JP2021529690A - 少なくとも1種の強化繊維を含有する焼結粉末粒子(sp)を製造する方法 - Google Patents
少なくとも1種の強化繊維を含有する焼結粉末粒子(sp)を製造する方法 Download PDFInfo
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- JP2021529690A JP2021529690A JP2020573332A JP2020573332A JP2021529690A JP 2021529690 A JP2021529690 A JP 2021529690A JP 2020573332 A JP2020573332 A JP 2020573332A JP 2020573332 A JP2020573332 A JP 2020573332A JP 2021529690 A JP2021529690 A JP 2021529690A
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Abstract
Description
a) 少なくとも1種の連続フィラメントを提供する工程、
b) 工程a)で提供された少なくとも1種の連続フィラメントを少なくとも1種の熱可塑性ポリマーでコーティングして、少なくとも1種の熱可塑性ポリマーでコーティングされた少なくとも1種の連続フィラメントを含む連続ストランドを得る工程であって、ストランドの平均断面直径が10〜300μmの範囲である工程、及び
c) 工程b)で提供された連続ストランドの寸法を低減して、焼結粉末粒子(SP)を得る工程であって、焼結粉末粒子(SP)の平均長さが10〜300μmの範囲である工程、
を含む方法によって達成される。
工程a)において、少なくとも1種の連続フィラメントを提供する。本発明の文脈では、「連続フィラメント」とは、長さが少なくとも1000メートル、好ましくは少なくとも10000メートルの繊維材料である。本発明の文脈において、特に好ましい実施態様では、「連続フィラメント」とは、DIN60001T2(1974年12月)で定義される通り、実質的に無限の繊維である。
工程b)において、工程a)で提供された少なくとも1種の連続フィラメントを、少なくとも1種の熱可塑性ポリマーでコーティングして、少なくとも1種の熱可塑性ポリマーでコーティングされた少なくとも1種の連続フィラメントを含む連続ストランドを得る。
PA4 ピロリドン
PA6 ε−カプロラクタム
PA7 エナントラクタム
PA8 カプリロラクタム
PA11 ウンデカンラクタム
PA12 ラウリンラクタム
AA/BBポリマー:
PA46 テトラメチレンジアミン、アジピン酸
PA66 ヘキサメチレンジアミン、アジピン酸
PA69 ヘキサメチレンジアミン、アゼライン酸
PA610 ヘキサメチレンジアミン、セバシン酸
PA612 ヘキサメチレンジアミン、デカンジカルボン酸
PA613 ヘキサメチレンジアミン、ウンデカンジカルボン酸
PA6T ヘキサメチレンジアミン、テレフタル酸
PA9T ノナンジアミン、テレフタル酸
PA MXD6 m−キシリレンジアミン、アジピン酸
PA6I/6T (ヘキサメチレンジアミン、イソフタル酸、テレフタル酸)
PA6T/6I (ヘキサメチレンジアミン、テレフタル酸、イソフタル酸)
PA6/6l (PA6参照)、ヘキサメチレンジアミン、イソフタル酸
PA6/6T (PA6及びPA6T参照)
PA6/3T (PA6参照)、テレフタル酸及びプロピレンジアミン
PA6/66 (PA6及びPA66参照)
PA6/12 (PA6参照)、ラウリロラクタム
PA66/6/610 (PA66、PA6及びPA610参照)
PA6l/6T/PACM PA6I/6Tと同様及びジアミノジシクロヘキシルメタン
PA6/6I6T (PA6及びPA6T参照)、ヘキサメチレンジアミン、イソフタル酸
工程c)
工程c)において、工程b)で提供された連続ストランドの寸法を低減して、焼結粉末粒子(SP)を得る。
Claims (15)
- 焼結粉末粒子(SP)を製造する方法であって、以下の工程、
a) 少なくとも1種の連続フィラメントを提供する工程、
b) 工程a)で提供された前記少なくとも1種の連続フィラメントを少なくとも1種の熱可塑性ポリマーでコーティングして、前記少なくとも1種の熱可塑性ポリマーでコーティングされた前記少なくとも1種の連続フィラメントを含む連続ストランドを得る工程であって、前記ストランドの平均断面直径が10〜300μmの範囲である工程、及び
