JP3918369B2

JP3918369B2 - ハロゲン化銀乳剤、ハロゲン化銀感光材料、熱現像感光材料及びこれを用いた画像記録方法及び画像形成方法、並びに熱現像感光材料の製造方法

ハロゲン化銀乳剤、ハロゲン化銀感光材料、熱現像感光材料及びこれを用いた画像記録方法及び画像形成方法、並びに熱現像感光材料の製造方法 Download PDF

Info

Publication number: JP3918369B2
Authority: JP; Japan
Prior art keywords: group; silver halide; photosensitive; atom; light
Prior art date: 1999-03-05
Legal status : Expired - Fee Related

Application number

JP19665999A

Other languages

English (en)

Japanese (ja)

Other versions

JP2000321704A (ja

Inventor

宣明香川

紀恭喜多

達夫田中

寛司柏木

Current Assignee

Konica Minolta Inc

Original Assignee

Konica Minolta Inc

Priority date

1999-03-05

Filing date

1999-07-09

Publication date

2007-05-23

1999-07-09 Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc

1999-07-09 Priority to JP19665999A priority Critical patent/JP3918369B2/ja

2000-02-28 Priority to US09/514,891 priority patent/US20020106593A1/en

2000-03-03 Priority to DE60017212T priority patent/DE60017212D1/de

2000-03-03 Priority to EP00301724A priority patent/EP1035430B1/en

2000-11-24 Publication of JP2000321704A publication Critical patent/JP2000321704A/ja

