JP4073085B2 - サスペンジョン型シリコーン系粘着剤、その製造方法、および粘着性基材の製造方法 - Google Patents
サスペンジョン型シリコーン系粘着剤、その製造方法、および粘着性基材の製造方法 Download PDFInfo
- Publication number
- JP4073085B2 JP4073085B2 JP22028398A JP22028398A JP4073085B2 JP 4073085 B2 JP4073085 B2 JP 4073085B2 JP 22028398 A JP22028398 A JP 22028398A JP 22028398 A JP22028398 A JP 22028398A JP 4073085 B2 JP4073085 B2 JP 4073085B2
- Authority
- JP
- Japan
- Prior art keywords
- silicone gel
- silicone
- sensitive adhesive
- pressure
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000725 suspension Substances 0.000 title claims description 64
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- 239000000853 adhesive Substances 0.000 title claims description 18
- 230000001070 adhesive effect Effects 0.000 title claims description 18
- 239000013464 silicone adhesive Substances 0.000 title claims description 13
- 239000000758 substrate Substances 0.000 title description 23
- 229920001296 polysiloxane Polymers 0.000 claims description 204
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 76
- 239000000203 mixture Substances 0.000 claims description 60
- 239000007863 gel particle Substances 0.000 claims description 41
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 40
- 239000004094 surface-active agent Substances 0.000 claims description 34
- 239000002245 particle Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 13
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 12
- 239000010410 layer Substances 0.000 claims description 7
- -1 tertiary aliphatic amine salts Chemical class 0.000 description 61
- 239000000839 emulsion Substances 0.000 description 22
- 235000014113 dietary fatty acids Nutrition 0.000 description 17
- 239000000194 fatty acid Substances 0.000 description 17
- 229930195729 fatty acid Natural products 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 12
- 125000003342 alkenyl group Chemical group 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 description 10
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 10
- 229910052710 silicon Inorganic materials 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 125000005388 dimethylhydrogensiloxy group Chemical group 0.000 description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000007605 air drying Methods 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000011256 inorganic filler Substances 0.000 description 4
- 229910003475 inorganic filler Inorganic materials 0.000 description 4
- 229920000069 polyphenylene sulfide Polymers 0.000 description 4
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- 125000005023 xylyl group Chemical group 0.000 description 3
- 239000002888 zwitterionic surfactant Substances 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- BITPLIXHRASDQB-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane Chemical compound C=C[Si](C)(C)O[Si](C)(C)C=C BITPLIXHRASDQB-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 125000006038 hexenyl group Chemical group 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 238000007348 radical reaction Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 208000000474 Poliomyelitis Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RCNRJBWHLARWRP-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane;platinum Chemical compound [Pt].C=C[Si](C)(C)O[Si](C)(C)C=C RCNRJBWHLARWRP-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- FURYAADUZGZUGQ-UHFFFAOYSA-N phenoxybenzene;sulfuric acid Chemical compound OS(O)(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 FURYAADUZGZUGQ-UHFFFAOYSA-N 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22028398A JP4073085B2 (ja) | 1998-08-04 | 1998-08-04 | サスペンジョン型シリコーン系粘着剤、その製造方法、および粘着性基材の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22028398A JP4073085B2 (ja) | 1998-08-04 | 1998-08-04 | サスペンジョン型シリコーン系粘着剤、その製造方法、および粘着性基材の製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000044921A JP2000044921A (ja) | 2000-02-15 |
| JP2000044921A5 JP2000044921A5 (enExample) | 2005-10-20 |
