JP2022509074A - ケラチン物質をケア及び/又はメイクアップするための無水組成物 - Google Patents
ケラチン物質をケア及び/又はメイクアップするための無水組成物 Download PDFInfo
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- JP2022509074A JP2022509074A JP2021527054A JP2021527054A JP2022509074A JP 2022509074 A JP2022509074 A JP 2022509074A JP 2021527054 A JP2021527054 A JP 2021527054A JP 2021527054 A JP2021527054 A JP 2021527054A JP 2022509074 A JP2022509074 A JP 2022509074A
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- 239000000203 mixture Substances 0.000 title claims abstract description 140
- 239000000126 substance Substances 0.000 title claims abstract description 32
- 102000011782 Keratins Human genes 0.000 title claims abstract description 19
- 108010076876 Keratins Proteins 0.000 title claims abstract description 19
- -1 hydride functionality Chemical group 0.000 claims abstract description 73
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 72
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 44
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 40
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 28
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 41
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- YFCVAZGXPLMNDG-UHFFFAOYSA-N dimethyl-bis[[methyl(diphenyl)silyl]oxy]silane Chemical compound C=1C=CC=CC=1[Si](C)(C=1C=CC=CC=1)O[Si](C)(C)O[Si](C)(C=1C=CC=CC=1)C1=CC=CC=C1 YFCVAZGXPLMNDG-UHFFFAOYSA-N 0.000 claims description 6
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 229940117985 trimethyl pentaphenyl trisiloxane Drugs 0.000 claims description 6
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- ABTZKZVAJTXGNN-UHFFFAOYSA-N stearyl heptanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCC ABTZKZVAJTXGNN-UHFFFAOYSA-N 0.000 claims description 4
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 3
- PGJDCIDLMPSNPX-UHFFFAOYSA-N 2-octyldecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCC PGJDCIDLMPSNPX-UHFFFAOYSA-N 0.000 claims description 3
- HXVCOQUDJKMJQY-UHFFFAOYSA-N 2-octyldodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC HXVCOQUDJKMJQY-UHFFFAOYSA-N 0.000 claims description 3
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 3
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 claims description 3
- SZAMSYKZCSDVBH-CLFAGFIQSA-N [(z)-octadec-9-enyl] (z)-docos-13-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(=O)OCCCCCCCC\C=C/CCCCCCCC SZAMSYKZCSDVBH-CLFAGFIQSA-N 0.000 claims description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 3