2002-04-10 Priority to US10/119,822 priority patent/US6677113B2/en

2007-05-23 Application granted granted Critical

2007-05-23 Publication of JP3918369B2 publication Critical patent/JP3918369B2/ja

2019-07-09 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

-1 Silver halide Chemical class 0.000 title claims description 314
229910052709 silver Inorganic materials 0.000 title claims description 194
239000004332 silver Substances 0.000 title claims description 194
239000000463 material Substances 0.000 title claims description 145
238000000034 method Methods 0.000 title claims description 94
239000000839 emulsion Substances 0.000 title claims description 73
238000004519 manufacturing process Methods 0.000 title description 19
150000001875 compounds Chemical class 0.000 claims description 122
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 50
239000000203 mixture Substances 0.000 claims description 32
125000000217 alkyl group Chemical group 0.000 claims description 30
150000002500 ions Chemical class 0.000 claims description 28
125000004429 atom Chemical group 0.000 claims description 23
125000003118 aryl group Chemical group 0.000 claims description 20
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 20
125000001424 substituent group Chemical group 0.000 claims description 19
150000002678 macrocyclic compounds Chemical class 0.000 claims description 17
125000000623 heterocyclic group Chemical group 0.000 claims description 16
125000005842 heteroatom Chemical group 0.000 claims description 15
125000003545 alkoxy group Chemical group 0.000 claims description 14
239000003638 chemical reducing agent Substances 0.000 claims description 14
229910052717 sulfur Inorganic materials 0.000 claims description 14
125000005843 halogen group Chemical group 0.000 claims description 12
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 11
229910052711 selenium Inorganic materials 0.000 claims description 11
125000001931 aliphatic group Chemical group 0.000 claims description 10
125000003277 amino group Chemical group 0.000 claims description 9
125000003710 aryl alkyl group Chemical group 0.000 claims description 9
125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 9
125000004434 sulfur atom Chemical group 0.000 claims description 9
125000000753 cycloalkyl group Chemical group 0.000 claims description 8
125000004430 oxygen atom Chemical group O* 0.000 claims description 8
125000004104 aryloxy group Chemical group 0.000 claims description 7
125000004414 alkyl thio group Chemical group 0.000 claims description 6
125000005110 aryl thio group Chemical group 0.000 claims description 6
239000010410 layer Substances 0.000 description 167
239000000975 dye Substances 0.000 description 107
239000000243 solution Substances 0.000 description 102
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 84
239000011248 coating agent Substances 0.000 description 55
238000000576 coating method Methods 0.000 description 55
230000035945 sensitivity Effects 0.000 description 52
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 36
239000002245 particle Substances 0.000 description 35
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
229910001868 water Inorganic materials 0.000 description 34
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 33
239000000523 sample Substances 0.000 description 30
238000002360 preparation method Methods 0.000 description 27
238000003860 storage Methods 0.000 description 25
239000000126 substance Substances 0.000 description 25
206010070834 Sensitisation Diseases 0.000 description 24
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
239000002253 acid Substances 0.000 description 24
230000008313 sensitization Effects 0.000 description 24
230000001235 sensitizing effect Effects 0.000 description 22
238000011161 development Methods 0.000 description 21
239000006224 matting agent Substances 0.000 description 20
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
239000002904 solvent Substances 0.000 description 19
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 18
239000000654 additive Substances 0.000 description 18
239000000460 chlorine Substances 0.000 description 18
229910052736 halogen Inorganic materials 0.000 description 18
LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical class C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 18
239000011230 binding agent Substances 0.000 description 17
230000015572 biosynthetic process Effects 0.000 description 17
230000000694 effects Effects 0.000 description 17
239000007864 aqueous solution Substances 0.000 description 16
238000006243 chemical reaction Methods 0.000 description 16
238000001035 drying Methods 0.000 description 16
239000011241 protective layer Substances 0.000 description 16
230000003595 spectral effect Effects 0.000 description 16
125000004432 carbon atom Chemical group C* 0.000 description 15
150000002367 halogens Chemical class 0.000 description 15
238000011160 research Methods 0.000 description 14
108010010803 Gelatin Proteins 0.000 description 13
239000003795 chemical substances by application Substances 0.000 description 13
239000008273 gelatin Substances 0.000 description 13
229920000159 gelatin Polymers 0.000 description 13
235000019322 gelatine Nutrition 0.000 description 13
235000011852 gelatine desserts Nutrition 0.000 description 13
238000002156 mixing Methods 0.000 description 13
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 13
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
150000007513 acids Chemical class 0.000 description 12
239000003960 organic solvent Substances 0.000 description 12
239000006185 dispersion Substances 0.000 description 11
238000010438 heat treatment Methods 0.000 description 11
229910052751 metal Inorganic materials 0.000 description 11
239000002184 metal Substances 0.000 description 11
238000003756 stirring Methods 0.000 description 11
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 10
XSCHRSMBECNVNS-UHFFFAOYSA-N benzopyrazine Natural products N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 10
235000019441 ethanol Nutrition 0.000 description 10
125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 10
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 10
238000003786 synthesis reaction Methods 0.000 description 10
238000010521 absorption reaction Methods 0.000 description 9
150000008064 anhydrides Chemical class 0.000 description 9
239000007788 liquid Substances 0.000 description 9
229910052757 nitrogen Inorganic materials 0.000 description 9
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 9
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
229910052782 aluminium Inorganic materials 0.000 description 8
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
239000013078 crystal Substances 0.000 description 8
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
