JP3282149B2 - 肥料添加剤濃厚物用改良配合物 - Google Patents
肥料添加剤濃厚物用改良配合物Info
- Publication number
- JP3282149B2 JP3282149B2 JP52283297A JP52283297A JP3282149B2 JP 3282149 B2 JP3282149 B2 JP 3282149B2 JP 52283297 A JP52283297 A JP 52283297A JP 52283297 A JP52283297 A JP 52283297A JP 3282149 B2 JP3282149 B2 JP 3282149B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- solution
- group
- triamide
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 239000012528 membrane Substances 0.000 description 1
- DSKJXGYAJJHDOE-UHFFFAOYSA-N methylideneurea Chemical compound NC(=O)N=C DSKJXGYAJJHDOE-UHFFFAOYSA-N 0.000 description 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 description 1
- ZWDZJRRQSXLOQR-UHFFFAOYSA-N n-butyl-n-phenylacetamide Chemical compound CCCCN(C(C)=O)C1=CC=CC=C1 ZWDZJRRQSXLOQR-UHFFFAOYSA-N 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- YOEZZCLQJVMZGY-UHFFFAOYSA-N octane-4,5-diol Chemical compound CCCC(O)C(O)CCC YOEZZCLQJVMZGY-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- GTCCGKPBSJZVRZ-UHFFFAOYSA-N pentane-2,4-diol Chemical compound CC(O)CC(C)O GTCCGKPBSJZVRZ-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 229950006800 prenderol Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- OJTDGPLHRSZIAV-UHFFFAOYSA-N propane-1,2-diol Chemical compound CC(O)CO.CC(O)CO OJTDGPLHRSZIAV-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000013094 purity test Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000031068 symbiosis, encompassing mutualism through parasitism Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S71/00—Chemistry: fertilizers
- Y10S71/902—Nitrification inhibition
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/575,025 US5698003A (en) | 1995-12-19 | 1995-12-19 | Formulation for fertilizer additive concentrate |
| US08/575,025 | 1995-12-19 | ||
| PCT/US1996/019223 WO1997022568A1 (en) | 1995-12-19 | 1996-12-10 | Improved formulation for fertilizer additive concentrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000502037A JP2000502037A (ja) | 2000-02-22 |
| JP3282149B2 true JP3282149B2 (ja) | 2002-05-13 |
Family
ID=24298625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52283297A Expired - Fee Related JP3282149B2 (ja) | 1995-12-19 | 1996-12-10 | 肥料添加剤濃厚物用改良配合物 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5698003A (enEXAMPLES) |
| EP (1) | EP0869933B1 (enEXAMPLES) |
| JP (1) | JP3282149B2 (enEXAMPLES) |
| KR (1) | KR100419454B1 (enEXAMPLES) |
| CN (1) | CN1163442C (enEXAMPLES) |
| AR (1) | AR005137A1 (enEXAMPLES) |
| AU (1) | AU708702B2 (enEXAMPLES) |
| BR (1) | BR9612034A (enEXAMPLES) |
| CA (1) | CA2240284C (enEXAMPLES) |
| DE (1) | DE69637957D1 (enEXAMPLES) |
| ES (1) | ES2329201T3 (enEXAMPLES) |
| IN (1) | IN186192B (enEXAMPLES) |
| NZ (1) | NZ324974A (enEXAMPLES) |
| WO (1) | WO1997022568A1 (enEXAMPLES) |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6030659A (en) * | 1998-05-28 | 2000-02-29 | Whitehurst Associates, Inc. | Phosphate coated urea |
| JP2002104893A (ja) * | 2000-09-27 | 2002-04-10 | Chisso Corp | 被覆粒状物およびそれを用いた作物の栽培方法 |
| US20030145639A1 (en) * | 2001-04-12 | 2003-08-07 | Secretary Of Army | Efficient fertilizer and enzyme-assisted method of production |
| NZ511606A (en) * | 2001-05-09 | 2002-11-26 | Summit Quinphos Nz Ltd | Fertiliser compositions comprising urea granules coated with wet ground sulphur |
| GB0503152D0 (en) * | 2005-02-16 | 2005-03-23 | Ciba Sc Holding Ag | Foliar feed compositions,their preparations and use |
