JP2022046683A - 水中油型乳化日焼け止め化粧料 - Google Patents
水中油型乳化日焼け止め化粧料 Download PDFInfo
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- JP2022046683A JP2022046683A JP2021212442A JP2021212442A JP2022046683A JP 2022046683 A JP2022046683 A JP 2022046683A JP 2021212442 A JP2021212442 A JP 2021212442A JP 2021212442 A JP2021212442 A JP 2021212442A JP 2022046683 A JP2022046683 A JP 2022046683A
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- oil
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- ultraviolet absorber
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- 239000000516 sunscreening agent Substances 0.000 title abstract description 14
- 238000002156 mixing Methods 0.000 abstract description 21
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 16
- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 abstract description 16
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 abstract description 13
- 239000007788 liquid Substances 0.000 abstract description 13
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- 238000002835 absorbance Methods 0.000 description 3
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- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
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- XFKBBSZEQRFVSL-UHFFFAOYSA-N dipropan-2-yl decanedioate Chemical compound CC(C)OC(=O)CCCCCCCCC(=O)OC(C)C XFKBBSZEQRFVSL-UHFFFAOYSA-N 0.000 description 2
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Abstract
Description
(A)(a1)スルホン酸基含有水溶性紫外線吸収剤、
(a2)ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、
(a3)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、及び、
(a4)エチルヘキシルトリアゾンを含む紫外線吸収剤、
(B)極性油、
(C)高級アルコール、及び、
(D)非イオン性界面活性剤を含み、
前記(a2)ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、(a3)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、(a4)エチルヘキシルトリアゾン、及び(B)極性油の合計配合量が45質量%以下であることを特徴とする水中油型乳化化粧料を提供する。
(a1)成分としては、限定されないが、スルホン酸基を有するフェニルベンズイミダゾール誘導体又はベンジリデンショウノウ誘導体等が好ましく用いられる。
ベンジリデンショウノウ誘導体としては、ベンジリデンショウノウスルホン酸、テレフタリリデンジショウノウスルホン酸等が挙げられ、いずれも、シメックス(Chimex)社からメギゾリル(Mexoryl)SD及びメギゾリル(Mexoryl)SXという商品名で市販されている。
本発明の乳化化粧料におけるビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン(a2成分)の配合量は、0.1~10質量%が好ましく、より好ましくは0.5~5質量%である。
本発明の乳化化粧料におけるジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル(a3成分)の配合量は、0.1~10質量%が好ましく、より好ましくは0.5~5質量%である。
本発明の乳化化粧料におけるエチルヘキシルトリアゾン(a4成分)の配合量は、0.1~10質量%が好ましく、より好ましくは0.5~5質量%である。
なお、(a2)、(a3)及び(a4)を含む油溶性紫外線吸収剤の合計配合量は、0.5~19.5質量%とするのが好ましく、より好ましくは1~15質量%である。
本発明の日焼け止め化粧料で使用する高級アルコール(C成分)としては、化粧品、医薬品、医薬部外品等の分野において使用できる炭素数6以上の高級アルコールであれば特に限定されず、飽和直鎖一価アルコール及び不飽和一価アルコール等を包含する。飽和直鎖一価アルコールとしては、ドデカノール(ラウリルアルコール)、トリドデカノール、テトラドデカノール(ミリスチルアルコール)、ペンタデカノール、ヘキサデカノール(セチルアルコール)、ヘプタデカノール、オクタデカノール(ステアリルアルコール)、ノナデカノール、イコサノール(アラキルアルコール)、ヘンイコサノール、ドコサノール(ベヘニルアルコール)、トリコサノール、テトラコサノール(カルナービルアルコール)、ペンタコサノール、ヘキサコサノール(セリルアルコール)等が挙げられる。不飽和一価アルコールとしては、エライジルアルコール等が挙げられる。本発明では経時安定性の点から飽和直鎖一価アルコールが好ましい。