- 229940105984 diethylhexyl succinate Drugs 0.000 claims description 3
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940100463 hexyl laurate Drugs 0.000 claims description 3
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 3
- 229940120511 oleyl erucate Drugs 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 claims description 2
- KMUBFTBPGVULKC-UHFFFAOYSA-N 2-hexyldecyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC KMUBFTBPGVULKC-UHFFFAOYSA-N 0.000 claims description 2
- LNRUVXAPKCPQGX-UHFFFAOYSA-N 2-octyldodecyl benzoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)C1=CC=CC=C1 LNRUVXAPKCPQGX-UHFFFAOYSA-N 0.000 claims description 2
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 claims description 2
- 241000283153 Cetacea Species 0.000 claims description 2
- GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 claims description 2
- 241000238631 Hexapoda Species 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 240000000111 Saccharum officinarum Species 0.000 claims description 2
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- 239000012164 animal wax Substances 0.000 claims description 2
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- 239000007799 cork Substances 0.000 claims description 2
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- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims description 2
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- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 2
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- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 claims 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims 1
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- PVNIQBQSYATKKL-UHFFFAOYSA-N Glycerol trihexadecanoate Natural products CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 claims 1
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- 150000003219 pyrazolines Chemical class 0.000 description 1
- 150000003220 pyrenes Chemical class 0.000 description 1
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 235000019246 rhodoxanthin Nutrition 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 235000009514 rubixanthin Nutrition 0.000 description 1
- 239000000455 rubixanthin Substances 0.000 description 1
