FR2666443A1 - Materiau a base de polymere conducteur electronique comprenant des particules magnetiques et son procede de fabrication. - Google Patents
Materiau a base de polymere conducteur electronique comprenant des particules magnetiques et son procede de fabrication. Download PDFInfo
- Publication number
- FR2666443A1 FR2666443A1 FR9010883A FR9010883A FR2666443A1 FR 2666443 A1 FR2666443 A1 FR 2666443A1 FR 9010883 A FR9010883 A FR 9010883A FR 9010883 A FR9010883 A FR 9010883A FR 2666443 A1 FR2666443 A1 FR 2666443A1
- Authority
- FR
- France
- Prior art keywords
- magnetic particles
- polymer
- magnetic
- particles
- conductive polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006249 magnetic particle Substances 0.000 title claims abstract description 80
- 229920001940 conductive polymer Polymers 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims description 32
- 239000002861 polymer material Substances 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims abstract description 51
- 239000000178 monomer Substances 0.000 claims abstract description 48
- 239000000725 suspension Substances 0.000 claims abstract description 35
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 33
- 230000005291 magnetic effect Effects 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000004020 conductor Substances 0.000 claims abstract description 9
- 239000002019 doping agent Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 53
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 47
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- 239000002243 precursor Substances 0.000 claims description 17
- 229910052742 iron Inorganic materials 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 14
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical group OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 11
- 150000002500 ions Chemical class 0.000 claims description 11
- 239000008139 complexing agent Substances 0.000 claims description 10
- 239000003792 electrolyte Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 230000000536 complexating effect Effects 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 238000006056 electrooxidation reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 125000000962 organic group Chemical group 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 229930192474 thiophene Natural products 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 125000002490 anilino group Chemical class [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 238000010668 complexation reaction Methods 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 150000003577 thiophenes Chemical class 0.000 claims description 2
- 229920001007 Nylon 4 Polymers 0.000 claims 1
- 150000003235 pyrrolidines Chemical class 0.000 claims 1
- 239000002322 conducting polymer Substances 0.000 abstract description 2
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 21
- 239000000243 solution Substances 0.000 description 17
- 229920000128 polypyrrole Polymers 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000010408 film Substances 0.000 description 10
- 150000001450 anions Chemical class 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 5
- -1 alkyl radical Chemical class 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical class [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 238000002484 cyclic voltammetry Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000004435 EPR spectroscopy Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 241000577218 Phenes Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000011554 ferrofluid Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 229920000767 polyaniline Polymers 0.000 description 2
- 229920006295 polythiol Polymers 0.000 description 2
- 150000003233 pyrroles Chemical class 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 238000012549 training Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- OHZAHWOAMVVGEL-UHFFFAOYSA-N 2,2'-bithiophene Chemical compound C1=CSC(C=2SC=CC=2)=C1 OHZAHWOAMVVGEL-UHFFFAOYSA-N 0.000 description 1
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- PBCJIPOGFJYBJE-UHFFFAOYSA-N acetonitrile;hydrate Chemical compound O.CC#N PBCJIPOGFJYBJE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- YDVNLQGCLLPHAH-UHFFFAOYSA-N dichloromethane;hydrate Chemical compound O.ClCCl YDVNLQGCLLPHAH-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000011553 magnetic fluid Substances 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- XEEVLJKYYUVTRC-UHFFFAOYSA-N oxomalonic acid Chemical compound OC(=O)C(=O)C(O)=O XEEVLJKYYUVTRC-UHFFFAOYSA-N 0.000 description 1
- 230000005298 paramagnetic effect Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000001075 voltammogram Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/08—Fountains