c) 工程b)で提供された前記連続ストランドの寸法を低減して、焼結粉末粒子(SP)を得る工程であって、前記焼結粉末粒子(SP)の平均長さが10〜300μmの範囲である工程、
を含む方法。 - 前記連続フィラメントの断面直径が3〜30μmの範囲である、請求項1に記載の方法。
- 前記連続フィラメントが、連続炭素繊維、連続ホウ素繊維、連続ガラス繊維、連続シリカ繊維、連続バサルト繊維及び連続アラミド繊維からなる群から選択される、請求項1又は2に記載の方法。
- 前記焼結粉末粒子(SP)の平均長さと、前記焼結粉末粒子(SP)の平均断面直径との間の平均の比が、1:2〜10:1の範囲である、請求項1から3のいずれか一項に記載の方法。
- 工程c)において、工程b)で得られた前記ストランドを10〜300μmの範囲の長さに切断する、請求項1から4のいずれか一項に記載の方法。
- 前記少なくとも1種の熱可塑性ポリマーが、ポリアミド、ポリエチレン、ポリプロピレン、ポリエーテルケトン、ポリオキシメチレン、ポリテトラフルオロエチレン、ポリフェニレンスルフィド、ポリエステル、これらのコポリマー、及びこれらの組み合わせからなる群から選択される、請求項1から5のいずれか一項に記載の方法。
- 前記焼結粉末粒子(SP)の少なくとも70%が本質的な円筒形状を有する、請求項1から6のいずれか一項に記載の方法。
- 前記少なくとも1種のポリマーが、ポリアミドポリマーからなる群から選択される、請求項1から7のいずれか一項に記載の方法。
- 前記少なくとも1種の熱可塑性ポリマーが、PA4、PA6、PA7、PA8、PA11、PA12、PA46、PA66、PA69、PA610、PA612、PA613、PA6T、PA MXD6、PA6I/6T、PA6T/6I、PA6/6l、PA6/6T、PA6/66、PA6/12、PA66/6/610、PA6l/6T/PACM、及びPA6/6I6T、及びそれらの混合物からなる群から選択される、請求項1から8のいずれか一項に記載の方法。
- 請求項1から9のいずれか一項に記載の方法により得られる焼結粉末粒子(SP)。
- 請求項10に記載の焼結粉末粒子(SP)を、選択的レーザー焼結、選択的抑制焼結、及び高速焼結からなる群から選択される粉末ベースの付加製造プロセスで使用する方法。
- 本質的な円筒形状を有し、10〜300μmの範囲の平均断面直径を有し、及び10〜300μmの範囲の平均長さを有し、本質的な円筒粒子のコアに少なくとも1種の強化繊維、及び円筒粒子の側部表面を形成する少なくとも1種の熱可塑性ポリマーのコーティングを含む、焼結粉末粒子(SP)。
- 前記焼結粉末の総質量に基づいて、10〜90質量%の請求項10又は請求項12に記載の焼結粉末粒子(SP)、及び前記焼結粉末粒子(SP)とは異なる90〜10質量%の他の焼結粉末粒子を含む、焼結粉末。
- 請求項9又は12に記載の焼結粉末粒子(SP)のレーザー焼結又は高速焼結による成形体を製造する方法。
- 請求項13に記載の焼結粉末の選択的レーザー焼結又は高速焼結による、成形体を製造する方法。
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PCT/EP2019/067270 WO2020007721A1 (en) | 2018-07-02 | 2019-06-27 | Process for the production of sinter powder particles (sp) containing at least one reinforcement fiber |
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US20150336292A1 (en) * | 2012-03-13 | 2015-11-26 | James Mikulak | Materials for powder-based additive manufacturing processes |
US20130309491A1 (en) * | 2012-05-15 | 2013-11-21 | Satoshi Seike | Milled carbon fiber |
JP2018086757A (ja) * | 2016-11-28 | 2018-06-07 | 株式会社リコー | 立体造形物の製造方法、及び立体造形物の製造装置 |
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