JP2021116361A - 改質天然ゴム及びゴム組成物 - Google Patents
改質天然ゴム及びゴム組成物 Download PDFInfo
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- JP2021116361A JP2021116361A JP2020010866A JP2020010866A JP2021116361A JP 2021116361 A JP2021116361 A JP 2021116361A JP 2020010866 A JP2020010866 A JP 2020010866A JP 2020010866 A JP2020010866 A JP 2020010866A JP 2021116361 A JP2021116361 A JP 2021116361A
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- natural rubber
- mass
- rubber
- acid
- raw material
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- BGNGWHSBYQYVRX-UHFFFAOYSA-N 4-(dimethylamino)benzaldehyde Chemical compound CN(C)C1=CC=C(C=O)C=C1 BGNGWHSBYQYVRX-UHFFFAOYSA-N 0.000 description 7
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
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- 230000014759 maintenance of location Effects 0.000 description 6
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
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- 239000000312 peanut oil Substances 0.000 description 1
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- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
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- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
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- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
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- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- GBEYVKHMIPVAHD-UHFFFAOYSA-M potassium;hexadecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GBEYVKHMIPVAHD-UHFFFAOYSA-M 0.000 description 1
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- NPSSWQJHYLDCNV-UHFFFAOYSA-N prop-2-enoic acid;hydrochloride Chemical compound Cl.OC(=O)C=C NPSSWQJHYLDCNV-UHFFFAOYSA-N 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- XACWJIQLDLUFSR-UHFFFAOYSA-N pyrrolidine-1-carbonyl chloride Chemical compound ClC(=O)N1CCCC1 XACWJIQLDLUFSR-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- UPUIQOIQVMNQAP-UHFFFAOYSA-M sodium;tetradecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCOS([O-])(=O)=O UPUIQOIQVMNQAP-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
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- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
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- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