- ABTRFGSPYXCGMR-SDPRXREBSA-N rubixanthin Natural products O[C@H]1CC(C)(C)C(/C=C/C(=C\C=C\C(=C/C=C/C=C(\C=C\C=C(/C=C/C=C(\CC/C=C(\C)/C)/C)\C)/C)\C)/C)=C(C)C1 ABTRFGSPYXCGMR-SDPRXREBSA-N 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 1
- LLELVHKMCSBMCX-UHFFFAOYSA-M sodium 1-[(4-chloro-5-methyl-2-sulfophenyl)diazenyl]naphthalen-2-olate Chemical compound [Na+].Cc1cc(N=Nc2c(O)ccc3ccccc23)c(cc1Cl)S([O-])(=O)=O LLELVHKMCSBMCX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 1
- VRDAELYOGRCZQD-NFLRKZIHSA-M sodium;4-[(2z)-2-[(5e)-5-[(2,4-dimethylphenyl)hydrazinylidene]-4,6-dioxocyclohex-2-en-1-ylidene]hydrazinyl]benzenesulfonate Chemical compound [Na+].CC1=CC(C)=CC=C1N\N=C(/C(=O)C=C\1)C(=O)C/1=N\NC1=CC=C(S([O-])(=O)=O)C=C1 VRDAELYOGRCZQD-NFLRKZIHSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001797 sucrose acetate isobutyrate Substances 0.000 description 1
- 125000000185 sucrose group Chemical group 0.000 description 1
- 229940099373 sudan iii Drugs 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- UQSGRKAOAGGYCU-UHFFFAOYSA-N trimethyl-[phenyl(silyloxysilyloxy)silyl]oxysilane Chemical compound [SiH3]O[SiH2]O[SiH](O[Si](C)(C)C)C1=CC=CC=C1 UQSGRKAOAGGYCU-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019245 violaxanthin Nutrition 0.000 description 1
- SZCBXWMUOPQSOX-PSXNNQPNSA-N violaxanthin Chemical compound C(\[C@@]12[C@](O1)(C)C[C@H](O)CC2(C)C)=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/[C@]1(C(C[C@@H](O)C2)(C)C)[C@]2(C)O1 SZCBXWMUOPQSOX-PSXNNQPNSA-N 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- Veterinary Medicine (AREA)
- Birds (AREA)
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- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
a)組成物の総質量に対して10質量%~40質量%の少なくとも1種の不揮発性非フェニルシリコーン油、
b)少なくとも1種の不揮発性炭化水素系油及び/又はフェニルシリコーン油、
c)少なくとも1種の高粘度エステル、並びに
d)低粘度オルガノポリシロキサン中の、不飽和官能性シリコーン樹脂と、ペンダントヒドリド官能性を有するSi-H官能性オルガノポリシロキサン架橋剤と、任意選択で、4個以上の炭素原子を有する不飽和炭化水素との反応生成物
を含む、組成物に関する。
本発明はまた、皮膚及び唇等のケラチン物質、好ましくは唇をケア及び/又はメイクアップするための方法であって、本発明による無水組成物をケラチン物質に塗布することによる、方法に関する。
Description
- 組成物の総質量に対して5~30質量%の不揮発性炭化水素化無極性油又はこれらの混合物と、
- 組成物の総質量に対して43~90質量%の総含有量の不揮発性シリコーン油であって、前記不揮発性シリコーン油の少なくとも1種は不揮発性フェニル化シリコーン油である、不揮発性シリコーン油と、
- 組成物の総質量に対して3~30質量%のワックス又はこれらの混合物と
を含む少なくとも1つの脂肪相を含む、固体化粧用組成物を開示している。
a)10質量%~40質量%の少なくとも1種の不揮発性非フェニルシリコーン油、
b)少なくとも1種の不揮発性炭化水素系油及び/又はフェニルシリコーン油、
c)少なくとも1種の高粘度エステル、並びに