| US7494525B2 (en) * | 2005-02-22 | 2009-02-24 | Tessenderlo Kerley, Inc. | Calcium polysulfide, potassium polysulfide, calcium thiosulfate, and magnesium thiosulfate as urease inhibitors |
| WO2007087180A2 (en) * | 2006-01-12 | 2007-08-02 | Agrotain International, L.L.C. | Additive containing n-(n-butyl) thiophosphoric triamide for urea-based fertilizer |
| EP1820788A1 (de) * | 2006-02-16 | 2007-08-22 | BASF Aktiengesellschaft | Zubereitungen mit verbesserter Urease-hemmender Wirkung und diese enthaltende harnstoffhaltige Düngemittel |
| US8419819B2 (en) | 2006-06-23 | 2013-04-16 | Koch Agronomic Services, Llc | Solid urea fertilizer |
| CZ301509B6 (cs) | 2006-06-28 | 2010-03-31 | Agra Group, A. S. | Rozpouštedlová soustava pro prípravu roztoku N-alkyltriamidu kyseliny thiofosforecné, kompozice s obsahem N-alkyltriamidu kyseliny thiofosforecné a její použití |
| MX2009001482A (es) * | 2006-08-24 | 2009-02-18 | Basf Se | Uso de triamidas fosforicas en inodoros. |
| WO2008022925A1 (de) * | 2006-08-24 | 2008-02-28 | Basf Se | Verwendung von phosphorsäuretriamiden in reiniger- und hygieneanwendungen |
| US7666241B2 (en) * | 2007-01-24 | 2010-02-23 | Specialty Fertilizer Products, Llc | Fertilizer-polymer mixtures which inhibit nitrification in soils |
| FR2925826B1 (fr) * | 2007-12-31 | 2010-01-29 | Agrofinance Internationale | Composition inhibitrice d'urease et de nitrification |
| US7771505B2 (en) * | 2008-07-16 | 2010-08-10 | Agrium Inc. | Controlled release fertilizer composition |
| CZ2008842A3 (cs) | 2008-12-23 | 2010-06-30 | Agra Group, A. S. | Kapalná kompizice s obsahem derivátu triamidu kyseliny fosforecné nebo thifosforecné a její použití |
| US20100206031A1 (en) * | 2009-02-17 | 2010-08-19 | Whitehurst Associates, Inc. | Amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors |
| US8048189B2 (en) * | 2009-02-17 | 2011-11-01 | Whitehurst Associates Inc. | Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors |
| GB0913760D0 (en) * | 2009-08-06 | 2009-09-16 | Rothamsted Res Ltd | A method of reducing nitrate leaching from soil |
| CN104093681B (zh) * | 2011-11-14 | 2016-11-09 | 茵斯泰克中心有限公司 | 尿素酶抑制剂制剂 |
| US10173935B2 (en) * | 2011-12-12 | 2019-01-08 | Rhodia Operations | Solvent systems of N-alkyl thiophosphoric triamides and methods of use in agricultural applications |
| MX365580B (es) * | 2011-12-12 | 2019-06-07 | Rhodia Operations | Sistemas de solvente de triamidas n-alquil tiofosforicas y metodos de uso en aplicaciones agricolas. |
| JP2015513452A (ja) * | 2012-02-14 | 2015-05-14 | アルベマール・コーポレーシヨン | 活性成分とともに押出された担体を含む粉末を製造するためのプロセス |
| AR092147A1 (es) | 2012-08-15 | 2015-03-25 | Koch Agronomic Services Llc | Composiciones liquidas mejoradas que contienen inhibidores de ureasa y alcoholes aril alquilicos y metodos de elaboracion y uso de las mismas |
| US9682894B2 (en) | 2012-08-15 | 2017-06-20 | Koch Agronomic Services, Llc | Compositions of urea formaldehyde particles and methods of making thereof |
| BR112015003093A8 (pt) | 2012-08-15 | 2019-07-30 | Koch Agronomic Services Llc | composições melhoradas de partículas substancialmente esféricas |
| CN110436998A (zh) * | 2012-08-15 | 2019-11-12 | 科氏农艺服务有限责任公司 | 含有脲酶抑制剂和二醇烷基醚的改善的组合物及肥料组合物 |
| WO2014028715A1 (en) * | 2012-08-16 | 2014-02-20 | Helena Holding Company | Solvent free n-alkyl thiosphoric triamide formulations |
| WO2014036278A1 (en) * | 2012-08-31 | 2014-03-06 | Helena Holding Company | Stabilized n-alkyl thiosphoric triamide solvent systems for use in nitrogen fertilizer |
| US20210380496A1 (en) * | 2012-10-01 | 2021-12-09 | World Source Enterprises, Llc | Liquid Formulations of Urease Inhibitors for Fertilizers |
