JP2874884B2 - 熱可塑性芳香族ポリカーボネート樹脂用の衝撃強度変性剤、熱可塑性成形材料及び成形体 - Google Patents
熱可塑性芳香族ポリカーボネート樹脂用の衝撃強度変性剤、熱可塑性成形材料及び成形体Info
- Publication number
- JP2874884B2 JP2874884B2 JP1025958A JP2595889A JP2874884B2 JP 2874884 B2 JP2874884 B2 JP 2874884B2 JP 1025958 A JP1025958 A JP 1025958A JP 2595889 A JP2595889 A JP 2595889A JP 2874884 B2 JP2874884 B2 JP 2874884B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- impact strength
- polycarbonate
- strength modifier
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 18
- 229920005668 polycarbonate resin Polymers 0.000 title claims abstract description 6
- 239000004431 polycarbonate resin Substances 0.000 title claims abstract description 6
- 239000003607 modifier Substances 0.000 title claims description 30
- 229920001169 thermoplastic Polymers 0.000 title claims description 20
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 18
- 238000009757 thermoplastic moulding Methods 0.000 title claims description 9
- 239000012778 molding material Substances 0.000 title claims description 4
- 239000004417 polycarbonate Substances 0.000 claims abstract description 40
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 39
- 229920001577 copolymer Polymers 0.000 claims abstract description 21
- 229920001971 elastomer Polymers 0.000 claims abstract description 14
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 7
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 4
- 229920000642 polymer Polymers 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 11
- 230000009477 glass transition Effects 0.000 claims description 8
- 239000005060 rubber Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 4
- -1 cycloalkyl maleimides Chemical class 0.000 abstract description 6
- 239000000806 elastomer Substances 0.000 abstract description 6
- 150000003926 acrylamides Chemical class 0.000 abstract description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- 239000004415 thermoplastic moulding composition Substances 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 229920002943 EPDM rubber Polymers 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229920000578 graft copolymer Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
- 229920004011 Macrolon® Polymers 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000006887 Ullmann reaction Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- HPSGLFKWHYAKSF-UHFFFAOYSA-N 2-phenylethyl prop-2-enoate Chemical compound C=CC(=O)OCCC1=CC=CC=C1 HPSGLFKWHYAKSF-UHFFFAOYSA-N 0.000 description 2
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920005787 opaque polymer Polymers 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- CBHJQJMRGFCOIN-UHFFFAOYSA-N 1-(4-methylcyclohexyl)pyrrole-2,5-dione Chemical compound C1CC(C)CCC1N1C(=O)C=CC1=O CBHJQJMRGFCOIN-UHFFFAOYSA-N 0.000 description 1
- BQTPKSBXMONSJI-UHFFFAOYSA-N 1-cyclohexylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCCCC1 BQTPKSBXMONSJI-UHFFFAOYSA-N 0.000 description 1
- LGXIMOHTBATHCU-UHFFFAOYSA-N 2,3-di(propan-2-yl)benzenecarboperoxoic acid Chemical compound CC(C)C1=CC=CC(C(=O)OO)=C1C(C)C LGXIMOHTBATHCU-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 description 1
- ZHSTWAYJSZUXDS-UHFFFAOYSA-N 2-methyl-n-(2-methylcyclohexyl)prop-2-enamide Chemical compound CC1CCCCC1NC(=O)C(C)=C ZHSTWAYJSZUXDS-UHFFFAOYSA-N 0.000 description 1
- IJSVVICYGLOZHA-UHFFFAOYSA-N 2-methyl-n-phenylprop-2-enamide Chemical compound CC(=C)C(=O)NC1=CC=CC=C1 IJSVVICYGLOZHA-UHFFFAOYSA-N 0.000 description 1
- ILZXXGLGJZQLTR-UHFFFAOYSA-N 2-phenylethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC1=CC=CC=C1 ILZXXGLGJZQLTR-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical group CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- PMJFVKWBSWWAKT-UHFFFAOYSA-N n-cyclohexylprop-2-enamide Chemical compound C=CC(=O)NC1CCCCC1 PMJFVKWBSWWAKT-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3803405A DE3803405A1 (de) | 1988-02-05 | 1988-02-05 | Schlagzaeh-modifizierungsmittel fuer polycarbonat |
| DE3803405.0 | 1988-02-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01229070A JPH01229070A (ja) | 1989-09-12 |
| JP2874884B2 true JP2874884B2 (ja) | 1999-03-24 |
