JP4203417B2 - ナノサイズの金属粒子を含むバリア材料 - Google Patents
ナノサイズの金属粒子を含むバリア材料 Download PDFInfo
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- JP4203417B2 JP4203417B2 JP2003529851A JP2003529851A JP4203417B2 JP 4203417 B2 JP4203417 B2 JP 4203417B2 JP 2003529851 A JP2003529851 A JP 2003529851A JP 2003529851 A JP2003529851 A JP 2003529851A JP 4203417 B2 JP4203417 B2 JP 4203417B2
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- Prior art keywords
- cyclodextrin
- film
- zinc
- barrier
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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| US7166671B2 (en) * | 2002-12-10 | 2007-01-23 | Cellresin Technologies, Llc | Grafted cyclodextrin |
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| US7666410B2 (en) | 2002-12-20 | 2010-02-23 | Kimberly-Clark Worldwide, Inc. | Delivery system for functional compounds |
| US7582308B2 (en) | 2002-12-23 | 2009-09-01 | Kimberly-Clark Worldwide, Inc. | Odor control composition |
| US7470464B2 (en) * | 2003-09-05 | 2008-12-30 | Cellresin Technologies, Llc | Fiber material having improved malodor scavenger properties |
| US7141518B2 (en) | 2003-10-16 | 2006-11-28 | Kimberly-Clark Worldwide, Inc. | Durable charged particle coatings and materials |
| US7678367B2 (en) | 2003-10-16 | 2010-03-16 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified particles |
| US7413550B2 (en) | 2003-10-16 | 2008-08-19 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
| US7582485B2 (en) | 2003-10-16 | 2009-09-01 | Kimberly-Clark Worldride, Inc. | Method and device for detecting ammonia odors and helicobacter pylori urease infection |
| US7488520B2 (en) | 2003-10-16 | 2009-02-10 | Kimberly-Clark Worldwide, Inc. | High surface area material blends for odor reduction, articles utilizing such blends and methods of using same |
| US7438875B2 (en) | 2003-10-16 | 2008-10-21 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified silica particles |
| US7879350B2 (en) | 2003-10-16 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using colloidal nanoparticles |
| US7754197B2 (en) | 2003-10-16 | 2010-07-13 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using coordinated polydentate compounds |
| US20050129825A1 (en) * | 2003-12-16 | 2005-06-16 | Gray Kimberley H. | Stabilization of milk-based products |
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| EP2058066A4 (en) * | 2006-09-01 | 2012-01-25 | Toyo Seikan Kaisha Ltd | ADSORBABLE ULTRA-FINE METAL PARTS |
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| US8215089B2 (en) * | 2008-07-14 | 2012-07-10 | David Stravitz | Waste disposal devices |
| US20100005762A1 (en) * | 2008-07-14 | 2010-01-14 | Stravitz David M | Waste Disposal Devices |
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| US8292863B2 (en) | 2009-10-21 | 2012-10-23 | Donoho Christopher D | Disposable diaper with pouches |
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| US8833592B2 (en) | 2009-10-30 | 2014-09-16 | Munchkin, Inc. | System and method for disposing waste packages such as diapers |
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| US8647587B2 (en) | 2009-10-30 | 2014-02-11 | Munchkin, Inc | Powder dispensing assembly for a waste container |
| US8690017B2 (en) | 2009-10-30 | 2014-04-08 | Munchkin, Inc. | Powder dispensing assembly for a waste container |
| CN103819949B (zh) * | 2014-03-13 | 2015-04-29 | 福建师范大学 | 一种无机粉体的表面改性方法 |
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| CN107501618A (zh) * | 2017-09-19 | 2017-12-22 | 四川大学 | 降解膜氧化隔绝材料 |
| CN116987380B (zh) * | 2023-04-26 | 2024-12-31 | 东华大学 | 一种气体阻隔尼龙复合材料及其制备方法和应用 |
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| JPS59145037A (ja) | 1983-02-09 | 1984-08-20 | Hidefumi Hirai | 貴金属コロイドを製造する方法 |
| US4871790A (en) * | 1987-11-25 | 1989-10-03 | Minnesota Mining And Manufacturing Company | Colloidal metals in monomers or polymers |