| JP6126227B2 (ja) | 2012-10-01 | 2017-05-10 | ギャリー デイヴィッド マクナイト | 肥料用のウレアーゼ阻害剤の改善された液体製剤 |
| US9266789B2 (en) * | 2012-12-20 | 2016-02-23 | Rhodia Operations | Liquid dicyandiamide and/or alkyl thiophosphoric triamide compositions and their use in agricultural applications |
| US9174885B2 (en) | 2013-03-15 | 2015-11-03 | University Of Kentucky Research Foundation | Nitrogen fertilizer composition and method to improve detection and lessen the explosive potential of nitrogen-based fertilizers |
| DE102013012760B4 (de) | 2013-03-27 | 2023-07-06 | Dreiturm GmbH | Zusammensetzungen, enthaltend einen dispergierten Ureaseinhibitor, und deren Verwendung zur Behandlung von harnstoffbasierten Düngemitteln |
| ES2529363B1 (es) * | 2013-06-06 | 2016-01-18 | Universidad Pública de Navarra | Inhibidores de la ureasa capaces de disminuir el contenido de nitratos en hortalizas |
| RU2656416C2 (ru) | 2013-07-04 | 2018-06-05 | Басф Се | Композиции с улучшенным ингибирующим уреазу действием, содержащие триамид (тио)фосфорной кислоты и другие соединения |
| WO2015001391A1 (en) * | 2013-07-04 | 2015-01-08 | Basf Se | Compositions with improved urease-inhibiting effect comprising (thio)phosphoric acid triamide and further compounds |
| US8888886B1 (en) | 2013-08-06 | 2014-11-18 | Garnett B Whitehurst | NBPT solutions for preparing urease inhibited urea fertilizers prepared from N-substituted morpholines |
| MX353366B (es) | 2013-08-23 | 2018-01-10 | Koch Agronomic Services Llc | Composiciones estabilizadoras de urea y nitrógeno. |
| RU2665619C1 (ru) | 2013-11-26 | 2018-09-03 | Гэри Дэвид МАКНАЙТ | Ингибиторы нитрификации, разработанные для удобрений на основе мочевины и навоза |
| DE202014003261U1 (de) | 2014-04-16 | 2014-05-21 | Skw Stickstoffwerke Piesteritz Gmbh | Flüssige Zusammensetzungen, enthaltend einen Ureaseinhibitor, und deren Verwendung zur Behandlung von harnstoffbasierten Düngemitteln |
| WO2015161195A1 (en) | 2014-04-17 | 2015-10-22 | Mcknight Gary David | Compositions and methods comprising ntrification inhibitors containing a mixture of protic and aprotic solvent systems |
| KR20170062506A (ko) | 2014-09-30 | 2017-06-07 | 로디아 오퍼레이션스 | 티오인산 트리아미드 또는 디시안디아미드 용액을 위한 용매, 및 관련 방법 |
| CN119431081A (zh) | 2014-10-21 | 2025-02-14 | 法国特种经营公司 | 用于双氰胺和/或烷基硫代磷酰三胺的改进的溶剂体系以及在农业应用中的用途 |
| CA2964960A1 (en) | 2014-10-31 | 2016-05-06 | Koch Agronomic Services, Llc | Nitrification inhibitor compositions and methods of making thereof |
| CA2889430C (en) * | 2014-12-04 | 2016-09-13 | Active AgriProducts Inc. | Compositions and methods for reducing nitrogen volatilization of urea fertilizers |
| US10183897B2 (en) | 2014-12-04 | 2019-01-22 | Active Agriscience Inc. | Compositions and methods for reducing nitrogen volatilization of urea fertilizers |
| HUE070668T2 (hu) | 2014-12-23 | 2025-06-28 | Basf Se | (Tio)foszforsav-triamidot és további vegyületeket, például aminokat tartalmazó javított ureázgátló hatású készítmények |
| US20180044254A1 (en) | 2015-02-24 | 2018-02-15 | Koch Agronomic Services, Llc | Granular Urea Fertilizer with Nitrogen Stabilizer Additives |
| WO2016174648A1 (pt) * | 2015-04-30 | 2016-11-03 | Universidade Federal De Minas Gerais - Ufmg | Pérolas de ureia combinadas com aldiminas, processo de obtenção e usos na agricultura, e aplicações das aldiminas no tratamento de infecções bacterianas |
| AU2016270813B2 (en) | 2015-06-02 | 2018-02-15 | Koch Agronomic Services, Llc | Microbial inoculant compositions and uses thereof in agriculture |
