JP2023514934A - 排泄物を覆い隠し、飛沫や落下音を防止するための発泡性組成物 - Google Patents
排泄物を覆い隠し、飛沫や落下音を防止するための発泡性組成物 Download PDFInfo
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- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 229940061515 laureth-4 Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229960003136 leucine Drugs 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229940037627 magnesium lauryl sulfate Drugs 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229940057948 magnesium stearate Drugs 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- HBNDBUATLJAUQM-UHFFFAOYSA-L magnesium;dodecyl sulfate Chemical compound [Mg+2].CCCCCCCCCCCCOS([O-])(=O)=O.CCCCCCCCCCCCOS([O-])(=O)=O HBNDBUATLJAUQM-UHFFFAOYSA-L 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229960004249 sodium acetate Drugs 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229940045902 sodium stearyl fumarate Drugs 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940033134 talc Drugs 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/044—Solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C11D2111/14—
-
- C11D2111/42—
Abstract
Description
本発明に従った組成物の例
本発明に従った組成物の7例を、以下の表1~4に示す。これらの組成物は全てルースパウダーの形態である。
アルキル安息香酸ナトリウム塩の代わりにラウリルサルコシン酸ナトリウム、ココイルイセチオン酸ナトリウム、及びラウリル硫酸ナトリウムの混合物を用い、表1~4に示した組成物と同じ組成物を試験した。粉体を周囲温度で15日間保存した後、組成物を水に溶解しても、組成物は泡沫を形成しなくなった。
Mr.Bricolage社から販売されている、水平排水口を有する白色セラミック製の簡易設置型トイレCLEO WC 商品番号647982を試験に使用した。これらのトイレは固定しておらず、簡単に操作できる。
泡沫の高さは、30秒後:9.5cm;1分30秒後:9.5cm;2分00秒後:9.5cm;2分30秒後:9cm;3分後:9cm;4分後:9cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、粉体は完全には溶解せず、飛沫はなく、塊状物は見えない。
泡沫の高さは、30秒後:9cm;1分30秒後:8.5cm;2分00秒後:8.5cm;2分30秒後:8.5cm;3分後:8cm;4分後:7cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、飛沫はなく、塊状物は見えず、対象物は緩衝されている。
泡沫の高さは、30秒後:9cm;1分30秒後:8.5cm;2分00秒後:8.5cm;2分30秒後:8.5cm;3分後:8cm;4分後:7cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、飛沫はなく、塊状物は見えず、対象物は緩衝されている。
泡沫の高さは、30秒後:9cm;1分30秒後:8.5cm;2分00秒後:8.5cm;2分30秒後:8.5cm;3分後:8cm;4分後:7cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、飛沫はなく、塊状物は見えず、対象物は緩衝されている。
泡沫の高さは、30秒後:8cm;1分30秒後:7.5cm;2分00秒後:7cm;2分30秒後:6.5cm;3分後:6cm;4分後:5cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、飛沫はなく、塊状物は見えず、対象物は緩衝されている。
泡沫の高さは、30秒後:9.5cm;1分30秒後:8.5cm;2分00秒後:8cm;2分30秒後:7cm;3分後:6.5cm;4分後:5cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、飛沫はなく、塊状物は見えず、対象物は緩衝されている。
泡沫の高さは、30秒後:7cm;1分30秒後:5.5cm;2分00秒後:5cm;2分30秒後:5cm;3分後:4cm;4分後:3.5cmである。泡沫は崩壊しやすく、泡沫は落下後に密集せず、緩衝はごくわずかで、音がある。
泡沫の高さは、30秒後:9cm;1分30秒後:8.5cm;2分00秒後:8cm;2分30秒後:7.5cm;3分後:7cm;4分後:5.5cmである。泡沫は空気を含み、音は弱まり、穴は閉じ、飛沫はなく、塊状物は見えず、対象物は緩衝されている。
BETが120m2/gであるシリカを試験した。2か月後の粉体の凝集の結果は、BET法に従って測定した比表面積が450m2/gのシリカより劣る。シリカは泡沫中に固形で存在することから、泡沫を重くして気泡を壊す傾向がある。シリカが細かいほど(数値で示す)、泡沫は形成されたまま安定して残る。
シリカを2種の割合、つまり0.26%、即ち0.10g、及び0.51%、即ち0.20gで検討した。泡沫の高さ、緩衝性、対象物の落下時や落下後の泡沫の挙動の点でトイレの性能に影響はなかった。一方、シリカは保存後の性能、及び粉体の凝集に影響を与える。
40℃で15日間(閉鎖したオーブン内で保存)、周囲温度(平均湿度)で1か月間保存した後の、及び40℃で15日間、周囲温度(1か月間と同様)で2か月間保存した後の各組成物について、上記と同様の実験を実施した。符号Cは、組成物をカップ中で保存したことを示し、符号Sは、組成物を小袋中で保存したことを示す。
組成物184‐51は泡沫を形成するが、緩衝性は劣り、若干の飛沫が認められる(カップに保存した粉体)。カップに保存した組成物184‐52も同様である。カップに保存した組成物184‐53については、性能に変化はない。アルミニウム小袋に保存した場合、緩衝性は弱く、得られた泡沫は崩壊しやすく、塊状物の落下後に密集しない。小袋に保存した組成物184‐54については、変質は認められない。一方、カップに保存した場合は、泡沫が少なく、緩衝性もほとんど得られない。