d)低粘度オルガノポリシロキサン中の、不飽和官能性シリコーン樹脂と、ペンダントヒドリド官能性(pendant hydroid functionality)を有するSi-H官能性オルガノポリシロキサン架橋剤と、任意選択で、4個以上の炭素原子を有する不飽和炭化水素との反応生成物
を含む、組成物が提供される。
a)組成物の総質量に対して10質量%~40質量%の少なくとも1種の不揮発性非フェニルシリコーン油、
b)少なくとも1種の不揮発性炭化水素系油及び/又はフェニルシリコーン油、
c)少なくとも1種の高粘度エステル、並びに
d)低粘度オルガノポリシロキサン中の、不飽和官能性シリコーン樹脂と、ペンダントヒドリド官能性を有するSi-H官能性オルガノポリシロキサン架橋剤と、任意選択で、4個以上の炭素原子を有する不飽和炭化水素との反応生成物
を含む。
(Y×10-3×9.8)/L
によってNm-1に変換する。
「油」という用語は、室温(25℃)及び大気圧(760mmHg)で液体である、水不混和性の非水性化合物を意味する。
- ポリジメチルシロキサン(PDMS)、
- ペンダントである、且つ/又はシリコーン鎖の末端にある脂肪族基、特にアルキル基又はアルコキシ基を含むPDMSであって、これらの基がそれぞれ2~12個の炭素原子を含むPDMS、
- 脂肪族基、又はヒドロキシル、チオール、及び/若しくはアミン基等の官能基を含むPDMS、
- ヒドロキシル、チオール、及び/又はアミン基等の官能基で置換されているポリアルキルメチルシロキサン、
- 脂肪酸、脂肪族アルコール、又はポリオキシアルキレンで修飾されているポリシロキサン、及びこれらの混合物。
R1、R2、R5、及びR6は、一緒に又は別々に、1~6個の炭素原子を含有するアルキル基であり、
R3及びR4は、一緒に又は別々に、1~6個の炭素原子を含有するアルキル基、ビニル基、アミン基、又はヒドロキシル基であり、
Xは、1~6個の炭素原子を含有するアルキル基、ヒドロキシル基、又はアミン基であり、
n及びpは、流体化合物となるように、特に25℃での粘度が100センチストークス(cSt)から1000cStの間となるように選択される整数である]
のシリコーンから選択されうる。
- R1~R6置換基及びXがメチル基を表し、p及びnが、粘度を100cSt又は350cStとするもの、例えば、Dow Corning社によって、それぞれBelsil DM100及びDow Corning 200 Fluid 350 CSの名称で販売されている製品;
- R1~R6置換基がメチル基を表し、X基がヒドロキシル基を表し、n及びpが、粘度を700cStとするもの、例えばMomentive社によって、Baysilone Fluid T0.7の名称で販売されている製品;
- R1~R6置換基がメチル基を表し、X基がヒドロキシル基を表し、n及びpが、粘度を1000cStとするもの。
不揮発性炭化水素系油
「炭化水素系油」という用語は、炭素及び水素原子、並びに任意選択で酸素及び窒素原子から本質的に形成され、又は更にはこれらによって構成され、且つケイ素又はフッ素原子を含有しない油を意味する。これは、アルコール、エステル、エーテル、カルボン酸、アミン、及び/又はアミド基を含有してもよい。
- 流動パラフィン又はその誘導体、
- スクワラン、
- イソエイコサン、
- ナフタレン油、
- ポリブチレン、例えばAmoco社によって販売又は製造されている、Indopol H-100(モル質量、すなわちMW=965g/mol)、Indopol H-300(MW=1340g/mol)、及びIndopol H-1500(MW=2160 g/mol)、
- 水添又は非水添ポリイソブテン、例えば日本油脂株式会社によって販売されているParleam(登録商標)、Amoco社によって販売若しくは製造されているPanalane H-300 E(MW=1340g/mol)、Synteal社によって販売若しくは製造されているViseal 20000(MW=6000g/mol)、及びWitco社によって販売又は製造されているRewopal PIB 1000(MW=1000g/mol)、又は代替的には日油株式会社によって販売されているParleam Lite等、
- デセン/ブテンコポリマー、ポリブテン/ポリイソブテンコポリマー、特にIndopol L-14、
- 水添及び非水添ポリデセン、例えばMobil Chemicals社によって販売若しくは製造されているPuresyn 10(MW=723g/mol)及びPuresyn 150(MW=9200g/mol)、又は代替的にはExxonMobil Chemical社により販売されているPuresyn 6、
- 合成エステル、例えば、式R1COOR2[式中、R1は、4~40個の炭素原子を含む、直鎖状又は分枝状脂肪酸残基を表し、R2は、4~40個の炭素原子を含有する、とりわけ分枝状である炭化水素系鎖を表し、但しR1+R2≧16である]の油、例えば、パーセリン(purcellin)油(オクタン酸セトステアリル)、イソノナン酸イソノニル、安息香酸C12~C15アルキル、パルミチン酸2-エチルヘキシル、ネオペンタン酸オクチルドデシル、ヘプタン酸ステアリル、カプリル酸ステアリル、ステアリン酸2-オクチルドデシル、エルカ酸2-オクチルドデシル、エルカ酸オレイル、イソステアリン酸イソステアリル、安息香酸2-オクチルドデシル、オクタン酸、デカン酸、若しくはリシノール酸のアルコールエステル若しくはポリアルコールエステル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ステアリン酸ブチル、ラウリン酸ヘキシル、パルミチン酸2-エチルヘキシル、ラウリン酸2-ヘキシルデシル、パルミチン酸2-オクチルデシル、ミリスチン酸2-オクチルドデシル、又はコハク酸2-ジエチルヘキシル; 好ましくは、好ましい合成エステルR1COOR2[式中、R1は、4~40個の炭素原子を含む、直鎖状又は分枝状脂肪酸残基を表し、R2は、4~40個の炭素原子を含有する、とりわけ分枝状である炭化水素系鎖を表す]は、R1+R2≧20であるものである、
