CN115397555B - 包含氟膦配体及其前体的加氢甲酰化催化剂 - Google Patents
包含氟膦配体及其前体的加氢甲酰化催化剂 Download PDFInfo
- Publication number
- CN115397555B CN115397555B CN202180025650.XA CN202180025650A CN115397555B CN 115397555 B CN115397555 B CN 115397555B CN 202180025650 A CN202180025650 A CN 202180025650A CN 115397555 B CN115397555 B CN 115397555B
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- CN
- China
- Prior art keywords
- olefin
- reaction product
- hydroformylation
- hydroformylation reaction
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0208—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202063003600P | 2020-04-01 | 2020-04-01 | |
| US63/003,600 | 2020-04-01 | ||
| PCT/US2021/024068 WO2021202225A1 (en) | 2020-04-01 | 2021-03-25 | Hydroformylation catalysts comprising fluorophosphine ligands and precursors thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115397555A CN115397555A (zh) | 2022-11-25 |
| CN115397555B true CN115397555B (zh) | 2025-07-04 |
Family
ID=75562831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202180025650.XA Active CN115397555B (zh) | 2020-04-01 | 2021-03-25 | 包含氟膦配体及其前体的加氢甲酰化催化剂 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US12391638B2 (https=) |
| EP (1) | EP4126354A1 (https=) |
| JP (1) | JP2023520500A (https=) |
| CN (1) | CN115397555B (https=) |
| WO (1) | WO2021202225A1 (https=) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021202225A1 (en) | 2020-04-01 | 2021-10-07 | Exxonmobil Chemical Patents Inc. | Hydroformylation catalysts comprising fluorophosphine ligands and precursors thereof |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL134286C (https=) | 1962-01-23 | |||
| US3310576A (en) | 1963-02-05 | 1967-03-21 | Exxon Research Engineering Co | Hydroformylation catalyst and process relating thereto |
| US3418351A (en) | 1965-05-17 | 1968-12-24 | Shell Oil Co | Recovery of hydroformylation cobalt-carbonyl-hydrocarbyl-tert-phosphine catalyst complex |
| US3510524A (en) | 1966-08-23 | 1970-05-05 | Gulf Research Development Co | Oxo process |
| US3954877A (en) * | 1967-10-12 | 1976-05-04 | Jefferson Chemical Co., Inc. | Hydroformylation of olefins |
| US4070403A (en) | 1975-07-21 | 1978-01-24 | Uop Inc. | Catalytic hydroformylation process |
| GB8430225D0 (en) | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation catalyst removal |
| US5237105A (en) | 1992-05-29 | 1993-08-17 | Exxon Chemical Patents Inc. | Method for removing hydroformylation catalyst |
| WO2003082788A1 (en) | 2002-03-29 | 2003-10-09 | Exxonmobil Chemical Patents Inc. | Improved cobalt flash process |
| DE10349343A1 (de) * | 2003-10-23 | 2005-06-02 | Basf Ag | Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden |
| EP1697289B1 (en) * | 2003-12-18 | 2014-06-11 | ExxonMobil Chemical Patents Inc. | Improvements in or relating to hydroformylation |
| CN101600674B (zh) * | 2006-11-30 | 2013-09-11 | 巴斯夫欧洲公司 | 烯烃的加氢甲酰化方法 |
| ES2515266T5 (es) * | 2009-02-12 | 2018-12-03 | Lg Chem, Ltd. | Composición de catalizador para hidroformilación y procedimiento para la preparación de aldehídos utilizando la misma |
| KR101411040B1 (ko) * | 2012-05-24 | 2014-06-27 | 주식회사 엘지화학 | 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 히드로포밀화 방법 |
| KR102383971B1 (ko) * | 2014-02-23 | 2022-04-06 | 엔테그리스, 아이엔씨. | 코발트 전구체 |
| EP3144073A1 (en) | 2015-09-17 | 2017-03-22 | Henkel AG & Co. KGaA | Dispenser, kit and method for applying an activator for a curable material |
| WO2021202225A1 (en) | 2020-04-01 | 2021-10-07 | Exxonmobil Chemical Patents Inc. | Hydroformylation catalysts comprising fluorophosphine ligands and precursors thereof |
-
2021
- 2021-03-25 WO PCT/US2021/024068 patent/WO2021202225A1/en not_active Ceased
- 2021-03-25 EP EP21719773.0A patent/EP4126354A1/en not_active Withdrawn
- 2021-03-25 US US17/906,843 patent/US12391638B2/en active Active
- 2021-03-25 JP JP2022560140A patent/JP2023520500A/ja not_active Ceased
- 2021-03-25 CN CN202180025650.XA patent/CN115397555B/zh active Active
Non-Patent Citations (2)
| Title |
|---|
| Cobalt-Catalyzed Hydroformylation of Alkenes: Generation and Recycling of the Carbonyl Species, and Catalytic Cycle;Fre´de´ric Hebrard et al.，;《Chem. Rev.》;第109卷;第4272–4282页 * |
| Unsaturation in binuclear iron trifluorophosphine carbonyl derivatives: comparison with binary iron carbonyls;Shida Gong et al.，;《Journal of Coordination Chemistry》;第65卷(第14期);第2459–2477页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP4126354A1 (en) | 2023-02-08 |
| US20230159424A1 (en) | 2023-05-25 |
| US12391638B2 (en) | 2025-08-19 |
| CN115397555A (zh) | 2022-11-25 |
| JP2023520500A (ja) | 2023-05-17 |
| WO2021202225A1 (en) | 2021-10-07 |
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