Family
ID=6346666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1025958A Expired - Fee Related JP2874884B2 (ja) | 1988-02-05 | 1989-02-06 | 熱可塑性芳香族ポリカーボネート樹脂用の衝撃強度変性剤、熱可塑性成形材料及び成形体 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4997883A (fr) |
| EP (1) | EP0326938B1 (fr) |
| JP (1) | JP2874884B2 (fr) |
| AT (1) | ATE98977T1 (fr) |
| CA (1) | CA1319213C (fr) |
| DE (2) | DE3803405A1 (fr) |
| ES (1) | ES2047585T3 (fr) |
| HK (1) | HK103294A (fr) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0362724A3 (fr) * | 1988-10-07 | 1991-10-09 | BASF Aktiengesellschaft | Compositions à mouler thermoplastiques |
| DE3834549A1 (de) * | 1988-10-11 | 1990-04-12 | Basf Ag | Thermoplastische formmasse auf der grundlage von polycarbonat, pfropfkautschuken und n-substituierten methacrylamidcopolymeren |
| DE3837588A1 (de) * | 1988-11-05 | 1990-05-10 | Roehm Gmbh | Schlagzaehe, uv-absorber-haltige methacrylatschutzschicht fuer polycarbonat |
| DE4019626A1 (de) * | 1990-06-20 | 1992-01-02 | Roehm Gmbh | Vertraegliche polymermischungen |
| DE4030553A1 (de) * | 1990-09-27 | 1992-04-02 | Roehm Gmbh | Ternaere polymermischungen |
| US5500251A (en) * | 1992-05-01 | 1996-03-19 | Air Products And Chemicals, Inc. | Process for coating low energy surfaces |
| DE4243588A1 (de) * | 1992-07-21 | 1994-01-27 | Roehm Gmbh | UV-absorbierende Deckschichten für Co-Polycarbonate |
| US5338798A (en) * | 1992-09-30 | 1994-08-16 | Istituto Guido Donegani S.P.A. | Block copolymers containing stereoregular polymethyl methacrylate and their blends with polycarbonates |
| US5284916A (en) * | 1992-09-30 | 1994-02-08 | Istituto Guido Donegani S.P.A. | Block copolymers containing polyaromatic(alkyl)methacrylates and their blends with polycarbonates |
| US6545089B1 (en) * | 1997-09-04 | 2003-04-08 | General Electric Company | Impact modified carbonnate polymer composition having improved resistance to degradation and improved thermal stability |
| AU758859B2 (en) * | 1998-04-27 | 2003-04-03 | Kaneka Corporation | Resin composition containing multilayered graft polymer |
| US7799855B2 (en) | 2001-11-12 | 2010-09-21 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic polycarbonate compositions, use and method thereof |
| US7223804B2 (en) | 2003-12-30 | 2007-05-29 | General Electric Company | Polycarbonate composition |
| US20060004154A1 (en) * | 2004-07-02 | 2006-01-05 | Derudder James L | Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof |
| US20060030647A1 (en) * | 2004-08-05 | 2006-02-09 | Thomas Ebeling | Flame retardant thermoplastic polycarbonate compositions, use, and method of manufacture thereof |
| US7365125B2 (en) * | 2004-08-16 | 2008-04-29 | General Electric Company | Polycarbonate compositions, articles, and method of manufacture |
| US20060142486A1 (en) * | 2004-12-23 | 2006-06-29 | Derudder James L | Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture |
| US7432327B2 (en) | 2004-12-30 | 2008-10-07 | Sabic Innovative Plastics Ip B.V. | Transparent polymeric compositions comprising polysiloxane-polycarbonate copolymer, articles made therefrom and methods of making same |
| US7227149B2 (en) * | 2004-12-30 | 2007-06-05 | General Electric Company | Method and system for positron emission tomography image reconstruction |
| US20100010172A1 (en) * | 2006-05-25 | 2010-01-14 | Arkema Inc. | Impact modifier composition for transparent thermoplastics |
| KR20080063052A (ko) * | 2006-12-29 | 2008-07-03 | 제일모직주식회사 | 폴리카보네이트계 수지 조성물 및 플라스틱 성형품 |
| KR100885819B1 (ko) * | 2007-12-18 | 2009-02-26 | 제일모직주식회사 | 굴절률이 우수한 분지형 아크릴계 공중합체 및 그 제조방법 |
| KR101004040B1 (ko) * | 2007-12-18 | 2010-12-31 | 제일모직주식회사 | 상용성이 향상된 난연 내스크래치 열가소성 수지 조성물 |
| KR100902352B1 (ko) * | 2008-03-13 | 2009-06-12 | 제일모직주식회사 | 상용성이 향상된 열가소성 수지 조성물 |
| KR100886348B1 (ko) * | 2008-04-14 | 2009-03-03 | 제일모직주식회사 | 상용성이 개선된 난연 내스크래치 열가소성 수지 조성물 |
| KR101188349B1 (ko) * | 2008-12-17 | 2012-10-05 | 제일모직주식회사 | 투명성 및 내스크래치성이 향상된 폴리카보네이트계 수지 조성물 |
| US8735490B2 (en) * | 2009-12-30 | 2014-05-27 | Cheil Industries Inc. | Thermoplastic resin composition having improved impact strength and melt flow properties |
| KR101654721B1 (ko) | 2013-05-06 | 2016-09-13 | 롯데첨단소재(주) | 투명 폴리카보네이트 조성물 및 이를 포함한 성형품 |