- ビニルピロリドン/1-ヘキサデセンコポリマー等のビニルピロリドンのコポリマー、例えば、ISPによって市販又は製造されているAntaron V-216(MW=7300 g/mol)、
- 並びにこれらの混合物から選択されうる。
「フェニルシリコーン油」という表現は、少なくとも1つのフェニル置換基を有するシリコーン油を表す。
-Si(CH3)2-O-
に対応する。
に対応する、ジメチコン断片を任意選択で有するフェニルシリコーン油。
に対応する、ジメチコン断片を任意選択で有するフェニルシリコーン油。
に対応する。
に対応する、少なくとも1つのジメチコン断片を有するフェニルシリコーン油。
- R1~R10は、互いに独立して、飽和又は不飽和の、直鎖状、環状、又は分枝状C1~C30炭化水素系基であり、
- m、n、p、及びqは、互いに独立して、0から900の間の整数であり、但し、和m+n+qは0以外である]
に対応するフェニルシリコーン油及びこれらの混合物。
- R1~R6は、互いに独立して、飽和若しくは不飽和の、直鎖状、環状、若しくは分枝状C1~C30炭化水素系基、好ましくはC6~C14アリール基、又はアルキル部分がC1~C3アルキルであるアラルキル基であり、
- m、n、及びpは、互いに独立して、0から100の間の整数であり、但し、和n+mは1から100の間である]
に対応する、少なくとも1つのジメチコン断片を任意選択で有するフェニルシリコーン油及びこれらの混合物。
に対応する。特に、m及びpは、化合物(VIII)を不揮発性油とするような値である。
- Rは、互いに独立して、飽和又は不飽和の、直鎖状、環状、又は分枝状C1~C30炭化水素系基であり、好ましくはRは、C1~C30アルキル基、好ましくはC6~C14アリール基、又はアルキル部分がC1~C3アルキルであるアラルキル基であり、
- m及びnは、互いに独立して、0から100の間の整数であり、但し、和n+mは1から100の間である]
に対応する、ジメチコン断片を有しない不揮発性フェニルシリコーン油及びこれらの混合物。
同一であっても異なってもよいR1、R2、R5、及びR6は、1~6個の炭素原子を含有するアルキル基であり、
同一であっても異なってもよいR3及びR4は、1~6個の炭素原子を含有するアルキル基、又は(好ましくは、C6~C14)アリール基であり、但し、R3及びR4の少なくとも1つはフェニル基であり、
Xは、1~6個の炭素原子を含有するアルキル基、ヒドロキシル基、又はビニル基であり、
n及びpは、1以上の整数であり、油に、200000g/mol未満、好ましくは150000g/mol未満、より好ましくは100000g/mol未満の質量平均分子量を与えるように選択される]
に対応する、少なくとも1つのジメチコン断片を任意選択で有するフェニルシリコーン油及びこれらの混合物。
に対応する、ジメチコン断片を有しないフェニルシリコーン油、
より好ましくは、トリメチルペンタフェニルトリシロキサン又はテトラメチルテトラフェニルトリシロキサンから選択される不揮発性フェニルシリコーン油との両方を含む。
高粘度とは、エステルが、室温で少なくとも10000cpsの粘度を有することを意味する。
、スクロースの綿実油又はダイズ油の脂肪酸エステルが挙げられうる。
本発明の文脈において検討するワックスは、一般に、室温(25℃)で固体であり、固体/液体の可逆的な状態変化を伴い、30℃以上、好ましくは40℃以上の融点を有し、融点が最高200℃、特に最高120℃でありうる、親油性化合物である。
本発明の目的では、「着色剤」という用語は、好適な化粧品媒体中に十分な量で配合される場合、着色された光学効果をもたらすことができる化合物を意味する。
本発明によって用いられる水溶性着色剤は、より詳細には、水溶性染料である。
「顔料」という用語は、液体有機相に不溶性であり、組成物及び/又は組成物によって生成される沈着物を着色及び/又は不透明化することを意図する、白色の、又は着色されている無機(鉱物)又は有機粒子を意味するものとして理解するべきである。
- コチニールカルミン;
- アゾ染料、アントラキノン染料、インジゴイド染料、キサンテン染料、ピレン染料、キノリン染料、トリフェニルメタン染料、又はフルオラン染料の有機顔料。
- 有機レーキは、アゾ、アントラキノン、インジゴイド、キサンテン、ピレン、キノリン、トリフェニルメタン、又はフルオラン染料等の酸性染料の不溶性ナトリウム、カリウム、カルシウム、バリウム、アルミニウム、ジルコニウム、ストロンチウム、又はチタン塩であってもよく、これらの染料は少なくとも1つのカルボン酸又はスルホン酸基を場合によって含む。
本特許出願の目的では、「真珠層」という用語は、真珠光沢(iridescent)であってもなくてもよく、特に、特定の軟体動物によって殻の中で生成されるか、又は代替的には合成される、光学干渉による色彩効果を有する、任意の形状の着色粒子を意味する。