| BR112017023290B1 (pt) * | 2015-07-13 | 2022-03-15 | Koch Agronomic Services, Llc | Composição altamente concentrada de triamida tiofosfórica ou fosfórica, método e fertilizante à base de ureia que compreende a dita composição e método para produção da composição altamente concentrada de nbpt |
| US9725372B2 (en) | 2015-07-24 | 2017-08-08 | Koch Agronomic Services, Llc | Composition containing N-(N-butyl) thiophosphoric triamide adducts and reaction products |
| KR20180031771A (ko) | 2015-08-17 | 2018-03-28 | 로디아 오퍼레이션스 | 고온 아민-안정화된 dcd 및/또는 알킬 티오인산 트리아미드 용매계 및 농업 적용에 있어서의 용도 |
| ES2803749T3 (es) | 2015-10-19 | 2021-01-29 | Dow Global Technologies Llc | Composición estabilizadora de fertilizante que comprende un aceite aromático de bajo contenido en COV y poco olor |
| WO2017083714A1 (en) | 2015-11-11 | 2017-05-18 | Koch Agronomic Services, Llc | Composition containing n-(n-butyl) thiophosphoric triamide adducts and reaction products |
| FR3045037A1 (fr) | 2015-12-11 | 2017-06-16 | Koch Agronomic Services Llc | Compositions d'engrais contenant un inhibiteur d'urease resistant aux acides |
| EP3210959A1 (en) | 2016-02-24 | 2017-08-30 | YARA International ASA | Liquid urease inhibitor formulation, method of manufacturing and solid particulates comprising it |
| EP3436416B1 (en) | 2016-04-01 | 2024-01-24 | Basf Se | Use of a cation source to prevent decomposition of (thio)phosphoric acid triamide urease inhibitors when a phosphorus-containing fertilizer is present |
| WO2017184810A1 (en) | 2016-04-21 | 2017-10-26 | Koch Agronomic Services, Llc | Microbial inoculant compositions and uses thereof |
| MX2018014351A (es) | 2016-06-18 | 2019-03-14 | Milliken & Co | Composiciones adecuadas para usarse en la preparacion de fertilizantes, metodos para preparar dichas composiciones, y metodos para preparar fertilizantes usando las mismas. |
| WO2018007426A1 (en) | 2016-07-05 | 2018-01-11 | Rhodia Operations | Composition containing a urease inhibitor |
| MX2019008545A (es) | 2017-01-19 | 2019-09-11 | Koch Agronomic Services Llc | Estabilidad mejorada de composiciones que contienen inhibidor de la ureasa. |
| CN110072830A (zh) | 2017-01-20 | 2019-07-30 | 科氏农艺服务有限责任公司 | 包含n-(正丁基)硫代磷酰三胺加合物和反应产物的组合物 |
| BR112019014982A2 (pt) | 2017-01-20 | 2020-04-28 | Koch Agronomic Services Llc | composições de fertilizante contendo aduto de inibidor de urease resistentes a ácido |
| US11352303B2 (en) | 2017-02-15 | 2022-06-07 | World Source Enterprises, Llc | Compositions and methods for coating of nitrification inhibitors with a solution containing a high concentration of urease inhibitors |
| US12139443B2 (en) | 2017-02-15 | 2024-11-12 | Soilgenic Technologies, Llc | Concentrated liquid compositions of urease inhibitors for nitrogen sources |
| EP3585759B1 (en) * | 2017-02-24 | 2022-01-12 | Yara International ASA | Liquid urease inhibitor formulations |
| EP3652133A4 (en) | 2017-07-10 | 2021-04-21 | Basf Se | MIXTURES WITH A UREA INHIBITOR (UI) AND A NITRIFICATION INHIBITOR SUCH AS 2- (3,4-DIMETHYL-1H-PYRAZOL-1-YL) SUCCIC ACID (DMPSA) OR 3,4-DIMETHYLPYRAZOLYL GLYCOLATE (DMPG) |
| AU2019223390A1 (en) * | 2018-02-26 | 2020-10-29 | Anish Mahendrabhai AMIN | An additive for soil conditioning and an agricultural composition containing said additive for plant growth |
| US11866383B1 (en) | 2018-04-04 | 2024-01-09 | Synsus Private Label Partners, Llc | Nitrification inhibiting compositions and their use in agricultural applications |
| WO2019204163A1 (en) | 2018-04-20 | 2019-10-24 | Tessenderlo Kerley, Inc. | Liquid nitrogen fertilizer compositions and additives therefore |