| JP4073085B2 true JP4073085B2 (ja) | 2008-04-09 |
Family
ID=16748753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22028398A Expired - Fee Related JP4073085B2 (ja) | 1998-08-04 | 1998-08-04 | サスペンジョン型シリコーン系粘着剤、その製造方法、および粘着性基材の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4073085B2 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4783490B2 (ja) * | 2000-04-17 | 2011-09-28 | 東レ・ダウコーニング株式会社 | オルガノポリシロキサン組成物およびその製造方法 |
| JP4768902B2 (ja) * | 2000-04-17 | 2011-09-07 | 東レ・ダウコーニング株式会社 | オルガノポリシロキサン組成物およびその製造方法 |
| JP4718146B2 (ja) * | 2004-09-01 | 2011-07-06 | 株式会社Shindo | 多孔質シート用エマルション型シリコーン粘着剤組成物および再剥離性粘着シート |
| JP4505644B2 (ja) * | 2006-02-17 | 2010-07-21 | フジコピアン株式会社 | 固定シート |
| JP4505645B2 (ja) * | 2006-02-17 | 2010-07-21 | フジコピアン株式会社 | 固定シートの貼付方法 |
| JP4505646B2 (ja) * | 2006-02-20 | 2010-07-21 | フジコピアン株式会社 | 固定シート |
| JP4505649B2 (ja) * | 2006-03-23 | 2010-07-21 | フジコピアン株式会社 | 固定シート |
| EP3608383A4 (en) * | 2017-04-03 | 2020-12-30 | Dow Toray Co., Ltd. | CURING REACTIVE ORGANOPOLYSILOXANE RESIN, PRESSURE SENSITIVE ADHESIVE COMPOSITION USING AND USING IT |
| JP7046196B2 (ja) | 2018-08-10 | 2022-04-01 | ダウ・東レ株式会社 | 感圧接着層形成性オルガノポリシロキサン組成物およびその使用 |
| JP7046197B2 (ja) | 2018-08-10 | 2022-04-01 | ダウ・東レ株式会社 | 感圧接着層形成性オルガノポリシロキサン組成物およびその使用 |
| JP7246817B2 (ja) * | 2019-05-20 | 2023-03-28 | フジコピアン株式会社 | 紫外線吸収吸着フィルム |
-
1998
- 1998-08-04 JP JP22028398A patent/JP4073085B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000044921A (ja) | 2000-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8133586B2 (en) | Silicone microparticles comprising silicone elastomer spherical microparticles coated with polyorganosilsesquioxane, and method of producing same | |
| JP3824072B2 (ja) | プラスチックフィルム基材に密着良好なシリコーンエマルジョン組成物及び剥離フィルム | |
| EP0964023B1 (en) | Silicone oil emulsion, compositions, and method of manufacture | |
| JP5025024B2 (ja) | 離型用シリコーンエマルジョン組成物及びそれを用いてなる離型性基材 | |
| JP4073085B2 (ja) | サスペンジョン型シリコーン系粘着剤、その製造方法、および粘着性基材の製造方法 | |
| WO2002094938A2 (en) | Silicone composition and thermally conductive cured silicone product | |
| JP2008121012A (ja) | オルガノポリシロキサンの水性分散液の製造方法 | |
| TW201408732A (zh) | 加成硬化型聚矽氧乳膠組成物及剝離膜 | |
| KR20200067877A (ko) | 실리카 피복 실리콘 엘라스토머 구상 입자의 제조 방법 및 실리카 피복 실리콘 엘라스토머 구상 입자 | |
| CN105209550A (zh) | 固化性有机硅乳液组合物 | |
| JP7426283B2 (ja) | ポリエーテル／ポリシロキサン架橋ゴム球状粒子及びこれを製造する方法、並びにポリエーテル／ポリシロキサン架橋複合粒子及びこれを製造する方法 | |
| JP2008506006A (ja) | エマルション重合により生産される有機ポリシロキサン樹脂エマルション | |
| EP2478056A1 (en) | Cross-linkable silicone composition, emulsion thereof and method of manufactering | |
| JP2000204257A (ja) | シリコ―ン重合体組成物中で現場生成された樹脂―充填材およびそのシリコ―ン重合体組成物の製造法 | |
| CN110475808A (zh) | 有机硅粒子及其制造方法 | |
| JPH0655817B2 (ja) | アミノシリコーン微粒子エマルジョンの製造方法 | |
| JP6610370B2 (ja) | シリコーン粒子及びその製造方法 | |
| JP4761049B2 (ja) | エマルジョン型シリコーン粘着剤組成物 | |
| JP2732164B2 (ja) | シリコーン硬化物マイクロサスペンジョンの製造方法 | |
| EP2478038B1 (en) | Emulsion, its manufacturing method and silicone oil composition | |
| JP2006182936A (ja) | 水系コーティング剤組成物 | |
| JP3702942B2 (ja) | シリコーンエラストマー球状粉末ディスパージョン及びその製造方法 | |
| JP2000026724A (ja) | シリコーンゲルサスペンジョン、およびその製造方法 | |
| JPH0434575B2 (enExample) | ||
| TW202424111A (zh) | 矽酮橡膠粒子及矽酮橡膠粒子的水分散體 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050621 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050621 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20070830 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20070911 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20080108 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20080122 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110201 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120201 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120201 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130201 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130201 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140201 Year of fee payment: 6 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |