JP2023520500A - フルオロホスフィン配位子を含むヒドロホルミル化触媒及びその前駆体 - Google Patents

フルオロホスフィン配位子を含むヒドロホルミル化触媒及びその前駆体 Download PDF

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JP2023520500A
JP2023520500A JP2022560140A JP2022560140A JP2023520500A JP 2023520500 A JP2023520500 A JP 2023520500A JP 2022560140 A JP2022560140 A JP 2022560140A JP 2022560140 A JP2022560140 A JP 2022560140A JP 2023520500 A JP2023520500 A JP 2023520500A
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hydroformylation
reaction product
catalyst
hydroformylation reaction
olefinic
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JP2023520500A5 (https=
Inventor
アレックス イー カーペンター
ダニエル ジー シングルトン
サラ エイ ケイル
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エクソンモービル ケミカル パテンツ インコーポレイテッド
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2022560140A 2020-04-01 2021-03-25 フルオロホスフィン配位子を含むヒドロホルミル化触媒及びその前駆体 Ceased JP2023520500A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202063003600P 2020-04-01 2020-04-01
US63/003,600 2020-04-01
PCT/US2021/024068 WO2021202225A1 (en) 2020-04-01 2021-03-25 Hydroformylation catalysts comprising fluorophosphine ligands and precursors thereof

Publications (2)

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JP2023520500A true JP2023520500A (ja) 2023-05-17
JP2023520500A5 JP2023520500A5 (https=) 2024-04-03

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JP2022560140A Ceased JP2023520500A (ja) 2020-04-01 2021-03-25 フルオロホスフィン配位子を含むヒドロホルミル化触媒及びその前駆体

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US (1) US12391638B2 (https=)
EP (1) EP4126354A1 (https=)
JP (1) JP2023520500A (https=)
CN (1) CN115397555B (https=)
WO (1) WO2021202225A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021202225A1 (en) 2020-04-01 2021-10-07 Exxonmobil Chemical Patents Inc. Hydroformylation catalysts comprising fluorophosphine ligands and precursors thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007514703A (ja) * 2003-12-18 2007-06-07 エクソンモービル・ケミカル・パテンツ・インク ヒドロホルミル化の改良
JP2010511015A (ja) * 2006-11-30 2010-04-08 ビーエーエスエフ ソシエタス・ヨーロピア オレフィンのヒドロホルミル化法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL134286C (https=) 1962-01-23
US3310576A (en) 1963-02-05 1967-03-21 Exxon Research Engineering Co Hydroformylation catalyst and process relating thereto
US3418351A (en) 1965-05-17 1968-12-24 Shell Oil Co Recovery of hydroformylation cobalt-carbonyl-hydrocarbyl-tert-phosphine catalyst complex
US3510524A (en) 1966-08-23 1970-05-05 Gulf Research Development Co Oxo process
US3954877A (en) * 1967-10-12 1976-05-04 Jefferson Chemical Co., Inc. Hydroformylation of olefins
US4070403A (en) 1975-07-21 1978-01-24 Uop Inc. Catalytic hydroformylation process
GB8430225D0 (en) 1984-11-30 1985-01-09 Exxon Research Engineering Co Hydroformylation catalyst removal
US5237105A (en) 1992-05-29 1993-08-17 Exxon Chemical Patents Inc. Method for removing hydroformylation catalyst
WO2003082788A1 (en) 2002-03-29 2003-10-09 Exxonmobil Chemical Patents Inc. Improved cobalt flash process
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
ES2515266T5 (es) * 2009-02-12 2018-12-03 Lg Chem, Ltd. Composición de catalizador para hidroformilación y procedimiento para la preparación de aldehídos utilizando la misma
KR101411040B1 (ko) * 2012-05-24 2014-06-27 주식회사 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 히드로포밀화 방법
KR102383971B1 (ko) * 2014-02-23 2022-04-06 엔테그리스, 아이엔씨. 코발트 전구체
EP3144073A1 (en) 2015-09-17 2017-03-22 Henkel AG & Co. KGaA Dispenser, kit and method for applying an activator for a curable material
WO2021202225A1 (en) 2020-04-01 2021-10-07 Exxonmobil Chemical Patents Inc. Hydroformylation catalysts comprising fluorophosphine ligands and precursors thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007514703A (ja) * 2003-12-18 2007-06-07 エクソンモービル・ケミカル・パテンツ・インク ヒドロホルミル化の改良
US20070282132A1 (en) * 2003-12-18 2007-12-06 Beadle Stephen W Hydroformylation
JP2010511015A (ja) * 2006-11-30 2010-04-08 ビーエーエスエフ ソシエタス・ヨーロピア オレフィンのヒドロホルミル化法

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EP4126354A1 (en) 2023-02-08
US20230159424A1 (en) 2023-05-25
US12391638B2 (en) 2025-08-19
CN115397555A (zh) 2022-11-25
CN115397555B (zh) 2025-07-04
WO2021202225A1 (en) 2021-10-07

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