JP2020508368A - 共重合体およびこれを含む有機太陽電池 - Google Patents
共重合体およびこれを含む有機太陽電池 Download PDFInfo
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- JP2020508368A JP2020508368A JP2019543362A JP2019543362A JP2020508368A JP 2020508368 A JP2020508368 A JP 2020508368A JP 2019543362 A JP2019543362 A JP 2019543362A JP 2019543362 A JP2019543362 A JP 2019543362A JP 2020508368 A JP2020508368 A JP 2020508368A
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- 125000000623 heterocyclic group Chemical group 0.000 claims description 27
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- ZCSHNCUQKCANBX-UHFFFAOYSA-N lithium diisopropylamide Chemical compound [Li+].CC(C)[N-]C(C)C ZCSHNCUQKCANBX-UHFFFAOYSA-N 0.000 description 4
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- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
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- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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- H10K85/649—Aromatic compounds comprising a hetero atom
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- H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
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- H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
- H10K85/6576—Polycyclic condensed heteroaromatic hydrocarbons comprising only sulfur in the heteroaromatic polycondensed ring system, e.g. benzothiophene
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Abstract
Description
第1共役単量体;および
前記第1共役単量体とは異なる第2共役単量体を含む共重合体を提供する。
m1およびm2は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1およびm2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1およびq2は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1およびq2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
A1およびA1’は、互いに同一または異なり、それぞれ独立に、ハロゲン基;置換もしくは非置換のホウ素基;または−SnRaRbRcであり、
X1、X2およびZ1〜Z5は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
Ra、Rb、Rc、R、R’、R1〜R4およびR11〜R18は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。
下記化学式2で表される第2化合物;および
下記化学式3で表される第3化合物を反応させるステップを含む共重合体の製造方法を提供する。
m1およびm2は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1およびm2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1およびq2は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1およびq2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
A1、A1’、A2、A2’、A3およびA3’は、互いに同一または異なり、それぞれ独立に、ハロゲン基;置換もしくは非置換のホウ素基;または−SnRaRbRcであり、
E1は、第1共役単量体であり、
E2は、前記第1共役単量体とは異なる第2共役単量体であり、
X1、X2およびZ1〜Z5は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
Ra、Rb、Rc、R1〜R4およびR11〜R18は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。
前記第1電極に対向して備えられる第2電極と、
前記第1電極と前記第2電極との間に備えられ、光活性層を含む1層以上の有機物層とを含み、
前記有機物層のうちの1層以上は、前記共重合体を含むものである有機太陽電池を提供する。
m1、m2、m1’およびm2’は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1、m2、m1’およびm2’がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1、q2、q1’およびq2’は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1、q2、q1’およびq2’がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
X1、X2、X1’、X2’、Z1〜Z5およびZ1’〜Z5’は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
E1は、第1共役単量体であり、
E2は、第2共役単量体であり、