カップに保存した組成物184‐51は、15日間保存した場合より緩衝性が低い。組成物184‐52についても同様であり、更に若干の飛沫が発生している。他の組成物については、性能は安定しており、40℃で15日後に得られた場合と同一である。
カップに保存した組成物184‐51はあまり緩衝しない。組成物184‐52も同様であり、更に飛沫は多く、音を減衰することはない。他の組成物については、性能は安定しており、40℃で15日後に得られた場合と同一である。組成物184‐48、184‐50、及び184‐54については、驚くべきことに、得られた泡沫の高さが40℃で15日後に得られた泡沫よりも高いことが見出されている。
40℃で15日間保存した後、組成物184‐48を収容した小袋は膨張しており、これは、小袋内で化学反応が起こり、それによりCO2が放出されたことを示している。組成物184‐51及び184‐52についても同様であり、それらの粉体は小袋内で大幅に凝集し、膨張もしている。組成物184‐53を含む小袋は少し膨張しているが、組成物はルースパウダーの形態を保っている(塊が形成されてない)。
組成が不明なマリン香料は、2か月間の保存後、組成物を全体に渡って不安定にし、かつ/又は、もはや匂いを感知できない。
Claims (11)
- 排泄物の落下音をマスキングし、少なくとも1種の酸及び少なくとも1種の塩基から成る発泡剤を含有する発泡性組成物であって、前記塩基及び前記酸は二酸化炭素を生成しながら水の存在下で反応可能であり、前記組成物はアニオン性界面活性剤も含有し、前記組成物はルースパウダー状であり、前記界面活性剤の質量パーセントは3%以上4%以下、特に3.5%未満であり、かつ/又は酸(単数又は複数)+塩基(単数又は複数)の混合物の質量パーセントは90%以上であることを特徴とする組成物。
- 前記発泡剤は、クエン酸、スルファミン酸、及び重炭酸ナトリウムから成り、クエン酸の質量パーセントはスルファミン酸の質量パーセントより大きいことが好ましい、請求項1に記載の組成物。
- 前記重炭酸ナトリウムの平均径は130μm以下である、請求項2に記載の組成物。
- 前記界面活性剤はアルキルベンゼンスルホン酸ナトリウム塩、特にアルキル鎖が直鎖状であるアルキルベンゼンスルホン酸塩から選択される、請求項1~3のいずれか1項に記載の組成物。
- 前記界面活性剤の質量パーセントは1.5%以下、特に1.2%である、請求項1~4のいずれか1項に記載の組成物。
- ガム、特にグアーガム、デンプン、ペクチン、寒天、ゼラチン、カラギーナン、及びアルギン酸塩、特にアルギン酸ナトリウムから選択される増粘剤を更に含有する、請求項1~5のいずれか1項に記載の組成物。
- 前記増粘剤の質量パーセントはおよそ2.00%未満、特に1.60%である、請求項5に記載の組成物。
- 前記組成物は粉体状のシリカを更に含有し、前記シリカの比表面積は特に、Brunauer‐Emmett‐Teller(BET)法に従って測定すると420m2/g以上、特に420m2/gである、請求項1~7のいずれか1項に記載の組成物。
- 前記シリカの質量パーセントは0.08~0.3%、特に0.26%、又は0.51%である、請求項7に記載の組成物。
- 精油ではない合成香料を更に含有する、請求項1~9のいずれか1項に記載の組成物。
- 防水性及び気密性の可撓性小袋であって、請求項1~10のいずれか1項に記載の組成物を収容することを特徴とする小袋。
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JPH0372124A (ja) | 1989-08-11 | 1991-03-27 | Hiroaki Hino | 水洗便器内用水飛散防止剤 |
JPH06105893A (ja) | 1992-09-24 | 1994-04-19 | Saburou Takebe | 発泡式消臭剤 |
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US7563756B2 (en) | 2003-08-27 | 2009-07-21 | Brandi Brady | Scented tablet for toilet and method for scenting restroom effluent |
US20070039089A1 (en) | 2005-08-19 | 2007-02-22 | Worrel Keith A | Noise and splash attenuation agent and device |
US7638475B2 (en) * | 2006-03-24 | 2009-12-29 | Georgia-Pacific Consumer Products Lp | Space saving toilet cleaning system |
WO2008020246A2 (en) | 2006-08-18 | 2008-02-21 | Lavitec Corporation Limited | Sanitary composition |
JP2010063503A (ja) | 2008-09-08 | 2010-03-25 | Ishizaka Tsutomu | イレ用発泡組成物、およびトイレ用発泡剤ならびにトイレ用発泡剤充填スプレー |
JP2011012410A (ja) | 2009-06-30 | 2011-01-20 | Old Monterey:Kk | 洋式トイレ用屎尿飛散防止剤、及びその使用方法 |
CN102367399A (zh) | 2011-05-25 | 2012-03-07 | 王国松 | 卫生泡泡 |
JP2015052257A (ja) | 2013-09-06 | 2015-03-19 | 正太郎 外村 | トイレ排泄時水はね等防止泡 |
JP6425064B2 (ja) | 2014-07-29 | 2018-11-21 | とべる工房株式会社 | トイレ排泄時水はね等防止泡 |
CN109777634A (zh) * | 2019-01-25 | 2019-05-21 | 关汉杰 | 一种遇水发泡胶囊及其制备方法 |
-
2019
- 2019-12-18 WO PCT/FR2019/053167 patent/WO2021123511A1/fr unknown
- 2019-12-18 US US17/786,436 patent/US20230034564A1/en active Pending
- 2019-12-18 JP JP2022538180A patent/JP2023514934A/ja active Pending
- 2019-12-18 EP EP19850723.8A patent/EP4077609A1/fr active Pending
Also Published As
Publication number | Publication date |
---|---|
EP4077609A1 (fr) | 2022-10-26 |
WO2021123511A1 (fr) | 2021-06-24 |
US20230034564A1 (en) | 2023-02-02 |
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