JP2022057030A - バインダー用組成物、バインダー、電極材料、電極及び蓄電デバイス - Google Patents
バインダー用組成物、バインダー、電極材料、電極及び蓄電デバイス Download PDFInfo
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- JP2022057030A JP2022057030A JP2020165083A JP2020165083A JP2022057030A JP 2022057030 A JP2022057030 A JP 2022057030A JP 2020165083 A JP2020165083 A JP 2020165083A JP 2020165083 A JP2020165083 A JP 2020165083A JP 2022057030 A JP2022057030 A JP 2022057030A
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- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZWEDFBKLJILTMC-UHFFFAOYSA-N ethyl 4,4,4-trifluoro-3-hydroxybutanoate Chemical compound CCOC(=O)CC(O)C(F)(F)F ZWEDFBKLJILTMC-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 239000011302 mesophase pitch Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- HRDXJKGNWSUIBT-UHFFFAOYSA-N methoxybenzene Chemical group [CH2]OC1=CC=CC=C1 HRDXJKGNWSUIBT-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- WVFLGSMUPMVNTQ-UHFFFAOYSA-N n-(2-hydroxyethyl)-2-[[1-(2-hydroxyethylamino)-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCO WVFLGSMUPMVNTQ-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical class CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZWWQICJTBOCQLA-UHFFFAOYSA-N o-propan-2-yl (propan-2-yloxycarbothioyldisulfanyl)methanethioate Chemical compound CC(C)OC(=S)SSC(=S)OC(C)C ZWWQICJTBOCQLA-UHFFFAOYSA-N 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 150000003151 propanoic acid esters Chemical class 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 229910021384 soft carbon Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- LPBNNQBYFCZCTA-UHFFFAOYSA-N sulfuric acid;1-tridecoxytridecane Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCCOCCCCCCCCCCCCC LPBNNQBYFCZCTA-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- GJSGYPDDPQRWPK-UHFFFAOYSA-N tetrapentylammonium Chemical compound CCCCC[N+](CCCCC)(CCCCC)CCCCC GJSGYPDDPQRWPK-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
で表わされるモノマー、
及び、芳香族ノニオン性乳化剤を含有するバインダー用組成物。
項2 芳香族ノニオン性乳化剤がスチレン化フェニルエーテル系化合物である項1記載のバインダー用組成物。
項3 更に、アニオン性乳化剤を含有する項1又は2記載のバインダー用組成物。
項4 (メタ)アクリロイル基を2~5有するモノマーを、組成物中におけるモノマー成分(100質量%)に対して、5~15質量%含有する項1~3いずれか記載のバインダー用組成物。
項5 項1~4いずれか記載のバインダー用組成物より作製される電極用バインダー。
項6 項5記載の電極用バインダーと、活物質とを含む、電極材料。
項7 項6記載の電極材料を含む電極。
項8 項7に記載の電極を備える、蓄電デバイス。
