JP3151242B2 - 磁性粒子を有する電子伝導性材料およびその製造方法 - Google Patents
磁性粒子を有する電子伝導性材料およびその製造方法Info
- Publication number
- JP3151242B2 JP3151242B2 JP22041291A JP22041291A JP3151242B2 JP 3151242 B2 JP3151242 B2 JP 3151242B2 JP 22041291 A JP22041291 A JP 22041291A JP 22041291 A JP22041291 A JP 22041291A JP 3151242 B2 JP3151242 B2 JP 3151242B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- magnetic particles
- particles
- material according
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000178 monomer Substances 0.000 claims abstract description 52
- 239000000725 suspension Substances 0.000 claims abstract description 50
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 30
- 239000002322 conducting polymer Substances 0.000 claims abstract description 12
- 239000002019 doping agent Substances 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims description 65
- 238000000034 method Methods 0.000 claims description 53
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 45
- 238000006116 polymerization reaction Methods 0.000 claims description 34
- 229920000128 polypyrrole Polymers 0.000 claims description 24
- 239000002243 precursor Substances 0.000 claims description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 19
- 239000004816 latex Substances 0.000 claims description 17
- 229920000126 latex Polymers 0.000 claims description 17
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- 239000000654 additive Substances 0.000 claims description 7
- 125000000962 organic group Chemical group 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
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- 238000006056 electrooxidation reaction Methods 0.000 claims description 6
- 230000005389 magnetism Effects 0.000 claims description 6
- GIFWAJGKWIDXMY-UHFFFAOYSA-N 2-octylthiophene Chemical group CCCCCCCCC1=CC=CS1 GIFWAJGKWIDXMY-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 230000000536 complexating effect Effects 0.000 claims description 5
- 150000003233 pyrroles Chemical class 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
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- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
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- NQVMXJURHZVMKR-UHFFFAOYSA-N 2-(3-oxo-3-phenylprop-1-enyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=CC(=O)C1=CC=CC=C1 NQVMXJURHZVMKR-UHFFFAOYSA-N 0.000 description 4
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- 125000000129 anionic group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
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- 230000000694 effects Effects 0.000 description 4
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 4
- 125000001462 1-pyrrolyl group Chemical group [*]N1C([H])=C([H])C([H])=C1[H] 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
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- 125000004429 atom Chemical group 0.000 description 3
- 229910003437 indium oxide Inorganic materials 0.000 description 3
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- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- JJDNIFVXOIKYCT-UHFFFAOYSA-N 11-pyrrol-1-ylundecane-1-thiol Chemical compound SCCCCCCCCCCCN1C=CC=C1 JJDNIFVXOIKYCT-UHFFFAOYSA-N 0.000 description 2
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DQFBYFPFKXHELB-UHFFFAOYSA-N Chalcone Natural products C=1C=CC=CC=1C(=O)C=CC1=CC=CC=C1 DQFBYFPFKXHELB-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
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- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
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- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