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- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
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- 235000010215 titanium dioxide Nutrition 0.000 description 1
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- ZZUIPNXRUAGCJF-UHFFFAOYSA-N tributoxy(3-trimethylsilylsulfanylpropyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCCS[Si](C)(C)C ZZUIPNXRUAGCJF-UHFFFAOYSA-N 0.000 description 1
- FPBXRRDHCADTAL-UHFFFAOYSA-N triethoxy(3-nitropropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC[N+]([O-])=O FPBXRRDHCADTAL-UHFFFAOYSA-N 0.000 description 1
- IWJOAWOCUCJBII-UHFFFAOYSA-N triethoxy(3-trimethylsilylsulfanylpropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCS[Si](C)(C)C IWJOAWOCUCJBII-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
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- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- URIYERBJSDIUTC-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltrisulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSCC[Si](OCC)(OCC)OCC URIYERBJSDIUTC-UHFFFAOYSA-N 0.000 description 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- PTRSAJDNBVXVMV-UHFFFAOYSA-N triethoxy-[4-(4-triethoxysilylbutyldisulfanyl)butyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCSSCCCC[Si](OCC)(OCC)OCC PTRSAJDNBVXVMV-UHFFFAOYSA-N 0.000 description 1
- NOPBHRUFGGDSAD-UHFFFAOYSA-N triethoxy-[4-(4-triethoxysilylbutyltetrasulfanyl)butyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCSSSSCCCC[Si](OCC)(OCC)OCC NOPBHRUFGGDSAD-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- QPPXVBLDIDEHBA-UHFFFAOYSA-N trimethoxy(3-nitropropyl)silane Chemical compound CO[Si](OC)(OC)CCC[N+]([O-])=O QPPXVBLDIDEHBA-UHFFFAOYSA-N 0.000 description 1
- PMXKHNVLACXGAZ-UHFFFAOYSA-N trimethoxy(3-trimethylsilylsulfanylpropyl)silane Chemical compound CO[Si](OC)(OC)CCCS[Si](C)(C)C PMXKHNVLACXGAZ-UHFFFAOYSA-N 0.000 description 1
- JSXKIRYGYMKWSK-UHFFFAOYSA-N trimethoxy-[2-(2-trimethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CO[Si](OC)(OC)CCSSSSCC[Si](OC)(OC)OC JSXKIRYGYMKWSK-UHFFFAOYSA-N 0.000 description 1
- NQRACKNXKKOCJY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSCCC[Si](OC)(OC)OC NQRACKNXKKOCJY-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- BNBXBRPOAJZBNB-UHFFFAOYSA-N trimethoxy-[4-(4-trimethoxysilylbutyldisulfanyl)butyl]silane Chemical compound CO[Si](OC)(OC)CCCCSSCCCC[Si](OC)(OC)OC BNBXBRPOAJZBNB-UHFFFAOYSA-N 0.000 description 1