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/42—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of organic or organo-metallic materials, e.g. graphene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Soft Magnetic Materials (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9010883A FR2666443A1 (fr) | 1990-08-31 | 1990-08-31 | Materiau a base de polymere conducteur electronique comprenant des particules magnetiques et son procede de fabrication. |
| US07/747,526 US5264157A (en) | 1990-08-31 | 1991-08-20 | Material based on an electronic conductive polymer incorporating magnetic particles and its production process |
| DE69108144T DE69108144T2 (de) | 1990-08-31 | 1991-08-28 | Material auf Basis eines elektrisch leitenden Polymers mit Magnetteilchen und Herstellungsverfahren. |
| AT91402324T ATE120028T1 (de) | 1990-08-31 | 1991-08-28 | Material auf basis eines elektrisch leitenden polymers mit magnetteilchen und herstellungsverfahren. |
| EP91402324A EP0473511B1 (fr) | 1990-08-31 | 1991-08-28 | Matériau à base de polymère conducteur électronique comprenant des particules magnétiques et son procédé de fabrication |
| JP22041291A JP3151242B2 (ja) | 1990-08-31 | 1991-08-30 | 磁性粒子を有する電子伝導性材料およびその製造方法 |
| KR1019910015066A KR920004044A (ko) | 1990-08-31 | 1991-08-30 | 자기 입자가 균질 혼합되어 있는 전자 전도성 중합체를 기제로 하는 재료 및 그의 제조방법 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9010883A FR2666443A1 (fr) | 1990-08-31 | 1990-08-31 | Materiau a base de polymere conducteur electronique comprenant des particules magnetiques et son procede de fabrication. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2666443A1 true FR2666443A1 (fr) | 1992-03-06 |
| FR2666443B1 FR2666443B1 (cg-RX-API-DMAC7.html) | 1995-02-10 |
Family
ID=9400000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9010883A Granted FR2666443A1 (fr) | 1990-08-31 | 1990-08-31 | Materiau a base de polymere conducteur electronique comprenant des particules magnetiques et son procede de fabrication. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5264157A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0473511B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP3151242B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR920004044A (cg-RX-API-DMAC7.html) |
| AT (1) | ATE120028T1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE69108144T2 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2666443A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5532025A (en) * | 1993-07-23 | 1996-07-02 | Kinlen; Patrick J. | Corrosion inhibiting compositions |
| FR2736197B1 (fr) * | 1995-06-29 | 1997-09-12 | Univ Paris Curie | Nanoparticules magnetiques couplees a de l'annexine et leur utilisation |
| US6933331B2 (en) | 1998-05-22 | 2005-08-23 | Nanoproducts Corporation | Nanotechnology for drug delivery, contrast agents and biomedical implants |
| US5905000A (en) * | 1996-09-03 | 1999-05-18 | Nanomaterials Research Corporation | Nanostructured ion conducting solid electrolytes |
| ATE283536T1 (de) * | 1997-07-25 | 2004-12-15 | Ormecon Gmbh | Chemische verbindungen von intrinsisch leitfähigen polymeren mit metallen |
| US5938979A (en) * | 1997-10-31 | 1999-08-17 | Nanogram Corporation | Electromagnetic shielding |
| KR100296969B1 (ko) * | 1999-02-23 | 2001-09-22 | 허남욱 | 카드형 성형물 제조용 합성수지 사출 노즐 |
| FR2803224B1 (fr) * | 1999-12-30 | 2002-09-27 | Rhodia Chimie Sa | Dispersion colloidale aqueuse a base d'au moins un compose d'un metal et d'un complexant, procede de preparation et utilisation |
| US6379589B1 (en) * | 2000-10-23 | 2002-04-30 | Fractal Systems Inc. | Super-wide band shielding materials |
| US6855426B2 (en) | 2001-08-08 | 2005-02-15 | Nanoproducts Corporation | Methods for producing composite nanoparticles |
| WO2004029176A1 (en) * | 2002-09-24 | 2004-04-08 | E.I. Du Pont De Nemours And Company | Electrically conducting organic polymer/nanoparticle composites and methods for use thereof |
| US7708974B2 (en) | 2002-12-10 | 2010-05-04 | Ppg Industries Ohio, Inc. | Tungsten comprising nanomaterials and related nanotechnology |
| CN101595532B (zh) | 2005-06-28 | 2013-07-31 | E.I.内穆尔杜邦公司 | 缓冲组合物 |
| US20070099067A1 (en) * | 2005-09-23 | 2007-05-03 | Sanjiv Malhotra | Polymer catalyst composite as a membrane electrode assembly in Direct Methanol Fuel Cells |
| US8277690B2 (en) * | 2008-06-09 | 2012-10-02 | Council Of Scientific & Industrial Research | Conducting copolymer ferromagnetic composite and a process for the preparation thereof |
| JP2012520381A (ja) | 2009-03-12 | 2012-09-06 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | コーティング用途向け導電性ポリマー組成物 |
| JP5402777B2 (ja) * | 2009-03-31 | 2014-01-29 | 荒川化学工業株式会社 | 導電性高分子／ドーパント分散体、導電性組成物および導電性皮膜 |