本発明の目的では、「ゴニオクロマチック顔料」という用語は、組成物を支持体に広げた場合、CIE 1976色空間のa*b*平面において、45°の入射光角度について、法線に対する観測の角度を0°から80°の間で変更すると、色相角h°における少なくとも20°の変化量Dh°に対応する色軌跡を得ることができる顔料を表す。
好ましい実施形態では、本発明による組成物は、シロキシシリケート樹脂を更に含む。
特定の実施形態では、本発明による無水組成物は、検討する分野において通常用いられる少なくとも1種の添加剤を更に含んでもよい。特に、添加剤は、ガム、アニオン性、カチオン性、両性又は非イオン性の界面活性剤、シリコーン界面活性剤、樹脂、増粘剤、分散剤、抗酸化剤、保存剤、芳香剤、中和剤、防腐剤、追加の化粧活性剤、例えば、ビタミン、加湿剤、皮膚軟化剤又はコラーゲン保護剤、及びこれらの混合物から選択される。
a)合成ワックス、パラフィン、微結晶ワックス、又はこれらの混合物から選択される、少なくとも1種のワックス、
b)金属酸化物顔料、有機レーキ、合成若しくは天然水溶性染料、及びこれらの混合物から選択される、少なくとも1種の着色剤、
c)特に式(I):
R1、R2、R5、及びR6は、一緒に又は別々に、1~6個の炭素原子を含有するアルキル基であり、
R3及びR4は、一緒に又は別々に、1~6個の炭素原子を含有するアルキル基、ビニル基、アミン基、又はヒドロキシル基であり、
Xは、1~6個の炭素原子を含有するアルキル基、ヒドロキシル基、又はアミン基であり、
n及びpは、流体化合物となるように、特に25℃での粘度が100センチストークス(cSt)から1000cStの間となるように選択される整数である]
のシリコーンから選択される、組成物の総質量に対して10質量%~40質量%の少なくとも1種の不揮発性非フェニルシリコーン油、
d)水添ポリイソブテン、ネオペンタン酸オクチルドデシル、ヘプタン酸ステアリル、カプリル酸ステアリル、ビニルピロリドン/1-ヘキサデセンコポリマーから選択される、少なくとも1種の不揮発性炭化水素系油、及び下式(III):
に対応する、ジメチコン断片を有しないフェニルシリコーン油、より好ましくは、トリメチルペンタフェニルトリシロキサン又はテトラメチルテトラフェニルトリシロキサンから選択される、少なくとも1種のフェニルシリコーン油、
e)ジメチコン中の、ビニルMQ樹脂と、ポリ(メチルハイドロジェン)ジメチルシロキサンと、任意選択で、C10~C24不飽和の直鎖状又は分枝状アルケンとの反応生成物、並びに
f)式[(CH3)3SiO]x(SiO4/2)y(MQ単位)[式中、x及びyは50~80の範囲の整数である]のトリメチルシロキシシリケート
を含む、組成物に関する。
本発明の組成物は、スキンケア、メイクアップ、又は美容処置製品として用いるのに好適である。より詳細には、本発明の組成物は、メイクアップ製品の形態、例えば口紅等である。
以下の配合を有する口紅を調製する(別段の指示がない限り、含有量は活性物質の質量百分率として表す)。
以下の工程に従って口紅を調製した:
i)93℃ですべての成分を混合し、IKA Blender Euro - ST P CV S25モデルによって、300r/分で、混合物が均質になるまで撹拌する;
ii)均質になった混合物を93℃で口紅型に注ぎ、固体化するまで、25℃で混合物を型の中で放置する;
iii)固体混合物を口紅型から取り出す。
口紅の硬度、口紅の形状の安定性、口紅の展延性、色移り、色の摩耗、口紅の塗布後のべたつかない感覚及び乾燥しない感覚に関する評価を実行する。
組成物を24時間、38℃に加熱する;
加熱した温度で組成物を唇に塗布する。
同じ力を用いて、前腕の同じ領域に、組成物を3回繰り返し塗布する;
組成物の質量損失を計量する;
組成物が塗布された前腕の領域のサイズを測定する;
1平方センチメートル当たりの質量損失を計算する。
5: 非常に良好;
4: 基本的に良好;
3: 許容される;
2: 多少不良であり、許容されない:
1: 不良であり、許容されない。
5:低;
3:中;
1:高。
Claims (15)
- ケラチン物質をケア及び/又はメイクアップするための無水組成物であって、
a)組成物の総質量に対して10質量%~40質量%の少なくとも1種の不揮発性非フェニルシリコーン油、
b)少なくとも1種の不揮発性炭化水素系油及び/又はフェニルシリコーン油、
c)少なくとも1種の高粘度エステル、並びに
d)低粘度オルガノポリシロキサン中の、不飽和官能性シリコーン樹脂と、ペンダントヒドリド官能性を有するSi-H官能性オルガノポリシロキサン架橋剤と、任意選択で、4個以上の炭素原子を有する不飽和炭化水素との反応生成物
を含む、組成物。 - 少なくとも1種のワックス及び/又は少なくとも1種の着色剤を更に含むことを特徴とする、請求項1に記載の組成物。
- 少なくとも1種の不揮発性炭化水素系油が、水添ポリイソブチレン、水添ポリデセン、及び合成エステル、例えば、パーセリン油(オクタン酸セトステアリル)、イソノナン酸イソノニル、安息香酸C12~C15アルキル、パルミチン酸2-エチルヘキシル、ネオペンタン酸オクチルドデシル、ヘプタン酸ステアリル、カプリル酸ステアリル、ステアリン酸2-オクチルドデシル、エルカ酸2-オクチルドデシル、エルカ酸オレイル、イソステアリン酸イソステアリル、安息香酸2-オクチルドデシル、アルコール又はポリアルコールオクタノエート、デカノエート、若しくはリシノレエート、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ステアリン酸ブチル、ラウリン酸ヘキシル、パルミチン酸2-エチルヘキシル、ラウリン酸2-ヘキシルデシル、パルミチン酸2-オクチルデシル、ミリスチン酸2-オクチルドデシル、コハク酸2-ジエチルヘキシル、並びにビニルピロリドンのコポリマー、例えば、ビニルピロリドン/1-ヘキサデセンコポリマーから選択されることを特徴とする、請求項1から3のいずれか一項に記載の組成物。
