JP2021507012A5 - - Google Patents
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- Publication number
- JP2021507012A5 JP2021507012A5 JP2020531973A JP2020531973A JP2021507012A5 JP 2021507012 A5 JP2021507012 A5 JP 2021507012A5 JP 2020531973 A JP2020531973 A JP 2020531973A JP 2020531973 A JP2020531973 A JP 2020531973A JP 2021507012 A5 JP2021507012 A5 JP 2021507012A5
- Authority
- JP
- Japan
- Prior art keywords
- dry weight
- weight parts
- accelerator
- elastomeric article
- polysulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 claims description 57
- 239000000806 elastomer Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 32
- 238000004073 vulcanization Methods 0.000 claims description 26
- 229920000126 latex Polymers 0.000 claims description 22
- 239000004816 latex Substances 0.000 claims description 22
- 229920001021 polysulfide Polymers 0.000 claims description 21
- 239000005077 polysulfide Substances 0.000 claims description 21
- 150000008117 polysulfides Polymers 0.000 claims description 21
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 16
- 239000005060 rubber Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229910044991 metal oxide Inorganic materials 0.000 claims description 12
- 150000004706 metal oxides Chemical class 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 230000001052 transient effect Effects 0.000 claims description 12
- 239000008199 coating composition Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- HSNHLHNSJCYPNU-UHFFFAOYSA-N o-propan-2-yl propan-2-ylsulfanylmethanethioate Chemical compound CC(C)OC(=S)SC(C)C HSNHLHNSJCYPNU-UHFFFAOYSA-N 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 229920001400 block copolymer Polymers 0.000 claims description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000523 sample Substances 0.000 claims description 6
- 229920003051 synthetic elastomer Polymers 0.000 claims description 6
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 4
- 229920000459 Nitrile rubber Polymers 0.000 claims description 4
- 239000005062 Polybutadiene Substances 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000013566 allergen Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 229920003052 natural elastomer Polymers 0.000 claims description 4
- 229920001194 natural rubber Polymers 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- 229920001195 polyisoprene Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- ZWWQICJTBOCQLA-UHFFFAOYSA-N o-propan-2-yl (propan-2-yloxycarbothioyldisulfanyl)methanethioate Chemical compound CC(C)OC(=S)SSC(=S)OC(C)C ZWWQICJTBOCQLA-UHFFFAOYSA-N 0.000 claims description 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 3
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 2
- RCLNJBOMKAYJLR-UHFFFAOYSA-N aniline;heptanal Chemical compound NC1=CC=CC=C1.CCCCCCC=O RCLNJBOMKAYJLR-UHFFFAOYSA-N 0.000 claims description 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 2
- 239000000701 coagulant Substances 0.000 claims description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
- 239000012990 dithiocarbamate Substances 0.000 claims description 2
- 229910000464 lead oxide Inorganic materials 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002825 nitriles Chemical group 0.000 claims description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 2
- 229960002447 thiram Drugs 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000007598 dipping method Methods 0.000 claims 1
- KEVMYFLMMDUPJE-UHFFFAOYSA-N 2,7-dimethyloctane Chemical group CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000012991 xanthate Substances 0.000 description 2
- 235000010650 Hyssopus officinalis Nutrition 0.000 description 1
- 240000001812 Hyssopus officinalis Species 0.000 description 1
- -1 diisoamyl xanthate Chemical compound 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QDTDJKTWCDVRKH-UHFFFAOYSA-N o-butyl butylsulfanylmethanethioate Chemical compound CCCCOC(=S)SCCCC QDTDJKTWCDVRKH-UHFFFAOYSA-N 0.000 description 1
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2023092821A JP7550921B2 (ja) | 2017-12-13 | 2023-06-06 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