| EP3575278A1 (en) | 2018-05-31 | 2019-12-04 | Tessenderlo Kerley, Inc. | Liquid nitrogen fertilizer compositions and additives therefor |
| DE102018208770A1 (de) | 2018-06-04 | 2019-12-05 | Eurochem Agro Gmbh | Emulsion zur Behandlung von harnstoffhaltigen Düngemitteln |
| US20200022372A1 (en) | 2018-07-19 | 2020-01-23 | Koch Agronomic Services, Llc | Low temperature stable formulations of urease inhibitor-containing compositions |
| US11124462B1 (en) | 2018-08-27 | 2021-09-21 | Hocking International Laboratories, LLC | Compositions and their use in agricultural applications |
| KR102534716B1 (ko) * | 2018-09-14 | 2023-05-18 | 주식회사 엘지화학 | 용출제어형 비료를 위한 광분해성 캡슐 및 이를 포함하는 용출제어형 비료 |
| BR112021016174A2 (pt) * | 2019-02-22 | 2021-10-05 | Verdesian Life Sciences U.S., Llc | Combinação de ácido piroglutâmico e um inibidor de urease para efeitos melhorados em saúde de planta |
| EP3725756A2 (en) | 2019-04-18 | 2020-10-21 | Basf Se | Compositions with improved urease-inhibiting effect comprising amines, or colorants, and an adduct of the three compounds n-(n-butyl) thiophosphoric acid triamide (nbpt), urea, and formaldehyde |
| EP3725755A2 (en) | 2019-04-18 | 2020-10-21 | Basf Se | Compositions with improved urease-inhibiting effect comprising aromatic alcohols, or amines, or amides, and an adduct of the three compounds n-(n-butyl) thiophosphoric acid triamide (nbpt), urea, and formaldehyde |
| ES2987188T3 (es) | 2020-01-15 | 2024-11-14 | Grupa Azoty S A | Composiciones disolventes líquidas que contienen triamida N-(n-butil)tiofosfórica (NBPT) y su uso como un aditivo para fertilizantes que contienen nitrógeno amídico |
| PT3851426T (pt) | 2020-01-15 | 2024-01-12 | Grupa Azoty S A | Composições líquidas contendo triamida n-(n-butil)tiofosfórica (nbpt) e sua utilização como aditivo em fertilizantes contendo azoto de amida |
| US12098109B2 (en) | 2021-03-15 | 2024-09-24 | Soilgenic Technologies, Llc | Reaction methods for producing nitrogenous phosphoryl compounds that are in situ fluid compositions |
| DE102021108187A1 (de) | 2021-03-31 | 2022-10-06 | Skw Stickstoffwerke Piesteritz Gmbh | Granuliertes pH-neutrales Harnstoff-Ammoniumsulfat-Düngemittel mit Ureaseinhibitor |
| CN114230415B (zh) * | 2021-11-06 | 2022-06-24 | 中国科学院南京土壤研究所 | 1,9-癸二醇在延缓尿素水解中的应用 |
| CN114230416B (zh) * | 2021-11-06 | 2022-06-24 | 中国科学院南京土壤研究所 | 1,9-癸二醇在抑制土壤氨挥发中的应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5256181A (en) | 1991-03-28 | 1993-10-26 | Exxon Research And Engineering Company | Coatings with ionically and covalently crosslinked sulfonated polymers |
| US5352265A (en) | 1993-11-12 | 1994-10-04 | Freeport-Mcmoran Resource Partners, Limited Partnership | Granular urea-based fertilizer |
| US5364438A (en) | 1993-11-12 | 1994-11-15 | Freeport-Mcmoran Resource Partners, Limited Partnership | Fluid urea-containing fertilizer |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1092880B (de) * | 1958-03-27 | 1960-11-17 | Hoechst Ag | Verfahren zum Fixieren von Pigmenten auf Fasermaterial und Flaechengebilden |
| US3462256A (en) * | 1966-10-31 | 1969-08-19 | Allied Chem | Process for producing urea-formaledhyde aqueous concentrates |
| US3576613A (en) * | 1967-07-24 | 1971-04-27 | Thiokol Chemical Corp | Sulfur encapsulation of fertilizers to provide controlled dissolution rates |
| IL47144A (en) * | 1975-04-22 | 1978-06-15 | Chem & Phosphates Ltd | Fertilizer compound the ureaform type and a method for the production thereof |