- 少なくとも1種の高粘度エステルが、スクロースのC2~C6カルボン酸エステル、特に、酢酸、イソ酪酸、及びスクロースの混合エステルから選択されることを特徴とする、請求項1から5のいずれか一項に記載の組成物。
- 低粘度オルガノポリシロキサン中の、不飽和官能性シリコーン樹脂と、ペンダントヒドリド官能性を有するSi-H官能性オルガノポリシロキサン架橋剤と、任意選択で、4個以上の炭素原子を有する不飽和炭化水素との反応生成物が、ジメチコン中の、ビニルMQ樹脂と、ポリ(メチルハイドロジェン)ジメチルシロキサンと、任意選択で、C10~C24不飽和の直鎖状又は分枝状アルケンとの反応生成物から選択されることを特徴とする、請求項1から6のいずれか一項に記載の組成物。
- 少なくとも1種のワックスが、動物性ワックス、例えば、ビーワックス、鯨ワックス、ラノリンワックス、ラノリンの誘導体、及びチャイナインセクトワックス; 植物性ワックス、例えば、ライスワックス、カルナウバワックス、キャンデリラワックス、オーリクリーワックス、コルク繊維ワックス、サトウキビワックス、ココアバター、モクロウ、及びスマックワックス; 鉱物ワックス、例えば、モンタンワックス、微結晶ワックス、パラフィン、オゾケライト、石油ゼリー、及びセレシン; 合成ワックス、例えば、ポリエチレンホモポリマー及びコポリマーワックス、合成ビーワックス、フィッシャー・トロプシュ合成によって得られるワックス、並びにシリコーンワックスから選択されることを特徴とする、請求項2から7のいずれか一項に記載の組成物。
- 少なくとも1種の着色剤が、金属酸化物顔料、有機レーキ、合成又は天然水溶性染料、及びこれらの混合物から選択されることを特徴とする、請求項2から8のいずれか一項に記載の組成物。
- シロキシシリケート樹脂を更に含むことを特徴とする、請求項1から9のいずれか一項に記載の組成物。
- シロキシシリケート樹脂が、式[(CH3)3SiO]x(SiO4/2)y(MQ単位)[式中、x及びyは50~80の範囲の整数である]のトリメチルシロキシシリケートから選択されることを特徴とする、請求項10に記載の組成物。
- 少なくとも1種の不揮発性非フェニルシリコーン油が、組成物の総質量に対して、10質量%~40質量%、好ましくは15質量%~35質量%、より好ましくは18質量%~30質量%の範囲の量で存在することを特徴とする、請求項1から11のいずれか一項に記載の組成物。
- 少なくとも1種の不揮発性炭化水素系油及び/又はフェニルシリコーン油が、組成物の総質量に対して、30質量%~70質量%、好ましくは35質量%~65質量%、より好ましくは40質量%~60質量%の範囲の総含有量で存在することを特徴とする、請求項1から12のいずれか一項に記載の組成物。
- ケラチン物質をケア及び/又はメイクアップするための無水組成物であって、
a)合成ワックス、パラフィン、微結晶ワックス、又はこれらの混合物から選択される、少なくとも1種のワックス、
b)金属酸化物顔料、有機レーキ、合成若しくは天然水溶性染料、及びこれらの混合物から選択される、少なくとも1種の着色剤、
c)特に式(I):
R1、R2、R5、及びR6は、一緒に又は別々に、1~6個の炭素原子を含有するアルキル基であり、
R3及びR4は、一緒に又は別々に、1~6個の炭素原子を含有するアルキル基、ビニル基、アミン基、又はヒドロキシル基であり、
Xは、1~6個の炭素原子を含有するアルキル基、ヒドロキシル基、又はアミン基であり、
n及びpは、流体化合物となるように、特に25℃での粘度が100センチストークス(cSt)から1000cStの間となるように選択される整数である]
のシリコーンから選択される、組成物の総質量に対して10質量%~40質量%の少なくとも1種の不揮発性非フェニルシリコーン油、
d)水添ポリイソブテン、ネオペンタン酸オクチルドデシル、ヘプタン酸ステアリル、カプリル酸ステアリル、ビニルピロリドン/1-ヘキサデセンコポリマーから選択される、少なくとも1種の不揮発性炭化水素系油、及び下式(III):
に対応する、ジメチコン断片を有しないフェニルシリコーン油、
より好ましくは、トリメチルペンタフェニルトリシロキサン又はテトラメチルテトラフェニルトリシロキサンから選択される、少なくとも1種のフェニルシリコーン油、
e)ジメチコン中の、ビニルMQ樹脂と、ポリ(メチルハイドロジェン)ジメチルシロキサンと、任意選択で、C10~C24不飽和の直鎖状又は分枝状アルケンとの反応生成物、並びに
f)式[(CH3)3SiO]x(SiO4/2)y(MQ単位)[式中、x及びyは50~80の範囲の整数である]のトリメチルシロキシシリケート
を含む、組成物。 - 皮膚及び唇等のケラチン物質、好ましくは唇をケア及び/又はメイクアップするための方法であって、請求項1から14のいずれか一項に記載の組成物をケラチン物質に塗布することによる、方法。
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