本発明のバインダー用組成物は、重合することにより得られる重合体を含有するバインダーのための組成物であり、下記一般式(1)
で表わされるモノマー、
及び、芳香族ノニオン性乳化剤を含有する。
q、rは0~3の数であり、0~2の数であることが好ましく、q+r≧1を満たすことが好ましい。sは0~1の数である。
で表わされる水酸基を有するモノマーを例示することができる。
本発明の電極用バインダーは、「1.バインダー用組成物」の欄で説明した本発明のバインダー用組成物より作製される。具体的には、バインダー用組成物を重合して得られる。重合方法としては、バインダー用組成物を、攪拌しながら温度を上昇させて重合を開始させることで、重合体が水に分散した球形の重合体のラテックスを得ることができる。
本発明のバインダー組成物は、先述の「2.電極用バインダー」の欄で説明した本発明のバインダーを溶媒とともに含有するものであり、バインダーが溶媒に分散されたものであってよい。溶媒は、水、有機溶媒を用いることができる。有機溶媒としては、メタノール、エタノール、n-プロパノール、イソプロパノール、n-ブタノール、イソブタノール、t-ブタノール、ペンタノール、ヘキサノール、ヘプタノール、オクタノール、ノナノール、デカノール、アミルアルコールなどのアルコール類、アセトン、メチルエチルケトン、シクロヘキサノンなどのケトン類、酢酸エチル、酢酸ブチルなどのエステル類、ジエチルエーテル、ジオキサン、テトラヒドロフランなどのエーテル類、N,N-ジメチルホルムアミド、N-メチル-2-ピロリドン(NMP)などのアミド系極性有機溶媒、トルエン、キシレン、クロロベンゼン、オルトジクロロベンゼン、パラジクロロベンゼンなどの芳香族炭化水素類を例示することができる。
本発明の電極材料は、少なくとも活物質、及び先述の「2.電極用バインダー」の欄で説明した本発明のバインダーを含有し、更に導電助剤を含有していてもよい。本発明の電極材料の製造には、本発明の電極用バインダーを溶媒とともに含有する「3.電極用バインダー組成物」の欄で説明した本発明の電極用バインダー組成物を用いて製造されることが好ましい。具体的には、リチウムイオン電池においては、正極に用いる正極材料としては正極活物質、及び本発明の電極用バインダーを含有し、更に導電助剤を含有していてもよく、負極に用いる負極材料としては負極活物質、本発明の電極用バインダーを含有し、更に導電助剤を含有していてもよく、電気二重層キャパシタ(電気化学キャパシタ)においては、正極に用いる正極材料としては活物質として活性炭、及び本発明の電極用バインダーを含有し、更に導電助剤を含有していてもよく、負極に用いる負極材料としては活物質として活性炭、本発明の電極用バインダーを含有し、更に導電助剤を含有していてもよい。
活物質全量(100質量%)に対する炭素材料の含有量は、下限は20質量%以上であることが好ましく、40質量%以上であることがより好ましく、60質量%以上であることが特に好ましく、上限は99質量%以下であることが好ましく、98質量%以下であることがより好ましく、96質量%以下であることが特に好ましい。
活物質全量(100質量%)に対するシリコン系化合物の含有量は、下限は1質量%以上であることが好ましく、2質量%以上であることがより好ましく、4質量%以上であることが特に好ましく、上限は80質量%以下であることが好ましく、60質量%以下であることがより好ましく、40質量%以下であることが特に好ましい。
本発明の電極は、前述の「4.電極材料」の欄で説明した本発明の電極材料と、集電体とを備えることを特徴とする。本発明の電極材料の詳細については、前述の通りである。
本発明の蓄電デバイスは、前述の「5.電極」の欄で説明した正極と、負極と、電解液とを備えることを特徴としている。すなわち、本発明の蓄電デバイスに用いられる電極は、本発明の電極材料、即ち本発明の電極用バインダーを含んでいる。本発明の電極の詳細については、前述の通りである。尚、本発明の蓄電デバイスについては、正極と、負極の少なくとも一方に、本発明の電極用バインダーを含んだ電極材料を用いた電極を使用していればよく、本発明の電極用バインダーを含んだ電極材料を用いていない電極については、公知の電極を用いることができる。
作製した電極の物性評価としては、結着性試験を行った。評価結果を表2にまとめて示した。
(測定装置)
剥離強度試験機:ストログラフE3-L(東洋精機株式会社)
結着性試験は180°剥離試験にて行った。具体的には電極を幅1.8cm×長さ5cmに切り出し、集電体上に形成された活物質層にセロハンテープ(粘着テープ:ニチバン製、幅1.8cm)を貼り付け、試験片とした。集電体とSUS板とを両面テープを用いて貼り合わせ、活物質層に貼り付けたセロハンテープの一端を180°方向に試験速度50mm/min、荷重レンジ5Nで引き剥がした。試験は3回実施し、その単純平均値を求めた。
作製したスラリーの物性評価としては、分散安定性試験を行った。評価結果を表2にまとめて示した。
(測定装置)
沈降静水圧測定装置:HYSTAP
(測定方法)
スラリーの分散安定性は沈降静水圧測定にて行った。具体的には、作製したスラリーを初期高さが120mmとなるようにメスシリンダーに入れ、沈降静水圧式スラリー評価装置を用いて、スラリー底部から20mmの位置における静水圧の経時変化を測定して、以下で評価した。