| EP2881408B1 (fr) | 2013-12-04 | 2017-09-20 | Lotte Advanced Materials Co., Ltd. | Copolymère à base de styrène et composition de résine thermoplastique le comprenant |
| JP5896246B2 (ja) * | 2014-01-31 | 2016-03-30 | 三菱レイヨン株式会社 | グラフト共重合体及びその製造方法、難燃剤、熱可塑性樹脂組成物、並びに成形体 |
| US9902850B2 (en) | 2014-06-26 | 2018-02-27 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition |
| US9856371B2 (en) | 2014-06-27 | 2018-01-02 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and low-gloss molded article made therefrom |
| US9790362B2 (en) | 2014-06-27 | 2017-10-17 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and molded article made using the same |
| US9850333B2 (en) | 2014-06-27 | 2017-12-26 | Lotte Advanced Materials Co., Ltd. | Copolymers and thermoplastic resin composition including the same |
| KR101822697B1 (ko) | 2014-11-18 | 2018-01-30 | 롯데첨단소재(주) | 외관 특성이 우수한 열가소성 수지 조성물 및 이를 이용한 성형품 |
| WO2016120203A1 (fr) * | 2015-01-28 | 2016-08-04 | Sabic Global Technologies B.V. | Compositions thermoplastiques, compositions à base de plusieurs polymères, procédés de fabrication associés et composites préparés à partir de ceux-ci |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS524552A (en) * | 1975-06-28 | 1977-01-13 | Japan Synthetic Rubber Co Ltd | Thermoplastic resin composition |
| DE2653145A1 (de) * | 1976-11-23 | 1978-05-24 | Bayer Ag | Formmassen |
| DE2653143C2 (de) * | 1976-11-23 | 1985-01-31 | Bayer Ag, 5090 Leverkusen | Thermoplastische Formmassen |
| US4299928A (en) * | 1980-03-14 | 1981-11-10 | Mobay Chemical Corporation | Impact modified polycarbonates |
| DE3118526A1 (de) * | 1981-05-09 | 1982-12-02 | Bayer Ag, 5090 Leverkusen | "thermoplastische formmassen aus polycarbonat, polyalkylenterephthalat und pfropfpolymerisat" |
| DE3245292A1 (de) * | 1982-12-08 | 1984-06-20 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmassen |
| IL73684A0 (en) * | 1983-11-30 | 1985-02-28 | Clearfield Nv | Digester for animal wastes and its use for production of methane |
| US4491647A (en) * | 1983-12-05 | 1985-01-01 | Atlantic Richfield Company | Polymer composition containing polycarbonate and a copolymer of methylmethacrylate with N-phenylmaleimide |
| JPS624711A (ja) * | 1985-07-02 | 1987-01-10 | Sumitomo Chem Co Ltd | アクリル系グラフト共重合体の製造法 |
| JPS62149755A (ja) * | 1985-12-25 | 1987-07-03 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂の製造方法 |
| DE3631539A1 (de) * | 1986-09-17 | 1988-03-24 | Bayer Ag | Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit |
| DE3632946A1 (de) * | 1986-09-27 | 1988-03-31 | Roehm Gmbh | Vertraegliche mischungen aus polycarbonat und methylmethacrylat-copolymeren |
| DE3719239A1 (de) * | 1987-06-06 | 1988-12-15 | Roehm Gmbh | Vertraegliche polycarbonat-polymethacrylat-mischungen |
| DE3743199A1 (de) * | 1987-12-19 | 1989-06-29 | Roehm Gmbh | Schlagzaeh-modifizierungsmittel fuer kunststoffe |
-
1988
- 1988-02-05 DE DE3803405A patent/DE3803405A1/de not_active Withdrawn
-
1989
- 1989-01-26 ES ES89101325T patent/ES2047585T3/es not_active Expired - Lifetime
- 1989-01-26 EP EP89101325A patent/EP0326938B1/fr not_active Expired - Lifetime
- 1989-01-26 DE DE89101325T patent/DE58906463D1/de not_active Expired - Fee Related
- 1989-01-26 AT AT89101325T patent/ATE98977T1/de not_active IP Right Cessation
- 1989-02-03 CA CA000590047A patent/CA1319213C/fr not_active Expired - Fee Related
- 1989-02-03 US US07/305,780 patent/US4997883A/en not_active Expired - Lifetime
- 1989-02-06 JP JP1025958A patent/JP2874884B2/ja not_active Expired - Fee Related
-
1994
- 1994-09-29 HK HK103294A patent/HK103294A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0326938A3 (fr) | 1991-08-07 |
| US4997883A (en) | 1991-03-05 |
| ES2047585T3 (es) | 1994-03-01 |
| DE58906463D1 (de) | 1994-02-03 |
| EP0326938B1 (fr) | 1993-12-22 |
| EP0326938A2 (fr) | 1989-08-09 |
| DE3803405A1 (de) | 1989-08-17 |
| CA1319213C (fr) | 1993-06-15 |
| JPH01229070A (ja) | 1989-09-12 |
| ATE98977T1 (de) | 1994-01-15 |
| HK103294A (en) | 1994-10-07 |
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| LAPS | Cancellation because of no payment of annual fees |