238000011156 evaluation Methods 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
229920000642 polymer Polymers 0.000 description 8
238000012545 processing Methods 0.000 description 8
239000010948 rhodium Substances 0.000 description 8
150000003378 silver Chemical class 0.000 description 8
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 8
CWJJAFQCTXFSTA-UHFFFAOYSA-N 4-methylphthalic acid Chemical compound CC1=CC=C(C(O)=O)C(C(O)=O)=C1 CWJJAFQCTXFSTA-UHFFFAOYSA-N 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
230000008859 change Effects 0.000 description 7
238000001914 filtration Methods 0.000 description 7
150000004820 halides Chemical class 0.000 description 7
238000005259 measurement Methods 0.000 description 7
150000007524 organic acids Chemical class 0.000 description 7
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 7
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 7
230000005070 ripening Effects 0.000 description 7
238000005406 washing Methods 0.000 description 7
WZHHYIOUKQNLQM-UHFFFAOYSA-N 3,4,5,6-tetrachlorophthalic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(O)=O WZHHYIOUKQNLQM-UHFFFAOYSA-N 0.000 description 6
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
230000000996 additive effect Effects 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 6
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
229920006217 cellulose acetate butyrate Polymers 0.000 description 6
229910052801 chlorine Inorganic materials 0.000 description 6
238000009826 distribution Methods 0.000 description 6
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 6
VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 6
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
229910052740 iodine Inorganic materials 0.000 description 6
150000002736 metal compounds Chemical class 0.000 description 6
239000012046 mixed solvent Substances 0.000 description 6
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
230000008569 process Effects 0.000 description 6
230000002829 reductive effect Effects 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000011734 sodium Substances 0.000 description 6
229910052723 transition metal Inorganic materials 0.000 description 6
150000003624 transition metals Chemical class 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
239000012190 activator Substances 0.000 description 5
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 5
125000001309 chloro group Chemical group Cl* 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
150000002148 esters Chemical class 0.000 description 5
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 5
229910052731 fluorine Inorganic materials 0.000 description 5
125000001153 fluoro group Chemical group F* 0.000 description 5
230000006870 function Effects 0.000 description 5
239000003446 ligand Substances 0.000 description 5
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 5
125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 5
125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 5
229920000139 polyethylene terephthalate Polymers 0.000 description 5
239000005020 polyethylene terephthalate Substances 0.000 description 5
238000007639 printing Methods 0.000 description 5
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
230000009467 reduction Effects 0.000 description 5
238000006722 reduction reaction Methods 0.000 description 5
229910001961 silver nitrate Inorganic materials 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011593 sulfur Substances 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 5
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 4
125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 description 4
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
0 C*c(cc(*)cc1C(*)c2cc(*)cc(*C)c2O)c1O Chemical compound C*c(cc(*)cc1C(*)c2cc(*)cc(*C)c2O)c1O 0.000 description 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 4
150000001768 cations Chemical class 0.000 description 4
229920002301 cellulose acetate Polymers 0.000 description 4
239000000470 constituent Substances 0.000 description 4
230000006866 deterioration Effects 0.000 description 4
238000001125 extrusion Methods 0.000 description 4
238000004817 gas chromatography Methods 0.000 description 4
239000011630 iodine Substances 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
229910052753 mercury Inorganic materials 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
230000006911 nucleation Effects 0.000 description 4
238000010899 nucleation Methods 0.000 description 4
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 4
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 4
229920000515 polycarbonate Polymers 0.000 description 4
239000004417 polycarbonate Substances 0.000 description 4
229920000728 polyester Polymers 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
239000000047 product Substances 0.000 description 4
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
229910052703 rhodium Inorganic materials 0.000 description 4
239000011669 selenium Substances 0.000 description 4
239000004065 semiconductor Substances 0.000 description 4
238000001179 sorption measurement Methods 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
125000000547 substituted alkyl group Chemical group 0.000 description 4
125000003107 substituted aryl group Chemical group 0.000 description 4
KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 4
238000012360 testing method Methods 0.000 description 4
125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 3
AFBBKYQYNPNMAT-UHFFFAOYSA-N 1h-1,2,4-triazol-1-ium-3-thiolate Chemical compound SC=1N=CNN=1 AFBBKYQYNPNMAT-UHFFFAOYSA-N 0.000 description 3
AVRPFRMDMNDIDH-UHFFFAOYSA-N 1h-quinazolin-2-one Chemical class C1=CC=CC2=NC(O)=NC=C21 AVRPFRMDMNDIDH-UHFFFAOYSA-N 0.000 description 3
PWPPYWWWEVISEX-UHFFFAOYSA-N 2,7-dimethoxy-1,4,5,8-tetrahydronaphthalene Chemical compound C1C(OC)=CCC2=C1CC(OC)=CC2 PWPPYWWWEVISEX-UHFFFAOYSA-N 0.000 description 3
125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 description 3
125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 description 3
125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 description 3
125000006275 3-bromophenyl group Chemical group [H]C1=C([H])C(Br)=C([H])C(*)=C1[H] 0.000 description 3
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
235000021357 Behenic acid Nutrition 0.000 description 3
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
229930185605 Bisphenol Natural products 0.000 description 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
229920002284 Cellulose triacetate Polymers 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
206010034972 Photosensitivity reaction Diseases 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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