〇:600分のとき無次元静水圧が0.99以上
×:600分のとき無次元静水圧が0.99未満
重合体の平均粒子径は以下の条件で測定した。
(測定装置)
動的光散乱を用いた粒度分布測定装置:ゼータサイザーナノ(スペクトリス株式会社)
(測定条件)
1.合成したエマルジョン溶液50μLをサンプリングする。
2.サンプリングしたエマルジョン溶液にイオン交換水700μLを3回添加して希釈する。
3.希釈液から液を2100μL抜き取る。
4.残った50μLのサンプルに700μLイオン交換水を添加・希釈して測定する。
重合体の凝集物は以下のようにして測定した。
重合したエマルジョン溶液を150メッシュステンレス金網(関西金網株式会社製)で用いてろ過を行い、攪拌翼およびビーカーに付着している凝集物を掻き取る。その後、回収した凝集物をイオン交換水で洗浄し、24時間乾燥させ凝集物の質量を測定する。測定した凝集物量をエマルジョン収量で割り、凝集物量(質量%)とする。
ビーカーに、アクリル酸n-ブチル197.79g、メタクリル酸ベンジル146.65g、アクリル酸5.45g、メタクリル酸15.27g、ポリエチレングリコールモノメタクリレート(日油製:ブレンマーPE-90)14.51g、トリメチロールプロパントリメタクリレート(共栄社化学製:ライトエステル TMP)21.12g、乳化剤としてドデシル硫酸ナトリウム(花王ケミカル社製 エマール2FG)2.80g、ポリオキシエチレンジスチレン化フェニルエーテル(第一工業製薬株式会社製ノイゲンEA-157)1.20g、イオン交換水352g及び重合開始剤として過硫酸アンモニウム0.58gを入れ、超音波ホモジナイザーを用いて、十分攪拌し乳液とした。攪拌機付き反応容器を窒素雰囲気下、58℃に加温し220分かけて乳液を添加した。乳液の添加後、更に1時間重合し、その後冷却した。冷却後、28%アンモニア水溶液を用いて、重合液のpHを1.9から8.0に調整し、エマルジョン溶液であるバインダー組成物A(重合転化率99%以上、固形分濃度39.4wt%、凝集量:0.007wt%)を得た。得られた重合体の平均粒子径は0.291μmであった。重合体における質量%を表1に示す。
ビーカーに、アクリル酸n-ブチル202.60g、メタクリル酸ベンジル148.30g、アクリル酸5.50g、メタクリル酸15.50g、ポリエチレングリコールモノメタクリレート(日油製:ブレンマーPE-90)14.70g、トリメチロールプロパントリメタクリレート(共栄社化学製:ライトエステル TMP)14.20g、乳化剤としてドデシル硫酸ナトリウム(花王ケミカル社製 エマール2FG)4.00g、イオン交換水352g及び重合開始剤として過硫酸アンモニウム0.58gを入れ、超音波ホモジナイザーを用いて、十分攪拌し乳液とした。攪拌機付き反応容器を窒素雰囲気下、58℃に加温し220分かけて乳液を添加した。乳液の添加後、更に1時間重合し、その後冷却した。冷却後、28%アンモニア水溶液を用いて、重合液のpHを2.0から8.0に調整し、エマルジョン溶液であるバインダー組成物B(重合転化率99%以上、固形分濃度39.6wt%、凝集量:0.005wt%)を得た。得られた重合体の平均粒子径は0.261μmであった。重合体における質量%を表1に示す。
[電極の実施作製例1]
負極活物質としてグラファイト85質量部、SiO(大阪チタニウム社製)10質量部に、導電助剤としてアセチレンブラック2質量部、カルボキシメチルセルロースナトリウム塩2質量部、バインダー組成物の実施合成例1で得られたバインダー組成物Aの固形分として1質量部を加え、さらにスラリーの固形分濃度が50質量%となるように水を加えて遊星型ミルを用いて十分に混合して負極用スラリーを得た。スラリーの分散安定性試験の評価結果を表2の実施例1に示す。
負極活物質としてグラファイト85質量部、SiO(大阪チタニウム社製)10質量部に、導電助剤としてアセチレンブラック2質量部、カルボキシメチルセルロースナトリウム塩2質量部、バインダー組成物の比較合成例1で得られたバインダー組成物Bの固形分として1質量部を加え、さらにスラリーの固形分濃度が50質量%となるように水を加えて遊星型ミルを用いて十分に混合して負極用スラリーを得た以外は電極の実施例1と同様にして電極を作製した。得られた電極の厚みは40μmであった。スラリーの分散安定性試験の評価結果、結着性試験の評価結果を表2の比較例1に示す。
Claims (8)
- 芳香族ノニオン性乳化剤がスチレン化フェニルエーテル系化合物である請求項1記載のバインダー用組成物。
- 更に、アニオン性乳化剤を含有する請求項1又は2記載のバインダー用組成物。
- (メタ)アクリロイル基を2~5有するモノマーを、組成物中における重合体のためのモノマー成分(100質量%)に対して、5~15質量%含有する請求項1~3いずれか記載のバインダー用組成物。
- 請求項1~4いずれか記載のバインダー用組成物より作製される電極用バインダー。
- 請求項5記載の電極用バインダーと、活物質とを含む、電極材料。
- 請求項6記載の電極材料を含む電極。
- 請求項7に記載の電極を備える、蓄電デバイス。
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