- GSZUEPNJCPXEGU-UHFFFAOYSA-N trimethoxy-[4-(4-trimethoxysilylbutyltrisulfanyl)butyl]silane Chemical compound CO[Si](OC)(OC)CCCCSSSCCCC[Si](OC)(OC)OC GSZUEPNJCPXEGU-UHFFFAOYSA-N 0.000 description 1
- LQBHRPIAMBRGHZ-UHFFFAOYSA-N trimethyl(3-tripropoxysilylpropylsulfanyl)silane Chemical compound CCCO[Si](OCCC)(OCCC)CCCS[Si](C)(C)C LQBHRPIAMBRGHZ-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- ZUBNXRHITOZMOO-UHFFFAOYSA-N zinc;octadecanoic acid;oxygen(2-) Chemical compound [O-2].[Zn+2].CCCCCCCCCCCCCCCCCC(O)=O ZUBNXRHITOZMOO-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/25—Incorporating silicon atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/015—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
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Abstract
Description
前記ゴム組成物は、ゴム成分100質量部に対するフィラーの含有量が5〜150質量部であることが好ましい。
本発明はまた、前記ゴム組成物を用いたタイヤ部材を有するタイヤに関する。
本発明の改質天然ゴムは、(1)防腐殺菌剤を添加した天然ゴムラテックスより得られる固形原料及び/又は(2)天然ゴムラテックスの凝固物に防腐殺菌剤を添加して得られる固形原料から作製され、該防腐殺菌剤が、トリアジン類、パラベン類、ホウ酸類、グリコールエーテル類、並びに、pKa4以上の有機酸及びその金属塩からなる群より選択される少なくとも1種である。該天然ゴムは、固形原料を原材料として作製したものにもかかわらず、臭気抑制性及び耐劣化性能に優れている。
前記ゴム組成物は、改質天然ゴムを含有するゴム成分を含む。該ゴム組成物は、前記改質天然ゴムを含むため、臭気抑制性及び耐劣化性能に優れている。
なお、上記化合物(変性剤)による変性は公知の方法で実施可能である。
なお、カーボンブラックの窒素吸着比表面積は、ASTM D4820−93に従って測定される。
なお、シリカのN2SAは、ASTM D3037−93に準じてBET法で測定される値である。
前記ゴム組成物において、シランカップリング剤の含有量は、シリカ100質量部に対して、3質量部以上が好ましく、5質量部以上がより好ましい。3質量部以上であると、添加による効果が得られる傾向がある。また、上記含有量は、25質量部以下が好ましく、20質量部以下がより好ましい。25質量部以下であると、配合量に見合った効果が得られ、良好な混練時の加工性が得られる傾向がある。
なお、オイルの含有量には、ゴム(油展ゴム)に含まれるオイルの量も含まれる。
なお、本明細書において、石油樹脂のMwは、ゲルパーミエーションクロマトグラフィー(GPC)(東ソー(株)製GPC−8000シリーズ、検出器:示差屈折計、カラム:東ソー(株)製のTSKGEL SUPERMALTPORE HZ−M)による測定値を基に標準ポリスチレン換算により求めることができる。
本明細書において、石油樹脂の軟化点は、JIS K 6220−1:2001に規定される軟化点を環球式軟化点測定装置で測定し、球が降下した温度である。
前記タイヤは、ゴム組成物を用いて通常の方法で製造される。
すなわち、前記成分を配合したゴム組成物(未加硫)を、未加硫の段階で各タイヤ部材の形状にあわせて押出し加工し、他のタイヤ部材とともに、タイヤ成型機上にて通常の方法で成形することにより、未加硫タイヤを形成する。この未加硫タイヤを加硫機中で加熱加圧することによりタイヤを得る。
フィールドラテックス:ムヒバラテックス社から入手したフィールドラテックス
フェノキシエタノール:富士フィルム和光純薬(株)製のフェノキシエタノール
ホウ酸:富士フィルム和光純薬(株)製のホウ酸
デヒドロ酢酸:富士フィルム和光純薬(株)製のデヒドロ酢酸
1,3,5−トリアジン:シグマ・アルドリッチ社製の1,3,5−トリアジン
プロピルパラベン:シグマ・アルドリッチ社製のプロピルパラベン
塩基性物質:炭酸ナトリウム(Na2CO3)(シグマ・アルドリッチ社製)
界面活性剤:花王(株)製のエマールE−27C(ポリオキシエチレンラウリルエーテル硫酸ナトリウム)
硫酸:富士フィルム和光純薬(株)製(有効成分98%)
ギ酸:関東化学(株)製のギ酸