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- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- ACTRVOBWPAIOHC-UHFFFAOYSA-N succimer Chemical compound OC(=O)C(S)C(S)C(O)=O ACTRVOBWPAIOHC-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- KBLZDCFTQSIIOH-UHFFFAOYSA-M tetrabutylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC KBLZDCFTQSIIOH-UHFFFAOYSA-M 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- CCIDWXHLGNEQSL-UHFFFAOYSA-N undecane-1-thiol Chemical compound CCCCCCCCCCCS CCIDWXHLGNEQSL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/08—Fountains
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/42—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of organic or organo-metallic materials, e.g. graphene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Soft Magnetic Materials (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9010883 | 1990-08-31 | ||
| FR9010883A FR2666443A1 (fr) | 1990-08-31 | 1990-08-31 | Materiau a base de polymere conducteur electronique comprenant des particules magnetiques et son procede de fabrication. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04234453A JPH04234453A (ja) | 1992-08-24 |
| JP3151242B2 true JP3151242B2 (ja) | 2001-04-03 |
Family
ID=9400000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22041291A Expired - Fee Related JP3151242B2 (ja) | 1990-08-31 | 1991-08-30 | 磁性粒子を有する電子伝導性材料およびその製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5264157A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0473511B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP3151242B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR920004044A (cg-RX-API-DMAC7.html) |
| AT (1) | ATE120028T1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE69108144T2 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2666443A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5532025A (en) * | 1993-07-23 | 1996-07-02 | Kinlen; Patrick J. | Corrosion inhibiting compositions |
| FR2736197B1 (fr) * | 1995-06-29 | 1997-09-12 | Univ Paris Curie | Nanoparticules magnetiques couplees a de l'annexine et leur utilisation |
| US6933331B2 (en) | 1998-05-22 | 2005-08-23 | Nanoproducts Corporation | Nanotechnology for drug delivery, contrast agents and biomedical implants |
| US5905000A (en) * | 1996-09-03 | 1999-05-18 | Nanomaterials Research Corporation | Nanostructured ion conducting solid electrolytes |
| ATE283536T1 (de) * | 1997-07-25 | 2004-12-15 | Ormecon Gmbh | Chemische verbindungen von intrinsisch leitfähigen polymeren mit metallen |
| US5938979A (en) * | 1997-10-31 | 1999-08-17 | Nanogram Corporation | Electromagnetic shielding |
| KR100296969B1 (ko) * | 1999-02-23 | 2001-09-22 | 허남욱 | 카드형 성형물 제조용 합성수지 사출 노즐 |
| FR2803224B1 (fr) * | 1999-12-30 | 2002-09-27 | Rhodia Chimie Sa | Dispersion colloidale aqueuse a base d'au moins un compose d'un metal et d'un complexant, procede de preparation et utilisation |
| US6379589B1 (en) * | 2000-10-23 | 2002-04-30 | Fractal Systems Inc. | Super-wide band shielding materials |
| US6855426B2 (en) | 2001-08-08 | 2005-02-15 | Nanoproducts Corporation | Methods for producing composite nanoparticles |
| WO2004029176A1 (en) * | 2002-09-24 | 2004-04-08 | E.I. Du Pont De Nemours And Company | Electrically conducting organic polymer/nanoparticle composites and methods for use thereof |
| US7708974B2 (en) | 2002-12-10 | 2010-05-04 | Ppg Industries Ohio, Inc. | Tungsten comprising nanomaterials and related nanotechnology |
| CN101595532B (zh) | 2005-06-28 | 2013-07-31 | E.I.内穆尔杜邦公司 | 缓冲组合物 |
| US20070099067A1 (en) * | 2005-09-23 | 2007-05-03 | Sanjiv Malhotra | Polymer catalyst composite as a membrane electrode assembly in Direct Methanol Fuel Cells |
| US8277690B2 (en) * | 2008-06-09 | 2012-10-02 | Council Of Scientific & Industrial Research | Conducting copolymer ferromagnetic composite and a process for the preparation thereof |
| JP2012520381A (ja) | 2009-03-12 | 2012-09-06 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | コーティング用途向け導電性ポリマー組成物 |
| JP5402777B2 (ja) * | 2009-03-31 | 2014-01-29 | 荒川化学工業株式会社 | 導電性高分子／ドーパント分散体、導電性組成物および導電性皮膜 |
| KR101581990B1 (ko) | 2009-04-21 | 2015-12-31 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 전기 전도성 중합체 조성물 및 그로부터 제조된 필름 |