| US4240923A (en) * | 1978-05-30 | 1980-12-23 | Exxon Research & Engineering Co. | Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures |
| JPS5510626A (en) * | 1978-07-07 | 1980-01-25 | Toshiba Corp | General controller |
| US4530714A (en) * | 1983-03-16 | 1985-07-23 | Allied Corporation | N-aliphatic and N,N-aliphatic phosphoric triamide urease inhibitors and urease inhibited urea based fertilizer compositions |
| US4518413A (en) * | 1983-06-06 | 1985-05-21 | Allied Corporation | Poly-phosphorodiamide urease inhibitors and urease inhibited urea based fertilizer compositions |
| USH25H (en) * | 1985-06-17 | 1986-02-04 | Tennessee Valley Authority | Thiophosphoryl triamide as a urease inhibitor |
| US4676822A (en) * | 1986-07-24 | 1987-06-30 | Tennessee Valley Authority | Fluid fertilizers containing thiophosphoryl triamide |
| US5160528A (en) * | 1989-12-11 | 1992-11-03 | Isp Investments Inc. | Delivery system for agricultural chemicals |
| US5071463A (en) * | 1989-12-11 | 1991-12-10 | Isp Investments Inc. | Delivery system for agricultural chemicals |
| US5188654A (en) * | 1991-03-28 | 1993-02-23 | Exxon Research And Engineering Company | Coatings with ionically and covalently crosslinked neutralized carboxylated polymers |
-
1995
- 1995-12-19 US US08/575,025 patent/US5698003A/en not_active Expired - Lifetime
-
1996
- 1996-12-10 NZ NZ324974A patent/NZ324974A/xx not_active IP Right Cessation
- 1996-12-10 ES ES96943561T patent/ES2329201T3/es not_active Expired - Lifetime
- 1996-12-10 KR KR10-1998-0704111A patent/KR100419454B1/ko not_active Expired - Fee Related
- 1996-12-10 AU AU12775/97A patent/AU708702B2/en not_active Expired
- 1996-12-10 EP EP96943561A patent/EP0869933B1/en not_active Expired - Lifetime
- 1996-12-10 WO PCT/US1996/019223 patent/WO1997022568A1/en active IP Right Grant
- 1996-12-10 JP JP52283297A patent/JP3282149B2/ja not_active Expired - Fee Related
- 1996-12-10 CN CNB961990015A patent/CN1163442C/zh not_active Expired - Lifetime
- 1996-12-10 DE DE69637957T patent/DE69637957D1/de not_active Expired - Lifetime
- 1996-12-10 CA CA002240284A patent/CA2240284C/en not_active Expired - Lifetime
- 1996-12-10 BR BR9612034-7A patent/BR9612034A/pt not_active IP Right Cessation
- 1996-12-16 IN IN603BO1996 patent/IN186192B/en unknown
- 1996-12-18 AR ARP960105764A patent/AR005137A1/es active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5256181A (en) | 1991-03-28 | 1993-10-26 | Exxon Research And Engineering Company | Coatings with ionically and covalently crosslinked sulfonated polymers |
| US5352265A (en) | 1993-11-12 | 1994-10-04 | Freeport-Mcmoran Resource Partners, Limited Partnership | Granular urea-based fertilizer |
| US5364438A (en) | 1993-11-12 | 1994-11-15 | Freeport-Mcmoran Resource Partners, Limited Partnership | Fluid urea-containing fertilizer |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ324974A (en) | 1999-08-30 |
| AR005137A1 (es) | 1999-04-14 |
| CA2240284A1 (en) | 1997-06-26 |
| ES2329201T3 (es) | 2009-11-23 |
| JP2000502037A (ja) | 2000-02-22 |
| US5698003A (en) | 1997-12-16 |
| CA2240284C (en) | 2005-01-18 |
| CN1163442C (zh) | 2004-08-25 |
| EP0869933A4 (en) | 2004-10-20 |
| IN186192B (enEXAMPLES) | 2001-07-07 |
| CN1204310A (zh) | 1999-01-06 |
| AU1277597A (en) | 1997-07-14 |
| WO1997022568A1 (en) | 1997-06-26 |
| KR100419454B1 (ko) | 2004-06-12 |
| EP0869933B1 (en) | 2009-06-24 |
| AU708702B2 (en) | 1999-08-12 |
| KR20000064362A (ko) | 2000-11-06 |
| BR9612034A (pt) | 2000-03-28 |
| DE69637957D1 (de) | 2009-08-06 |
| EP0869933A1 (en) | 1998-10-14 |
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