通常のゴム農園で作製されたカップランプを入手した。そして、入手したカップランプをナチュラルラバーマシーンアンドイクイップメント社製のハンマーミルで処理した後、ラバーグラヌュエイターで微細化(粉砕)した後、粉砕したカップランプを、水浴で撹拌しながら洗浄し、水相のみを排出して粉砕したカップランプを取り出すことにより洗浄した(粉砕洗浄処理)。粉砕、洗浄後のカップランプの平均径は5mmであった。
フィールドラテックスの固形分濃度(DRC)を30%(w/v)に調整した後、該ラテックスのゴム固形分100質量部に対して、防腐殺菌剤の含有量が表1に示す量になるように防腐殺菌剤の水溶液を添加、混合した。次いで、得られた混合物に、表1の濃度の酸を添加、混合して凝固(凝集)させ、含水凝固物(固形原料)を得た。含水凝固物を約1ヶ月間貯蔵した。貯蔵する前の含水凝固物の水分率を下記方法にて測定したところ、表1のとおりであった。
上述のように約1ヶ月間貯蔵した含水凝固物を、破砕し、水で5回繰り返し洗浄した後、表1に示す濃度で作製した水溶液1Lに、当該含水凝固物100gを、6時間、室温(20〜30℃)で浸漬した。浸漬中は含水凝固物が水溶液の液面に浮いてこないように適宜重し等を載せ、全体が水溶液に沈むよう配置した。含水凝固物を取り出し、水で洗浄した後、表1に記載の温度で乾燥し、各天然ゴムサンプル(改質NR1〜8)を得た。
粉砕、洗浄後のカップランプを室温(20〜30℃)で約1ヶ月間貯蔵した。貯蔵する前のカップランプの水分率を下記方法にて測定したところ、表1のとおりであった。
上述のように約1ヶ月間貯蔵したカップランプを、破砕し、水で5回繰り返し洗浄した後、表1に示す濃度で作製した水溶液1Lに、当該カップランプ100gを、6時間、室温(20〜30℃)で浸漬した。浸漬中はカップランプが水溶液の液面に浮いてこないように適宜重し等を載せ、全体が水溶液に沈むよう配置した。カップランプを取り出し、水で洗浄した後、表1に記載の温度で乾燥し、各天然ゴムサンプル(NR1〜3)を得た。
フィールドラテックスの固形分濃度(DRC)を30%(w/v)に調整した後、該ラテックスのゴム固形分100質量部に対して、表1の濃度の酸を添加、混合して凝固(凝集)させ、含水凝固物(固形原料)を得た。含水凝固物を約1ヶ月間貯蔵した。貯蔵する前の含水凝固物の水分率を下記方法にて測定したところ、表1のとおりであった。
上述のように約1ヶ月間貯蔵した含水凝固物を、破砕し、水で5回繰り返し洗浄した後、表1に示す濃度で作製した水溶液1Lに、当該含水凝固物100gを、6時間、室温(20〜30℃)で浸漬した。浸漬中は含水凝固物が水溶液の液面に浮いてこないように適宜重し等を載せ、全体が水溶液に沈むよう配置した。含水凝固物を取り出し、水で洗浄した後、表1に記載の温度で乾燥し、各天然ゴムサンプル(NR4〜5)を得た。
改質NR1〜8、NR1〜5:上記比較例、実施例で製造した天然ゴムサンプル
BR:宇部興産(株)製のBR150B(シス含量98質量%)
カーボンブラック:三菱ケミカル(株)製のダイアブラックN550(N2SA42m2/g)
石油樹脂:東ソー(株)製のペトロタック100V(C5C9系石油樹脂、Mw3800、軟化点96℃)
ワックス:日本精蝋(株)製のオゾエース0355
老化防止剤6C:大内新興化学工業(株)製のノクラック6C(N−(1,3−ジメチルブチル)−N’−フェニル−p−フェニレンジアミン)
老化防止剤RD:大内新興化学工業(株)製のノクラック224(2,2,4−トリメチル−1,2−ジヒドロキノリン重合体)
ステアリン酸:日油(株)製のビーズステアリン酸つばき
酸化亜鉛:三井金属鉱業(株)製の酸化亜鉛2種
オイル:H&R社製のVIVATEC400(TDAEオイル)
硫黄:鶴見化学工業(株)製の粉末硫黄(5%オイル含有)
加硫促進剤:大内新興化学工業(株)製のノクセラーCZ(N−シクロヘキシル−2−ベンゾチアジルスルフェンアミド(CBS))
表2に示す配合内容に従い、(株)神戸製鋼所製の1.7Lバンバリーミキサーを用いて、硫黄及び加硫促進剤以外の材料を150℃の条件下で5分間混練りし、混練り物を得た。次に、得られた混練り物に硫黄及び加硫促進剤を添加し、オープンロールを用いて、80℃の条件下で5分間練り込み、未加硫ゴム組成物を得た。
得られた未加硫ゴム組成物をサイドウォールの形状に成形し、他のタイヤ部材とともに貼り合わせて未加硫タイヤを形成し、150℃の条件下で12分間加硫し、試験用タイヤ(サイズ:195/65R15)を製造した。
カップランプ又は天然ゴムサンプル1gを正確に量り取り(乾燥前の重量)、細かく切断してから70℃、14時間乾燥させた後、乾燥後の重量を測定した。そして、下記式により、水分率を求めた。
水分率(%)={(乾燥前の重量(g)−乾燥後の重量(g))/乾燥前の重量(g)}×100
(天然ゴムの臭気成分指数)
天然ゴムの臭気の主な原因物質としては、酢酸、吉草酸、イソ吉草酸、イソ吉草酸アルデヒド、酪酸のような低級脂肪酸及びそれらのアルデヒドが挙げられる。
そこでHead−Space GCMS(株式会社島津製作所製、製品名「GCMS−QP2010 Ultra」、ヘッドスペースサンプラ―として株式会社島津製作所製「HS−20」を使用)を用いて検出される上記成分のピーク面積比を各成分の嗅覚閾値で補正し、全てを足したものを臭気成分指数(天然ゴム)とした。
上記で得られた臭気成分指数について、下記式により、臭気成分率を評価した。
天然ゴムの臭気成分率(%)=(各例の天然ゴムサンプルにおける臭気成分指数/比較例1の天然ゴムサンプルにおける臭気成分指数)×100
