JP3459919B2 - ポスト・コンスーマポリエチレンテレフタレート供給物流から異物を除去する方法 - Google Patents

ポスト・コンスーマポリエチレンテレフタレート供給物流から異物を除去する方法

Info

Publication number
JP3459919B2
JP3459919B2 JP51706193A JP51706193A JP3459919B2 JP 3459919 B2 JP3459919 B2 JP 3459919B2 JP 51706193 A JP51706193 A JP 51706193A JP 51706193 A JP51706193 A JP 51706193A JP 3459919 B2 JP3459919 B2 JP 3459919B2
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JP
Japan
Prior art keywords
liquid
poise
polyethylene terephthalate
pet
foreign matter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP51706193A
Other languages
English (en)
Japanese (ja)
Other versions
JPH07505424A (ja
Inventor
バーケツト，ユージン・ジヨン
ジエンクス，ランデイ・スー
Original Assignee
エム・アンド・ジー・ポリメリ・イタリア・エッセ・ピー・アー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by エム・アンド・ジー・ポリメリ・イタリア・エッセ・ピー・アー filed Critical エム・アンド・ジー・ポリメリ・イタリア・エッセ・ピー・アー
Publication of JPH07505424A publication Critical patent/JPH07505424A/ja
Application granted granted Critical
Publication of JP3459919B2 publication Critical patent/JP3459919B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
    • C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/88—Post-polymerisation treatment
    • C08G63/90—Purification; Drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B5/00—Washing granular, powdered or lumpy materials; Wet separating
    • B03B5/28—Washing granular, powdered or lumpy materials; Wet separating by sink-float separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
    • B29B13/022—Melting the material to be shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00168—Controlling or regulating processes controlling the viscosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00171—Controlling or regulating processes controlling the density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/0077—Baffles attached to the reactor wall inclined
    • B01J2219/00772—Baffles attached to the reactor wall inclined in a helix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0203—Separating plastics from plastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0217—Mechanical separating techniques; devices therefor
    • B29B2017/0237—Mechanical separating techniques; devices therefor using density difference
    • B29B2017/0244—Mechanical separating techniques; devices therefor using density difference in liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0255—Specific separating techniques using different melting or softening temperatures of the materials to be separated
    • B29B2017/0258—Specific separating techniques using different melting or softening temperatures of the materials to be separated using heated surfaces for selective softening or melting of at least one plastic ingredient
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/065—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts containing impurities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • B29L2031/7158—Bottles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Thermal Sciences (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Processing Of Solid Wastes (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP51706193A 1992-03-31 1993-03-24 ポスト・コンスーマポリエチレンテレフタレート供給物流から異物を除去する方法 Expired - Fee Related JP3459919B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/860,963 US5223544A (en) 1992-03-31 1992-03-31 Process for the removal of foreign materials from a post-consumer plyethylene terephthalate feed stream
US860,963 1992-03-31
PCT/EP1993/000737 WO1993020125A2 (en) 1992-03-31 1993-03-24 Process for the removal of foreign materials from a post-consumer polyethylene terephthalate feed stream

Publications (2)

Publication Number Publication Date
JPH07505424A JPH07505424A (ja) 1995-06-15
JP3459919B2 true JP3459919B2 (ja) 2003-10-27

Family

ID=25334501

Family Applications (1)

Application Number Title Priority Date Filing Date
JP51706193A Expired - Fee Related JP3459919B2 (ja) 1992-03-31 1993-03-24 ポスト・コンスーマポリエチレンテレフタレート供給物流から異物を除去する方法

Country Status (11)

Country Link
US (1) US5223544A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0637326B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP3459919B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR100245206B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU671109B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR9306156A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2133214C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69329279T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2149810T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW237463B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO1993020125A2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