| JP2024151110A JP7781993B2 (ja) | 2017-12-13 | 2024-09-03 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762598048P | 2017-12-13 | 2017-12-13 | |
| US62/598,048 | 2017-12-13 | ||
| US16/216,640 | 2018-12-11 | ||
| US16/216,640 US10759913B2 (en) | 2017-12-13 | 2018-12-11 | Vulcanization composition for reducing allergenic potential and elastomeric articles formed therewith |
| PCT/US2018/065164 WO2019118570A1 (en) | 2017-12-13 | 2018-12-12 | Vulcanization composition for reducing allergenic potential and elastomeric articles formed therewith |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023092821A Division JP7550921B2 (ja) | 2017-12-13 | 2023-06-06 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2021507012A JP2021507012A (ja) | 2021-02-22 |
| JP2021507012A5 true JP2021507012A5 (enExample) | 2021-12-16 |
| JP7292277B2 JP7292277B2 (ja) | 2023-06-16 |
Family
ID=66735152
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020531973A Active JP7292277B2 (ja) | 2017-12-13 | 2018-12-12 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
| JP2023092821A Active JP7550921B2 (ja) | 2017-12-13 | 2023-06-06 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
| JP2024151110A Active JP7781993B2 (ja) | 2017-12-13 | 2024-09-03 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023092821A Active JP7550921B2 (ja) | 2017-12-13 | 2023-06-06 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
| JP2024151110A Active JP7781993B2 (ja) | 2017-12-13 | 2024-09-03 | アレルゲンのポテンシャルを低減するための加硫組成物およびそれを用いて形成されたエラストマー物品 |
Country Status (10)
| Country | Link |
|---|---|
| US (5) | US10759913B2 (enExample) |
| EP (1) | EP3723957A4 (enExample) |
| JP (3) | JP7292277B2 (enExample) |
| KR (2) | KR102663178B1 (enExample) |
| CN (2) | CN112512770B (enExample) |
| AU (2) | AU2018383760B2 (enExample) |
| CA (1) | CA3085639C (enExample) |
| MY (1) | MY203793A (enExample) |
| NZ (2) | NZ765257A (enExample) |
| WO (1) | WO2019118570A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3161886A1 (en) | 2019-12-20 | 2021-06-24 | Church & Dwight Co., Inc. | Polymer compositions and products formed therewith |
| EP4108404A4 (en) * | 2020-02-20 | 2024-03-20 | Zeon Corporation | METHOD FOR PRODUCING A LATEX COMPOSITION |
| US12492279B2 (en) | 2020-03-26 | 2025-12-09 | Denka Company Limited | Chloroprene-based block copolymer, latex, latex composition, and rubber composition |
| JP7503129B2 (ja) * | 2020-03-26 | 2024-06-19 | デンカ株式会社 | 浸漬成形体 |
| AU2020452517A1 (en) | 2020-06-08 | 2023-02-09 | Kimberly-Clark Worldwide, Inc. | Method for determining residual carbamate compounds on an elastomeric article |
| US12409255B2 (en) * | 2020-10-22 | 2025-09-09 | Thai Nippon Rubber Industry Public Company Limited | Synthetic polyisoprene latex condoms with reduced nitrosamine |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1417970A (en) * | 1921-05-28 | 1922-05-30 | Naugatuck Chem Co | Vulcanization of rubber employing amines and open-chain aldehydes and similar substances and products obtained thereby |
| FR592877A (fr) * | 1923-08-08 | 1925-08-11 | Naugatuck Chem Co | Procédé pour le traitement du caoutchouc par des produits de condensation d'aldéhyde aliphatique et d'amine aromatique |
| FR613040A (fr) * | 1925-03-13 | 1926-11-06 | Grasselli Chemical Co | Nouveaux produits de condensation des aldéhydes et des amines, procédé pour les préparer et leur application à la vulcanisation des substances à base de caoutchouc |
| NL20499C (enExample) * | 1926-01-27 | |||
| US2600414A (en) | 1947-08-22 | 1952-06-17 | William C Mast | Vulcanization of acrylic resins |
| US2781288A (en) * | 1954-08-30 | 1957-02-12 | Dow Corning | Laminated rubber article and a method of making same |
| US3626052A (en) * | 1969-06-24 | 1971-12-07 | Nicholas A Sisco | Polyisoprene-neoprene meteorological balloons |
| US3821134A (en) * | 1973-01-02 | 1974-06-28 | Goodrich Co B F | Vulcanizable polymer blends of diene rubbers and grafted epdm polymers |
| DE2651172C2 (de) * | 1976-11-10 | 1982-11-18 | Basf Ag, 6700 Ludwigshafen | Als Klebrigmacher für Kautschuk verwendete Aldehyd-Kondensate |
| US4258105A (en) * | 1979-05-30 | 1981-03-24 | Phillips Petroleum Company | Sealant compositions containing thiol-terminated polyesters |