天然ゴムサンプルの劣化特性は、下記式により、80℃で72時間老化させた後のムーニー粘度の保持率を評価した。ムーニー粘度保持率の値が大きいほど、天然ゴムサンプルが劣化特性(耐熱老化性)に優れていることを示す。具体的には、85%以上であれば非常に劣化特性に優れているといえる。
ムーニー粘度保持率(%)=(老化後のムーニー粘度/老化前のムーニー粘度)×100
(ゴム組成物の臭気成分指数)
試験用タイヤのサイドウォール部からサンプル(ゴム組成物サンプル)を採取し、そのサンプルについて、天然ゴムの臭気成分の分析方法と同様に測定し、検出される上記成分のピーク面積比を各成分の嗅覚閾値で補正し、全てを足したものを臭気成分指数(ゴム組成物)とした。
上記で得られた臭気成分指数について、下記式により、臭気成分率を評価した。
ゴム組成物の臭気成分率(%)=(各例のゴム組成物サンプルにおける臭気成分指数/比較例1のゴム組成物サンプルにおける臭気成分指数)×100
JIS K6251に準じて、サンプル(ゴム組成物サンプル)からなる3号ダンベル型試験片を用いて引張試験を実施し、各サンプルの破断強度(TB)を測定した。次に、サンプルを80℃、168時間熱老化させた後のTBを測定した。下記式により、老化前後の破断強度(TB)の保持率を求めた。数値が高い方が熱老化によるゴム物性変化が小さく、耐熱老化性に優れる。具体的には、破断強度保持率が70%以上であれば充分劣化特性に優れているといえる。
保持率(%)=熱老化後のTB/熱老化前のTB×100
Claims (7)
- (1)防腐殺菌剤を添加した天然ゴムラテックスより得られる固形原料及び/又は(2)天然ゴムラテックスの凝固物に防腐殺菌剤を添加して得られる固形原料から作製され、該防腐殺菌剤が、トリアジン類、パラベン類、ホウ酸類、グリコールエーテル類、並びに、pKa4以上の有機酸及びその金属塩からなる群より選択される少なくとも1種である改質天然ゴム。
- 前記防腐殺菌剤は、ホウ酸類、グリコールエーテル類、並びに、pKa4以上の有機酸及びその金属塩からなる群より選択される少なくとも1種である請求項1記載の改質天然ゴム。
- 前記天然ゴムラテックスのゴム固形分100質量部に対する前記防腐殺菌剤の添加量が0.01〜10質量部である請求項1又は2記載の改質天然ゴム。
- 請求項1〜3のいずれかに記載の改質天然ゴムを含むゴム組成物。
- ゴム成分100質量部に対するフィラーの含有量が5〜150質量部である請求項4記載のゴム組成物。
- 臭気成分指数が5.0×105以下である請求項4又は5記載のゴム組成物。
- 請求項4〜6のいずれかに記載のゴム組成物を用いたタイヤ部材を有するタイヤ。
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Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60238326A (ja) * | 1984-01-10 | 1985-11-27 | マンケム リミテツド | ゴムと金属との接着促進剤及びその製造方法 |
WO2005012365A1 (ja) * | 2003-08-04 | 2005-02-10 | Thai Rubber Latex Corporation (Thailand) Public Company Limited | タンパク質を除去した天然ゴム、その組成物および用途 |
JP2007284637A (ja) * | 2006-04-20 | 2007-11-01 | Bridgestone Corp | 酵素処理天然ゴムラテックスの製造方法、天然ゴム及びそのゴム組成物 |
JP2007291347A (ja) * | 2006-03-28 | 2007-11-08 | Sumitomo Rubber Ind Ltd | タイヤ用油展ゴムの製造方法、該タイヤ用油展ゴム、それを用いたゴム組成物およびタイヤ |
JP2009256482A (ja) * | 2008-04-17 | 2009-11-05 | Bridgestone Corp | 天然ゴム及びその製造方法、並びにゴム組成物及びタイヤ |
WO2010074245A1 (ja) * | 2008-12-25 | 2010-07-01 | 横浜ゴム株式会社 | 天然ゴムの製造方法 |
JP2011512429A (ja) * | 2008-02-07 | 2011-04-21 | コンティネンタル・ライフェン・ドイチュラント・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特にゴム物品のためのシーラント |
WO2012105681A1 (ja) * | 2011-02-03 | 2012-08-09 | 株式会社ブリヂストン | 天然ゴム及びそれを用いたゴム組成物並びにタイヤ |
JP5364231B2 (ja) * | 2006-01-31 | 2013-12-11 | 株式会社ブリヂストン | 改質天然ゴムラテックス及びその製造方法、並びに天然ゴム及びゴム組成物 |
JP2015199866A (ja) * | 2014-04-09 | 2015-11-12 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
JP2018058975A (ja) * | 2016-10-04 | 2018-04-12 | 住友ゴム工業株式会社 | 天然ゴムの製造方法 |