| DE4137139A1 (de) | 1991-11-12 | 1993-05-13 | Basf Lacke & Farben | Anorganische fuellstoffe enthaltende thermoplastische kunststoffolie, anorganische fuellstoffe enthaltender metall-kunststoff-verbund sowie verfahren zur herstellung |
| US5296472A (en) * | 1991-12-05 | 1994-03-22 | Vyrex Corporation | Methods for delipidation of skin and cerumen removal |
| US5429628A (en) * | 1993-03-31 | 1995-07-04 | The Procter & Gamble Company | Articles containing small particle size cyclodextrin for odor control |
| US5744056A (en) | 1993-07-16 | 1998-04-28 | Amoco Corporation | Oxygen-scavenging compositions and articles |
| US5776842A (en) * | 1994-06-23 | 1998-07-07 | Cellresin Technologies, Llc | Cellulosic web with a contaminant barrier or trap |
| US5492947A (en) * | 1994-06-23 | 1996-02-20 | Aspen Research Corporation | Barrier material comprising a thermoplastic and a compatible cyclodextrin derivative |
| DE19756790A1 (de) | 1997-12-19 | 1999-07-01 | Fraunhofer Ges Forschung | Prepolymer mit darin isoliert dispergierten nanoskaligen Feststoffteilchen, Verfahren zu seiner Herstellung und seine Verwendung |
| US6528013B1 (en) * | 1998-04-27 | 2003-03-04 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
| CA2350696C (en) * | 1998-11-25 | 2007-03-20 | The Procter & Gamble Company | Improved uncomplexed cyclodextrin compositions for odor control |
| US6613703B1 (en) * | 2000-04-27 | 2003-09-02 | Kimberly-Clark Worldwide, Inc. | Thermoplastic nonwoven web chemically reacted with a cyclodextrin compound |
| US6403653B1 (en) * | 2000-06-02 | 2002-06-11 | The United States Of America As Represented By The Secretary Of The Army | Active topical skin protectants using reactive nanoparticles |
| WO2002064877A2 (en) * | 2001-01-30 | 2002-08-22 | The Procter & Gamble Company | Coating compositions for modifying surfaces |
-
2002
- 2002-09-13 US US10/243,620 patent/US6894085B2/en not_active Expired - Lifetime
- 2002-09-16 EP EP02775012A patent/EP1427784B1/en not_active Expired - Lifetime
- 2002-09-16 CA CA2457759A patent/CA2457759C/en not_active Expired - Fee Related
- 2002-09-16 CN CNB028181557A patent/CN1304484C/zh not_active Expired - Fee Related
- 2002-09-16 KR KR1020047003909A patent/KR100696247B1/ko not_active Expired - Fee Related
- 2002-09-16 AT AT02775012T patent/ATE382073T1/de active
- 2002-09-16 MX MXPA04002540A patent/MXPA04002540A/es active IP Right Grant
- 2002-09-16 WO PCT/IB2002/003804 patent/WO2003025067A1/en not_active Ceased
- 2002-09-16 ES ES02775012T patent/ES2298398T3/es not_active Expired - Lifetime
- 2002-09-16 BR BRPI0212558-7A patent/BR0212558B1/pt not_active IP Right Cessation
- 2002-09-16 JP JP2003529851A patent/JP4203417B2/ja not_active Expired - Fee Related
- 2002-09-16 DE DE60224292T patent/DE60224292T2/de not_active Expired - Lifetime
-
2004
- 2004-02-18 ZA ZA200401289A patent/ZA200401289B/xx unknown
-
2005
- 2005-03-21 US US11/085,632 patent/US20050182163A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| ATE382073T1 (de) | 2008-01-15 |
| DE60224292T2 (de) | 2008-12-11 |
| CN1304484C (zh) | 2007-03-14 |
| CA2457759A1 (en) | 2003-03-27 |
| CA2457759C (en) | 2011-08-16 |
| EP1427784B1 (en) | 2007-12-26 |
| KR100696247B1 (ko) | 2007-03-20 |
| CN1555403A (zh) | 2004-12-15 |
| JP2005503466A (ja) | 2005-02-03 |
| BR0212558A (pt) | 2004-10-19 |
| HK1068014A1 (en) | 2005-04-22 |
| US6894085B2 (en) | 2005-05-17 |
| ZA200401289B (en) | 2004-07-19 |
| US20050182163A1 (en) | 2005-08-18 |
| ES2298398T3 (es) | 2008-05-16 |
| WO2003025067A1 (en) | 2003-03-27 |
| US20030129403A1 (en) | 2003-07-10 |
| EP1427784A1 (en) | 2004-06-16 |
| DE60224292D1 (de) | 2008-02-07 |
| BR0212558B1 (pt) | 2012-06-26 |
| KR20040062544A (ko) | 2004-07-07 |
| MXPA04002540A (es) | 2004-05-31 |
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