| JPS5833253B2 (ja) | 1979-06-01 | 1983-07-19 | 住友ゴム工業株式会社 | 糸ゴム組成物 |
| US4451615A (en) | 1980-05-09 | 1984-05-29 | Loctite (Ireland) Limited | Polyisoprene toughened adhesive composition |
| EP0103695A1 (en) | 1982-07-16 | 1984-03-28 | Showa Denko Kabushiki Kaisha | Vulcanized olefin-based rubber composition |
| ATE40144T1 (de) * | 1984-10-25 | 1989-02-15 | Robinson Bros Ltd | Gummiprodukte und vulkanisationssysteme. |
| DE69030694T2 (de) | 1989-08-18 | 1997-09-11 | Robinson Bros Ltd | Gummiprodukte und Vulkanisationssysteme |
| US5486613A (en) * | 1993-07-15 | 1996-01-23 | Great Lakes Chemical Italia S.R.L. | Vulcanization accelerators |
| JP3464042B2 (ja) * | 1994-06-02 | 2003-11-05 | 出光石油化学株式会社 | ゴム組成物 |
| US6618861B2 (en) | 2000-12-28 | 2003-09-16 | Microflex Corporation | Medical gloves with watch viewing capabilities |
| CA2408626C (en) | 2001-03-12 | 2009-02-17 | Allegiance Corporation | Polyisoprene articles and process for making the same |
| US20030161975A1 (en) * | 2002-02-27 | 2003-08-28 | Lucas David M. | Polyisoprene condom |
| JP2005036141A (ja) | 2003-07-17 | 2005-02-10 | Daiso Co Ltd | ブレンドゴム加硫用組成物 |
| US7566502B1 (en) | 2003-09-17 | 2009-07-28 | Allegiance Corporation | Surface modification of elastomeric articles |
| US7041746B2 (en) | 2003-09-24 | 2006-05-09 | R.T. Vanderbilt Company, Inc. | Accelerator system for synthetic polyisoprene latex |
| US7528181B2 (en) | 2004-04-08 | 2009-05-05 | Michelin Recherche Et Technique, S.A. | Rubber composition and tire comprising same |
| CA2617281C (en) * | 2005-08-05 | 2013-04-30 | Kraton Polymers Research B.V. | Latex accelerator composition |
| US8110266B2 (en) | 2007-02-08 | 2012-02-07 | Allegiance Corporation | Glove coating and manufacturing process |
| US8087412B2 (en) | 2008-05-01 | 2012-01-03 | Ansell Healthcare Products Llc | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
| JP5488137B2 (ja) | 2010-04-06 | 2014-05-14 | 日本ゼオン株式会社 | ディップ成形用組成物及びディップ成形体 |
| ES2947559T3 (es) * | 2010-06-25 | 2023-08-11 | Allegiance Corp | Composición de vulcanización que tiene un potencial alergénico reducido |
| JP6008479B2 (ja) * | 2011-08-19 | 2016-10-19 | 株式会社ブリヂストン | タイヤ及びその製造方法、並びに、該タイヤの製造方法に用いた補修用ゴム部材 |
| US20150128329A1 (en) | 2013-11-14 | 2015-05-14 | Ansell Limited | Polymeric compositions comprising polyisoprene |
| JP6679041B2 (ja) | 2013-12-11 | 2020-04-15 | 株式会社クラレ | シーラント |
| WO2015159934A1 (ja) * | 2014-04-16 | 2015-10-22 | 株式会社ブリヂストン | ゴム組成物 |
| NL2013636B1 (en) | 2014-10-15 | 2016-10-04 | Kraton Polymers Us Llc | An accelerator system, a composition comprisng a synthetic isoprene polymer and the accelerator system, and dipped goods made from the composition. |
| KR102386374B1 (ko) | 2016-05-18 | 2022-04-13 | 주식회사 쿠라레 | 발포 성형체, 댐 러버, 댐 러버와 패널의 복합체, 음향 투과 손실을 증대시키는 방법 |
-
2018
- 2018-12-11 US US16/216,640 patent/US10759913B2/en active Active
- 2018-12-12 EP EP18888314.4A patent/EP3723957A4/en active Pending
- 2018-12-12 NZ NZ765257A patent/NZ765257A/en unknown
- 2018-12-12 KR KR1020207019702A patent/KR102663178B1/ko active Active
- 2018-12-12 MY MYPI2020002939A patent/MY203793A/en unknown
- 2018-12-12 CN CN201880089327.7A patent/CN112512770B/zh active Active
- 2018-12-12 AU AU2018383760A patent/AU2018383760B2/en active Active
- 2018-12-12 KR KR1020247014394A patent/KR20240064033A/ko active Pending
- 2018-12-12 JP JP2020531973A patent/JP7292277B2/ja active Active
- 2018-12-12 NZ NZ801876A patent/NZ801876A/en unknown
- 2018-12-12 WO PCT/US2018/065164 patent/WO2019118570A1/en not_active Ceased
- 2018-12-12 CN CN202211412971.8A patent/CN115651271A/zh active Pending
- 2018-12-12 CA CA3085639A patent/CA3085639C/en active Active
-
2020
- 2020-07-09 US US16/924,953 patent/US11242435B2/en active Active
-
2022
- 2022-02-01 US US17/590,558 patent/US11780972B2/en active Active
- 2022-11-04 AU AU2022263563A patent/AU2022263563B2/en active Active
-
2023
- 2023-06-06 JP JP2023092821A patent/JP7550921B2/ja active Active
- 2023-09-05 US US18/461,248 patent/US12215205B2/en active Active
-
2024
- 2024-09-03 JP JP2024151110A patent/JP7781993B2/ja active Active
- 2024-12-16 US US18/982,809 patent/US20250115724A1/en active Pending
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