JP2018199790A (ja) * | 2017-05-29 | 2018-12-20 | 住友ゴム工業株式会社 | 天然ゴムの製造方法 |
JP2020090640A (ja) * | 2018-12-07 | 2020-06-11 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB744688A (en) * | 1953-07-02 | 1956-02-15 | Revertex Ltd | Process of treating aqueous rubber dispersions |
GB852280A (en) * | 1955-11-15 | 1960-10-26 | British Rubber Prod Res | Improvements in the preservation of natural rubber latex |
GB1517025A (en) * | 1975-08-20 | 1978-07-05 | Malaysia Rubber Res Inst | Preservation of natural rubber latex |
JP5457378B2 (ja) * | 2011-01-17 | 2014-04-02 | 住友ゴム工業株式会社 | 改質天然ゴム、その製造方法、タイヤ用ゴム組成物及び空気入りタイヤ |
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Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60238326A (ja) * | 1984-01-10 | 1985-11-27 | マンケム リミテツド | ゴムと金属との接着促進剤及びその製造方法 |
WO2005012365A1 (ja) * | 2003-08-04 | 2005-02-10 | Thai Rubber Latex Corporation (Thailand) Public Company Limited | タンパク質を除去した天然ゴム、その組成物および用途 |
JP5364231B2 (ja) * | 2006-01-31 | 2013-12-11 | 株式会社ブリヂストン | 改質天然ゴムラテックス及びその製造方法、並びに天然ゴム及びゴム組成物 |
JP2007291347A (ja) * | 2006-03-28 | 2007-11-08 | Sumitomo Rubber Ind Ltd | タイヤ用油展ゴムの製造方法、該タイヤ用油展ゴム、それを用いたゴム組成物およびタイヤ |
JP2007284637A (ja) * | 2006-04-20 | 2007-11-01 | Bridgestone Corp | 酵素処理天然ゴムラテックスの製造方法、天然ゴム及びそのゴム組成物 |
JP2011512429A (ja) * | 2008-02-07 | 2011-04-21 | コンティネンタル・ライフェン・ドイチュラント・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特にゴム物品のためのシーラント |
JP2009256482A (ja) * | 2008-04-17 | 2009-11-05 | Bridgestone Corp | 天然ゴム及びその製造方法、並びにゴム組成物及びタイヤ |
WO2010074245A1 (ja) * | 2008-12-25 | 2010-07-01 | 横浜ゴム株式会社 | 天然ゴムの製造方法 |
WO2012105681A1 (ja) * | 2011-02-03 | 2012-08-09 | 株式会社ブリヂストン | 天然ゴム及びそれを用いたゴム組成物並びにタイヤ |
JP2015199866A (ja) * | 2014-04-09 | 2015-11-12 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
JP2018058975A (ja) * | 2016-10-04 | 2018-04-12 | 住友ゴム工業株式会社 | 天然ゴムの製造方法 |
JP2018199790A (ja) * | 2017-05-29 | 2018-12-20 | 住友ゴム工業株式会社 | 天然ゴムの製造方法 |
JP2020090640A (ja) * | 2018-12-07 | 2020-06-11 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
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JP7463738B2 (ja) | 2024-04-09 |
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US20230059624A1 (en) | 2023-02-23 |
CN114945601A (zh) | 2022-08-26 |
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EP4098664A1 (en) | 2022-12-07 |
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