JP2868523B2 - 高い衝撃強度を有するポリマー組成物 - Google Patents
高い衝撃強度を有するポリマー組成物Info
- Publication number
- JP2868523B2 JP2868523B2 JP21959988A JP21959988A JP2868523B2 JP 2868523 B2 JP2868523 B2 JP 2868523B2 JP 21959988 A JP21959988 A JP 21959988A JP 21959988 A JP21959988 A JP 21959988A JP 2868523 B2 JP2868523 B2 JP 2868523B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- elastomer
- layer
- polymer
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 239000004816 latex Substances 0.000 claims abstract description 17
- 229920000126 latex Polymers 0.000 claims abstract description 17
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000178 monomer Substances 0.000 claims description 26
- 229920001971 elastomer Polymers 0.000 claims description 24
- 239000000806 elastomer Substances 0.000 claims description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- -1 aralkyl acrylate Chemical compound 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical class CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 150000003440 styrenes Chemical class 0.000 claims description 3
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims 1
- 239000011159 matrix material Substances 0.000 abstract description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 229920006373 Solef Polymers 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L19/00—Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
- C08L19/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C08L21/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
- Y10T428/31544—Addition polymer is perhalogenated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8712295 | 1987-09-04 | ||
| FR8712295A FR2620127A1 (fr) | 1987-09-04 | 1987-09-04 | Composition polymere a base de fluorure de vinylidene et de methacrylate de methyle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6470549A JPS6470549A (en) | 1989-03-16 |
| JP2868523B2 true JP2868523B2 (ja) | 1999-03-10 |
Family
ID=9354627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21959988A Expired - Fee Related JP2868523B2 (ja) | 1987-09-04 | 1988-09-01 | 高い衝撃強度を有するポリマー組成物 |
Country Status (11)
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3907019A1 (de) * | 1989-03-04 | 1990-09-06 | Roehm Gmbh | Thermoplastisch verarbeitbare loesungsmittelbestaendige kunststoffmischungen |
| KR920000177B1 (ko) * | 1989-03-31 | 1992-01-09 | 다이낀 고오교오 가부시끼가이샤 | 방진제진용 고분자 재료 |
| FR2659085B1 (fr) * | 1990-03-02 | 1992-05-15 | Atochem | Composition coextrudable avec le polyfluorure de vinylidene permettant l'adhesion de ce dernier avec une resine polymerique non compatible - composite obtenu avec cette composition. |
| US5898051A (en) * | 1996-01-31 | 1999-04-27 | Central Glass Company, Limited | Elastic fluorohydrocarbon resin-based polymer blend with graft copolymers of rubbers |
| FR2775978B1 (fr) * | 1998-03-12 | 2000-05-19 | Atohaas Holding Cv | Article faconne presentant une resistance amelioree aux agents fissurants, obtenu a partir d'une composition de resine methacrylique thermoplastique contenant un polymere a base de fluorure de vinylidene |
| FR2842529B1 (fr) * | 2002-07-17 | 2004-09-03 | Atofina | Composition coextrudable avec le pvdf |
| FR2842530B1 (fr) * | 2002-07-17 | 2004-09-03 | Atofina | Composition coextrudable avec le pvdf |