| JP2012524834A (ja) | 2009-04-24 | 2012-10-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性ポリマー組成物およびそれから作製されたフィルム |
| TWI485210B (zh) * | 2011-12-09 | 2015-05-21 | Ind Tech Res Inst | 具有導電性與鐵磁性之複合材料及其混成漿料 |
| WO2015168556A1 (en) * | 2014-05-01 | 2015-11-05 | The University Of Utah Research Foundation | Magnetically-modified conducting polymer composites and methods of preparation thereof |
| JP6712413B2 (ja) * | 2016-08-09 | 2020-06-24 | 国立研究開発法人物質・材料研究機構 | 磁場下でのイオン輸送を利用する帯電状態の制御方法及びその用途 |
| CN108305947B (zh) * | 2017-01-11 | 2021-10-22 | 华邦电子股份有限公司 | 传感器、复合材料及其制造方法 |
| US10823691B2 (en) * | 2017-01-11 | 2020-11-03 | Winbond Electronics Corp. | Sensor, composite material and method of manufacturing the same |
| CN107311636B (zh) * | 2017-07-04 | 2020-12-22 | 马鞍山起劲磁塑科技有限公司 | 一种高性能永磁铁氧体的制备方法 |
| KR102224357B1 (ko) * | 2018-10-10 | 2021-03-10 | (주)플렉솔루션 | 도데실 설페이트 도핑된 pedot 필름 및 그 제조방법 |
| CN117480222A (zh) * | 2021-02-26 | 2024-01-30 | 罗兰大学 | 含铁氧化物/氢氧化物的导电聚合物复合材料及其使用高铁酸盐的制备 |
| HUE071342T2 (hu) * | 2021-02-26 | 2025-08-28 | Eoetvoes Lorand Tudomanyegyetem | Vas-oxid/hidroxidot tartalmazó vezetõ polimer kompozitok és azok elõállítása ferrátsók felhasználásával |
| US20240376332A1 (en) * | 2021-09-10 | 2024-11-14 | Virginia Commonwealth University | Method for connection to a rigid or flexible device using multifunctional ink |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5525482B2 (cg-RX-API-DMAC7.html) * | 1972-02-24 | 1980-07-07 | ||
| JPS5142990A (cg-RX-API-DMAC7.html) * | 1974-10-11 | 1976-04-12 | Fuji Photo Film Co Ltd | |
| JPS5180998A (cg-RX-API-DMAC7.html) * | 1975-01-14 | 1976-07-15 | Fuji Photo Film Co Ltd | |
| FR2461521A1 (fr) * | 1979-07-20 | 1981-02-06 | Anvar | Fluides magnetiques, notamment ferrofluides, et procede pour leur obtention |
| IT1145696B (it) * | 1979-08-24 | 1986-11-05 | Rhone Poulenc Ind | Procedimento di preparazione di perle magnetiche di polimeri vinilaromatici |
| US4334887A (en) * | 1980-02-05 | 1982-06-15 | Akzona Incorporated | Method for flocculating metal oxide particles in an organic medium |
| US4421660A (en) * | 1980-12-15 | 1983-12-20 | The Dow Chemical Company | Colloidal size hydrophobic polymers particulate having discrete particles of an inorganic material dispersed therein |
| JPS61254669A (ja) * | 1985-05-07 | 1986-11-12 | Katsumi Yoshino | 磁性導電性高分子 |
| US4626586A (en) * | 1985-08-13 | 1986-12-02 | Regents Of The University Of California | Transition metal poly(benzodithiolene) |
| FR2628746B1 (fr) * | 1988-03-21 | 1992-03-27 | Solvay | Procede de preparation d'un latex a base de polypyrrole et utilisation de ce latex pour former un film conducteur |
| DE3824333A1 (de) * | 1988-07-18 | 1990-01-25 | Fraunhofer Ges Forschung | Verfahren zur fixierung einer anorganischen spezies in einer organischen matrix |
-
1990
- 1990-08-31 FR FR9010883A patent/FR2666443A1/fr active Granted
-
1991
- 1991-08-20 US US07/747,526 patent/US5264157A/en not_active Expired - Fee Related
- 1991-08-28 DE DE69108144T patent/DE69108144T2/de not_active Expired - Fee Related
- 1991-08-28 EP EP91402324A patent/EP0473511B1/fr not_active Expired - Lifetime
- 1991-08-28 AT AT91402324T patent/ATE120028T1/de not_active IP Right Cessation
- 1991-08-30 JP JP22041291A patent/JP3151242B2/ja not_active Expired - Fee Related
- 1991-08-30 KR KR1019910015066A patent/KR920004044A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04234453A (ja) | 1992-08-24 |
| EP0473511B1 (fr) | 1995-03-15 |
| DE69108144T2 (de) | 1995-10-19 |
| FR2666443B1 (cg-RX-API-DMAC7.html) | 1995-02-10 |
| ATE120028T1 (de) | 1995-04-15 |
| FR2666443A1 (fr) | 1992-03-06 |
| KR920004044A (ko) | 1992-03-27 |
| EP0473511A1 (fr) | 1992-03-04 |
| US5264157A (en) | 1993-11-23 |
| DE69108144D1 (de) | 1995-04-20 |
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| LAPS | Cancellation because of no payment of annual fees |