本発明の水中油型乳化化粧料に使用される非イオン性界面活性剤(D成分)は、特に限定されるものではない。具体例としては、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレン脂肪酸グリセリル、ポリオキシエチレン・メチルポリシロキサン共重合体、脂肪酸ポリオキシエチレンソルビタン、ポリオキシエチレンアルキルエーテル、マルチトールヒドロキシ脂肪族アルキルエーテル、アルキル化多糖、アルキルグルコシド、ショ糖脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油グリセリル、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレン・ポリオキシプロピレンブロック共重合体、テトラポリオキシエチレン・テトラポリオキシプロピレン-エチレンジアミン縮合物、ポリオキシエチレン-ミツロウ・ラノリン誘導体、アルカノールアミド、ポリオキシエチレン-プロピレングリコール脂肪酸エステル、ポリオキシエチレン-アルキルアミン、ポリオキシエチレン-脂肪酸アミド、アルキルエトキシジメチルアミンオキシド、トリオレイルリン酸などが挙げられる。本発明の化粧料では、HLBが8以上の親水性の非イオン性界面活性剤、例えば、ベヘネス-20、ポリソルベート60、ステアリン酸PEG-40等が特に好ましい例として挙げられる。非イオン性界面活性剤は、1種又は2種以上を用いることができる。
本発明の日焼け止め化粧料は水中油型乳化物であるので、水(E成分)を含んでいる。本発明では、前記(C)高級アルコールは、前記(D)非イオン性界面活性剤及び(E)水とともにラメラ液晶構造を有する会合体(「αゲル」ともいう)を形成する。(C)高級アルコールと(D)界面活性剤との配合比は、(C):(D)=2:1~25:1(モル比)の範囲内とするのが好ましい。
他の任意成分としては、限定されないが、例えば、粉末成分、色材、保湿剤、油分((A)油性の紫外線吸収剤及び(B)極性油を除く)、増粘剤、分散剤、防腐剤、香料、各種薬剤等が挙げられる。
評価基準:
A:析出や分離がみられず、極めて安定であった
B:乳化は可能だが、低温(0℃)で経時的に析出がみられた
C:乳化は可能だが、高温(37℃)で経時的に乳化粒子の増大がみられた
D:乳化は可能だが、室温で経時的に分離がみられた
各例の試料を1.75mg/cm2でPMMA製基板に塗布し、波長310nmにおける吸光度を、(吸光度計:HITACHI U-4100 Spectrophotometer)を用いて測定した。
専門パネルによる実使用試験を実施し、みずみずしさ及びべたつきの無さの観点から使用感を以下の基準で評価した。
+:優れている
-:劣っている
専門パネルによる実使用試験を実施し、塗布後の肌のつやを以下の基準で評価した。
A:優れている
B:普通
C:劣っている
処方例1:
配合成分 配合量(質量%)
フェニルベンズイミダゾールスルホン酸(a1) 3
ビスエチルヘキシルオキシフェノールメトキシ
フェニルトリアジン(a2) 0.3
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル(a3) 0.3
エチルヘキシルトリアジン(a4) 0.3
セバシン酸ジイソプロピル(B) 5
ステアリルアルコール 2
ベヘニルアルコール 3
ベヘネス-20 1
イオン交換水 残余
EDTA-3Na,2H2O 0.1
グリセリン 5
トリエタノールアミン 2
エタノール 5
二酸化チタン 0.5
酸化鉄(ベンガラ) 0.002
黄酸化鉄 0.003
[第1項]
(A)(a1)スルホン酸基含有水溶性紫外線吸収剤、
(a2)ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、
(a3)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、及び、
(a4)エチルヘキシルトリアゾンを含む紫外線吸収剤、
(B)極性油、
(C)高級アルコール、及び、
(D)非イオン性界面活性剤を含み、
前記(a2)ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、(a3)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、(a4)エチルヘキシルトリアゾン、及び(B)極性油の合計配合量が45質量%以下であることを特徴とする水中油型乳化化粧料。
[第2項]
前記(B)極性油の配合量の、(a2)ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、(a3)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、及び(a4)エチルヘキシルトリアゾンの合計配合量に対する比率[(B)/(a2+a3+a4)]が0.6以上である、第1項に記載の乳化化粧料。
[第3項]
(A)紫外線吸収剤が、(a1)フェニルベンズイミダゾールスルホン酸、(a2)ビスエチルヘキシルオキシフェノールメトキシフェニルトリアジン、(a3)ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、及び(a4)エチルヘキシルトリアゾンのみからなる、第1項に記載の乳化化粧料。
[第4項]
(B)極性油が、IOB=0.1~0.5のエステル油からなる、第1項から第3項のいずれか一項に記載の乳化化粧料。
[第5項]
(C)高級アルコールが、ステアリルアルコールとベヘニルアルコールとの組み合わせからなる、第1項から第4項のいずれか一項に記載の乳化化粧料。
[第6項]
日焼け止め化粧料である、第1項から第5項のいずれか一項に記載の乳化化粧料。
Claims (1)
- 明細書に記載された発明。
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