R、R’、R1〜R4、R1’〜R4’、R11〜R18およびR11’〜R18’は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基であり、
fは、モル分率であって、0< f <1の実数であり、
gは、モル分率であって、0< g <1の実数であり、
f+g=1であり、
nは、単位の繰り返し単位数であって、1〜10,000の整数である。
a、a’、bおよびb’は、それぞれ1〜5の整数であり、
a、a’、bおよびb’がそれぞれ2以上の場合、括弧内の置換基は、互いに同一または異なり、
X11〜X30およびX33〜X40は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NRd、CRdRe、SiRdRe、PRd、またはGeRdReであり、
X31およびX32は、互いに同一または異なり、それぞれ独立に、C、Si、またはGeであり、
R101〜R124、RdおよびReは、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。
X11〜X14、X19、X20、X33〜X40、X11’およびX11’’は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NRd、CRdRe、SiRdRe、PRd、またはGeRdReであり、
R101〜R110、R117〜R124、R101’、R101’’、R102’、R102’’、RdおよびReは、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。
f、g、n、m1、m2、m1’、m2’、q1、q2、q1’、q2’、X1、X2、X1’、X2’、Z1〜Z5、Z1’〜Z5’、E1、E2、R1、R4、R1’、R4’、R11〜R18およびR11’〜R18’は、化学式1−1で定義したものと同じであり、
R51、R51’、R52およびR52’は、互いに同一または異なり、それぞれ独立に、 置換もしくは非置換のアルキル基;または置換もしくは非置換のアリール基である。
fは、モル分率であって、0< f <1の実数であり、
gは、モル分率であって、0< g <1の実数であり、
f+g=1であり、
nは、単位の繰り返し単位数であって、1〜10,000の整数である。
下記化学式2で表される第2化合物;および
下記化学式3で表される第3化合物を反応させるステップを含む共重合体の製造方法を提供する。
m1およびm2は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1およびm2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1およびq2は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1およびq2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
A1、A1’、A2、A2’、A3およびA3’は、互いに同一または異なり、それぞれ独立に、ハロゲン基;置換もしくは非置換のホウ素基;または−SnRaRbRcであり、
E1は、第1共役単量体であり、
E2は、前記第1共役単量体とは異なる第2共役単量体であり、
X1、X2およびZ1〜Z5は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
Ra、Rb、Rc、R、R’、R1〜R4およびR11〜R18は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。
前記第1電極に対向して備えられる第2電極と、
前記第1電極と第2電極との間に備えられ、光活性層を含む1層以上の有機物層とを含み、
前記有機物層のうちの1層以上は、前記共重合体を含むものである有機太陽電池を提供する。
前記製造例2−1における化合物Aおよび化合物Bを下記表のように変更したことを除けば、製造例2−1と同様の方法で製造した。
前記製造例1で製造した共重合体1をドナーとして用い、PCBMをアクセプタとして用いて、1:2の比率でクロロベンゼン(Chlorobenzene、CB)に溶かして複合溶液(composit solution)を製造した。この時、濃度は2.0wt%に調節し、有機太陽電池はITO/ZnO/光活性層/MoO3/Agの構造とした。ITOがコーティングされたガラス基板は、蒸留水、アセトン、2−プロパノールを用いて超音波洗浄し、ITO表面を10分間オゾン処理した後、ZnO前駆体溶液をスピンコーティングして、120℃で10分間熱処理した。その後、複合溶液を0.45μmのPPシリンジフィルタ(syringe filter)で濾過した後、スピンコーティングして光活性層を形成した。その後、熱蒸着器でMoO3を0.4Å/sの速度で5nm〜20nmの厚さに前記光活性層上に蒸着して正孔輸送層を製造した。その後、熱蒸着器の内部でAgを1Å/sの速度で前記正孔輸送層上に10nmに蒸着して有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−3で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−4で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−5で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−6で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−9で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−10で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−14で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
前記実施例1における共重合体1の代わりに、製造例2−19で製造された共重合体を用いたことを除けば、実施例1と同様の方法で有機太陽電池を製造した。
102 第1電極
103 正孔輸送層
104 光活性層
105 第2電極
Claims (15)
- 下記化学式1で表される化合物に由来する繰り返し単位;
第1共役単量体;および
前記第1共役単量体とは異なる第2共役単量体を含む共重合体:
m1およびm2は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1およびm2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1およびq2は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1およびq2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
A1およびA1’は、互いに同一または異なり、それぞれ独立に、ハロゲン基;置換もしくは非置換のホウ素基;または−SnRaRbRcであり、