| DE102004024429A1 (de) * | 2004-05-14 | 2005-12-08 | Röhm GmbH & Co. KG | Formkörper, enthaltend eine Polymermischung aus schlagzähmodifizierten Poly(meth)-acrylat und Fluorpolymer |
| EP2220756A1 (en) * | 2007-11-21 | 2010-08-25 | Arkema, Inc. | Photovoltaic module using pvdf based flexible glazing film |
| CN101952117B (zh) * | 2008-02-25 | 2014-01-22 | 阿科玛法国公司 | 透明的、耐化学性的冲击性丙烯酸类合金 |
| CN102443098B (zh) * | 2011-10-27 | 2013-11-06 | 中国海洋石油总公司 | 一种用于聚偏二氟乙烯卷材面漆的高分子量丙烯酸树脂 |
| WO2016190276A1 (ja) * | 2015-05-27 | 2016-12-01 | 三菱レイヨン株式会社 | 樹脂組成物及び樹脂組成物からなるフィルム |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3253060A (en) * | 1964-08-03 | 1966-05-24 | Pennsalt Chemicals Corp | Molding compositions comprising polyvinylidene fluoride and polymethyl methacrylate |
| US3294871A (en) * | 1964-09-15 | 1966-12-27 | American Cyanamid Co | Poly (tetrafluoroethylene)-thermoplastic resin composition |
| GB1065780A (en) * | 1965-02-15 | 1967-04-19 | American Cyanamid Co | Poly(vinylidene fluoride) compositions |
| US3524906A (en) * | 1967-10-10 | 1970-08-18 | American Cyanamid Co | Transparent and weatherable polymer blends of acrylate polymers and polyvinylidene fluoride |
| US3843753A (en) * | 1972-02-09 | 1974-10-22 | Rohm & Haas | Composite interpolymer and low haze impact resistant thermoplastic compositions thereof |
| US3969469A (en) * | 1973-05-21 | 1976-07-13 | Tenneco Chemicals, Inc. | Vinyl halide resin compositions |
| JPS5532298A (en) * | 1978-08-28 | 1980-03-06 | Mca Disco Vision | Producing video disk structure |
| JPS57147539A (en) * | 1981-03-09 | 1982-09-11 | Mitsubishi Rayon Co Ltd | Thermoplastic resin composition |
| US4400487A (en) * | 1981-12-31 | 1983-08-23 | Ppg Industries, Inc. | Textured fluorocarbon coating compositions |
| JPS6028443A (ja) * | 1983-07-26 | 1985-02-13 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂組成物 |
| JPS61106649A (ja) * | 1984-10-31 | 1986-05-24 | Kureha Chem Ind Co Ltd | フツ化ビニリデン樹脂組成物 |
-
1987
- 1987-09-04 FR FR8712295A patent/FR2620127A1/fr active Pending
-
1988
- 1988-08-04 BR BR8804137A patent/BR8804137A/pt not_active IP Right Cessation
- 1988-08-11 AT AT88402093T patent/ATE72822T1/de not_active IP Right Cessation
- 1988-08-11 DE DE8888402093T patent/DE3868567D1/de not_active Expired - Fee Related
- 1988-08-11 EP EP19880402093 patent/EP0306385B1/fr not_active Expired - Lifetime
- 1988-08-11 ES ES88402093T patent/ES2037858T3/es not_active Expired - Lifetime
- 1988-08-30 KR KR1019880011065A patent/KR960007318B1/ko not_active Expired - Fee Related
- 1988-09-01 JP JP21959988A patent/JP2868523B2/ja not_active Expired - Fee Related
- 1988-09-02 US US07/239,868 patent/US4868036A/en not_active Expired - Lifetime
- 1988-09-02 CA CA 577070 patent/CA1310152C/fr not_active Expired - Lifetime
-
1992
- 1992-04-01 GR GR920400591T patent/GR3004221T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0306385B1 (fr) | 1992-02-26 |
| JPS6470549A (en) | 1989-03-16 |
| US4868036A (en) | 1989-09-19 |
| ATE72822T1 (de) | 1992-03-15 |
| DE3868567D1 (de) | 1992-04-02 |
| KR960007318B1 (ko) | 1996-05-30 |
| BR8804137A (pt) | 1989-05-02 |
| CA1310152C (fr) | 1992-11-10 |
| FR2620127A1 (fr) | 1989-03-10 |
| ES2037858T3 (es) | 1993-07-01 |
| GR3004221T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-03-31 |
| EP0306385A1 (fr) | 1989-03-08 |
| KR890005216A (ko) | 1989-05-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |