | 2003-08-06 | Abb Research Ltd. | Brenner für einen Wärmeerzeuger |
| US7279137B2 (en) | 2001-08-30 | 2007-10-09 | Tda Research, Inc. | Burners and combustion apparatus for carbon nanomaterial production |
| US6887291B2 (en) | 2001-08-30 | 2005-05-03 | Tda Research, Inc. | Filter devices and methods for carbon nanomaterial collection |
| EP1423561B1 (en) | 2001-08-31 | 2018-06-27 | Nano-C, Inc. | Method for combustion synthesis of fullerenes |
| JP3892371B2 (ja) | 2001-09-10 | 2007-03-14 | 三菱化学株式会社 | フラーレンの製造方法 |
| JP2003160317A (ja) | 2001-11-22 | 2003-06-03 | Mitsubishi Chemicals Corp | フラーレン類の製造方法およびフラーレン類の製造装置 |
| JP2003160316A (ja) | 2001-11-22 | 2003-06-03 | Mitsubishi Chemicals Corp | フラーレン類の製造方法およびフラーレン類の製造装置 |
| JP2003221216A (ja) | 2001-11-22 | 2003-08-05 | Mitsubishi Chemicals Corp | フラーレン類の製造方法及びその装置 |
| JP2003171106A (ja) | 2001-12-05 | 2003-06-17 | Mitsubishi Chemicals Corp | フラーレン類の製造方法およびフラーレン類の製造装置 |
| AU2002364510A1 (en) | 2001-12-05 | 2003-06-23 | Tda Research Inc. | Combustion process for synthesis of carbon nanomaterials from liquid hydrocarbon |
| JP2003192318A (ja) | 2001-12-21 | 2003-07-09 | Mitsubishi Chemicals Corp | フラーレンの製造装置及びその製造方法 |
| JP2003192319A (ja) | 2001-12-25 | 2003-07-09 | Mitsubishi Chemicals Corp | フラーレンの製造装置 |
| JP2003192320A (ja) | 2001-12-25 | 2003-07-09 | Mitsubishi Chemicals Corp | フラーレンの製造炉 |
| JP2003192321A (ja) | 2001-12-25 | 2003-07-09 | Mitsubishi Chemicals Corp | フラーレンの製造装置 |
| JP2003238132A (ja) | 2002-02-12 | 2003-08-27 | Mitsubishi Chemicals Corp | フラーレン類の製造用バーナー及びこれを用いたフラーレン類の製造方法 |
| JP2004018360A (ja) | 2002-06-20 | 2004-01-22 | Mitsubishi Chemicals Corp | フラーレン類の製造装置及び方法 |
| EP1567219A1 (en) | 2002-11-29 | 2005-08-31 | Coloplast A/S | A catheter |
| JP3892821B2 (ja) | 2003-03-06 | 2007-03-14 | 三菱化学株式会社 | フラーレンの製造方法 |
| CN100381356C (zh) | 2003-06-10 | 2008-04-16 | 先锋奈米碳素株式会社 | 富勒烯的制造方法 |
| US20050129607A1 (en) | 2003-12-16 | 2005-06-16 | Hiroaki Takehara | Method for producing fullerenes |
| US20050129608A1 (en) | 2003-12-16 | 2005-06-16 | Hiroaki Takehara | Method for producing fullerenes |
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| CA2458223A1 (en) | 2003-03-13 |
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| EP1423561A1 (en) | 2004-06-02 |
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| US7771692B2 (en) | 2010-08-10 |
| CN1556876B (zh) | 2012-01-18 |
| AU2002326799B2 (en) | 2008-08-14 |
| US20080286190A1 (en) | 2008-11-20 |
| JP2008273839A (ja) | 2008-11-13 |
| EP1423561B1 (en) | 2018-06-27 |
| WO2003021018A1 (en) | 2003-03-13 |
| US20050147552A1 (en) | 2005-07-07 |
| CA2458223C (en) | 2012-02-21 |
| US20080280240A1 (en) | 2008-11-13 |
| EP1423561A4 (en) | 2006-03-08 |
| JP5226428B2 (ja) | 2013-07-03 |
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