X1、X2およびZ1〜Z5は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
Ra、Rb、Rc、R、R’、R1〜R4およびR11〜R18は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。 - 前記第1共役単量体および第2共役単量体は、それぞれ独立に、置換もしくは非置換のアルケニレン基、置換もしくは非置換のアリーレン基、および置換もしくは非置換の2価のヘテロ環基のうち1または2以上の基の組み合わせを含むものである、請求項1に記載の共重合体。
- 前記第1共役単量体および第2共役単量体は、それぞれ独立に、下記構造のうちのいずれか1つまたは2つ以上の組み合わせを含むものである、請求項1または2に記載の共重合体:
a、a’、bおよびb’は、それぞれ1〜5の整数であり、
a、a’、bおよびb’がそれぞれ2以上の場合、括弧内の置換基は、互いに同一または異なり、
X11〜X30およびX33〜X40は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NRd、CRdRe、SiRdRe、PRd、またはGeRdReであり、
X31およびX32は、互いに同一または異なり、それぞれ独立に、C、Si、またはGeであり、
R101〜R124、RdおよびReは、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。 - 前記R1〜R4およびR11〜R18は、互いに同一または異なり、それぞれ独立に、水素;ハロゲン基;または置換もしくは非置換のアルコキシ基である、請求項1〜3のいずれか一項に記載の共重合体。
- 前記X1、X2およびZ1〜Z5は、それぞれSである、請求項1〜4のいずれか一項に記載の共重合体。
- 前記共重合体は、下記化学式1−1で表される単位を含むものである、請求項1〜5のいずれか一項に記載の共重合体。
m1、m2、m1’およびm2’は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1、m2、m1’およびm2’がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1、q2、q1’およびq2’は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1、q2、q1’およびq2’がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
X1、X2、X1’、X2’、Z1〜Z5およびZ1’〜Z5’は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
E1は、第1共役単量体であり、
E2は、第2共役単量体であり、
R、R’、R1〜R4、R1’〜R4’、R11〜R18およびR11’〜R18’は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基であり、
fは、モル分率であって、0< f <1の実数であり、
gは、モル分率であって、0< g <1の実数であり、
f+g=1であり、
nは、単位の繰り返し単位数であって、1〜10,000の整数である。 - 下記化学式1で表される第1化合物;
下記化学式2で表される第2化合物;および
下記化学式3で表される第3化合物を反応させるステップを含む共重合体の製造方法:
m1およびm2は、互いに同一または異なり、それぞれ独立に、0〜5の整数であり、
m1およびm2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
q1およびq2は、互いに同一または異なり、それぞれ独立に、1〜5の整数であり、
q1およびq2がそれぞれ2以上の場合、括弧内の構造は、互いに同一または異なり、
A1、A1’、A2、A2’、A3およびA3’は、互いに同一または異なり、それぞれ独立に、ハロゲン基;置換もしくは非置換のホウ素基;または−SnRaRbRcであり、
E1は、第1共役単量体であり、
E2は、前記第1共役単量体とは異なる第2共役単量体であり、
X1、X2およびZ1〜Z5は、互いに同一または異なり、それぞれ独立に、S、O、Se、Te、NR、CRR’、SiRR’、PR、またはGeRR’であり、
Ra、Rb、Rc、R、R’、R1〜R4およびR11〜R18は、互いに同一または異なり、それぞれ独立に、水素;重水素;ハロゲン基;ニトリル基;ニトロ基;ヒドロキシ基;カルボニル基;エステル基;イミド基;アミド基;置換もしくは非置換のアルキル基;置換もしくは非置換のシクロアルキル基;置換もしくは非置換のアルコキシ基;置換もしくは非置換のアリールオキシ基;置換もしくは非置換のアルキルチオキシ基;置換もしくは非置換のアリールチオキシ基;置換もしくは非置換のアルキルスルホキシ基;置換もしくは非置換のアリールスルホキシ基;置換もしくは非置換のアルケニル基;置換もしくは非置換のシリル基;置換もしくは非置換のホウ素基;置換もしくは非置換のアミン基;置換もしくは非置換のアリールホスフィン基;置換もしくは非置換のホスフィンオキシド基;置換もしくは非置換のアリール基;または置換もしくは非置換のヘテロ環基である。 - 前記共重合体の製造方法は、溶媒に第1化合物;第2化合物;および第3化合物を溶解させるステップを含むものである、請求項9に記載の共重合体の製造方法。
- 第1電極と、
前記第1電極に対向して備えられる第2電極と、
前記第1電極と前記第2電極との間に備えられ、光活性層を含む1層以上の有機物層とを含み、
前記有機物層のうちの1層以上は、請求項1〜8のいずれか1項に記載の共重合体を含むものである有機太陽電池。 - 前記有機物層は、正孔輸送層、正孔注入層、または正孔輸送および正孔注入を同時に行う層を含み、
前記正孔輸送層、正孔注入層、または正孔輸送および正孔注入を同時に行う層は、前記共重合体を含む、請求項11に記載の有機太陽電池。 - 前記有機物層は、電子注入層、電子輸送層、または電子注入および電子輸送を同時に行う層を含み、
前記電子注入層、電子輸送層、または電子注入および電子輸送を同時に行う層は、前記共重合体を含む、請求項11に記載の有機太陽電池。 - 前記光活性層は、電子供与体および電子受容体を含み、
前記電子供与体は、前記共重合体を含むものである、請求項11〜13のいずれか一項に記載の有機太陽電池。 - 前記有機太陽電池は、正孔注入層、正孔輸送層、正孔阻止層、電荷発生層、電子阻止層、電子注入層、および電子輸送層からなる群より選択される1または2以上の有機物層をさらに含むものである、請求項11〜14のいずれか一項に記載の有機太陽電池。
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TWI686426B (zh) | 2020-03-01 |
CN110325566B (zh) | 2021-12-07 |
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