| KR101581990B1 (ko) | 2009-04-21 | 2015-12-31 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 전기 전도성 중합체 조성물 및 그로부터 제조된 필름 |
| JP2012524834A (ja) | 2009-04-24 | 2012-10-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性ポリマー組成物およびそれから作製されたフィルム |
| TWI485210B (zh) * | 2011-12-09 | 2015-05-21 | Ind Tech Res Inst | 具有導電性與鐵磁性之複合材料及其混成漿料 |
| WO2015168556A1 (en) * | 2014-05-01 | 2015-11-05 | The University Of Utah Research Foundation | Magnetically-modified conducting polymer composites and methods of preparation thereof |
| JP6712413B2 (ja) * | 2016-08-09 | 2020-06-24 | 国立研究開発法人物質・材料研究機構 | 磁場下でのイオン輸送を利用する帯電状態の制御方法及びその用途 |
| CN108305947B (zh) * | 2017-01-11 | 2021-10-22 | 华邦电子股份有限公司 | 传感器、复合材料及其制造方法 |
| US10823691B2 (en) * | 2017-01-11 | 2020-11-03 | Winbond Electronics Corp. | Sensor, composite material and method of manufacturing the same |
| CN107311636B (zh) * | 2017-07-04 | 2020-12-22 | 马鞍山起劲磁塑科技有限公司 | 一种高性能永磁铁氧体的制备方法 |
| KR102224357B1 (ko) * | 2018-10-10 | 2021-03-10 | (주)플렉솔루션 | 도데실 설페이트 도핑된 pedot 필름 및 그 제조방법 |
| CN117480222A (zh) * | 2021-02-26 | 2024-01-30 | 罗兰大学 | 含铁氧化物/氢氧化物的导电聚合物复合材料及其使用高铁酸盐的制备 |
| HUE071342T2 (hu) * | 2021-02-26 | 2025-08-28 | Eoetvoes Lorand Tudomanyegyetem | Vas-oxid/hidroxidot tartalmazó vezetõ polimer kompozitok és azok elõállítása ferrátsók felhasználásával |
| US20240376332A1 (en) * | 2021-09-10 | 2024-11-14 | Virginia Commonwealth University | Method for connection to a rigid or flexible device using multifunctional ink |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61254669A (ja) * | 1985-05-07 | 1986-11-12 | Katsumi Yoshino | 磁性導電性高分子 |
| EP0223336A1 (en) * | 1985-08-13 | 1987-05-27 | The Regents Of The University Of California | Transition metal poly(benzodithiolenes) |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5525482B2 (cg-RX-API-DMAC7.html) * | 1972-02-24 | 1980-07-07 | ||
| JPS5142990A (cg-RX-API-DMAC7.html) * | 1974-10-11 | 1976-04-12 | Fuji Photo Film Co Ltd | |
| JPS5180998A (cg-RX-API-DMAC7.html) * | 1975-01-14 | 1976-07-15 | Fuji Photo Film Co Ltd | |
| FR2461521A1 (fr) * | 1979-07-20 | 1981-02-06 | Anvar | Fluides magnetiques, notamment ferrofluides, et procede pour leur obtention |
| IT1145696B (it) * | 1979-08-24 | 1986-11-05 | Rhone Poulenc Ind | Procedimento di preparazione di perle magnetiche di polimeri vinilaromatici |
| US4334887A (en) * | 1980-02-05 | 1982-06-15 | Akzona Incorporated | Method for flocculating metal oxide particles in an organic medium |
| US4421660A (en) * | 1980-12-15 | 1983-12-20 | The Dow Chemical Company | Colloidal size hydrophobic polymers particulate having discrete particles of an inorganic material dispersed therein |
| FR2628746B1 (fr) * | 1988-03-21 | 1992-03-27 | Solvay | Procede de preparation d'un latex a base de polypyrrole et utilisation de ce latex pour former un film conducteur |
| DE3824333A1 (de) * | 1988-07-18 | 1990-01-25 | Fraunhofer Ges Forschung | Verfahren zur fixierung einer anorganischen spezies in einer organischen matrix |
-
1990
- 1990-08-31 FR FR9010883A patent/FR2666443A1/fr active Granted
-
1991
- 1991-08-20 US US07/747,526 patent/US5264157A/en not_active Expired - Fee Related
- 1991-08-28 DE DE69108144T patent/DE69108144T2/de not_active Expired - Fee Related
- 1991-08-28 EP EP91402324A patent/EP0473511B1/fr not_active Expired - Lifetime
- 1991-08-28 AT AT91402324T patent/ATE120028T1/de not_active IP Right Cessation
- 1991-08-30 JP JP22041291A patent/JP3151242B2/ja not_active Expired - Fee Related
- 1991-08-30 KR KR1019910015066A patent/KR920004044A/ko not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61254669A (ja) * | 1985-05-07 | 1986-11-12 | Katsumi Yoshino | 磁性導電性高分子 |
| EP0223336A1 (en) * | 1985-08-13 | 1987-05-27 | The Regents Of The University Of California | Transition metal poly(benzodithiolenes) |
Non-Patent Citations (3)
| Title |
|---|
| JAPANESE JOURNAL OF APPLIED PHYSICS. vol. 24, no. 9, septembre 1985, TOKYO JP pages L687 - L688; K.Yoshino et Al.: "Preparation of Magnetic Conducting Polymer and Its Characteristics" * |
| JOURNAL OF THE ELECTROCHEMICAL SOCIETY. vol. 137, no. 6, juin 1990, MANCHESTER, NEW HAMP pages 1793 - 1796; K.Kawai et Al.: "Electrochemical Synthesis of Polypyrrole Films Containing TiO2 powderParticles" * |
| PATENT ABSTRACTS OF JAPAN vol. 11, no. 106 (C-414)(2553) 3 avril 1987, & JP-A-61 254669 (KATSUMI YOSHINO) 12 novembre 1986, * |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04234453A (ja) | 1992-08-24 |
| EP0473511B1 (fr) | 1995-03-15 |
| DE69108144T2 (de) | 1995-10-19 |
| FR2666443B1 (cg-RX-API-DMAC7.html) | 1995-02-10 |
| ATE120028T1 (de) | 1995-04-15 |
| KR920004044A (ko) | 1992-03-27 |
| EP0473511A1 (fr) | 1992-03-04 |
| JP3151242B2 (ja) | 2001-04-03 |
| US5264157A (en) | 1993-11-23 |
| DE69108144D1 (de) | 1995-04-20 |
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