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US5602187A (en) * 1992-05-18 1997-02-11 Swig Pty Ltd. Polyethylene terephthalate decontamination
US5504121A (en) * 1992-05-18 1996-04-02 Swig Pty Ltd. Polyethylene terephthalate decontamination
ATE192136T1 (de) * 1993-07-05 2000-05-15 Du Pont Herstellung von dicarbonsäuren
DE4410672C2 (de) * 1994-03-26 1996-04-04 Christian O Schoen Verfahren zur Wiederverwertung von Kunststoff
DE4417721A1 (de) * 1994-05-20 1995-11-23 Veba Oel Ag Vorrichtung zur Depolymerisation von Alt- und Abfallkunststoffen
DE4428355A1 (de) * 1994-05-20 1996-02-15 Veba Oel Ag Vorrichtung zur Depolymerisation von Alt- und Abfallkunststoffen
US5468780A (en) * 1994-06-21 1995-11-21 Miyaso Chemical Co. Method of recycling unsaturated polyester resin waste
US5559159A (en) * 1995-12-07 1996-09-24 Eastman Chemical Company Process including depolymerization in polyester reactor for recycling polyester materials
US6284808B1 (en) * 1997-02-03 2001-09-04 Illinois Tool Works Inc. Inline solid state polymerization of PET flakes for manufacturing plastic strap by removing non-crystalline materials from recycled PET
US5945460A (en) * 1997-03-20 1999-08-31 Eastman Chemical Company Process for continuously producing polyester articles with scrap recycle in a continuous melt-to-preform process
JP3715812B2 (ja) * 1998-12-10 2005-11-16 株式会社アイエス ポリエチレンテレフタレート廃棄物のケミカルリサイクル方法
US6410607B1 (en) * 1999-02-10 2002-06-25 Eastman Chemical Company Glycolysis process for recycling of post-consumer pet
US7666368B2 (en) * 2002-09-27 2010-02-23 Meishin Kogyo Kabushikigaisha Apparatus for treating volume-reduced polystyrene resin in gel state for material separation and recovery
TWI311572B (en) * 2002-09-27 2009-07-01 Shigenobu Haman Apparatus for treating volume-reduced polystyrene resin in gel state for material separation and recovery
US7297721B2 (en) * 2003-06-20 2007-11-20 Futura Polyesters Limited Process for controlled polymerization of a mixed polymer
ITTP20030002A1 (it) * 2003-10-09 2005-04-10 Giovanni Maurizio Di Processo ossidoriduzione per riciclare qualsiasi frazione rifiuto:fanghi, scarti industriali, agroalimentari, macellazione, ittici, ecc. in biostabilizzato sterile e/o polixano espanso isolante termoacustico, in innovativo impianto mobile o fisso con
JP2005131856A (ja) * 2003-10-29 2005-05-26 Teijin Fibers Ltd 脂肪族ポリエステルから異素材を除去する方法
JP2005132901A (ja) * 2003-10-29 2005-05-26 Teijin Fibers Ltd 脂肪族ポリエステルから異素材を除去する方法
WO2010137756A1 (en) * 2009-05-28 2010-12-02 Byung Kyoo Park Method and apparatus for recycling thermoplastic resin from a resin mixture
US9458354B2 (en) 2010-10-06 2016-10-04 Resinate Technologies, Inc. Polyurethane dispersions and methods of making and using same
US20120279023A1 (en) * 2011-05-06 2012-11-08 Avery Dennison Corporation Plastic Fastening Device Comprising a Recycled Thermoplastic Resin
EP2718383A4 (en) 2011-06-10 2015-05-20 Kristopher M Felice CLEAR VARNISH, ACRYLIC COATINGS
TWI576367B (zh) * 2012-08-29 2017-04-01 東洋紡股份有限公司 熱收縮性聚酯系薄膜
US9732026B2 (en) 2012-12-14 2017-08-15 Resinate Technologies, Inc. Reaction products containing hydroxyalkylterephthalates and methods of making and using same
KR102090218B1 (ko) * 2018-05-23 2020-03-17 주식회사 포스코 탕도
US20220372217A1 (en) 2019-10-08 2022-11-24 Eastman Chemical Company Catalyst systems for crystallizable reactor grade resins with recycled content
JP7698637B2 (ja) 2019-10-25 2025-06-25 イーストマン ケミカル カンパニー 再資源化物を有する反応器級樹脂から製造される結晶化可能な収縮性フィルムならびに熱成形性フィルムおよびシート
NL2024181B1 (en) * 2019-11-07 2021-07-20 Ioniqa Tech B V Reactor system and method of separating a first contaminant from a feed stream
US12013191B2 (en) * 2020-10-20 2024-06-18 Katz Water Tech, Llc Coiled spring
CN113351140B (zh) * 2021-06-23 2022-10-18 山东佳星环保科技有限公司 高分散全混流反应釜
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US4542239A (en) * 1981-11-18 1985-09-17 Board Of Control Of Michigan Technological University Process for recovering terephthalic acid from waste polyethylene terephthalate
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US4746422A (en) * 1985-07-26 1988-05-24 Rutgers University Method for the separation of a mixture of plastic and contaminant
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Also Published As

Publication number Publication date
TW237463B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1995-01-01
KR950700954A (ko) 1995-02-20
DE69329279T2 (de) 2001-04-26
KR100245206B1 (ko) 2000-02-15
AU3752493A (en) 1993-11-08
BR9306156A (pt) 1998-06-23
JPH07505424A (ja) 1995-06-15
CA2133214A1 (en) 1993-10-14
ES2149810T3 (es) 2000-11-16
EP0637326B1 (en) 2000-08-23
WO1993020125A2 (en) 1993-10-14
AU671109B2 (en) 1996-08-15
US5223544A (en) 1993-06-29
CA2133214C (en) 2003-10-14
EP0637326A1 (en) 1995-02-08
WO1993020125A3 (en) 1994-04-14
DE69329279D1 (de) 2000-09-28

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